• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.617-620
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• 2008

When the RC structure repaired by patching repair method, which method refilles with patching repair material after removes degraded area, It is necessary to determine chloride ion's permeation from outside of the RC structure repaired by patching repair material. Therefore, in this study, damage from sea environment of structure was predicted, moreover, diffusion coefficient of concrete also determined to figure out rebar's corrosion and concentration of chloride ion. RCPT(Rapid Chloride Permeability Test) was used for ditermination of patching repair material's diffusion coefficient, also connection between material thickness and effect of chloride ion's permeation was examined in analytically. Results which derived by experimental test was used in FEM(Finite Element Method) and equation suggested by JSCE to predict concentration of chloride ion in different distance from surface.

• Korean Journal of Materials Research
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• v.18 no.3
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• pp.153-158
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• 2008

Fe-aluminides have the potential to replace many types of stainless steels that are currently used in structural applications. Once commercialized, it is expected that they will be twice as strong as stainless steels with higher corrosion resistance at high temperatures, while their average production cost will be approximately 10% of that of stainless steels. Self-propagating, high-temperature Synthesis (SHS) has been used to produce intermetallic and ceramic compounds from reactions between elemental constituents. The driving force for the SHS is the high thermodynamic stability during the formation of the intermetallic compound. Therefore, the advantages of the SHS method include a higher purity of the products, low energy requirements and the relative simplicity of the process. In this work, a Fe-aluminide intermetallic compound was formed from high-purity elemental Fe and Al foils via a SHS reaction in a hot press. The formation of iron aluminides at the interface between the Fe and Al foil was observed to be controlled by the temperature, pressure and heating rate. Particularly, the heating rate plays the most important role in the formation of the intermetallic compound during the SHS reaction. According to a DSC analysis, a SHS reaction appeared at two different temperatures below and above the metaling point of Al. It was also observed that the SHS reaction temperatures increased as the heating rate increased. A fully dense, well-bonded intermetallic composite sheet with a thickness of $700\;{\mu}m$ was formed by a heat treatment at $665^{\circ}C$ for 15 hours after a SHS reaction of alternatively layered 10 Fe and 9 Al foils. The phases and microstructures of the intermetallic composite sheets were confirmed by EPMA and XRD analyses.

• The Journal of Engineering Geology
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• v.25 no.4
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• pp.511-524
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• 2015

Groundwater causing subsidence in limestone mines is uncommon, and thus relatively poorly investigated. This case study investigated the cause and possibility of future subsidence through an evaluation of ground stability at the Samsung limestone mine, Chungcheongbuk-do. The ground near the mine area was evaluated as unstable due to rainfall permeation, and subsidence in the unmined area resulted from groundwater level drawdown. Future subsidence might occur through the diffusion of subsidence resulting from the small thickness of the mined rock roof, fracture rock joints, and poor ground conditions around the mine. In addition, the risk of additional subsidence by limestone sinkage in corrosion cavities, groundwater level drawdown due to artificial pumping, and rainfall permeation in the limestone zone necessitates reinforcements and other preventative measures.

• Nuclear Engineering and Technology
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• v.50 no.3
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• pp.416-424
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• 2018

Microstructure of oxide formed on Zr-Nb-Sn tube sample was intensively examined by scanning transmission electron microscopy after exposure to simulated primary water chemistry conditions of various concentrations of Zn (0 or 30 ppb) and dissolved hydrogen ($H_2$) (30 or 50 cc/kg) for various durations without applying desirable heat flux. Microstructural analysis indicated that there was no noticeable change in the microstructure of the oxide corresponding to water chemistry changes within the test duration of 100 days (pretransition stage) and no significant difference in the overall thickness of the oxide layer. Equiaxed grains with nano-size pores along the grain boundaries and microcracks were dominant near the water/oxide interface, regardless of water chemistry conditions. As the metal/oxide interface was approached, the number of pores tended to decrease. However, there was no significant effect of $H_2$ concentration between 30 cc/kg and 50 cc/kg on the corrosion of the oxide after free immersion in water at $360^{\circ}C$. The adsorption of Zn on the cladding surface was observed by X-ray photoelectron spectroscopy and detected as ZnO on the outer oxide surface. From the perspective of $OH^-$ ion diffusion and porosity formation, the absence of noticeable effects was discussed further.

• Korean Journal of Materials Research
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• v.21 no.11
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• pp.596-603
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• 2011

The very high temperature gas reactor (VHTR) is one of the next generation nuclear reactors for its safety, long-term stability, and proliferation-resistance. The high operating temperature of over 800$^{\circ}C$ enables various applications with high energy efficiency. Heat is transferred from the primary helium loop to the secondary helium loop through the intermediate heat exchanger (IHX). The IHX material requires creep resistance, oxidation resistance, and corrosion resistance in a helium environment at high operating temperatures. A Ni-based superalloy such as Alloy 617 is considered as a primary candidate material for the intermediate heat exchanger. In this study, the microstructures of Alloy 617 crept in pure helium and air environments at 950$^{\circ}C$ were observed. The rupture time in helium was shorter than that in air under small applied stresses. As the exposure time increased, the thickness of outer oxide layer of the specimens clearly increased but delaminated after a long creep time. The depth of the carbide-depleted zone was rather high in the specimens under high applied stress. The reason was elucidated by the comparison between the ruptured region and grip region of the samples. It is considered that decarburization caused by minor gas impurities in a helium environment caused the reduction in creep rupture time.

