• Title/Summary/Keyword: corrosion control

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Effects of Zn Coating and Heat Treatment on the Corrosion of Aluminum Heat Exchanger Tubes (아연 코팅과 열처리에 따른 알루미늄 열교환기 소재의 부식)

  • Cho, Soo Yeon;Kim, Jae Jung;Jang, Hee Jin
    • Corrosion Science and Technology
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    • v.18 no.1
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    • pp.24-32
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    • 2019
  • The effects of zinc coating and heat treatment on the corrosion resistance of aluminum alloys including A1100 and the modified A3003, used as heat exchanger tube were investigated in this study. The grain size of the heat-treated specimen is larger than that of the specimen without heat treatment, but the grain size did not significantly affect the corrosion behavior. The concentration of zinc was noted at 11.3 ~ 31.4 at.% for the as-received Zn-coated samples and reduced to 1.2 ~ 2.4 at.% after the heat treatment, as measured by the scanning electron microscopy (SEM) with an energy dispersive spectrometer (EDS) on the surface. The concentration of oxygen is 22 ~ 46 at.% for the zinc coated specimens while noted at 7.4 ~ 12.8 at.% for the specimens after the removal of the coating. The corrosion behavior depended largely on the concentrations of zinc, aluminum, and oxygen on the specimen surface, but not on the Mo content. The corrosion potential was high and the corrosion rate was low for a specimen with a low zinc content, a high aluminum content, and a high oxygen content.

Correlation of Surface Oxide Film Growth with Corrosion Resistance of Stainless Steel (스테인리스 스틸의 표면 산화피막 성장과 내부식성 상관관계)

  • Park, Youngju;Yu, Jinseok;Sim, Seong Gu;Jeong, Chanyoung
    • Corrosion Science and Technology
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    • v.20 no.3
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    • pp.152-157
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    • 2021
  • Stainless steel is a metal that does not generate rust. Due to its excellent workability, economic feasibility, and corrosion resistance, it is used in various industrial fields such as ships, piping, nuclear power, and machinery. However, stainless steel is vulnerable to corrosion in harsh environments. To solve this problem, its corrosion resistance could be improved by electrochemically forming an anodized film on its surface. In this study, 316L stainless steel was anodized at room temperature with ethylene glycol-based 0.1 M NH4F and 0.1M H2O electrolyte to adjust the thickness of the oxide film using different anodic oxidation voltages (30 V, 50 V, and 70 V) with time control. The anodic oxidation experiment was performed by increasing the time from 1 hour to 7 hours at 2-hour intervals. Corrosion resistance according to the thickness of the anodic oxide film was observed. Electrochemical corrosion behavior of oxide films was investigated through polarization experiments.

Algorithm for Determining Aircraft Washing Intervals Using Atmospheric Corrosion Monitoring of Airbase Data and an Artificial Neural Network (인공신경망과 대기부식환경 모니터링 데이터를 이용한 항공기 세척주기 결정 알고리즘)

  • Hyeok-Jun Kwon;Dooyoul Lee
    • Corrosion Science and Technology
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    • v.22 no.5
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    • pp.377-386
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    • 2023
  • Aircraft washing is performed periodically for corrosion control. Currently, the aircraft washing interval is qualitatively set according to the geographical conditions of each base. We developed a washing interval determination algorithm based on atmospheric corrosion environment monitoring data at the Republic of Korea Air Force (ROKAF) bases and United States Air Force (USAF) bases to determine the optimal interval. The main factors of the washing interval decision algorithm were identified through hierarchical clustering, sensitivity analysis, and analysis of variance, and criteria were derived. To improve the classification accuracy, we developed a washing interval decision model based on an artificial neural network (ANN). The ANN model was calibrated and validated using the atmospheric corrosion environment monitoring data and washing intervals of the USAF bases. The new algorithm returned a three-level washing interval, depending on the corrosion rate of steel and the results of the ANN model. A new base-specific aircraft washing interval was proposed by inputting the atmospheric corrosion environment monitoring results of the ROKAF bases into the algorithm.

Repid Corrosion Test on Reinforcing Steels in Chloride-Penetrating Concrete Structures with Various Crack Patterns (균열특성에 따른 콘크리트 구조물의 염분침투에 관한 실험적 연구)

  • 이상국;정영수;문홍식;안태송;유환구
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.345-350
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    • 2001
  • Reinforced concrete is, in general, known as a high durability material due to a strong alkalinity of cement. Probable concrete cracks could incur steel corrosion of RC structures and then could easily deteriorate the concrete durability, which can be fully secured by a systematic quality control for the construction of concrete structures. For the corrosion protection of reinforcing steels in concrete, however, current design specifications of concrete cover depth do not in-depth consider the effect of the cracks as well as the chloride content of RC structures. Therefore, appropriate provisions for concrete cover depth should be coded by considering the influence of concrete cracks on the corrosion of reinforcing steels. The objective of this research is to investigate pertinent cover depth, which can prohibit rebar corrosion, on the basis of experimental corrosion measurements of reinforcing steels on crack characteristics such as the width, depth and frequency of concrete cracks.

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Study on The Corrosion Inhibition Characteristics of Carbon Steel by Sodium Phosphate And Sodium Nitrite (삼인산 나트륨과 아질산 나트륨에 의한 탄소강 부식방지 특성 연구)

  • Moon, Jeon-Soo;Lee, Jae-Kun
    • Corrosion Science and Technology
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    • v.9 no.3
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    • pp.137-141
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    • 2010
  • Sodium nitrite is widely used as one of the popular corrosion inhibitors for the protection of ferrous metal in closed cooling water system, such as a diesel engine and a chiller. The optimum treatment conditions are studied through laboratory tests using linear polarization resistance (LPR) technique. Corrosion rate of the carbon steel electrode could be maintained less than $2.5{\times}10^{-3}$ mmpy in the test condition of 500 ppm as ${NO_2}^-$, 200 ppm as $Cl^-$, $70^{\circ}C$ and pH 6.8. The pH control is confirmed not to be an important factor in the protection of carbon steel by sodium nitrite inhibitor. The addition of tolyltriazole was needed for the protection of the copper alloy in the sodium nitrite treatment system.

