• Corrosion Science and Technology
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• v.20 no.2
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• pp.85-93
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• 2021

The corrosion damage of materials in marine environment mainly occurs by Cl^- ions due to the breakdown of passive films. Additionally, various characteristics in seawater such as salinity, temperature, immersion time, flow rate, and biological activity also affect corrosion characteristics. In this study, the corrosion characteristics of stainless steels (STS 304 and STS 316L) and anodized aluminum alloys (AA 3003 and AA 6063) were evaluated with seawater temperature parameters. A potentiodynamic polarization experiment was conducted in a potential range of -0.25 V to 2.0 V at open circuit potential (OCP). Corrosion current density and corrosion potential were obtained through the Tafel extrapolation method to analyze changes in corrosion rate due to temperature. Corrosion behavior was evaluated by measuring weight loss before/after the experiment and also observing surface morphology through a scanning electronic microscope (SEM) and 3D microscopy. Weight loss, maximum damage depth and pitting damage increased as seawater temperature increased, and furthermore, the tendency of higher corrosion current density with an increase of temperature attributed to an increase in corrosion rate. There was lower pitting damage and lower corrosion current density for anodized aluminum alloys than for stainless steels as the temperature increased.

• Corrosion Science and Technology
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• v.4 no.5
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• pp.171-177
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• 2005

A comprehensive framework for numerical simulation of time-dependent performance change of reinforced concrete (RC) structures subjected to chloride attack is presented in this paper. The system is composed of simplified computational models for transport of moisture and chloride ions in concrete pore structure and crack, corrosion of reinforcement in concrete and mechanical behavior of RC member with reinforcement corrosion. Service-life of RC structures under various conditions is calculated.

• Corrosion Science and Technology
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• v.7 no.2
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• pp.130-133
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• 2008

Corrosion of silver by outgassed sulfur species from rubber has been investigated by means of quartz crystal microbalance technique (QCM) and cathodic reduction technique. Silver specimens were placed together with a rubber of predefined quantity in an enclosed environment. Corrosion progressed linearly with time and silver sulfide was found as the corrosion product during all the tests. No significant dependence on RH was observed, while the corrosion rate increased as temperature rose. Furthermore the corrosion rate increased logarithmically with the quantity of the rubber placed in the exposure environment. It may be suggested that the corrosion rate of silver is determined by the amount of outgassed sulfur species which is a function of temperature and the quantity of rubber contained in the exposure environment.

• Corrosion Science and Technology
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• v.7 no.2
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• pp.125-129
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• 2008

Results of corrosion testing for different grades of titanium, copper, zinc, alluminium alloys and steels after two years of outdoor exposure under humid tropical urban and marine conditions have been presented and discussed. Mass loss and corrosion product characteristics for the exposed specimens at Hanoi testing site with high humidity and Nhatrang marine stations (at 100 and 1,000 meters distances from sea) with different airborne salinities (35.9 and $90.0mg/m^2.d$ respectively) have been selected for investigation. From time dependence of the specimen mass loss and corrosion product characteristics, the strong influence of environmental parameters upon durability for the investigated metals and alloys has been demonstrated. Only titanium alloys show high resistance to the marine conditions. All the other specimens (copper, zinc, alluminium alloys and steels) have been underwent strong deterioration under influence of aerosol salinity. Results of corrosion products analysis have been also presented for characterization of environmental impact on the metal degradation processes.

• Corrosion Science and Technology
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• v.11 no.5
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• pp.157-164
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• 2012

In first experiment series, this paper is devoted for examining progress of reinforcement corrosion due to carbonation in concrete and to quantify uncarbonation depth to protect reinforcement from corroding. The tolerance of cover depth should be considered in order to prevent carbonation-induced corrosion. From the relationship between the weight loss of reinforcement and corrosion current density for a given time, therefore, the tolerance of cover depth to prevent carbonation-induced corrosion is computed. It is observed that corrosion occurs when the distance between carbonation front and reinforcement surface (uncarbonated depth) is smaller than 5 mm.As a secondary purpose of this study, it is investigated to examine the interaction between carbonation and chloride penetration and their effects on concrete. This was examined experimentally under various boundary conditions. For concrete under the double condition, the risk of deterioration due to carbonation was not severe. However, it was found that the carbonation of concrete could significantly accelerate chloride penetration. As a result, chloride penetration in combination with carbonation is a serious cause of deterioration of concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.657-662
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• 2003

In this study. a micro-corrosion model of steel in RC structure is established for micro-structure development in view to micro-mechanics and the model is composed of chloride penetration model and oxygen diffusion model to evaluate for corrosion rate and accumulated corrosion amounts. Also the model is composed of corrosion-cracking model for prediction of corrosion-cracking. The time and space dependent induced corrosion-cracking of RC structures including changes of corrosion rates and concentrations of chloride ion are simulated using the finite element analysis adopted the proposed model Then, results of the analysis are compared with test results for verification.

