• 한국표면공학회지
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• 제41권3호
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• pp.109-113
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• 2008

High strength 7xxx series Al-Zn-Mg alloy have been investigated for using light weight automotive parts especially for bump back beam. The composition of commercial 7xxx aluminum has the Zn/Mg ratio about 3 and Cu over 2 wt%, but this composition isn't adequate for appling to automotive bump back beam due to its high resistance to extrusion and bad weldability. In this study the Zn/Mg ratio was increased for better extrusion and Cu content was reduced for better welding. With this new composition we investigated the effect of composition on the resistivity against stress corrosion cracking. As the Zn/Mg ratio is increased fracture energy obtained by slow strain rate test was decreased, which means degradation of SCC resistance. While the fracture energy was increased with Cu contents although it is below 1%, which means improvement of SCC resistance. These effects of composition change on the SCC resistivity were identified by observing the fracture surface and crack propagation.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.177-180
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• 2006

Reinforced concrete has been widely used as a semi-permanent construction materials. However, sea sand, deicing salt, and marine condition might induce the corrosion of embedded reinforcement due to the penetration of chlorides in concrete structures. This reinforcement corrosion causes serious problems on safety and serviceability of structures during lifetime. Also, reinforcement corrosion may cause the collapse of structures in worst case, so that the corrosion problem is more and more intensely growing. The purpose of this paper is to provide the fundamental data for the mechanical effect of corrosion through evaluation on bond characteristics of reinforced concrete using corroded bars.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2011년도 추계 학술논문 발표대회
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• pp.253-254
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• 2011

The purpose of this study is to investigate chloride ion adsoption property of cement mortar using nitrite type hydrocalumite(calumite) with self-corrosion inhibition function. Superior corrosion inhibition function of the VA/E/MMA-modified mortars with calumite was ascertained from accelerated corrosion test in the previous study. In this study, VA/E/MMA-modified mortars with calumite were prepared with calumite contents of 0, 5, 10% and polymer-binder ratio of 0, 10%, and tested for chloride ion adsorption to make it clear how calumite gives self-corrosion inhibition function to cement mortar. As a result, chloride ion adsorption property of VA/E/MMA-modified mortars with calumite was improved by increasing calumite contents compared to unmodified mortar regardless of using VA/E/MMA terpolymer powder or not.

• Advances in concrete construction
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• 제9권2호
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• pp.149-159
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• 2020

The present work proposes new engineering models for determining corrosion initiation time in concrete reinforcing steels in marine environment. The models are based on Fick's second law that is commonly used for chloride diffusion. The latter is based on deterministic analyses involving the most influencing parameters such as distance of the concrete structure from the seaside, depth of steel concrete cover, ambient temperature, relative humidity and the water-cement ratio. However, a realistic corrosion initiation time cannot be estimated because of the uncertainties associated to the different parameters of the models. Therefore a reliability approach using FORM/SORM method has been applied to develop the proposed engineering models integrating a limit state function and a reliability index β. As a result, the corrosion initiation time is expressed by new exponential engineering models where the uncertainties are associated to the model parameters. The main emerging result is a realistic decision tool for corrosion planning inspection.

• 한국정밀공학회지
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• 제6권1호
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• pp.75-84
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• 1989

This paper deals with the effect of $N_2$ and $H_2$gas mixture ratio and ion-nitriding time in the corrosion fatigue fracture behavior of ion-nitrided SCM4 steel with notch subject to rotary bending stress. The specimens were treated rapid water cooling after ion-nitriding at $500^{\circ}C$ Torr for 1 hour and 3 hours in gas mixtures of 80% $N_2$and 50% $N_2$. The fatigue limit and the fracture strength of corrosion fatigue depended on $N_2$gas quantity and ion-nitriding time. The ion-nitrided specimens showed about 88 .approx. 158% increase in the fracture strength of corrosion fatigue in $10^6$ cycles than non-nitrided specimens. The corrosion failure is due to corrosion pitting of the surface, and the propargation of cracks started at the surface into the core.

