• Title/Summary/Keyword: controlled porous glass

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Microstructure and Physical Properties of Porous Material Fabricated from a Glass Abrasive Sludge (유리연마슬러지를 사용한 다공성 소재의 미세구조 및 물리적 특성에 관한 연구)

  • Chu, Yong-Sik;Kwon, Choon-Woo;Lee, Jong-Kyu;Shim, Kwang-Bo
    • Journal of the Korean Ceramic Society
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    • v.43 no.5 s.288
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    • pp.277-283
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    • 2006
  • A porous material with a surface layer was fabricated from glass abrasive sludge and expanding agents. The glass abrasive sludges were mixed with expanding agents and compacted into precursors. These precursors were sintered in the range of $700-900^{\circ}C$ for 20 min. The sintered porous materials had a surface layer with smaller pores and inner parts with larger pores. The surface layer and closed pores controlled water absorption. As the expanding agent fraction and the sintering temperature increased, the porosity and pore size increased. The porous materials with $Fe_2O_3$ and graphite as the expanding agents had a low absorption ratio of about 3% or lower while the porous material with $CaCO_3$ as the expanding agent had a higher absorption ratio and more open pores.

Fabrication of Porous Material Using Glass Abrasive Sludge

  • Chu, Yong-Sik;Kwon, Chun-Woo;Lee, Jong-Kyu;Shim, Kwang-Bo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.606-607
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    • 2006
  • A porous material with a surface layer was fabricated using glass abrasive sludge and expanding agents. The glass abrasive sludges were mixed with expanding agents and compacted into pellets. These pellets were sintered in the range of $700-900^{\circ}C$ for 20min. The sintered porous materials had a surface layer with smaller pores and inner parts with larger pores. The surface layer and pores controlled the absorption ratio and physical properties.

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Purification of the Candida utilis Extracellular Invertase using Affinity Chromatography

  • Ginalska, G.;Belcarz, A.;Lobarzewski, J.;Leonowicz, A.;Cho, Nam-Seok
    • Journal of the Korean Wood Science and Technology
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    • v.30 no.3
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    • pp.12-17
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    • 2002
  • The extracellular invertase (EC 3.2.1.26) (Candida utilis) preparation was obtained from the liquid medium after desalting and freeze drying. This prepared enzyme was used for the comparative purification on 4 activated matrices by liquid column affinity chromatography method. In this method there were used controlled porous glass (CPG) silanized covalently activated by keratin, silanized silica gel and silica gel covalently covered by keratin. It was found that the invertase purification process was better using both CPG matrices (silanized CPG and keratin activated CPG) than these with two silica gel supports. Also the elution coefficient of the invertase from the two CPG columns was about 93 to 94%. Two silica gel supports found to be superior in terms of purification efficiency. The invertase purification process was confirmed by PAGE electrophoresis.

Adsorption of Nicotinic Acid on the Porous Powders (니코틴 산의 다공성 분체 흡착)

  • Shin, Sang-Chul;Cho, Cheong-Weon
    • Journal of Pharmaceutical Investigation
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    • v.27 no.1
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    • pp.39-49
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    • 1997
  • Nicotinic acid was mixed with glass powders such as controlled pore glass (CPG), glyceryl controlled pore glass (GPG) and glass beads (GB) at room temperature. The physicochemical properties of nicotinic acid in the various mixtures were examined by differential thermal analysis, X-ray diffraction study. Infrared spectroscopy and BET gas adsorption measurements. The peak area at the melting point from the various mixtures of nicotinic acid and CPG was increased with an increase of nicotinic acid concentration while the broad peak area was remained unchanged in the DTA curve. As shown in the powder X-ray diffraction patterns, the crystalline peaks of nicotinic acid disappeared in mixture with CPG, suggesting the interaction of nicotinic acid and porous powders. It was found that the larger the content of CPG, the higher the ratio of an amorphous state to a crystalline state. BET isotherm showed that as the amount of nicotinic acid was increased, the specific surface area was reduced proportionally to nicotinic acid content of up to 40% and remained constant thereafter. Sublimation of nicotinic acid from the mixture of nicotinic acid and CPG was examined. A large quantity of nicotinic acid was retained in the mixture when stored on various temperatures in vacuo for 10 hours. The nicotinic acid mixtures with CPG or GPG showed a high dissolution rates of nicotinic acid in aqueous solution, especially in the initial dissolution stage. CPG is expected to be a good pharmaceutical excipient to reduce the crystallinity of drugs and to prevent sublimation of drugs.

