Browse > Article
http://dx.doi.org/10.5012/bkcs.2011.32.10.3712

Confined Pt and CoFe2O4 Nanoparticles in a Mesoporous Core/Shell Silica Microsphere and Their Catalytic Activity  

Kang, Dong-Hyeon (Department of Chemistry, Sogang University)
Eum, Min-Sik (Department of Chemistry, Sogang University)
Lee, Byeong-No (Department of Chemistry, Sogang University)
Bae, Tae-Sung (Korea Basic Science Institute)
Lee, Kyu-Reon (Department of Chemistry, Sogang University)
Lim, Heung-Bin (Department of Chemistry, Dankook University)
Hur, Nam-Hwi (Department of Chemistry, Sogang University)
Publication Information
Bulletin of the Korean Chemical Society / v.32, no.10, 2011 , pp. 3712-3719 More about this Journal
Abstract
Confined Pt and $CoFe_2O_4$ nanoparticles (NPs) in a mesoporous core/shell silica microsphere, Pt-$CoFe_2O_4$@meso-$SiO_2$, were prepared using a bi-functional linker molecule. A large number of Pt NPs in Pt-$CoFe_2O_4$@meso-$SiO_2$, ranging from 5 to 8 nm, are embedded into the shell and some of them are in close contact with $CoFe_2O_4$ NPs. The hydrogenation of cyclohexene over the Pt-$CoFe_2O_4$@meso-$SiO_2$ microsphere at $25^{\circ}C$ and 1 atm of $H_2$ yields cyclohexane as a major product. In addition, it gives oxygenated products. Control experiments with $^{18}O$-labelled water and acetone suggest that surface-bound oxygen atoms in $CoFe_2O_4$ are associated with the formation of the oxygenated products. This oxidation reaction is operative only if $CoFe_2O_4$ and Pt NPs are in close contact. The Pt-$CoFe_2O_4$@meso-$SiO_2$ catalyst is separated simply by a magnet, which can be re-used without affecting the catalytic efficiency.
Keywords
Magnetic nanoparticles; Core/Shell silica; Catalyst; Proximity effect;
Citations & Related Records
Times Cited By KSCI : 8  (Citation Analysis)
Times Cited By Web Of Science : 0  (Related Records In Web of Science)
Times Cited By SCOPUS : 0
연도 인용수 순위
1 Hughes, M. D.; Xu, Y.-J.; Jenkins, P.; McMorn, P.; Landon, P.; Enache, D. I.; Carley, A. F.; Attard, G. A.; Hutchings, G. J.; King, F.; Stitt, E. H.; Johnston, P.; Griffin, K.; Kiely, C. J. Nature 2005, 437, 1132.   DOI   ScienceOn
2 Enache, D. I.; Edwards, J. K.; Landon, P.; Solsona-Espriu, B.; Carley, A. F.; Herzing, A. A.; Watanabe, M.; Kiely, C. J.; Knight, D. W.; Hutchings, G. J. Science 2006, 311, 362.   DOI   ScienceOn
3 Polshettiwar, V.; Varma, R. S. Org. Biomol. Chem. 2009, 7, 37.   DOI   ScienceOn
4 Campelo, J. M.; Luna, D.; Luque, R.; Marinas, J. M.; Romero, A. A. ChemSusChem 2009, 2, 18.   DOI   ScienceOn
5 Jeong, U.; Teng, X.; Wang, Y.; Yang, H.; Xia, Y. Adv. Mater. 2007, 19, 33.   DOI   ScienceOn
6 Yoon, T.-J.; Lee, W.; Oh, Y.-S.; Lee, J.-K. New J. Chem. 2003, 27, 227.   DOI   ScienceOn
7 Lee, K. R.; Kim, S.; Kang, D. H.; Lee, J. I.; Lee, Y. J.; Kim, W. S.; Cho, D.-H.; Lim, H. B.; Kim, J.; Hur, N. H. Chem. Mater. 2008, 20, 6738.   DOI   ScienceOn
