• Title/Summary/Keyword: corrosion behaviors

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Characteristics of Flexural Behaviors for Marine Concrete Members Using High-Durable Materials (고내구성 재료를 사용한 해양 콘크리트 부재의 휨 거동 특성)

  • Yang, Eun-Ik;Kim, Myung-Yu;Park, Hae-Geun;Lee, Dong-Gun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.6
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    • pp.249-256
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    • 2008
  • The durability of marine concrete structure is severely degraded by corrosion due to penetration and diffusion of chloride. So, many researches have been performed to improve the durability in marine concrete structure. In this study, the concrete members mixed with the mineral admixtures(SF and BFS), the epoxy-coated steel, and corrosion inhibitors are prepared, and four-point bending test of specimens are performed to investigate the flexural behaviors and the applicability for marine concrete structure. From the test results, the mineral admixtures and inhibitors are useful for safety against the initial cracking and the bending resistance in specimens. When the durable material is used in specimen, the tensile stress of reinforcing rod was less variable in same bending span length, and the durable member showed a stable behavior. And it is evaluated that the crack spacing is not larger in specimen used the durable material.

Electrochemical and Sludge Dissolution Behavior During a Copper Removal Process for Chemical Cleaning on the Secondary Side of Nuclear Steam Generators (원전 증기발생기 2차측 화학세정을 위한 제동공정중의 전기화학적 거동 및 슬러지용해 거동)

  • Hur, Do-Haeng;Chung, Han-Sub;Kim, Uh-Chul;Chae, Sung-Ki;Park, Kwang-Kyoo;Kim, Jae-Pyong
    • Nuclear Engineering and Technology
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    • v.24 no.2
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    • pp.154-162
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    • 1992
  • Two major goals for chemical cleaning on the secondary side of nuclear steam generators are to remove sludge effectively and to minimize corrosion of base metals. In this work, electrochemical and sludge dissolution behaviors have been investigated in order to find out which parameters are critical and important during a copper removal process for chemical cleaning and to evaluate safety aspects and effectiveness of two major copper removal processes developed commercially in foreign countries. Hydrogen peroxide is vert effective for the process to use EDTA, NH$_4$OH and EDA at 38$^{\circ}C$ to control the potential of copper in a potential range sood for copper sludge removal. Corrosion rates for carbon steel SA 285 Gr.C and Alloy 600 are very small during this process if it is controlled properly. However, the corrosion rate of SA 285 Gr.C will be increased greatly if its corrosion potential is maintained below -450mV. The process to use EDA and ammonium carbonate is effective at 6$0^{\circ}C$ to dissolve copper sludge if the corrosion potential of copper can be controlled above -200mV. However, it is very difficult to raise the corrosion potential of copper to this range by air blowing and stirring.

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Corrosion behaviors of Cp-Ti and Ti-6Al-4V alloys by TiN coating (TiN 코팅된 Ti 및 Ti-6Al-4V합금의 부식거동)

  • Lee, Soon-Hyun;Jung, Yoong-Hun;Choi, Han-Chul;Ko, Yeong-Mu
    • Journal of Technologic Dentistry
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    • v.30 no.1
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    • pp.25-31
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    • 2008
  • Cp-Ti and Ti-6Al-4V alloys commonly used dental implant materials, particularly for orthopaedic and osteosynthesis because of its suitable mechanical properties and excellent biocompatibility. This alloys have excellent corrosion behavior in the clinical environment. The first factor to decide the success of dental implantation is sufficient osseointegration and high corrosion resistance between on implant fixture and its surrounding bone tissue. In this study, in order to increase corrosion resistance and biocompatibility of Cp-Ti and Ti-6Al-4V alloy that surface of manufactured alloy was coated with TiN by RF-magnetron sputtering method. The electrochemical behavior of TiN coated Cp-Ti and Ti-6Al-4V alloy were investigated using potentiodynamic (EG&G Co, PARSTAT 2273. USA) and potentiostatic test (250mV) in 0.9% NaCl solution at 36.5 $\pm$ 1$^{\circ}C$. These results are as follows : 1. From the microstructure analysis, Cp-Ti showed the acicular structure of $\alpha$-phase and Ti-6Al-4V showed the micro-acicular structure of ${\alpha}+{\beta}$ phase. 2. From the potentiodynamic test, Ecorr value of Cp-Ti and Ti-6Al-4V alloys showed -702.48mV and -319.87mV, respectively. Ti-6Al-4V alloy value was higher than Cp-Ti alloy. 3. From the analysis of TiN and coated layer, TIN coated surface showed columnar structure with 800 nm thickness. 4. The corrosion resistance of TiN coated Cp-Ti and Ti-6Al-4V alloys were higher than those of the non-coated Ti alloys in 0.9% NaCl solution from potentiodynamic test, indicating better protective effect. 5. The passivation current density of TiN coated Cp-Ti and Ti-6Al-4V alloys were smaller than that of the noncoated implant fixture in 0.9% NaCl solution, indicating the good protective effect resulting from more compact and homogeneous layer formation.

