• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.514-519
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• 2001

Converter has been slag produced 10 million tons per year in Japan. It is a steel making by product produced in the same way as the blast-furnace slag. Though blast-furnace slag is being used effectively as a concrete admixture, the converter stag has never been used effectively because of the expansion action of contained free lime and iron oxide. This is an important environmental problem in the steel industry. Beta-2CaOSiO$_2$(beta-C$_2$S) is contained 40 percent in converter slag, therefore it is very promising as a concrete admixture. We proposed an accelerated aging processes capable of stabilizing the converter slag in a short time. The converter slag is dipped into alkali aqueous solution after heating at low temperature. It was subsequently ground to a grain size of 75 ${\mu}{\textrm}{m}$ , inner 30 percent of OPC. The properties of mortar and concrete using the blended cement were determined. As a result, it has become apparent that the expansion was reduced and long term compressive strength was increased while that at early ages was not so remarkable. The hydration exotherm rate was lower than that of the OPC.

• Journal of Korean Society of Water and Wastewater
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• v.29 no.5
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• pp.565-573
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• 2015

The influencing factors to remove phosphate were evaluated by converter slag (CS). Experiments were performed by batch tests using different CS sizes and column test. Solutions were prepared at the different pH and concentrations. The maximum removal efficiency was obtained over 98% with the finest particle size, $CS_a$ within 2 hours in batch tests. The removal efficiency was increased in the order of decreasing size with same amount of CS for any pH of solutions. The adsorption data were well fitted to Freundlich isotherm. From the column experiment, the specific factors were revealed that the breakthrough removal capacity (BRC) $x_b/m_{cs}$, was decreased by increasing the influent concentration. The breakthrough time, tb was lasted shorter as increasing the influent concentration. The pH drop simultaneously led to lower BRC drop during the experimental hours. The relation between the breakthrough time and the BRC to influent concentration was shown in the logarithmic decrease. Results suggested that the large surface area of CS possessed a great potential for adsorptive phosphate removal. Consequently particle size and initial concentration played the major influencing factors in phosphate removal by converter slag.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.8 no.1
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• pp.136-142
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• 2007

Recent publications have paid attention on the utilization of solid reagents for the removal of substances causing eutrophication, in particular $PO_4^{3-}$ ions. The adsorption of dissolved inorganic phosphate on slag produced by the refining process of iron ore was fundamentally studied for suppressing the liberation of phosphate from wastewater. This study has been conducted in order to find a possibility to improve the phosphate removal and to evaluate the phosphate removal variation to form hydroxyapatite, when the converter slag is used for phosphate removal. The result shows that the converter slag can be applied to remove phosphate using Freundlich isotherm. The size of converter slag, $2{\sim}0.425 mm$ was more efficient than $2{\sim}4.75mm$ to remove phosphate. In particular, 1 mg/L of phosphate can be removed up to 80% of the initial concentration for the continuous column experiment.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.02a
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• pp.93-112
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• 2000

The permeability of converter slag, replacing material of sand mat on improving soft clay foundation, was evaluated in the laboratory. The effects of grain size, flow water time and aging were investigated using sea and fresh water. Converter slag being submerged with fresh water, the coefficients of permeability in A and B samples less than 10mm grain sizes were measured as 6.52${\times}$10$\^$-2/cm/sec and 5.99${\times}$10$\^$-1/cm/sec, while changed as 1.88${\times}$10$\^$-2/cm/sec, 3.86${\times}$10$\^$-1/cm/sec under sea water condition. Also, the condition of turbulent flow may exit and was experimentally identified from the relationship between hydraulic gradient and seepage velocity. After 180 days on using sea water, the coefficients of permeability of sample A and B samples decreased ten times smaller than those initial values. And after that time continually decreased as for till 360 days. The reduction of permeability coefficient was considered to influence filled with voids in high-calcium quicklime(CaO). However, in-situ coefficient of permeability was practically satisfactory.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.02a
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• pp.12-31
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• 2000

The permeability of converter slag, replacing material of sand mat on improving soft clay foundation, was evaluated in the laboratory. The effects of grain size, flow water time and aging were investigated using sea and fresh water. Converter slag being submerged with fresh water, the coefficients of permeability in A and B samples less than 10mm grain sizes were measured as 6.52${\times}$10$\^$-2/cm/sec and 5,99${\times}$10$\^$-1/cm/sec, while changed as 1,88${\times}$10$\^$-2/cm/sec, 3.86${\times}$10$\^$-1/cm/sec under sea water condition. Also, the condition of turbulent flow may exit and was experimentally identified from the relationship between hydraulic gradient and seepage velocity. After 180 days on using sea water, the coefficients of permeability of sample A and B samples decreased ten times smaller than those initial values. And after that time continually decreased as for till 360 days. The reduction of permeability coefficient was considered to influence filled with voids in high-calcium quicklime(CaO). However, in-situ coefficient of permeability was practically satisfactory.