8 Buchel, G.; Unger, K. K.; Matsumoto, A.; Tsutsumi, K. Adv. Mater. 1998, 10, 1036.   DOI   ScienceOn
9 Pasricha, R.; Bala, T.; Biradar, A. V.; Umbarkar, S.; Sastry, M. Small 2009, 5, 1467.   DOI   ScienceOn
10 Olivas, A.; Jerdev, D. I.; Koel, B. E. J. Catal. 2004, 222, 285.
11 Sakurai, H.; Ueda, A.; Kobayashi, T.; Haruta, M. Chem. Commun. 1997, 271.
12 Hoxha, F.; Schmidt, E.; Mallat, T.; Schimmoeller, B.; Pratsinis, S. E.; Baiker, A. J. Catal. 2011, 278, 94.   DOI   ScienceOn
13 Zope, B. N.; Hibbitts, D. D.; Neurock, M.; Davis, R. J. Science 2010, 330, 74.   DOI   ScienceOn
14 Zhai, Y.; Pierre, D.; Si, R.; Deng, W.; Ferrin, P.; Nilekar, A. U.; Peng, G.; Herron, J. A.; Bell, D. C.; Saltsburg, H.; Mavrikakis, M.; Flytzani-Stephanopoulos, M. Science 2010, 329, 1633.   DOI   ScienceOn
15 Liu, H.; Jiang, T.; Han, B.; Liang, S.; Zhou, Y. Science 2009, 326, 1250.   DOI   ScienceOn
16 Casaletto, M. P.; Longo, A.; Martorana, A.; Prestianni, A.; Venezia, A. M. Surf. Interface Anal. 2006, 38, 215.   DOI   ScienceOn
17 Alfredsson, M.; Catlow, C. R. A. PCCP 2002, 4, 6100.   DOI   ScienceOn
18 Venezia, A. M.; Rossi, A.; Duca, D.; Martorana, A.; Deganello, G. Appl. Catal., A 1995, 125, 113.   DOI   ScienceOn
19 Sankar, G.; Rao, C. N. R.; Rayment, T. J. Mater. Chem. 1991, 1, 299.   DOI
20 Xu, L.; Ma, Y.; Zhang, Y.; Jiang, Z.; Huang, W. J. Am. Chem. Soc. 2009, 131, 16366.   DOI   ScienceOn
21 Wang, C.; Daimon, H.; Sun, S. Nano Lett. 2009, 9, 1493.   DOI   ScienceOn
22 Kim, Y. N.; Lee, E. K.; Lee, Y. B.; Shim, H.; Hur, N. H.; Kim, W. S. J. Am. Chem. Soc. 2004, 126, 8672.   DOI   ScienceOn
23 Bonanni, S.; Ait-Mansour, K.; Brune, H.; Harbich, W. ACS Catal. 2011, 1, 385.   DOI   ScienceOn
24 Fu, Q.; Li, W.-X.; Yao, Y.; Liu, H.; Su, H.-Y.; Ma, D.; Gu, X.-K.; Chen, L.; Wang, Z.; Zhang, H.; Wang, B.; Bao, X. Science 2010, 328, 1141.   DOI   ScienceOn
25 Gonzalez, J. C.; Hernandez, J. C.; Lopez-Haro, M.; del Rio, E.; Delgado, J. J.; Hungria, A. B.; Trasobares, S.; Bernal, S.; Midgley, P. A.; Calvino, J. J. Angew. Chem. Int. Ed. 2009, 48, 5313.   DOI   ScienceOn
26 Roh, H.-S.; Jun, K.-W.; Baek, S.-C.; Park, S.-E. Bull. Korean Chem. Soc. 2002, 23, 799.   DOI   ScienceOn
27 Lee, J.-K.; Kim, D.-W.; Cheong, M.-S.; Lee, H.-J.; Cho, B.-W.; Kim, H.-S.; Mukherjee, D. Bull. Korean Chem. Soc. 2010, 31, 2195.   DOI   ScienceOn
28 Wong, K.; Zeng, Q. H.; Yu, A. B. J. Phys. Chem. C 2011, 115, 4656.   DOI   ScienceOn
