• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.38 no.3 s.116
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• pp.66-71
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• 2006

The objective of this study was to find in what color Hanji(Korean hand-made paper) is dyed when it is dyed with a pigment extracted from clove tree using different kinds of mordant, and how the paper is discolored and variety of strength under the condition of accelerated aging test. The results of this experiment are as follows. The Hanji dyed with aluminum acetate mordant was colored yellowish brown at pH 4.82, discoloration after aging was as much as a slight difference of color was recognized, and the decrease of strength after aging test was small. Thus, the method using aluminum acetate mordant was usable in coloring Hanji. The second most useful Hanji dyeing moth of was using distilled water and ferrous sulfate mordant, which dyed Hanji light brown at pH 6.03. However, when pigment was extracted using distilled water and copper sulfate mordant was used, discoloration was satisfactory but strength decreased too much and pale brown was obtained. Thus, this method was not usable.

• Journal of the Korean Home Economics Association
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• v.41 no.2
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• pp.107-121
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• 2003

This study was discussed the dyeing of wool and nylon fabrics with Chinese Scholar Tree extract. The extracts of Chinese Scholar Tree was prepared in the condition of heating at $95{\pm}5C$, for 1 hour and cooling to 40C. And then the extracts of color matter treate with vacuum concentration at $60{\pm}2^{\circ}C$, 30mmHg and dried with spray dryer. The dyeing of wool and nylon fabric in this experiment was also employed the mordant dyeing method such as pre-mordant, post-mordant and simultaneous mordant method. The mordanting agents used in this study were as followings ; aluminium potassium sulfate, copper(II) acetate monohydrate, chromium potassium sulfate$.$$7H_2O$, Tin(II) chloride dihydrate, iron(II)sulfate $7H_2O$. For an evaluation of the dyeing property of the mordanting agents, the pre-mordant method, the repeat dyeing and the fastness of the light, dry cleaning, washing and rubbing measured respectively. From the results of the dye absorption, the optimum dyeing condition of the wool and nylon fabrics with Chinese Scholar Tree extract is at 80C dyeing temperature for 60 minutes. The optimum concentration of mordanting agent is Al, Cr, Sn 1%, Fe, Cu 2% solution. In general, the fastness property of the dyed wool and nylon fabrics had a comparatively high grade.

• Journal of the Korean Society of Clothing and Textiles
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• v.21 no.5
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• pp.911-921
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• 1997

Recently the interest in natural dyeing has been increased because of the color clarity, natural grace and reactionism in fashion. Indigo dyeing, safflower dyeing and Gal-ott in Cheju-Do become generally known, so the study about the natural dyeing is continued with national intrust and support. In this study, 1 used artemisia for various dyeing tests because we can get it easily. 1 tested the dyeability in wool as well as cotton and silk with wormwood in natural dyeing material. I also dyed nylon with the same material for the comparison of the molecular structure. The mercerization and the chitosan treatment were done in cotton to improve the low dyeability in the natural dyeing. The result of this study are as follows; We have to dye repeatedly to get deep color in natural dyeing, and mordant treatment brought good result in color difference and dyeing fastness. 1. Compared with silk, wool and nylon, the dyeability of cotton was the worse. The color difference of cotton was 18.81 without mordants , and 24.05 with mordant. The dyeability of cotton was much increased by mordants such as potassiumdichromate, copper sulfate, iron sulfate and salt water. The color of cotton was turned into yellow-green in potassium dichromate and yellow-green with deep green in copper sulfate. The mercerization and the chitosan treatment of cotton made the improvement in color, dyeability, laundering fastness, abrasion fastness. 2. The color difference of silk was 3 times as high as cotton. It showed the similar degree with the chitosan treated-cotton. That is to say, silk had good dyeability because it contains amino group and carboxyl group. The dyebility of silk was increased by a mordant such as iron sulfate, potassium dichromate and salt water, Drycleaning fastness showed 5 grade, abrasion-fastness was high over 4~5 grade and sunlight fastness showed 1 grade in all case. 3. The color difference of wool was the best among four fabrics because of 18 kinds of amino acids. It is considered that the sulfate of wool has the polarity and help metal- mordants get the better dyeability such as potassium dichromate, iron sulfate, copper sulfate, and aluminum chloride. The color was reddish-green in potassium dichromate, yellow.greenin iron sulfate and copper sulfate, and yellow in the rest mordants. Drycleaning fastness of wool showed over 4~5 grade, abrasion fastness 5 grade. Sunlight-fastness 1 grade. 4. The dyeability of nylon was almost same because of the similar molecular structure with silk. The clarity of color was poor. The color was yellow-green in copper sulfate and yellow in the rest mordants. Laundering fastness and abrasion-fastness of nylon was good. Sunlight- fastness represented 1 grade.

