• 한국광물학회지
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• 제16권1호
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• pp.107-123
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• 2003

본 연구는 0가 철 (ZVI)의 설치위치와 전극의 배열에 따른 다양한 조합의 전기적 투수성 반응벽을 대상으로 트리클로로에틸렌의 탈염소화 반응에 의한 정화시 ZVI의 부식에 기인하는 광물상침전물에 대해 알아보고, 이에 대한 조절 요소를 알아보고자 한다. 광물학적 연구 결과, 지하수 유입부의 ZVI 시료는 상대적으로 많은 레피도크로사이트, 훼리하이드라이트 혹은 철 수산화물과 (phospho)siderite가 산출되는 반면, 용출부의 ZVI 시료는 아카가나이트, 자철석/마그헤마이트, 그리고 중간 산물인 green rust (CR) I 과 CR II가 산출되었다. 이러한 광물 조합의 변화는 용존 산소 및 pH의 상승에 주로 기인한 것으로 나타났다. 또한 전기적 투수성 반응벽 내에 산출되는 광물상 침전물들의 조절 요소들은 (1) pH, (2) 용존산소, (3) 철의 부식시 중간 산물, (4) 음이온 종류 등으로 밝혀졌다.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2005년도 전기학술대회논문집
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• pp.395-400
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• 2005

The ship hull part is always exposed to severe corrosive environments. Therefore, it should be protected in appropriate ways to reduce corrosion problems. So there are two effective methods in order to protect the corrosion of ship hull. One is the paint coating as a barrier between steel and electrolyte (seawater) and the other is the cathodic protection(CP) supplying protection current. In the conventional design process of the cathodic protection system the required current densities of protected materials have been used. However, the anode position of field or laboratory experiment for obtaining the required current density for CP is significantly different from anode position for real structures. Therefore, the recent CP design must consider the optimum anode position for potential distribution equally over the ship hull. The CP design companies in the advanced countries can obtain the potential distribution results on the cathodic materials by using the computer analysis module. This study would show how to approach the potential analysis in the field of corrosion engineering. The computer program can predict the under protection area on the structure when the boundary condition and analysis procedure are reasonable. In this analysis the polarization curve is converted to the boundary condition in material data.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2012년도 추계총회 및 학술대회 논문집
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• pp.12-13
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• 2012

An environmentally friendly method for in situ growth of Mg-Al hydrotalcite (HT) film on AZ31 magnesium alloy has been developed. The growth processes and corrosion resistance of the HT film were investigated. Then the HT film was surface modified by phytic acid solution to further improve the corrosion resistance. The film formation involves the dissolution of AZ31 substrate, adsorption of the ions from solution, nucleation of the precursor, followed by the dissolution of $Al^{3+}$, exchanging of $OH^-$ by $CO{_3}^{2-}$ and growth of the HT film. The HT film is very compact and acts as a barrier against $Cl^-$ attack in the early stage of corrosion, and then the surface of the film is dissolved gradually. This dense HT film can provide effective protection to the AZ31 alloy. The HT film with surface modification by phytic acid presents a self-healing feature and exhibits better corrosion resistance.

• 한국표면공학회지
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• 제36권1호
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• pp.9-13
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• 2003

Plasma polymerized organic thin films were deposited on Si(100), glass and metal substrates at $25∼100 ^{\circ}C$ using thiophene and toluene precursors by PECVD method. In order to compare physical and electrochemical properties of the as-grown thin films, the effects of the RF plasma power in the range of 30∼100 W and deposition temperature on both corrosion protection efficiency and physical properties were studied. We found that the corrosion protection efficiency ($P_{k}$), which is one of the important factors for corrosion protection in the interlayer dielectrics of microelectronic devices application, was increased with increasing RF power. The highest $P_{k}$ value of plasma polymerized toluene film (85.27% at 70 W) was higher than that of the plasma polymerized thiophene film (65.17% at 100 W), indicating inhibition of oxygen reduction. The densely packed and tightly interconnected toluene film could act as an efficient barrier layer to the diffusion of molecular oxygen. The result of contact angle measurement showed that the plasma polymerized toluene films have more hydrophobic surface than those of the plasma polymerized thiophene films.

• Journal of Electrochemical Science and Technology
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• 제10권2호
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• pp.148-158
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• 2019

The corrosion protection of AA2024 PPy coated samples doping with nanosized metal oxides, including $TiO_2$ and $CeO_2$ nanoparticles and $Nd_2O_3$ nanorods, during exposure to the solutions of 0.1 M $H_2SO_4$ and 3.5% NaCl was evaluated by electrochemical impedance spectroscopy (EIS) and linear polarization resistance (LPR) techniques. The nanorods of $Nd_2O_3$ were synthesized by cathodic pulse electrochemical deposition technique. The barrier properties of the different PPy coatings containing nanosized metal oxides immersed in $H_2SO_4$ solution were ranked as follows: $Nd_2O_3$ > $TiO_2$ > $CeO_2$. Therefore, the $Nd_2O_3$ coating sample provided the highest corrosion protection at any time of immersion up to 72 hours after immersing in $H_2SO_4$ solution. On the other hand, the $CeO_2$ coating sample displayed the best anticorrosive properties among the other coating samples after immersion in NaCl solution up to 28 days. This is due to the inhibition effect of cerium ions on aluminum alloys at near-neutral solutions.