29 Routray, K.; Zhou, W.; Kiely, C. J.; Wachs, I. E. ACS Catal. 2011, 1, 54.   DOI   ScienceOn
30 Herzing, A. A.; Kiely, C. J.; Carley, A. F.; Landon, P.; Hutchings, G. J. Science 2008, 321, 1331.   DOI   ScienceOn
31 Corma, A.; Serna, P. Science 2006, 313, 332.   DOI   ScienceOn
32 Chen, C.-S.; Chen, H.-W.; Cheng, W.-H. Appl. Catal., A 2003, 248, 117.   DOI   ScienceOn
33 Shon, J.-K.; Park, J.-N.; Hwang, S.-H.; Jin, M.; Moon, K.-Y.; Boo, J.-H.; Han, T.-H.; Kim, J.-M. Bull. Korean Chem. Soc. 2010, 31, 415.   DOI   ScienceOn
34 Santos, V. P.; Carabineiro, S. A. C.; Tavares, P. B.; Pereira, M. F. R.; Orfao, J. J. M.; Figueiredo, J. L. Appl. Catal., B 2010, 99, 198.   DOI   ScienceOn
35 Min, M.-K.; Kim, J.-H.; Kim, H.-S. Bull. Korean Chem. Soc. 2010, 31, 151.   DOI   ScienceOn
36 Jiang, H.-L.; Liu, B.; Akita, T.; Haruta, M.; Sakurai, H.; Xu, Q. J. Am. Chem. Soc. 2009, 131, 11302.   DOI   ScienceOn
37 Haruta, M.; Kobayashi, T.; Sano, H.; Yamada, N. Chem. Lett. 1987, 16, 405.
38 Rodriguez, J. A.; Graciani, J.; Evans, J.; Park, J. B.; Yang, F.; Stacchiola, D.; Senanayake, S. D.; Ma, S.; Pérez, M.; Liu, P.; Sanz, J. F.; Hrbek, J. Angew. Chem. Int. Ed. 2009, 48, 8047.   DOI   ScienceOn
39 Burch, R. PCCP 2006, 8, 5483.   DOI   ScienceOn
40 Byun, I.-S.; Choi, O.-L.; Choi, J.-G.; Lee, S.-H. Bull. Korean Chem. Soc. 2002, 23, 1513.   DOI   ScienceOn
41 Grybos, R.; Benco, L.; Bucko, T.; Hafner, J. J. Chem. Phys. 2009, 130, 104503/1.
42 Weerachawanasak, P.; Praserthdam, P.; Arai, M.; Panpranot, J. J. Mol. Catal. A: Chem. 2008, 279, 133.   DOI   ScienceOn
43 Turner, M.; Golovko, V. B.; Vaughan, O. P. H.; Abdulkin, P.; Berenguer-Murcia, A.; Tikhov, M. S.; Johnson, B. F. G.; Lambert, R. M. Nature 2008, 454, 981.   DOI   ScienceOn
44 Haruta, M. Catal. Today 1997, 36, 153.   DOI   ScienceOn
45 Tauster, S. J.; Fung, S. C.; Garten, R. L. J. Am. Chem. Soc. 1978, 100, 170.   DOI
46 Panagiotopoulou, P.; Kondarides, D. I.; Verykios, X. E. J. Phys. Chem. C 2011, 115, 1220.   DOI   ScienceOn
47 Huang, H.; Leung, D. Y. C. ACS Catal. 2011, 1, 348.   DOI   ScienceOn
48 Huang, S.-Y.; Ganesan, P.; Park, S.; Popov, B. N. J. Am. Chem. Soc. 2009, 131, 13898.   DOI   ScienceOn
49 Lopez-Sanchez, J. A.; Lennon, D. Appl. Catal., A 2005, 291, 230.   DOI   ScienceOn
50 Li, Y.; Xu, B.; Fan, Y.; Feng, N.; Qiu, A.; He, J. M. J.; Yang, H.; Chen, Y. J. Mol. Catal. A: Chem. 2004, 216, 107.   DOI   ScienceOn
