• Title/Summary/Keyword: corrosion effects

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A Study on Damage Effects Assessment for Asphyxiation Accident due to Malfunction of Gas Type Fire Extinguishing System (가스계 소화설비 오작동으로 인한 질식사고의 피해영향 평가)

  • Kim, Eui-Soo
    • Journal of the Korean Institute of Gas
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    • v.24 no.2
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    • pp.36-43
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    • 2020
  • Gas system fire extinguishing equipment is a very economically useful facility, but if it is not used for a long period of time after installing the equipment, there is possibility of rupture due to corrosion of containers and operation errors of equipment systems, and this is very dangerous. However, it is impossible to experiment to check whether the equipment is operating normally. If gas is temporarily released into the enclosed space due to rupture and malfunction, it can cause serious human damage due to gas suffocation. In this study, based on the suffocation death accident of gas system fire extinguishing facility, the inflow path of released gas and the possibility of death and time to death were estimated using a 3D scan and FLACS.

Analysis of Chloride ion Penetration of Marine Concrete Structure (해양 콘크리트 구조물의 염소이온 침투해석)

  • 한상훈;박우선;김동현
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.15 no.2
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    • pp.71-79
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    • 2003
  • The estimation functions were proposed for calculating diffusion coefficient, chloride binding, and evaporable water. The program estimating chloride ion penetration was developed on the basis of these functions and the effects of humidity, curing temperature, water-cement ratio, and $C_3$A on chloride penetration were analyzed. The relative humidity increases the depth of chloride ion penetration and the trend becomes greater with aging. On the contrary, the influence of curing temperature on chloride ion penetration decreases with aging. By the way, the rise of $C_3$A in cement increases total chloride concentration on the surface as the bound chloride concentration increases but it decreases total chloride concentration on the inner part as the diffusion velocity of free chloride decreases. The fall of water-cement ratio decreases the chloride penetration depth rapidly. Therefore, the reduction of water-cement ratio may be the most effective method for reducing of the steel corrosion by chloride penetration.

Restrained Shrinkage Properties of Polypropylene Fiber Reinforced Rapid-Setting Cement Concrete (합성섬유보강 초속경 콘크리트의 구속건조수축 특성)

  • 원치문
    • Journal of the Korea Concrete Institute
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    • v.14 no.1
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    • pp.76-82
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    • 2002
  • The rapid-set cement concrete causes high hydration temperature and nay result in a high drying shrinkage and shrinkage-induced cracking. This problem may be fixed by incorporating polypropylene fibers in rapid-set cement concrete, because of increased toughness, resistance to impact, corrosion, fatigue, and durability. A series of concrete drving shrinkage tests was peformed in order to investigate the shrinkage properties of polypropylene fiber reinforced concrete with experimental variables such as concrete types, fiber reinforcement, W/C ratio, with and without restraint. Uni-axially restrained bar specimens were used for the restrained shrinkage tests. The results were as follows; The dry shrinkage of rapid-set cement concrete was much lessor than that oi OPC, probably because of smaller weight reduction rate by early hydration and strength development. The constraint and bridging effects caused by polypropylene fibers were great for the rapid-setting cement concrete when compared with that of plain concrete, and this resulted In increased resistance against tensile stress and cracking.

Numerical Study of the Averaging BDFT(bidirectional flow tube) Flow Meter on the Applicability in the Fouling Condition (수치해석을 이용한 평균 양방향 유동 튜브 유량계의 파울링 환경 적용성 연구)

  • Park, JongPil;Jeong, JiHwan;Kang, KyongHo;Baek, WonPil;Yun, ByongJo
    • The KSFM Journal of Fluid Machinery
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    • v.16 no.4
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    • pp.35-43
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    • 2013
  • Most of the nuclear power plants(NPPs) adopts pressure difference type flow meters such as venturi and orifice meters for the measurement of feedwater flow rates to calculate reactor thermal power. However, corrosion products in the feedwater deposits on the flow meter by fouling as operating time goes. These effects lead to severe errors in the flow indication and then determination of reactor thermal power. The averaging BDFT, which has developed by Yun et al., has a potentiality to minimize this problem thanks to its inherent measurement principle. Therefore, it is expected that the averaging BDFT can replace the venturi meter for the feedwater pipe of steam generator of NPPs. The present work compares the amplification factor, K, based on CFD calculation against the K obtained from experiments in order to confirm whether a commercial CFD code can be applicable to the evaluation of characteristic for the averaging BDFT. In addition to this, the simulations to take into account of fouling effect are also carried out by rough wall option. The results show that the averaging BDFT is a promising flow meter for the accurate measurement of flow rates in the fouling condition of the NPPs.