• 열처리공학회지
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• 제28권5호
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• pp.229-238
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• 2015

The effects of Sn addition and solution treatment on corrosion behavior were studied in AZ91 magnesium casting alloy. The addition of 5%Sn contributed to the introduction of $Mg_2Sn$ phase, to the reduction in dendritic cell size and to the increase in the amount of secondary phases. After the solution treatment, trace amount of $Al_8Mn_5$ particles were observed in the ${\alpha}$-(Mg) matrix for the AZ91 alloy, while $Mg_2Sn$ phase with high thermal stability was additionally found in the AZ91-5%Sn alloy. Before the solution treatment, the AZ91-5%Sn alloy had better corrosion resistance than the Sn-free alloy, which is caused by the enhanced barrier effect of the (${\beta}+Mg_2Sn$) phases formed more continuously along the dendritic cell boundaries. It is interesting to note that after the solution treatment, the corrosion rate of both alloys became increased, but the Sn-added alloy showed higher corrosion rate than the Sn-free alloy. The microstructural examination on the corroded surfaces revealed that the remaining $Mg_2Sn$ particles in the solution-treated AZ91-5%Sn alloy play a role in accelerating corrosion by galvanic coupling with the ${\alpha}$-(Mg) matrix.

• Corrosion Science and Technology
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• 제11권6호
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• pp.280-285
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• 2012

Aluminum is on active metal, but it is well known that its oxide film plays a role as protective barrier which is comparatively stable in air and neutral aqueous solution. Thus, aluminum alloys have been widely applied in architectural trim, cold & hot-water storage vessels and piping etc., furthermore, the aluminum alloy of AC8A have been widely used in mold casting material of engine piston because of its properties of temperature and wear resistance. In recent years, the oil price is getting higher and higher, thus the using of low quality oil has been significantly increased in engines of ship and vehicle. Therefore it is considered that evaluation of corrosion resistance as well as wear resistance of AC8A material is also important to improve its property and prolong its lifetime. In this study, the effect of solution and tempering heat treatment to corrosion and wear resistance is investigated with electrochemical method and measurement of hardness. The hardness decreased with solution heat treatment compared to mold casting condition, but its value increased with tempering heat treatment and exhibited the highest value of hardness with tempering heat treatment temperature at $190^{\circ}C$ for 24hrs. Furthermore, corrosion resistance increased with decreasing of the hardness, and decreased with increasing of the hardness reversely. As a result, it is suggested that the optimum heat treatment to improve both corrosion and wear resistance is tempering heat treatment temperature at $190^{\circ}C$ for 16hrs.

• 지질공학
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• 제26권1호
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• pp.79-85
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• 2016

방사성폐기물 처분시설 공학적방벽을 구성하는 콘크리트는 주변 환경의 영향으로 내구 수명에 영향을 받게 된다. 현재까지 개발된 수치해석 모델 및 실험을 통하여 방사성폐기물 처분시설 공학적방벽 소재로 가장 널리 사용되는 콘크리트에 대해 주변환경을 고려하여 그 영향을 살펴보았다. 본 연구에 해당하는 철근 콘크리트 구조물은 지리적으로 해안과 인접한 지하수 포화대에 위치하고 있다. 일반적인 철근콘크리트 구조물의 가장 민감한 열화인자인 염해에 의한 철근부식에 대한 영향을 염화물 확산모델을 이용하여 평가한 결과 철근 부식 개시기간이 1,284년이며, 최종적으로 구조물이 내구수명을 상실하는데 도달하는 시간은 1,924년인 것으로 예측되었다. 또한, Mock-up 실험을 통해 공극분포, 공극률, 부식정도 등 물리화학적 특성을 평가한 결과 콘크리트 내 철근 부식정도는 미비한 것으로 나타나 500년 이상의 상당히 오랜 기간 건전성을 유지할 수 있는 것으로 판단된다.

• 한국통신학회논문지
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• 제40권5호
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• pp.974-980
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• 2015

해양환경 하에서 강재에 대한 방식 목적으로 Al-3%Mg 용사선재를 이용하여 아크 용사코팅을 실시하였다. 그리고 Al-3%Mg 용사코팅 층의 내식성을 개선하기 위하여 유/무기 복합 세라믹 후처리를 실시하였다. 후처리 적용에 따른 용사코팅 층의 다양한 전기화학적 실험 결과, 양극분극과 음극분극 실험 시 모든 전위구간에서 후처리 적용 시 전류밀도가 작게 나타나 내식성 개선이 확인되었다. 그리고 후처리된 용사코팅 층의 표면에서 관찰된 마이크로 크랙의 영향으로 자연전위 계측 시 심한 전위변동이 나타났으며, 양극분극 실험 시에는 후처리 층의 탈리손상이 용이하게 발생하였다. 그럼에도 불구하고 타펠분석을 기반으로 외부 환경차단 효과를 나타내는 코팅 효율이 92.11%로 산출되어 Al-3%Mg 용사코팅 층의 내식성이 향상되었다.

• 한국세라믹학회지
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• 제50권6호
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• pp.353-358
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• 2013

The hot corrosion behavior of plasma sprayed 4 mol% $Y_2O_3-ZrO_2$ (YSZ) thermal barrier coatings (TBCs) with volcanic ash is investigated. Volcanic ash that deposited on the TBCs in gas-turbine engines can attack the surface of TBCs itself as a form of corrosive melt. YSZ coating specimens with a thickness of 430-440 ${\mu}m$ are prepared using a plasma spray method. These specimens are subjected to hot corrosion environment at $1200^{\circ}C$ with five different duration time, from 10 mins to 100 h in the presence of corrosive melt from volcanic ash. The microstructure, composition, and phase analysis are performed using Field emission scanning electron microscopy, including Energy dispersive spectroscopy and X-ray diffraction. After the heat treatment, hematite ($Fe_2O_3-TiO_2$) and monoclinic YSZ phases are found in TBCs. Furthermore the interface area between the molten volcanic ash layers and YSZ coatings becomes porous with increases in the heat treatment time as the YSZ coatings dissolved into molten volcanic ash. The maximum thickness of this a porous reaction zone is 25 ${\mu}m$ after 100 h of heat treatment.