• Title/Summary/Keyword: core products

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Confined Pt and CoFe2O4 Nanoparticles in a Mesoporous Core/Shell Silica Microsphere and Their Catalytic Activity

  • Kang, Dong-Hyeon;Eum, Min-Sik;Lee, Byeong-No;Bae, Tae-Sung;Lee, Kyu-Reon;Lim, Heung-Bin;Hur, Nam-Hwi
    • Bulletin of the Korean Chemical Society
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    • v.32 no.10
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    • pp.3712-3719
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    • 2011
  • Confined Pt and $CoFe_2O_4$ nanoparticles (NPs) in a mesoporous core/shell silica microsphere, Pt-$CoFe_2O_4$@meso-$SiO_2$, were prepared using a bi-functional linker molecule. A large number of Pt NPs in Pt-$CoFe_2O_4$@meso-$SiO_2$, ranging from 5 to 8 nm, are embedded into the shell and some of them are in close contact with $CoFe_2O_4$ NPs. The hydrogenation of cyclohexene over the Pt-$CoFe_2O_4$@meso-$SiO_2$ microsphere at $25^{\circ}C$ and 1 atm of $H_2$ yields cyclohexane as a major product. In addition, it gives oxygenated products. Control experiments with $^{18}O$-labelled water and acetone suggest that surface-bound oxygen atoms in $CoFe_2O_4$ are associated with the formation of the oxygenated products. This oxidation reaction is operative only if $CoFe_2O_4$ and Pt NPs are in close contact. The Pt-$CoFe_2O_4$@meso-$SiO_2$ catalyst is separated simply by a magnet, which can be re-used without affecting the catalytic efficiency.

The Effect of Reward Channel and Reward Time of Customer Loyalty Programs for On-offline Channels -Focusing on Department Stores and Online Shopping Stores- (온-오프라인 채널에서 운영하는 고객보상프로그램의 보상채널과 보상시점에 따른 효과 분석 -백화점과 온라인 종합몰을 중심으로-)

  • Park, Minjung
    • Journal of the Korean Society of Clothing and Textiles
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    • v.37 no.4
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    • pp.467-481
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    • 2013
  • The study examined the main effect of the reward channel and reward time of customer loyalty programs for on-offline shopping channels; in addition, it investigated the interaction effect of the reward channels and merchandise as well as the interaction effect of the reward time and merchandise. An online apparel shopping web experiment was conducted with a 2 (reward channel: online channel reward vs. offline channel reward) ${\times}2$ (reward time: immediate vs. delayed) ${\times}2$ (merchandise: online channel product vs. offline channel products) between-subject factorial design. An online shopping channel was considered the core-shopping channel and a department store was considered the cross-shopping channel. Loyalty program value, core-channel loyalty and cross-channel loyalty were measured as dependent variables. A total of 845 shoppers (who had experiences in shopping in both channels) participated in the experiment. The results of the study revealed (1) the main effect of the reward channel on loyalty program value, core-channel loyalty and cross-channel loyalty [online>offline channel rewards], (2) the main effect of reward time on loyalty program value, core-channel loyalty and cross-channel loyalty [immediate>delayed reward], and (3) the interaction effect of the reward channel and merchandise on loyalty program value, core-channel loyalty, and cross-channel loyalty. (4) Finally the study found that loyalty program value affected cross-channel loyalty indirectly through core-channel loyalty. This study suggested diverse theoretical and managerial implications for multi-channel retailers.