The Effect of Seawater on Hydration of Clinker Minerals (I) Effects of SO42- and Cl- ions (시멘트 클린커 광물의 수화에 미치는 해수성분의 영향 (I)SO42- 및 Cl-이온에 의한 영향)

  • 신도철;송태웅;한기성;최상흘
    • Journal of the Korean Ceramic Society
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    • v.24 no.1
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    • pp.77-85
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    • 1987
  • Hardened cement paste is mainly affected by corrosion of sulphate and chlorine ions in sea water. In this investigation, many specimens were made with the cement clinker minerals such as C3S, C3A, C4AF and their mixture according to cement composition added various blending materials. After the specimens were immersed in 4% MgSO4 and MgCl2 solutions, the product of reaction, the microstructure of specimen and Ca+2 ion leached in the solution were studied. The formation of Ca(OH)2 in the specimen of C3S is reduced relatively by adding pozzolanic admixtures. The chlorine ion is easily diffuse into the C3S specimen and produced CaCl2 compound, and it makes the specimen porous by leaching out itself into the solution. The specimen of C3A, C4AF are broken down by expanding reaction of ettringite and gypsum compound produced in the MgSO4 solution. At a later period, the ettringite is transformed into gypsum and 5MgO.2Al2O3·15H2O. The C3A in the MgCl2 solution combines chlorine ion to form Friedel's salt and prevents the diffusion reaction of chlorine ion into the specimen. Granulated slag shows inferior effect on the resistance of the specimen in MgSO4 solution by forming ettringite and gypsum, but good result in MgCl2 solution. Pozzolanic materials, on the whole, offer noticable effect on the resistance of the specimen in both solutions.

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Fatigue Life Analysis and Prediction of 316L Stainless Steel Under Low Cycle Fatigue Loading (저사이클 피로하중을 받는 316L 스테인리스강의 피로수명 분석 및 예측)

  • Oh, Hyeong;Myung, NohJun;Choi, Nak-Sam
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.12
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    • pp.1027-1035
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    • 2016
  • In this study, a strain-controlled fatigue test of widely-used 316L stainless steel with excellent corrosion resistance and mechanical properties was conducted, in order to assess its fatigue life. Low cycle fatigue behaviors were analyzed at room temperature, as a function of the strain amplitude and strain ratio. The material was hardened during the initial few cycles, and then was softened during the long post period, until failure occurred. The fatigue life decreased with increasing strain amplitude. Masing behavior in the hysteresis loop was shown under the low strain amplitude, whereas the high strain amplitude caused non-Masing behavior and reduced the mean stress. Low cycle fatigue life prediction based on the cyclic plastic energy dissipation theory, considering Masing and non-Masing effects, showed a good correlation with the experimental results.

Optimal Remediation of TCE-contaminated Groundwater using Direct Current and Fe$^0$ (직류전원과 0가 철을 이용한 지하수내 TCE정화효율의 최적화 연구)

  • Moon, Ji-Won;Moon, Hi-Soo;Roh, Yul;Kim, Heon-Ki;Song, Yun-Goo
    • Economic and Environmental Geology
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    • v.35 no.3
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    • pp.229-239
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    • 2002
  • The objective of this study was to design an optimal electro-remediation system for TCE contaminated water using zero talent iron (ZVI) and direct current (DC). A series of column experiments were conducted to evaluate the effects of electrode arrangement and the location of permeable iron barrier in the column on the TCE removal efficiency and iron corrosion process. In twelve different combinations of ZVI and/or DC application in the test columns, the rate of reductive degradation of TCE was improved with simultaneous application of both ZVI and DC compared to that used ZVI only. The moot effective arrangement of electrode and ZVI for TCE removal from water was a column set with ZVI and cathode installed at the down gradient, respectively.

