• 제목/요약/키워드: corrosive

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The Safety Design of Corrosive Chemical Handling Process based on Reliability Database (신뢰도 데이터베이스 기반 부식성 화학물질 취급공정의 안전설계)

  • Chu, Chang Yeop;Baek, Jong Bae
    • Journal of the Korean Society of Safety
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    • v.33 no.5
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    • pp.141-149
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    • 2018
  • In a PCB factory, there is a corrosive chemical substance supply system that can causes major leakage accidents. These accidents can give rise to shut down the factory and do residents damage that cause enormous loss of properties. To mitigate these risks, it is necessary to provide a chemical disaster prevention system. Moreover, after considering the situation and environment of the production site, it is of great importance to build an optimal chemical accident prevention system by reflecting risk reduction measures from the point of process design and by assessing quantitative risk based on reliability data. However, because there was no established database of the reliability about facilities and equipment that can be used in the domestic, the business site and consulting organization had being used the reliability data such as USA CCPS(Center for Chemical Process Safety). In these days, Korean institutes are studying on reliability data utilization method of quantitative risk assessment for preventing chemical accidents and domestic utilization algorithms and storage bed of reliability data. This study presents samples of reliability database about the chemical substance supply system that constructed from the history data such as failure, maintenance for 10 years at a PCB factory. Also, this work proposes the safety design criteria for supply facilities of corrosive chemical substance by assessing quantitative risk on the basis of the reliability data.

Structural and Corrosive Properties of ZrO2 Thin Films using N2O as a Reactive Gas by RF Reactive Magnetron Sputtering (N2O 반응 가스를 주입한 RF Reactive Magnetron Sputtering에 의한 ZrO2 박막의 구조 및 부식특성 연구)

  • Jee, Seung-Hyun;Lee, Seok-Hee;Baek, Jong-Hyuk;Kim, Jun-Hwan;Yoon, Young-Soo
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.69-73
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    • 2011
  • A $ZrO_2$ thin film as a corrosion protective layer was deposited on Zircaloy-4 (Z-4) clad material using $N_2O$ as a reactive gas by RF reactive magnetron sputtering at room temperature. The Z-4 substrate was located in plasma or out of plasma during the $ZrO_2$ deposition process to investigate mechanical and corrosive properties for the plasma immersion. Tetragonal and monoclinic phases were existed in $ZrO_2$ thin film immersed in plasma. We observed that a grain size of the $ZrO_2$ thin film immersed in plasma state is larger than that of the $ZrO_2$ thin film out of plasma state. In addition, the corrosive property of the $ZrO_2$ thin films in the plasma was characterized using the weight gains of Z-4 after the corrosion test. Compared with the $ZrO_2$ thin film immersed out of plasma, the weight gains of $ZrO_2$ thin film immersed in plasma were larger. These results indicate that the $ZrO_2$ film with the tetragonal phase in the $ZrO_2$ can protect the Z-4 from corrosive phenomena.

Corrosive Injury Due to Edible Vinegar (식이 식초 음독 후 발생한 부식성 손상)

  • Kim, Do-Hyoun;Lee, Sung-Woo;NamGung, In;Park, Jong-Hak;Kim, Su-Jin;Hong, Yun-Sik
    • Journal of The Korean Society of Clinical Toxicology
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    • v.9 no.1
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    • pp.34-38
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    • 2011
  • Vinegar is a very popular ingredient used in many cuisines. It is also known for its beneficial health, beauty and possible weight-loss properties. The authors report on a patient who presented to the emergency department with unstable vital signs complaining of generalized abdominal pain after ingestion of 450 ml of apple cider vinegar. We documented a case of corrosive gastrointestinal injury with persistent metabolic acidosis occurring after ingesting apple cider vinegar with an acetic acid concentration of 12~14%. Toxic damage to the liver and kidney were also observed, peaking on post-ingestion day 3. The patient received supportive care and hemoperfusion for three days without much clinical improvement and died in the seventh day of intensive care due to disseminated intravascular coagulation and multi organ failure. Edible vinegar, when taken in large amounts, is capable of inducing corrosive injuries of the GI tract as well as severe systemic toxicities, such as metabolic acidosis. Safety precautions regarding vinegar deserve more public attention and clinicians also should be astute enough to recognize the potential damage accompanying vinegar ingestion.

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A Study on the Aging Behavior of Ship Organic Coating by the Flow Induced Shear Stress (유동 전단응력에 의한 선박 유기도막의 열화거동 연구)

  • Park Hyun;Park Jin-Hwan;Ha Hyo-Min;Chun H.H.;Lee In-Won
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.12 no.1 s.24
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    • pp.9-14
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    • 2006
  • Analysis has been made of the anti-corrosive property of organic coating under the shear stress of the flow by means of AC impedance method. Marine anti-corrosive painted panels were placed in the water channel with varying flow rate, thereby experiencing varying flow shear stress on the surfaces. The velocities of the salt water were ranged from 1.48 to 5.2 m/s and the coating thickness of from $70{\mu}m\;to\;140{\mu}m$. For all coating thicknesses investigated, the poorer anti-corrosive property and the lower adhesion strength have been found for the higher shear stress. It has been found that the shear stress accelerates the aging of organic marine coatings.

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Jejunal Free Graft for Complicated Corrosive Esophageal Stricture (유리공장이식편을 이용한 합병된 부식성 식도협착의 재건술)

  • I Hoseok;Lee Sungsoo;Shim Young Mog
    • Journal of Chest Surgery
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    • v.38 no.6 s.251
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    • pp.445-449
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    • 2005
  • The management of failure of colonic graft or corrosive stricture with impaired colonic circulation continues to be a challenge to surgeons. We present four cases of complicated corrosive esophageal stricture, which were successfully treated using jejunal free graft. As the initial surgical treatment, three patients underwent colonic interposition, and one underwent Whipple's procedure due to panperitonitis. Ore patient underwent transposition of jejunal free patch graft, two underwent interposition of jejunal free graft, and one underwent esophagojejunocolojejunostomy using jejunal free graft. All patients did not show dysphagia after long term follow-up. Complex esophageal reconstruction with jejunal free graft was performed successfully and long term functional outcome was good.