Densified Pellet Fuel Using Woody Core of Industrial Hemp (Cannabis sativa L.) as an Agricultural waste (농업부산물인 산업용 대마(Cannabis sativa L.) 목부를 이용한 고밀화 펠릿 연료)

  • Han, Gyu-Seong;Lee, Soo-Min;Shin, Soo-Jeong
    • Korean Journal of Plant Resources
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    • v.22 no.4
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    • pp.293-298
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    • 2009
  • We prepared densified wood pellet by agricultural waste. The hemp woody core was used as replacing wood resource. Hemp was separated into the bast fiber and the woody core by hot steaming treatment. The hemp woody core had a similar lignin content(19.4%) and carbohydrate composition with hardwood(20-25% lignin in hardwood), respectively. Also, the hemp had a low ash content(0.5%), which resulted in a low ash formation in pellet burning. Heating value of the hemp pellet(18.40 MJ/kg) had a very similar to the pellet made by hardwoods. The hemp woody core could be replaced the hardwood for densified wood pellet.

Investigation of Gas Evolution in Shell Cores during Casting Processes of Aluminum Alloys (알루미늄 합금 주조공정의 쉘 코아 가스 발생 전산모사 연구)

  • In-Sung Cho;Jeong-Ho Nam;Hee-Soo Kim
    • Journal of Korea Foundry Society
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    • v.43 no.4
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    • pp.187-193
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    • 2023
  • Shell core making is an excellent process in terms of formability and desanding, but when the molten aluminum comes into con- tact with the shell core, gas generation by pyrolysis of the resin is inevitable. In addition, when the ventilation is inadequate, pores will remain inside the casting, which can directly lead to defects of the casting. While studies on the gas generation behavior of shell core making have been reported, the modeling of gas generation has not been extensively investigated. We will develop a gas evolution analysis method that considers the relationship between temperature and gas quantity for the core to be developed. We then use the developed method to analyze the flow and solidification behavior of metal molten metal during core mold design and low-pressure casting of cylinder head products, and predict the occurrence of casting defects to derive a casting method that min- imizes the occurrence of defects.

A STUDY OF CORE TYPE AND LUTING CEMENTS ON COMPLETE CAST CROWN RETENTION (코어 형태와 시멘트 종류에 따른 전부주조금관의 유지력에 관한 연구)

  • Paek, Sang-Hyun;Chang, Ik-Tae;Lee, Sun-Hyung;Yang, Jae-Ho;Heo, Seong-Joo
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.2
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    • pp.169-177
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    • 2000
  • The purpose of this study was to compare the retention of complete cast crown over amalgam ores, composite resin cores, and cast gold cores when cemented with three different luting agents. Eighteen core specimens each of amalgam(Bestaloy, Dong Myung, Seoul, Korea), composite resin (Z100, 3M Dental product, st. Paul, Minn) and type IV gold alloy (Ba-4, Heesung Engelhard Corp., Korea) were made in a customized milling stainless steel die. A wax pattern with a loop attached to occlusal surface was made for each core and a type II gold alloy casting was fabricated. The castings which had clinically acceptable marginal fit were used as test samples. The following luting cements were used to cement cast crowns on each core material : (1) zinc phosphate cement (Confi-dental Products Co., USA) (2) glass-ionomer cement (Fuji Plus, GC Industrial Corp., Tokyo, Japan) (3) resin cement (Panavia 21, Kuraray Co., USA). All cements were mixed according to manufacturers' instructions. A static load of 5kg was then applied for 10 minutes on the crowns. All specimens were stored in saline solution for 24 hours at $37^{\circ}C$ and thermocycled for 500 cycles. After storage and cycling, the tensile bond strengths were measured by using a universal testing machine (Instron Corp., Canton, Mass.) at a crosshead speed of 0.5mm/min. The results were as follows 1. The retentive strength of resin cement was the highest of alt three types of cement for resin core (p<0.05). 2. There was no statistical difference among the retentive strengths of three cements for amalgam core (p>0.05). 3. The retentive strength of resin cement was higher than that of zinc phosphate for cast core, but there was no difference between the retentive strength of glass ionomer cement and those of rein and zinc phosphate cement. 4. The retentive strength of the zinc phosphate cement for amalgam core was the highest of all type of cores.