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Evaluation of the corrosion property on the welded zone of seawater pipe by A.C shielded metal arc welding (교류 피복아크 용접에 의한 해수 배관 용접부위의 부식 특성 평가)

  • Jeong, Jae-Hyun;Kim, Yun-Hae;Moon, Kyung-Man;Lee, Myeong-Hoon;Kim, Jin-Gyeong
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.8
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    • pp.877-885
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    • 2013
  • A seawater pipe of the engine room in the ships is being surrounded with severely corrosive environments caused by fast flowing of the seawater, containing aggressive chloride ion and high conductivity etc.. Therefore, the leakage of the seawater from its pipe have been often occurred due to its local corrosion by aggressive chloride ions. Subsequently, its leakage area is usually welded by AC shielded metal arc welding with various electrodes. In this study, when the sea water pipe is welded with several types of electrodes such as E4301, E4311, E4313 and E4316, a difference of the corrosion resistance on the welding metal zones was investigated using an electrochemical method, observing microstructure, measuring polarization behaviors and hardness. The weld metal zone welded with E4313 electrode exhibited the lowest value of hardness compared to other weld metal zones. In addition, its zone indicated also the best corrosion resistance than those of other weld metal zones. Furthermore, all of the weld metal zones revealed a relatively better corrosion resistance than those of the base metal zones. and also showed higher hardness than the base metal zones.

Lifetime Prediction of Geogrids for Reinforcement of Embankments and Slopes through Time-Temperature Superposition

  • Koo, Hyun-Jin;Kim, You-Kyum;Kim, Dong-Whan
    • Corrosion Science and Technology
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    • v.4 no.4
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    • pp.147-154
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    • 2005
  • The creep resistance of geogrids is one of the most significant long-term safety characteristics used as the reinforcement in slopes and embankments. The failure of geogrids is defined as creep strain greater than 10%. In this study, the accelerated creep tests were applied to polyester geogrids at various loading levels of 30, 50% of the yield strengths and temperatures using newly designed test equipment. Also, the new test equipment permitted the creep testing at or above glass transition temperature($T_g$) of 75, 80, $85^{\circ}C$. The time-dependent creep behaviors were observed at various temperatures and loading levels. And then the creep curves were shifted and superposed in the time axis by applying time-temperature supposition principles. The shifting factors(AFs) were obtained using WLF equation. In predicting the lifetimes of geogrids, the underlying distribution for failure times were determined based on identification of the failure mechanism. The results confirmed that the failure distribution of geogrids followed Weibull distribution with increasing failure rate and the lifetimes of geogrids were close to 100 years which was required service life in the field with 1.75 of reduction factor of safety. Using the newly designed equipment, the creep test of geogrids was found to be highly accelerated. Furthermore, the time-temperature superposition with the newly designed test equipment was shown to be effective in predicting the lifetimes of geogrids with shorter test times and can be applied to the other geosynthetics.

Electrochemical Polarization Characteristics and Effect of the CMP Performances of Tungsten and Titanium Film by H2O2 Oxidizer (H2O2 산화제가 W/Ti 박막의 전기화학적 분극특성 및 CMP 성능에 미치는 영향)

  • Na, Eun-Young;Seo, Yong-Jin;Lee, Woo-Sun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.6
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    • pp.515-520
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    • 2005
  • CMP(chemical mechanical polishing) process has been attracted as an essential technology of multi-level interconnection. Also CMP process got into key process for global planarization in the chip manufacturing process. In this study, potentiodynamic polarization was carried out to investigate the influences of $H_2O_2$ concentration and metal oxide formation through the passivation on tungsten and titanium. Fortunately, the electrochemical behaviors of tungsten and titanium are similar, an one may expect. As an experimental result, electrochemical corrosion of the $5\;vol\%\;H_2O_2$ concentration of tungsten and titanium films was higher than the other concentrations. According to the analysis, the oxidation state and microstructure of surface layer were strongly influenced by different oxidizer concentration. Moreover, the oxidation kinetics and resulting chemical state of oxide layer played critical roles in determining the overall CMP performance. Therefore, we conclude that the CMP characteristics tungsten and titanium metal layer including surface roughness were strongly dependent on the amounts of hydrogen peroxide oxidizer.