51 Sohn, J. R.; Lee, J. S. Bull. Korean Chem. Soc. 2003, 24, 159.   DOI   ScienceOn
52 Sharma, S.; Hegde, M. S. J. Chem. Phys. 2009, 130, 114706/1.
53 Miedziak, P. J.; Tang, Z.; Davies, T. E.; Enache, D. I.; Bartley, J. K.; Carley, A. F.; Herzing, A. A.; Kiely, C. J.; Taylor, S. H.; Hutchings, G. J. J. Mater. Chem. 2009, 19, 8619.   DOI   ScienceOn
54 Costi, R.; Saunders, A. E.; Banin, U. Angew. Chem. Int. Ed. 2010, 49, 4878.   DOI   ScienceOn
55 Azad, A.-M.; Duran, M. J.; McCoy, A. K.; Abraham, M. A. Appl. Catal., A 2007, 332, 225.   DOI   ScienceOn
56 Yeung, C. M. Y.; Yu, K. M. K.; Fu, Q. J.; Thompsett, D.; Petch, M. I.; Tsang, S. C. J. Am. Chem. Soc. 2005, 127, 18010.   DOI   ScienceOn
57 Kim, Y.-W.; Kim, M.-J. Bull. Korean Chem. Soc. 2010, 31, 1368.   DOI   ScienceOn
58 Ojeda, M.; Iglesia, E. Angew. Chem. Int. Ed. 2009, 48, 4800.   DOI   ScienceOn
59 Guo, S.; Dong, S.; Wang, E. J. Phys. Chem. C 2008, 112, 2389.   DOI   ScienceOn
60 Yoo, J. W.; Lee, S.-M.; Kim, H.-T.; El-Sayed, M. A. Bull. Korean Chem. Soc. 2004, 25, 843.   DOI   ScienceOn
61 Mallat, T.; Baiker, A. Chem. Rev. 2004, 104, 3037.   DOI   ScienceOn
62 Mager-Maury, C.; Bonnard, G.; Chizallet, C.; Sautet, P.; Raybaud, P. ChemCatChem 2011, 3, 200.   DOI
63 Kaden, W. E.; Wu, T.; Kunkel, W. A.; Anderson, S. L. Science 2009, 326, 826.   DOI   ScienceOn
64 Kwak, J. H.; Hu, J.; Mei, D.; Yi, C.-W.; Kim, D. H.; Peden, C. H. F.; Allard, L. F.; Szanyi, J. Science 2009, 325, 1670.   DOI   ScienceOn
65 Concepcion, P.; Corma, A.; Silvestre-Albero, J.; Franco, V.; Chane-Ching, J. Y. J. Am. Chem. Soc. 2004, 126, 5523.   DOI   ScienceOn
66 Ammari, F.; Lamotte, J.; Touroude, R. J. Catal. 2004, 221, 32.   DOI   ScienceOn
67 von Arx, M.; Mallat, T.; Baiker, A. J. Mol. Catal. A: Chem. 1999, 148, 275.   DOI   ScienceOn
68 Tsuji, H.; Hattori, H. ChemPhysChem 2004, 5, 733.   DOI   ScienceOn
69 Martin, D.; Duprez, D. J. Phys. Chem. B 1997, 101, 4428.   DOI   ScienceOn
70 Carrier, X.; Marceau, E.; Carabineiro, H.; Rodriguez-Gonzalez, V.; Che, M. PCCP 2009, 11, 7527.   DOI   ScienceOn
71 Rodriguez, J. A.; Hrbek, J. Acc. Chem. Res. 1999, 32, 719.   DOI   ScienceOn
72 Dapurkar, S. E.; Shervani, Z.; Yokoyama, T.; Ikushima, Y.; Kawanami, H. Catal. Lett. 2009, 130, 42.   DOI
73 Lucchesi, C.; Inasaki, T.; Miyamura, H.; Matsubara, R.; Kobayashi, S. Adv. Synth. Catal. 2008, 350, 1996.   DOI   ScienceOn