• Magazine of the Korean Society of Agricultural Engineers
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• v.43 no.5
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• pp.93-105
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• 2001

The permeability of converter slag, replacing material of sand mat on improving soft clay foundation, was evaluated in the laboratory as well as in situ test. Effects of grain size, flow water time and aging were investigated using sea and fresh water Converter slag which has a grain size less than 10mm were submerged with fresh water and sea water. In fresh water, the coefficients of permeability in samples A and B were measured as 4.50${\times}$10$^{-2}$ cm per second and 1.20${\times}$10$^{-1}$ cm per second, respectively while as 1.88$\times$10$^{-2}$ cm per second and 3.86$\times$10$^{-1}$ cm per second in sea water. The condition of turbulent flow may exit and was experimentally certified based on the relationship of hydraulic gradient and seepage velocity. After 180 days in using sea water, the coefficients of permeability of samples A and B decreased ten times smaller than those initial values, and after that time continually decreased as for till 360 days. Finally, filling with voids in high-calcium quicklime(CaO) may result in the reduction of coefficient of permeability. In-situ coefficient of permeability however was Practically satisfactory.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.6
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• pp.841-849
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• 2012

The effluent quality of phosphorus is strengthened by the national standard to conserve water resources to lessen the eutrophication threat. The soluble phosphate in the wastewater effluent can be removed using the converter slag as solid waste produced through the steel making process. The experiments for removal efficiencies and removal constants were performed for this research with the artificial wastewater following several different conditions, particle size, phosphate concentration and initial pH. The correlation coefficients of Freundlich adsorption isothem were 0.9505 for $PS_A$, 0.9183 for $PS_B$, respectively. The removal efficiency was 87-94 % for $PS_A$ and 90-96 % for $PS_B$ respectively. The pH of the wastewater was elevated to pH 11.8 for the initial pH 8.5, phosphate removal efficiency was the highest as 84 % ~ 98 %. In case of 10 mg/L of the intial phosphate, the removal efficiency was 96 ~ 98 %. The more initial pH increases, the higher the reaction rate constant is.

• Journal of the Korean Geotechnical Society
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• v.15 no.4
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• pp.69-83
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• 1999

The permeability of converter slag, replacing material of sand mat on improving soft clay foundation, was evaluated in the laboratory. The effects of grain size, flow water time and aging were investigated using sea and fresh water. In the case of converter slag submerged with fresh water, the coefficients of permeability in A and B samples less than 10 mm grain sizes were measured as $6.52\times10^{-2}cm\; per\; sec\; and\; 5.99\times10^{-1}/cm$ per sec respectively, while they were $1.88\times10^{-2}/cm\; per\; sec,\; 3.86\times10^{-1}/cm$ per sec respectively under sea water condition. Also, the condition of turbulent flow may exit and was experimentally identified from the relationship between hydraulic gradient and seepage velocity. After 100 days under sea water condition, the coefficients of permeability of A and B samples decreased ten times than initial values. The reduction of permeability coefficient was considered to result from the filling of voids in high-calcium quicklime(CaO).

• Journal of Korean Society of Environmental Engineers
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• v.22 no.6
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• pp.1139-1148
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• 2000

To treat and recycle a large quantity of converter slag. the milling properties of -14/ +24 mesh-sized slag has been considered. The optimal conditions in milling process were investigated for producing powder-type slag and the required consumption was derived for the economical grinding. The characteristics of milling processes were studied in the variation of the rotational speed, milling time, filling ratio of ball, and size and amount of feed. The grinding efficiency was also examined. The optimal rotational speed in this experimental condition was observed to be the value of 79% of critical speed. The extent of grinding was increased with increasing the grinding time. but the efficiency of milling was decreased with the time. 50% ball filling was shown to have the optimal grinding effect, and less amount and small-sized feed made the milling efficiency high. As the result, using Bond's equation, power required for efficient milling was considered and the highest value was observed in the condition of high grinding time and optimal rotational speed.

• Journal of Korean Society on Water Environment
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• v.21 no.1
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• pp.59-65
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• 2005

A phosphate recovery system from artificial wastewater was developed using a completely mixed phosphorus crystallization reactor, in which powdered converter slag was used as a seeding crystal. In preliminary test, the optimal pH range for meta-stable hydroxyapatite crystallization for high phosphorus concentration was observed to be 6.0 to 7.0, which was different from the conventionally known pH range (8.0~9.5) for effective crystallization in relatively low phosphorus concentration less than 5 mg/L. The average phosphorus removal efficiency in a lab-scaled completely mixed crystallization system for artificial wastewater with about 100 mg/L of average $PO_4-P$ concentration was shown to be 60.9% for 40 days of lapsed time. XRD analysis exhibited that crystalline of hydroxyapatite formed on the surface of seed crystal, which was also observed in SEM analysis. In EDS mapping analysis, composition mole ratio (=Ca/P) of the crystalline was found to be 1.78, indicating the crystalline on the surface of seed crystal is likely to be hydroxyapatite. Particle size distribution analysis showed that average size of seed crystal increased from $28{\mu}m$ up to $50{\mu}m$, suggesting that phosphorus recycling from wastewater with high phosphorus concentration can be successfully obtained by using the phosphorus crystallization recovery system.