Evaluation of Creep Behaviors of Alloy 690 Steam Generator Tubing Material (Alloy 690 증기발생기 전열관 재료의 크리프 거동 평가)

  • Kim, Jong Min;Kim, Woo Gon;Kim, Min Chul
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.15 no.2
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    • pp.64-70
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    • 2019
  • In recent years, attention has been paid to the integrity of steam generator (SG) tubes due to severe accident and beyond design basis accident conditions. In these transient conditions, steam generator tubes may be damaged by high temperature and pressure, which might result in a risk of fission products being released to the environment due to the failure. Alloy 690 which has increased the Cr content has been replaced for the SG tube due to its high corrosion resistance against stress corrosion cracking (SCC). However, there is lack of research on the high temperature creep rupture and life prediction model of Alloy 690. In this study, creep test was performed to estimate the high temperature creep rupture life of Alloy 690 using tube specimens. Based on manufacturer's creep data and creep test results performed in this study, creep life prediction was carried out using the Larson-Miller (LM) Parameter, Orr-Sherby-Dorn (OSD) parameter, Manson-Haford (MH) parameter, and Wilshire's approach. And a hyperbolic sine (sinh) function to determine master curves in LM, OSD and MH parameter methods was used for improving the creep life estimation of Alloy 690 material.

Application of frictional sliding fuse in infilled frames, fuse adjustment and influencing parameters

  • Mohammadi-Gh, M.;Akrami, V.
    • Structural Engineering and Mechanics
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    • v.36 no.6
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    • pp.715-727
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    • 2010
  • An experimental investigation is conducted here to study the effects of applying frictional sliding fuses (FSF) in concrete infilled steel frames. Firstly, the influences of some parameters on the behavior of the sliding fuse are studied: Methods of adjusting the FSF for a certain sliding strength are explained and influences of time duration, welding and corrosion are investigated as well. Based on the results, time duration does not significantly affect the FSF, however influences of welding and corrosion of the constitutive plates are substantial. Then, the results of testing two 1/3 scale single-storey single-bay concrete infilled steel frames having FSF are presented. The specimens were similar, except for different regulations of their fuses, tested by displacement controlled cyclic loading. The results demonstrate that applying FSF improves infill behaviors in both perpendicular directions. The infilled frames with FSF have more appropriate hysteresis cycles, higher ductility, much lower deteriorations in strength and stiffness in comparison with regular ones. Consequently, the infills, provided with FSF, can be regarded as an engineered element, however, special consideration should be taken into the affecting parameters of their fuses.

Crack growth rate evaluation of alloys 690/152 by numerical simulation of extracted CT specimens

  • Lee, S.H.;Kim, S.W.;Cho, C.H.;Chang, Y.S.
    • Nuclear Engineering and Technology
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    • v.51 no.7
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    • pp.1805-1815
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    • 2019
  • While nickel-based alloys have been widely used for power plants due to corrosion resistance and good mechanical properties, during the last couple of decades, failures of nuclear components increased gradually. One of main degradation mechanisms was primary water stress corrosion cracking at dissimilar metal welds of piping and reactor head penetrations. In this context, precise estimation of welding effects became an important issue for ensuring reliability of them. The present study deals with a series of finite element analyses and crack growth rate evaluation of Alloys 690/152. Firstly, variation of residual stresses and equivalent plastic strains was simulated taking into account welding of a cylindrical block. Subsequently, extraction and pre-cracking of compact tension (CT) specimens were considered from different locations of the block. Finally, crack growth curves of the alloys and heat affected zone were developed based on analyses results combined with experimental data in references. Characteristics of crack growth behaviors were also discussed in relation to mechanical and fracture parameters.

Investigation on Ultimate Strength of STS304L Stainless Steel Welded Connection with Base Metal Fracture Using Finite Element Analysis

  • Lee, HooChang;Kim, TaeSoo;Hwang, BoKyung;Cho, TaeJun
    • International journal of steel structures
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    • v.18 no.4
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    • pp.1139-1152
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    • 2018
  • Many studies on the application of stainless steels as structural materials in buildings and infra-structures have been performed thanks to superior characteristics of corrosion resistance, fire resistance and aesthetic appeal. Experimental investigation to estimate the ultimate strength and fracture mode of the fillet-welded connections of cold-formed austenitic stainless steel (STS304L) with better intergranular corrosion resistance than that of austenitic stainless steel, STS304 commonly used has carried out by authors. Specimens were fabricated to fail by base metal fracture not weld metal fracture with main variables of weld lengths according to loading direction. All specimens showed a block shear fracture mode. In this paper, finite element analysis model was developed to predict the ultimate behaviors of welded connection and its validity was verified through the comparison with test results. Since the block shear behavior of welded connection due to stress triaxiality and shear-lag effects is different from that of bolted connection, stress and strain distributions in the critical path of tensile and shear fracture section were investigated. Test and analysis strengths were compared with those by current design specifications such as AISC, EC3 and existing researcher's proposed equations. In addition, through parametric analysis with extended variables, the conditions of end distance and longitudinal weld length for block shear fracture and tensile fracture were suggested.