A Study on the Proper Installation of Storage Tank Measuring Instruments through a Case Study of Corrosive Fluid Leak Accident (부식성 유체 누출 사고사례 연구를 통한 저장탱크 레벨게이지 적정설치에 관한 연구 )

  • Sang Ryung Kim;Gyu Sun Cho;Won Baek Yang
    • Journal of the Korean Institute of Gas
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    • v.27 no.2
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    • pp.32-38
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    • 2023
  • In a chemical plant, while supplying corrosive fluid to a storage tank with a pump, an accident occurred where the corrosive fluid leaked through the upper exhaust vent because the level indicator was not accurately determined. There are various causes of leakage accidents, but we focused on the sticking of the level indicator of the level gauge, which is the direct cause. As a result of the analysis, the level indicator used in the workplace where the accident occurred was randomly replaced, and in the summer when the accident occurred, the tubular type level gauge was found to be more likely to stick than other types because thermal expansion easily occurs. In addition, there were difficulties in reviewing the proper installation because the installation standards for measuring instruments installed in storage tanks were not clear in Korea. Therefore, in this study, based on accident cases and overseas standards, we are going to find out about precautions when installing storage tank instrumentation.

A Study on Corrosive Characteristics of Inconel 625 for Petroleum Application by FCAW Process (석유시추용 인코넬 625강의 FCAW용접에 의한 부식성에 관한 연구)

  • PARK KEYUNG-DONG;AN DO-KEYUNG;AN JAE-PIL
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.365-369
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    • 2004
  • Recently, Inconel 625 is used widely in offshore processing piping in order to extend the maintenance tenn and improve the quality of anti-corrosion. According to the resistance to attack in various corrosive media at temperatures from $200^{\circ}C$ to aver $1090^{\circ}C$, in combination with good low- and high-temperature mechanical strength. In general, High quality weldments for this material are readily produced by commonly used processes. in recent years, the flux cored arc welding(FCAW) process is becoming more popular due to higher deposition rate and a better weld quality as compared to the shielded metal arc welding (SMAW) process, at the same time, exhibiting equally good weld metal toughness similar to the SAW process. In this study, the weldability and weldment characteristics(mechanical properties and corrosive environment) of Inconel 625 are considered in FCAW weld associated with the several weld shielding gases($80\%Ar\;+\;20\%\;CO_2,\;50\%Ar\;+\;50\%\;CO_2,\;100\%\;CO_2$) in viewpoint of welding productivity.

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Development of silicone mold applying corrosive pattern of tactile system (촉감시스템의 부식패턴을 적용한 실리콘 금형 개발)

  • Kim, Kwang-Hee;Kim, Jeong-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.9
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    • pp.3895-3899
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    • 2012
  • In this study, the start-type molded material, silicone resin(RTV-3040) was used to develop a mold that is utilized for embossing pattern. After selecting a required pattern using the commercial package (Freeform), we examined whether this is applicable to components creating projective embossed side on the surface. We responded to products that require corrosive pattern, such as aluminum mold, by making the starting type when small amounts of components are developing. However, the development of silicone mold that is applied to corrosive pattern showed the possible reduction in time and cost.

Vibration Analysis for Failure Diagnosis of Cylinder Liner of Large Ship Engine (선박엔진의 실린더 라이너의 손상 진단을 위한 진동 분석법)

  • Koo, Hyunho;Cho, Yonsang;Park, Junhong;Park, Heungsik
    • Tribology and Lubricants
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    • v.30 no.1
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    • pp.21-28
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    • 2014
  • Damage to the cylinder liner of large ship engines, such as scuffing on the surface, can occur very easily because it is operated in a corrosive environment. This scuffing may be due to oil film destruction and corrosive wear caused by water and sulfur included in the fuel, abrasive impurities, and poor lubricants. Thus, a method for monitoring the condition and diagnosing the failure of the cylinder liner and piston ring is needed. In this study, a reciprocating friction and wear test was carried out with a cast iron specimen, which simulated an engine cylinder in a corrosive atmosphere. The lubricants used were base oil, stirred oil with distilled water, a NaCl solution, and dilute sulfuric acid. The friction coefficient and frequency spectrum were measured using a load cell and acceleration sense in each experimental condition. We then used these results to diagnose the failure of the cylinder liner.

Development of anti-corrosive coating technique for alloy plated steel sheet using silane based organic-inorganic hybrid materials (Silane계 유무기 하이브리드 적용 합금도금강판 내식성 향상 코팅 기술 개발)

  • Park, Jongwon;Lee, Kyunghwang;Park, Byungkyu;Hong, Shinhyub
    • Corrosion Science and Technology
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    • v.12 no.6
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    • pp.295-303
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    • 2013
  • Silane surface treatments have been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. The silane performance is comparable to, or in some cases better than, that of chromate layers. Based on the tetra-ethylorthosilicate(TEOS) and methlyl trieethoxysilane(MTES), inorganic sol was synthesized and formed hybrid networks with $SiO_2$ nano particle and polypropylene glycol(PPG) on Zn alloyed steel surface. According to SST results, addition of 10nm and 50nm $SiO_2$ nanoparticle in synthesized solution improved anti-corrosion property by its shear stress relaxation effect during curing process. Also, SST results were shown that anti-corrosive property was affected by the amounts of organic compounds.