• 한국응용과학기술학회지
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• 제30권4호
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• pp.726-739
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• 2013

피셔-트롭쉬 합성 반응은 촉매 표면에서 합성가스 (CO+$H_2$)를 탄화수소로 전환하는 반응이다. 코발트 또는 철계 촉매는 친환경적인 디젤 연료를 생산할 수 있고 합성가스의 전환율이 높은 촉매로 알려져 있다. 피셔-트롭쉬 반응에 사용되는 촉매의 활성은 촉매 표면에서의 활성점에 의존적이다. 활성점은 활성 물질의 크기, 담지량, 환원율, 지지체와 활성물질의 상호작용에 의해 결정된다. FT 촉매 제조 방법으로 활성물질의 크기를 조절하는 등의 새로운 방법들이 시도되고 있다. 여기에서는 촉매의 제조방법과 환원 특성을 비롯한 촉매의 형태와 반응 조건을 포함한 반응기 형태에 대해 알아보겠다.

• BMB Reports
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• 제31권2호
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• pp.201-208
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• 1998

Amino acid analogs, like other inducers of stress response, induce the synthesis of stress proteins in mammalian cells. In this study, Drosophila Kc cells, in which translation is tightly controlled during stress response, was treated with proline analogs, L-azetidine-2-carboxylic acid (AzC) and 3,4-dehydro-L-proline (dh-P). Kc cells exposed to AzC or dh-P induced the synthesis of several proteins which had the same molecular weights as known heat shock proteins. However, in Kc cells, normal protein synthesis still continued in the presence of amino acids analogs unlike in heat-shocked cells. For the induction of stress response, the incorporation of dh-P into the protein was not essential, but the incorporation of AzC was. The stress protein synthesis was regulated mainly at the transcriptional level by AzC, whereas it was regulated by dh-P at the transcription level and possibly posttranscription level. During recovery, the stress protein synthesis stopped sooner in analog-treated cells than in heat-shocked cells even though the accumulated amount of Hsp70 was much less in proline analogstreated cells. It could be concluded that the proline analogs, AzC and dh-P, induced stress response through a different mechanism from heat shock.

• 폴리머
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• 제25권5호
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• pp.609-616
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• 2001

본 연구에서는 copper phthalocyanine (CUPc)을 높은 합성 수율로서 성공적으로 합성시킴에 따라 용매를 사용하는 고분자의 합성 분야에 마이크로파 기술의 응용 가능성을 제시하고자 하였다. 가정용 전자레인지의 용기를 개조시키고 마이크로파 출력 조절기를 부착시키는 방법으로 본 실험에 사용되는 가변식 마이크로파 합성 장치를 자체 제작하였다. 화학 분석법, X선 회절장치(XRD), 주사형 전자현미경 (SEM) 및 입도 분석법 (PSA)을 이용하여 재래식 열 공정 및 마이크로파 공정을 사용하여 여러 조건하에서 합성된 시료들의 특성을 비교 분석하였다.

• 한국동물번식학회:학술대회논문집
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• 한국동물번식학회 2002년도 춘계학술발표대회 발표논문초록집
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• pp.50-50
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• 2002

During fertilization, morphological and molecular events in male and female chromatin are precisely controlled in time. However, little information is available on onset of pronuclear formation and first S-phase entry in the pig following intracytoplasmic sperm injection. To assess species specific paternal effect on the pronuclear formation and initiation of first S-phase in the pig, we examined time of onset of male and female pronuclear formation and onset of DNA synthesis in the oocytes following pig or mouse sperm injection. (omitted)

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2000년도 추계학술대회 및 발표대회 강연 및 발표논문 초록집
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• pp.11-12
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• 2000

Non-stoichiometric ceramics of $Ni_{x}ZnO_{1-x}Fe_{2}O_{4}$ were prepared by self-propagating high temperature synthesis reaction with various processing conditions and their stoichometric numbers were determined by neutron diffraction. The neutron diffraction patterns were measured at room temperature using monochromatic neutrons with a wave length of 0.18339 nm from a Ge(331) mocochromator at a 90 degree take off angle. The Rietveld refinement of each pattern converged to good agreement (x2=1.88-2.24). The neutron diffraction analysis revealed the final stoichiometries of the ferrites were $Ni_{0.38}Zn_{0.62}Fe_{2}O_{4}$ and $Ni_{0.33}Zn_{0.67}Fe_{2}O_{4]$, respectively. This supports that final stoichiometric number of the self-propagating high temperature synthesis product can be controlled by the processing parameters during the combustion reaction.