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Preparation of Styrene-Ethyl acylate Core-shell Structured Detection Materials for aMeasurement of the Wall Contamination by Emulsion Polymerization

  • Hwang, Ho-Sang;Seo, Bum-Kyoung;Lee, Dong-Gyu;Lee, Kune-Woo
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2009.06a
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    • pp.84-85
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    • 2009
  • New approaches for detecting, preventing and remedying environmental damage are important for protection of the environment. Procedures must be developed and implemented to reduce the amount of waste produced in chemical processes, to detect the presence and/or concentration of contaminants and decontaminate fouled environments. Contamination can be classified into three general types: airborne, surface and structural. The most dangerous type is airborne contamination, because of the opportunity for inhalation and ingestion. The second most dangerous type is surface contamination. Surface contamination can be transferred to workers by casual contact and if disturbed can easily be made airborne. The decontamination of the surface in the nuclear facilities has been widely studied with particular emphasis on small and large surfaces. The amount of wastes being produced during decommissioning of nuclear facilities is much higher than the total wastes cumulated during operation. And, the process of decommissioning has a strong possibility of personal's exposure and emission to environment of the radioactive contaminants, requiring through monitoring and estimation of radiation and radioactivity. So, it is important to monitor the radioactive contamination level of the nuclear facilities for the determination of the decontamination method, the establishment of the decommissioning planning, and the worker's safety. But it is very difficult to measure the surface contamination of the floor and wall in the highly contaminated facilities. In this study, the poly(styrene-ethyl acrylate) [poly(St-EA)] core-shell composite polymer for measurement of the radioactive contamination was synthesized by the method of emulsion polymerization. The morphology of the poly(St-EA) composite emulsion particle was core-shell structure, with polystyrene (PS)as the core and poly(ethyl acrylate) (PEA) as the shell. Core-shell polymers of styrene (St)/ethyl acrylate (EA) pair were prepared by sequential emulsion polymerization in the presence of sodium dodecyl sulfate (SOS) as an emulsifier using ammonium persulfate (APS) as an initiator. The polymer was made by impregnating organic scintillators, 2,5-diphenyloxazole (PPO) and 1,4-bis[5-phenyl-2-oxazol]benzene (POPOP). Related tests and analysis confirmed the success in synthesis of composite polymer. The products are characterized by IT-IR spectroscopy, TGA that were used, respectively, to show the structure, the thermal stability of the prepared polymer. Two-phase particles with a core-shell structure were obtained in experiments where the estimated glass transition temperature and the morphologies of emulsion particles. Radiation pollution level the detection about under using examined the beta rays. The morphology of the poly(St-EA) composite polymer synthesized by the method of emulsion polymerization was a core-shell structure, as shown in Fig. 1. Core-shell materials consist of a core structural domain covered by a shell domain. Clearly, the entire surface of PS core was covered by PEA. The inner region was a PS core and the outer region was a PEA shell. The particle size distribution showed similar in the range 350-360 nm.

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Characteristic for Growth and Fruit Body Polysaccharide of Caterpillar Fungi, Cordyceps sobolifera(Hill.) Berk. et Br.

  • Ohga, Shoji;Yoshimoto, Hiroaki;Pokhrel, Chandra;Yang, Bai-Song;Miyazawa, Noriko;Meng, Tianxiao;Hosoda, Shun;Mae, Masuo;Sun, Zhu
    • Korean Journal of Agricultural Science
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    • v.35 no.2
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    • pp.199-212
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    • 2008
  • Mycelial expansion and fruit body development of caterpillar fungi, Cordyceps sobolifera(Hill.) Berk. et Br. was examined on various carbon and nitrogen sources, some substrates with various supplements. Best temperature for the mycelial expansion was $25^{\circ}C$, while optimal pH was 7. Glucose and polypeptone were the best sources of carbon and nitrogen, respectively, as well as 1:1 was the best ratio of carbon and nitrogen. The unpolish rice and bean curd lees were used as core substrates combined individually with five various supplements. In substrates based, all the supplements with all combinations were found to exhibit the mycelial growth and fruit body formation. Likewise, yolk was found as a superior supplement and also clarified quite high polysaccharide content in the fruit body.