• Textile Coloration and Finishing
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• v.12 no.2
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• pp.129-137
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• 2000

Silk fabrics were dyed by Cochineal extracts after mordanted with various mordants and their properties of dyeing, fastness and change of surface color were investigated. Silk fabrics were mordanted with aluminum potassium sulfate, copper acetate, tin chloride, iron sulfate or chromium potassium sulfate at $60^\circ{C}$ for 30 minutes and subsequently dyed at $60^\circ{C}$ for 60 minutes unless mentioned otherwise. The dye-uptake of silk fabrics increased with the concentration of Cochineal extracts and mordants used. Maximum dye-uptake was obtained at pH 3.5-4, regardless of the type of mordants used. Surface color of silk fabrics changed from red purple to purple when mordanted with Al or Cu mordant, from purple to purple blue with Fe mordant and showed red purple with Sn or Cr mordant, respectively. It also changed according to pH of dyeing bath. Dyed silk fabrics showed poor light fastness but good dry-cleaning, perspiration and rubbing fastness.

• Textile Coloration and Finishing
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• v.11 no.4
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• pp.39-49
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• 1999

In order to study the properties of cochineal colors, uv-visible spectra of cochineal colors solution, dyeing properties on the wool in several dyeing conditions and thermodynamic parameters were investigated. UV-visible spectra of cochineal colors solution showed hypochromic effect with the lapse of irradiation time but bathochromic shift with decreasing acidity of solution and addition of metallic ions. The concentration of cochineal colors in wool fiber increased with the increase of dyeing temperature, time, and acidity of initial dyebath. The value of apparent diffusion coefficients and standard affinities of dyeing decreased with the increase of dyeing temperature. The standard heats of dyeing$(\Delta{H}^\circ)$ and variation of entropy$(\Delta{S}^\circ)$ increased with the increase of concentration of initial dyebath. The activation energy$(E_a)$ were calculated to be 1.399~2.595kcal/mol in condition of 6~1%(o.w.f) dyebath. Wool fabrics were dyed reddish blue by iron sulfate, copper sulfate, aluminum acetate and tannic acid, and red by tin chloride, respectively. Lightfastness of wool fabrics dyed by cochineal colors were increased by mordant treatment, especially copper sulfate and iron sulfate treatment.

• Fashion & Textile Research Journal
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• v.17 no.5
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• pp.838-843
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• 2015

In this study, a cotton knit was dyed with elm bark extract; subsequently, the dyed fabric was measured according to the types of mordants and the preprocessing cationizers used. Additionally, antibiosis against super bacteria was examined. The results follow. First, the color of the dyed cotton knit appeared reddish and yellowish for fabrics treated with non-mordants and mordants. When preprocessing with a cationizer was conducted, the dyeing properties were the best. Second. even when mordants were not used for dyeing, color fastness after washing, sweating, and rubbing was generally good Grade 4 and 5. Color fastness after exposure to sunlight was the best Grade 4 for fabric prepared with ferrous sulfate as the mordant. Third. as for antimicrobial properties, or resistance to super bacteria, the growth of bacteria was suppressed in a meaningful way for fabrics treated with non-mordants and mordants, compared to the control group fabric. The dyeing methods with the most powerful antimicrobial effects were dyeing after preprocessing with a cationizer and preparing fabric with copper sulfate as the mordant. The results stated above show that in case of dyeing with elm bark extract, preprocessing of the cotton knit with a cationizer and dying with copper mordant displayed high levels of antimicrobial properties that were useful for resisting super bacteria. Of these the dyeing properties were the best when preprocessing with a cationizer.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2012.03a
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• pp.121-121
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• 2012