• 한국세라믹학회지
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• 제35권7호
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• pp.749-756
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• 1998

TiC-Ni and TiC-Ni-Mo cermet powders were produced by Self-propagating High temperature Synthesis (SHS) process. The cooling rate of synthesized powders were controlled by using the V-shaped copper jig and the carbide size decreased with increasing the cooling rate I. e decreasing the width of copper jig Round shape carbide particles were produced after SHS reaction in TiC-Ni as well as TiC-Ni-Mo powders. Local segregation of Mo rich phases was observed in SHS powder of TiC-Ni-Mo and the uneven dis-triobution of Mo promoted the faster growth rate of carbide particles during sintering compared to the same composition specimen with commercial TiC powder. Howogeneous microstructure of TiC-Ni-Mo cermet was obtained when the elemental Mo powder was mixed with the SHS powder of TiC-Ni.

• 대한화학회지
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• 제34권4호
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• pp.370-376
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• 1990

질화 알루미늄을 AlO(OH)로부터 가장 낮은 온도에서 얻은 γ- alumina와 무수 염화 알루미늄 그리고 금속 알루미늄 분말을 출발물질로 하여 합성하는 연구를 하였다. 특히 반응온도에 주목하고 질화 알루미늄을 합성하였고 그 반응 조건들을 결정하였으며 그 결과에 대하여 논의하였다. 금속 알루미늄과 질소 가스의 반응은 비교적 낮은 온도에서 진행 되었고, 이 반응에 대한 반응 파라미터를 속도론적으로 연구하였다.

• 한국정밀공학회지
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• 제16권8호
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• pp.122-129
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• 1999

A 5-axis CNC machine tool is more useful compared with a 3-axis machine tool, because the position and the orientation of a tool tip can be controlled simultaneously. Unlike the 3-axis machine tool, the 5-axis machine tool has the volumetric position error and volumetric orientation error due to the quasi-static error of each machine tool joint which is a major source of machined part error. So, the generalized error synthesis model of the 5-axis CNC machine tool was developed to predict and to compensate for the volumetric position error and the volumetric orientation error. It was proposed that a compensation algorithm to correct simultaneously the volumetric position error and the volumetric orientation error of the 5-axis CNC machine by error inverse kinematic.

• Macromolecular Research
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• 제16권2호
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• pp.85-102
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• 2008

The development of reliable synthetic routes to polymer nanomaterials with well-defined size and morphology is a critical research topic in contemporary materials science. The ability to generate nanometer-sized polymer materials can offer unprecedented, interesting insights into the physical and chemical properties of the corresponding materials. In addition, control over shape and geometry of polymer nanoparticles affords versatile polymer nanostructures, encompassing nanospheres, core-shell nanoparticles, hollow nanoparticles, nanorods/fibers, nanotubes, and nanoporous materials. This review summarizes a diverse range of synthetic methods (broadly, hard template synthesis, soft template synthesis, and template-free synthesis) for fabricating polymer nanomaterials. The basic concepts and significant issues with respect to the synthetic strategies and tools are briefly introduced, and the examples of some of the outstanding research are highlighted. Our aim is to present a comprehensive review of research activities that concentrate on fabrication of various kinds of polymer nanoparticles.

• 한국정밀공학회지
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• 제15권11호
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• pp.67-75
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• 1998

Geometric and thermal errors are key contributors to the errors of a computer numerically controlled turning center. A planar error synthesis model is obtained by synthesizing 11 geometric and thermal error components of a turning center with homogeneous coordinate transformation method. This paper shows the sensitivity analysis on the temperature change, the confidence evaluation on the uncertainty Of measurement systems, and the error contribution analysis from the planar error synthesis model. Planar error in the z direction was very sensitive to the temperature change. and planar errors in the x and z directions were not affected by the uncertainty of measurement systems. The error contribution analysis ,which is applicable to designing a new turning center, was helpful to find the large error components which affect planar errors of the turning center.