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A Development Technique of Core Architecture Data Model(CADM) for Defense Information Resource Management (국방 정보자원관리를 위한 핵심아키텍처데이터모델 개발 기법)

  • Choi, Nam-Yong;Jin, Jong-Hyeon;Song, Young-Jae
    • The KIPS Transactions:PartD
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    • v.11D no.3
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    • pp.683-690
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    • 2004
  • MND(Ministry of National Defense) has developed .nm AF(Ministry of National Defense Architecture Framework) to guarantee interoperability among defense information systems. Users can easily and consistently develop architecture products through MND AF. There is necessity for development if CADM(Core Architecture Data Model), which facilitate exchange, integration, and comparison for architecture data, to store architecture data from architecture products and reuse them. We developed CADM from defining entities and relationships that satisfy data requirement of each architecture product from MND AF. After we developed architecture products about MIMS(Military Intelligence Management System), and inserted these architecture data to CADM repository. we verified CADM entities and relationships through query. Through CABM which provides common data model for the whole my architectures, interoperability and integration among defense information systems ran be improved, and integrated defense information resources efficiently can be managed.

Expressing Variability in Software Product Line Architecture Models: A Comparative Study (소프트웨어 제품라인 아키텍처 모델에서의 가변성 표현 방법 비교 연구)

  • Lee, Hyesun;Cho, Sungbae;Kang, Kyo Chul
    • Journal of Software Engineering Society
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    • v.24 no.3
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    • pp.77-89
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    • 2011
  • Software product line engineering is a software reuse paradigm that helps organizations improve software productivity and quality by developing software products from reusable core assets. For the satisfaction of common and variable requirements among products in the product line, the core assets must be configurable according to the selection of variable features. Therefore, unlike software architecture model of a single product, product line architecture model must embed and express variabilities among the products. Many researches have proposed methods of embedding and expressing variabilities in the product line architecture models, but there are few comparative studies on the proposed methods. In this paper we discuss strong points and weak points of the proposed methods and compare expressiveness of the methods, which helps select a proper method.

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Study of fission gas products effect on thermal hydraulics of the WWER1000 with enhanced subchannel method

  • Bahonar, Majid;Aghaie, Mahdi
    • Advances in Energy Research
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    • v.5 no.2
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    • pp.91-105
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    • 2017
  • Thermal hydraulic (TH) analysis of nuclear power reactors is utmost important. In this way, the numerical codes that preparing TH data in reactor core are essential. In this paper, a subchannel analysis of a Russian pressurized water reactor (WWER1000) core with enhanced numerical code is carried out. For this, in fluid domain, the mass, axial and lateral momentum and energy conservation equations for desired control volume are solved, numerically. In the solid domain, the cylindrical heat transfer equation for calculation of radial temperature profile in fuel, gap and clad with finite difference and finite element solvers are considered. The dependence of material properties to fuel burnup with Calza-Bini fuel-gap model is implemented. This model is coupled with Isotope Generation and Depletion Code (ORIGEN2.1). The possibility of central hole consideration in fuel pellet is another advantage of this work. In addition, subchannel to subchannel and subchannel to rod connection data in hexagonal fuel assembly geometry could be prepared, automatically. For a demonstration of code capability, the steady state TH analysis of a the WWER1000 core is compromised with Thermal-hydraulic analysis code (COBRA-EN). By thermal hydraulic parameters averaging Fuel Assembly-to-Fuel Assembly method, the one sixth (symmetry) of the Boushehr Nuclear Power Plant (BNPP) core with regular subchannels are modeled. Comparison between the results of the work and COBRA-EN demonstrates some advantages of the presented code. Using the code the thermal modeling of the fuel rods with considering the fission gas generation would be possible. In addition, this code is compatible with neutronic codes for coupling. This method is faster and more accurate for symmetrical simulation of the core with acceptable results.