• Korean Journal of Metals and Materials
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• v.48 no.10
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• pp.901-906
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• 2010

The first stage blade of a gas turbine was operated under a severe environment which included both $1300^{\circ}C$ hot gas and thermal stress. To obtain high efficiency, a thermal barrier coating (TBC) and an internal cooling system were used to increase the firing temperature. The TBC consists of multi-layer coatings of a ceramic outer layer (top coating) and a metallic inner layer (bond coat) between the ceramic and the substrate. The top and bond coating layer respectively act as a thermal barrier against hot gas and a buffer against the thermal stress caused by the difference in the thermal expansion coefficient between the ceramic and the substrate. Particularly, the bondcoating layer improves the resistance against oxidation and corrosion. An inter-diffusion layer is generated between the bond coat and the substrate due to the exposure at a high temperature and the diffusion phenomenon. A thickness measurement result showed that the bond coat of the suction side was thicker than that of the pressure side. The thickest inter-diffusion zone was noted at SS1 (Suction Side point 1). A chemical composition analysis of the bond coat showed aluminum depletion around the inter-diffusion layer. In this study, we evaluated the properties of the bond coat and the degradation of the coating layer used on a $1300^{\circ}C$-class gas turbine blade. Moreover, the operation temperature of the blade was estimated using the Arrhenius equation and this was compared with the result of a thermal analysis.

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.1
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• pp.122-129
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• 2019

Due to its nature the manufacturing industry faces a cyclical economy, and therefore there is an urgent need for a companion industry to cope with this cyclic pattern in the long run. The sector suitable for meeting this demand is the repair and shipbuilding industry. In order to operate a shipbuilding repair business, a floating dock is indispensable, and most obsolete floating docks were imported from overseas and operated through repair/maintenance. However, there is no precise guideline for floating dock safety, and most models have been in use for at least 30 years without being required to enter classification at the time of operation. In this study, structural strength analysis was carried out using measured thickness information of aged floating docks, and the residual structural strength of floating docks in operation was analyzed. The main results derived from this study can be referred to as guidelines for the review of the structural safety of similar equipment, and it is expected that an optimal solution will be found within a short time using this method for repair/maintenance.

• Nuclear Engineering and Technology
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• v.51 no.2
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• pp.518-525
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• 2019

The mechanical and corrosion behavior of the Russian zirconium fuel cladding alloy E110, predominantly used in VVERs, has been investigated for many decades. The recent commercialization of a new, optimized E110 alloy, produced on a sponge zirconium basis, gave the opportunity to compare the mechanical properties of the old and the new E110 fuel claddings. Axial and tangential tensile test experiments were performed with samples from both claddings in the MTA EK. Due to the anisotropy of the cladding tubes, the axial tensile strength was 10-15% higher than the tangential (measured by ring tensile tests). The tensile strength of the new E110G alloy was 11% higher than that of the E110 cladding at room temperature. Some samples underwent chemical treatment - slight oxidation in steam or hydrogenation - or heat treatment - in argon atmosphere at temperatures between 600 and $1000^{\circ}C$. The heat treatment during the oxidation had more significant effect on the tensile strength of the claddings than the oxidation itself, which lowered the tensile strength as the thickness of the metal decreased. The hydrogenation of the cladding samples slightly lowered the tensile strength and the samples but they remained ductile even at room temperature.

• Korean Journal of Metals and Materials
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• v.50 no.4
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• pp.324-330
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• 2012

The microstructural changes of three pieces from an ancient iron pot were studied in order to identify present the material degradation due to repeated heating for one-thousand years. The microstructures of the pieces were divided into the areas of ferrite/graphite, ferrite/pearlite, and corroded oxidation. The area of ferrite/graphite was undergone by severe Galvanic corrosion, but that of ferrite/pearlite was not even during a thousand years' using. The shape of the graphites was coexisted with types of A, B, and C of as modern graphite classification. In the ferrite/pearlite area, abnormal acicula precipitates with a high aspect ratio of $0.2{\mu}m$ thickness and several hundreds ${\mu}m$ length were presented. They might be a kind of carbide in the ferrite matrix with its special precipitate plane.

• Steel and Composite Structures
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• v.42 no.1
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• pp.91-106
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• 2022

Concrete-filled square stainless steel tubes (CFSSST), which possess relatively large flexural stiffness, high corrosion resistance and require simple joint configurations and low maintenance cost, have a great potential in constructional applications. Despite that the use of stainless steel may result in high initial cost compared to their conventional carbon steel counterparts, the whole-life cost of CFSSST is however considered to be lower, which offers a competitive choice in engineering practice. In this paper, a comprehensive experimental and numerical program on 24 CFSSST stub column specimens, including 3 austenitic and 3 duplex stainless steel square hollow section (SHS) stub columns and 9 austenitic and 9 duplex CFSSST stub columns, has been carried out. Finite element (FE) models were developed to be used in parametric analysis to investigate the influence of the tube thickness and concrete strength on the ultimate capacities more accurately. Comparisons of the experimental and numerical results with the predictions made by design guides ACI 318, ANSI/AISC 360, Eurocode 4 and GB 50936 have been performed. It was found that these design methods generally give conservative predictions to the ultimate capacities of CFSSST stub columns. Improved calculation methods, developed based on the Continuous Strength Method, have been proposed to provide more accurate estimations of the ultimate resistances of CFSSST stub columns. The suitability of these proposals has been validated by comparison with the test results, where a good agreement between the predictions and the test results have been achieved.