Effect of Steam Curing on Compressive Strength of Slag Binder Concrete (증기양생이 고로슬래그 콘크리트의 압축강도에 미치는 영향)

  • Lim, Byung-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.8
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    • pp.338-343
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    • 2017
  • In this study, blast furnace slag powder was used in concrete to help reduce carbon dioxide emissions and to recycle industrial waste. Blast furnace slag powder is a byproduct of smelting pig iron and is obtained by rapidly cooling molten high-temperature blast furnace slag. The powder has been used as an admixture for cement and concrete because of its high reactivity. Using fine blast furnace slag powders in concrete can reduce hydration heat, suppress temperature increases, improve long-term strength, improve durability by increasing watertightness, and inhibit corrosion of reinforcing bars by limiting chloride ion penetration. However, it has not been used much due to its low compressive strength at an early age. Therefore, this study evaluates the effects of steam curing for increasing the initial strength development of concrete made using slag powder. The relationship between compressive strength, SEM observations, and XRD measurements was also investigated. The concrete made with 30% powder showed the best performance. The steam curing seems to affect the compressive strength by destroying the coating on the powder and by producing hydrates such as ettringite and Calcium-Silicate-Hydrate gel.

Microscopic characterization of pretransition oxide formed on Zr-Nb-Sn alloy under various Zn and dissolved hydrogen concentrations

  • Kim, Sungyu;Kim, Taeho;Kim, Ji Hyun;Bahn, Chi Bum
    • Nuclear Engineering and Technology
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    • v.50 no.3
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    • pp.416-424
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    • 2018
  • Microstructure of oxide formed on Zr-Nb-Sn tube sample was intensively examined by scanning transmission electron microscopy after exposure to simulated primary water chemistry conditions of various concentrations of Zn (0 or 30 ppb) and dissolved hydrogen ($H_2$) (30 or 50 cc/kg) for various durations without applying desirable heat flux. Microstructural analysis indicated that there was no noticeable change in the microstructure of the oxide corresponding to water chemistry changes within the test duration of 100 days (pretransition stage) and no significant difference in the overall thickness of the oxide layer. Equiaxed grains with nano-size pores along the grain boundaries and microcracks were dominant near the water/oxide interface, regardless of water chemistry conditions. As the metal/oxide interface was approached, the number of pores tended to decrease. However, there was no significant effect of $H_2$ concentration between 30 cc/kg and 50 cc/kg on the corrosion of the oxide after free immersion in water at $360^{\circ}C$. The adsorption of Zn on the cladding surface was observed by X-ray photoelectron spectroscopy and detected as ZnO on the outer oxide surface. From the perspective of $OH^-$ ion diffusion and porosity formation, the absence of noticeable effects was discussed further.

Effects of the Changes in Flow Pattern on Convective Heat Transfer in the Vicinity of Pipe Elbow (유동형태 변화가 배관 곡관부 대류열전달에 미치는 영향)

  • Song, Seung-Hyun;Yoo, Hoseon
    • Plant Journal
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    • v.15 no.1
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    • pp.25-30
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    • 2019
  • In this study, by varying flow patterns, which is one of the hydraulic factors of FAC, a strategy to reduce pipe wall thinning by mass transfer has been investigated. A similarity between heat transfer and mass transfer was verified via theoretical analysis, and local convective heat transfer coefficients were analyzed using a commercial numerical analysis program. When ribs were installed inside and outside of the internal surface in the straight section of the pipe, the maximum local heat transfer coefficient was shown to decrease substantially by up to 24.9% compared to the basic flow depending on the position and shape of ribs. If a guide vein was inserted in the pipe elbow, the maximum local heat transfer coefficient decreased by up to 26.7% compared to the basic flow depending on the internal surface area of the pipe by the guide vein.