• Corrosion Science and Technology
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• 제5권1호
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• pp.15-22
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• 2006

The introduction of two-grid inside a conventional process system produces a reactive coating deposition and increases metal ion ratio in the plasma, resulting in denser and smoother films. The corrosion behaviors of TiN coatings were investigated by electrochemical methods, such as potentiodynamic polarization test and electrochemical impedance spectroscopy (EIS) in deaerated 3.5% NaCl solution. Electrochemical tests were used to evaluate the effect of microstructure on the corrosion behavior of TiN coatings exposed to a corrosive environment. The crystal structure of the coatings was examined by X-ray diffractometry (XRD) and the microstructure of the coatings was investigated by scanning electron microscopy (SEM) and transmission electron spectroscopy (TEM). In the potentiodynamic polarization test and EIS measurement, the corrosion current density of TiN deposited by two grid-attached magnetron sputtering was lower than TiN deposited by conventional magnetron type and also presented higher Rct values during 240 h immersion time. It is attributed to the formation of a dense microstructure, which promotes the compactness of coatings and yields lower porosity.

• Corrosion Science and Technology
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• 제9권1호
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• pp.29-33
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• 2010

Laser machining technique, which is used focusing pulse YAG laser beam irradiation was applied to form area ratio controlled model cut-edge on pre painted Zn coated steels. A corrosion behavior of formed model cut-edge was investigated by rest potential measurement in 1 mol $m^{-3}$ NaCl with and without 0.5 kmol $m^{-3}$ $H_3BO_4$/0.05kmol$m^{-3}$ $Na_2B_4O_7$. The rest potential showed almost constant value with fluctuations. The amplitude of fluctuations increased with exposed area of steel surface. White corrosion products of zinc oxide and simonkollite was formed after the experiments at the formed model cut-edge.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.801-804
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• 2004

It should be noted that the critical chloride threshold level is not considered to be a unique value for all conditions. This value is dependent on concrete mixture proportions, cement type and constituents, presence of admixtures, environmental factors, steel reinforcement surface conditions, and other factors. In this study, the accelerated corrosion test for reinforcing steel was conducted by electrochemical and sea water-circulated method, respectively and during the test, corrosion monitoring by half cell potential method was carried out to estimate the critical chloride threshold value when corrosion for reinforcing steel in concrete was perceived. For this purpose, lollypop and beam test specimens were made for $31.4\%,\;41.5\%\;and\;49.7\%$ of w/c. respectively and then the accelerated corrosion test for reinforcing steel was executed. It was observed from the test that the time to initiation of corrosion was found to be different with water-cement ratio and the critical chloride threshold value was found to range from 0.91 to $1.27kg/m^3$.

• Journal of Electrochemical Science and Technology
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• 제9권1호
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• pp.1-8
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• 2018

The effect of mixing ratio on the corrosion protection of carbon steel coated by a film composed of poly(vinylidene) fluoride (PVDF) and poly(methyl methacrylate) (PMMA) was examined using electrochemical impedance spectroscopy. Surface crystallization behavior and thermal properties of the PVDF/PMMA coated carbon steel were evaluated using polarized optical microscopy and differential scanning calorimetry, respectively. A Maltese cross-pattern spherulite crystal was observed in the PVDF/PMMA coating film, which became more apparent with increasing PVDF content. The highest corrosion protection performance was achieved with 60 wt.% PVDF-coated carbon steel, and delamination and corrosion reactions were observed for 20 wt.% PVDF-coated carbon steel. Further, corrosion protection performance with an amorphous/crystal mixture (PVDF/PMMA, 60/40 (w/w)) was better than those observed in the amorphous domain and the perfect-crystal domain of the PVDF/PMMA blended coating system.

• Advances in materials Research
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• 제7권2호
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• pp.105-118
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• 2018

Magnesium and its alloys are attracted towards all engineering applications like automotive, marine, aerospace etc. due to its inherent high strength to weight ratio. But, extensive use of Mg alloys is limited to the current scenario because of low wear and corrosion resistance behavior. However, equal channel angular press is one of the severe plastic deformation technique which has been effective method to improve the wear and corrosion resistance by achieving fine grain structure. In this study, the effect of grain refinement on wear and corrosion resistance of AZ80 Mg alloys were investigated. The wear behavior of the coarse and fine-grained Mg alloys was examined through $L_9$ orthogonal array experiments in order to comprehend the wear behavior under varies control parameters. It was shown that ECAPed alloy increased the wear and corrosion resistance of the Mg alloy through the formation of fine grain and uniform distribution of secondary ${\beta}-phase$. Also, the performance of AZ80 Mg alloy for these changeswas discussed through SEM morphology.