To evaluate the Hwangsu spring as natural mordants effect on dyeing. The natural mordant effect of Hwangsu spring was analyzed by pH, temperature, trace elements and organic matter. Hwangsu spring having pH 2.42 and $14.4^{\circ}C$ was harvested at the end of September, 2011, in Yeongcheon(Gyeongbuk Province, Korea) and left on a $0^{\circ}C$ and $25^{\circ}C$ before use. The Result of ICP analysis, it contain bned Fe(414.9 ppm), Al(88.9 ppm), Mn(4.9 ppm). Dyeing and post-mordant procedure; Fabrics(cotton, silk, rayon) were dyed with natural colorants(Sopbora Japonica L., Caesalpinia sappan L., Allium cepa L.) for 20 min at $80^{\circ}C$. Hwangsu spring, aluminium sulfate $14-18H_2O(Al_2(SO_4)_3{\cdot}14-18H_2O)$, iron sulfate peptahydrate($FeSO_4{\cdot}7H_2O$), copper sulfate pentahydrate($CuSO_4{\cdot}5H_2O$) were used by post mordants. But in the case of Caesalpinia sappan L. was dyed after pre-mordanting with Al(II). The fabrics were dyed with each mordant solutions at $25^{\circ}C$ for 10min. The colorless also was measured by color-differnce meter. Comparison with a synthetic mordants, the K/S values of cotton fabrics dyed with Hwangsu sping were increased.

• Korean Journal of Human Ecology
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• v.7 no.1
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• pp.167-173
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• 1998

Having silk dyed with some pigment extracted from the skin of an onion, examined the change of color by time and frequency of dyeing and a mordanted cloth, and the antibiosis of a dyed cloth and a mordanted cloth. The result of this were as follows ; 1. The pigment of an onion was easily extracted in the hot water of $40^{\circ}C$ and much more extracted as the temperature of water rises($70^{\circ}C$). 2. As a result of dyeing it by the change of time, 30minutes, 60minutes, 90minutes and the frequency of dyeing, once, twice, three times after filtering the extracted solution, the one dyed three times for 30minutes was the best. 3. The difference of color of a mordanted cloth was the highest in the mordant of $SnCl_2\;2H_2O$ on the basis of the value of L of the non-mordant dyed three times. 4. The mordant of copper sulfate was proved to have the highest antibiosis in the antibiosis of a dyed cloth and a mordanted cloth, and it was proved that the pigment of the skin of an onion had excellent antibiosis.

• Journal of the Korean Society of Clothing and Textiles
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• v.25 no.8
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• pp.1493-1499
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• 2001

This paper investigated the dyeabiltiy and surface color of Han Jee dyed with Gardenia extract after mordanted with mordants under the various dyeing conditions. The results obtained were as follows 1) λmax of the dyeing Han Jee dyed with Gardenia appeared at 660 and 710nm. 2)K/s value of dyeing Han Jee was increased when dyeing condition, temperature, time was higher. 3) Surface color of Han Jee with mordants changed differently according to the mordants used : 3.2Y by Aluminum acetate, 2.0GY by Copper sulfate, 9.5YR by Iron sulfate. 3.4Y by Tin chloride, and 4.5Y by non-mordanting.

• Korean Journal of Human Ecology
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• v.10 no.3
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• pp.263-274
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• 2001

This study investigated the dyeability on silk, wool and rotten fabrics dyed with Magnolia liliflora leafs. In addition, the fastness of washing, perspiration, rubbing, drycleaning and the effects of its pigment on bacterial reduction and uv-B protection were also investigated. The results were as follows : It was found that uv-visible absorption spectrum showed two strong absorption peaks in the range of $250{\sim}340nm$. The optimum dyeing condition of the pigments extracted from the Magnolia liliflora leafs was dyeing with 0.5% mordants and three repeated dyeing at $95^{\circ}C$ for 1hr. When the wool fabric was dyed with Magnolia liliflora leaf, dyeing properties was the best among the three fabrics. Washing fastness of dyed fabrics was very low, drycleaning fastness was good and the other fastness were good. Light fastness of three fabrics dyed by Magnolia liliflora leafs increased by mordant treatment, especially copper sulfate treatment. The bacterial reduction and uv-B protection of dyed wool fabric with Magnolia liliflora leafs also increased.