• Structural Engineering and Mechanics
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• v.54 no.6
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• pp.1111-1133
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• 2015

Rebar corrosion in concrete is one of the main causes of reduction of service life of reinforced concrete buildings. This paper presents the influence of rebar corrosion on the structural behavior of reinforced concrete (RC) buildings subjected to strong earthquake ground motion. Different levels of rebar corrosion scenarios were applied on a typical four story RC frame. The deteriorated conditions as a result of these scenarios include loss in cross-sectional area and loss of mechanical properties of the reinforcement bars, loss in bond strength, and loss in concrete strength and its modulus of elasticity. Dynamic analyses of the frame with different corrosion scenarios are performed with selected strong earthquake ground motion records. The influences of degradation in both concrete and reinforcement on structural behavior are investigated by comparing the various parameters of the frame under different corrosion scenarios with respect to each other. The results show that the progressive deterioration of the frame due to rebar corrosion causes serious structural behavior changes such as change in failure mode. The intensity, propagation time, and extensity of rebar corrosion have very important effects on the level of degradation of steel and concrete, as well as on the earthquake behavior of the structure.

• Journal of Ocean Engineering and Technology
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• v.11 no.3
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• pp.48-55
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• 1997

The steel for automotive exhaust system needs a good corrosion resistance at the atmosphere of high temperature NaCl. Effect of the alloying elements Me, Ti, Nb on the NaCl induced hot corrosion behavior was investigated at the temperatures between 55$0^{\circ}C$ and 75$0^{\circ}C$ for 18Cr ferritic stainless steels. The weight loss by corrosion has increased linearly with corrosion cycle time, and the corrosion rate has accelerated at higher temperature. The alloying of Mo significantly improved corrosion resistance of the steel and the effect was more pronounced at higher temperature. The addition of alloying elements Ti, Nb have also shown improved corrosion resistance by formation of Ti(C,N) or Nb(C, N) precipitates.

• Journal of the Korean Society for Nondestructive Testing
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• v.33 no.5
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• pp.409-414
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• 2013

In this work, corrosion of 304 stainless steel was evaluated by using acoustic emission(AE) technique. AE measurement system was set for detecting acoustic signal during accelerated corrosion test of the specimen. AE signal started to be detected after the time of pitting corrosion initiation was evaluated by anodic polarization curve. Pitting corrosion damage was confirmed by optical microscopic observation of the surface morphology. AE cumulative counts and amplitude according to corrosion time could be divided into three stages. These trends were discussed in relation with changing pitting corrosion mechanism. Feasibilities of AE technique for evaluation of corrosion damage and mechanism were suggested.

• Corrosion Science and Technology
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• v.2 no.2
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• pp.88-92
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• 2003

The technique for in situ simultaneous measurements of IR-RAS and QCM, which has been developed for investigation of corrosion in gaseous environments, was employed to study the effects of an extremely thin water layer on the corrosion rate. An evaporated copper film on a QCM element was exposed to air containing water vapor and $SO_2$, and time-resolved IR-RAS spectra were measured and mass gains were simultaneously followed with QCM. The tested ranges of relative humidity (RH) and concentration of $SO_2$ were 60% - 90% and 1 - 20 ppm, respectively. On the basis of 2D-IR analysis, the corrosion products were determined to be Chevreul's salt ($CuSO_3Cu_2SO_3{\cdot}2H_2O$) and $CuSO_4{\cdot}5H_2O$. By constructing curves of the relations between band intensities of IR spectra and mass gains of QCM for the corrosion products, the time variations in each product were determined from spectral experiments on copper plates. The thicknesses of physically adsorbed water layers in course of the corrosion process were also determined from water band intensities. The results showed that the thickness of the physically adsorbed water layer increased with increase in RH, and it also increased with increase in accumulation of corrosion products. The latter is probably due to the capillary effect of the corrosion products.