Threshold Chloride Contents of Steel Corrosion in Concrete Containing Chloride (염화물 혼입 콘크리트 중의 철근부식 임계 염화물량)

  • 문한영;김성수;김홍삼;이승태;김은호
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.395-398
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    • 2000
  • Recently, increasement of usage contents of sea sand in constructing concrete structures due to insufficiency of high quality river sand, led to many studies for steel corrosion and control methods on it in concrete. But, domestic studies for threshold chloride contents of steel corrosion are not so many as those of foreign states. In this study, the electrochemical test as half cell potential measurement and linear polarization method to estimate the corrosion of steel in contents mixed with several levels chloride contents was performed, thereby, pre-mixed chloride were compared with results measured quantitatively for steel corrosion. And, based on these data, a trial to determine threshold chloride contents of steel corrosion was made.

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Effects of pH, Alkalinity, Chloride Ion on the Copper Pipe Corrosion (동관에서 pH, 알칼리도, 염소이온이 부식에 미치는 영향)

  • Jo, Kwan-Hyung;Kim, Sun-Il;Woo, Dal-Sik
    • Journal of Environmental Health Sciences
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    • v.33 no.1 s.94
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    • pp.43-48
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    • 2007
  • This study investigated the effects of pH, alkalinity, and chlorine ion which are important water quality impact factors to the corrosion in the simulated distribution system where the copper pipe is affixed. The result shows that pitting index was increased as the alkalinity and chloride ion increase in the distilled water, but there was no relation to pH. Actually the uniform corrosion rate was decreased as the pH increase with the laboratory tap water. In conclusion, it is necessary to control the pH which stands above minimum 7.5 to prevent pitting corrosion in the copper pipe. Consequently, comprehensive research about the effect of lime soda($Ca(OH)_2$) which was used as a coagulation additive in the water treatment plant to pipe corrosion must be accomplished additionally.

Effect of grain refinement on the performance of AZ80 Mg alloys during wear and corrosion

  • Naik, Gajanan M;Gote, Gopal D.;Narendranath, S;Kumar, S.S. Satheesh
    • Advances in materials Research
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    • v.7 no.2
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    • pp.105-118
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    • 2018
  • Magnesium and its alloys are attracted towards all engineering applications like automotive, marine, aerospace etc. due to its inherent high strength to weight ratio. But, extensive use of Mg alloys is limited to the current scenario because of low wear and corrosion resistance behavior. However, equal channel angular press is one of the severe plastic deformation technique which has been effective method to improve the wear and corrosion resistance by achieving fine grain structure. In this study, the effect of grain refinement on wear and corrosion resistance of AZ80 Mg alloys were investigated. The wear behavior of the coarse and fine-grained Mg alloys was examined through $L_9$ orthogonal array experiments in order to comprehend the wear behavior under varies control parameters. It was shown that ECAPed alloy increased the wear and corrosion resistance of the Mg alloy through the formation of fine grain and uniform distribution of secondary ${\beta}-phase$. Also, the performance of AZ80 Mg alloy for these changeswas discussed through SEM morphology.

Characteristics and Improvement of Tap Water Corrosivity in Korea (국내 수돗물의 부식성 특성 및 개선방안)

  • Kim, Jin-Keun;Kim, Yeong-Kwan
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.5
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    • pp.731-739
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    • 2011
  • To investigate corrosivity characteristics of tap water in Korea, Langelier index (LI) of 30 multi-regional water treatment plants (WTPs) were evaluated. Weekly LI values of 30 WTPs were all negative, which means tap water in Korea might be very corrosive. Maximum LI decrease through water treatment processes was 0.95 under no additional corrosion control process. Based on the correlation results between LI and tap water qualities, pH and calcium concentration were confirmed as major parameters for LI control. Addition of calcium hydroxide with $CO_{2}$ or calcium hydroxide or sodium hydroxide can be chosen based on water quality. Continuous monitoring of LI and related parameters is recommended in water distribution system.

Corrosion control technique for pipeline system through injecting water stabilizer (수질안정화 약품 주입에 따른 상수도관 내부 부식제어 특성 연구)

  • Hwang, Byung-Gi;Woo, Dal-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.1
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    • pp.545-551
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    • 2011
  • Recently, demands for generating high quality tap waters are increasing with high concern of water pollution and corrosion of water pipelines. For the reasons, developing water quality stabilization technique in water purification system is sought rather than replacing to a new pipelines. In this study, high-purity liquid lime($Ca(OH)_2$) was introduced for a water quality stabilization technique in water purification process and simulated water distribution system of pilot-scale size was applied to evaluate anti-corrosion control effect. The effect of anti-corrosion control was calculated in terms of LSI(Langelier Saturation Index) In conclusion, the result of pilot plant showed improvement of corrosiveness by liquid lime($Ca(OH)_2$) with reduction of released iron(Fe). Application of anti-corrosion control technique to the mild steel coupon and the copper coupon were effective by indicating 35.4, 44.5% of improvements. Besides, sample pipes which were treated with liquid lime had formated more thicker layer of corrosion product inside of pipes. As a result, the process of injecting water stabilizer can greatly contribute to the high quality of tap water.