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Non-Contact Level on Air Levitation Table with Porous Chamber Array (다공성 패드를 갖는 챔버의 배열에 따른 공기 부상 테이블의 비접촉 부상 수준에 대한 연구)

  • Kim, Joon Hyun;Jeong, Young Suk;Lee, Tae Geol;Kim, Tae Hoon;Jung, Hyo Jae
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.6
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    • pp.913-920
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    • 2013
  • This paper presents an applicable basic design that can configure non-contact levitation table for conveying a large sheet of glass. The suggested air levitation table consists of a series of air chambers with porous pads and fans as the conveyor system. The air supply chambers are arrayed to supply an adequately strong upward airflow for supporting the glass. Levitation is controlled by the size and discharge velocity, of the chamber arrays, as well as the glass supporting height. After pre-evaluation of the glass rigidity and the filer functional performance, a one-way fluid structure interface (FSI) analysis is performed for predicting pressure and deflection working of the 8G glass in the transverse and longitudinal directions, respectively. After comparing calculated levels of flatness of the glass, it determines the chamber array for the linear non-contact conveying motion.

Interaction of Solid Particles with the Solidifying Front in the Liquid-Particle Mixture (액상-고체입자 혼합물의 응고 시 응고계면에서의 입자의 거동)

  • Lee, Ho-Suk;Lee, Kyu-Hee;Oh, Sung-Tag;Kim, Young Do;Suk, Myung-Jin
    • Journal of Powder Materials
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    • v.25 no.4
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    • pp.336-339
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    • 2018
  • A unique porous material with controlled pore characteristics can be fabricated by the freeze-drying process, which uses the slurry of organic material as the sublimable vehicle mixed with powders. The essential feature in this process is that during the solidification of the slurry, the dendrites of the organic material should repel the dispersed particles into the interdendritic region. In the present work, a model experiment is attempted using some transparent organic materials mixed with glass powders, which enable in-situ observation. The organic materials used are camphor-naphthalene mixture (hypo- and hypereutectic composition), salol, camphene, and pivalic acid. Among these materials, the constituent phases in camphor-naphthalene system, i.e. naphthalene plate, camphor dendrite, and camphor-naphthalene eutectic exclusively repel the glass powders. This result suggests that the control of organic material composition in the binary system is useful for producing a porous body with the required pore structure.

Technology Trend for the Preparation of Polymeric Particles by SPG Technique (SPG 막유화법을 이용한 고분자 입자 제조기술의 동향)

  • Lee, Sang-Kug;Kim, Sung-Wook;Choi, Kyoung-Ho;Lim, Eun-Hee
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.222-231
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    • 2009
  • Shirasu-porous-glass (SPG) membrane emulsification is highly attractive in the field of toner industries, foods and drug delivery systems because of its easy control of particle size in micro-scale, narrow size distribution and multiple emulsion. The particle size and morphology of emulsion droplets can be controlled by changing the type of initiators, additives, monomers, crosslinkers and inhibitors in SPG membrane emulsification. In this paper, principles of SPG membrane emulsification, influence of process parameters and industrial applications have been addressed.

Cracking Behavior Under Contact Stress in Densely Coated Porous Engineering Ceramics (치밀층으로 코팅된 다공성 엔지니어링 세라믹스에서의 접촉응력에 의한 균열 거동)

  • Kim, Sang-Kyum;Kim, Tae-Woo;Kim, Do-Kyung;Lee, Kee-Sung
    • Journal of the Korean Ceramic Society
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    • v.42 no.8 s.279
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    • pp.554-560
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    • 2005
  • The engineering ceramic needs the properties of high strength, hardness, corrosion-resistance and heat-resistance in order to withstand thermal shock or applied nonuniform stresses without failure. The densely coated porous ceramics can be used for machine component, electromagnetic component, bio-system component and energy-system component by their high-performances from superior coating properties and light-weight characteristics due to the structure including pore by itself. In this study we controlled the porosity of silica and alumina, $8.2\~25.4\%$ and $23.4\~36.0\%$, respectively, by the control of sintering temperature and starting powder size. We made bilayer structures, consisting of a transparent glass coating layer bonded to a thick substrate of different porous ceramics by a thin layer of epoxy adhesive, facilitated observations of crack initiation and propagation. The elastic modulus mismatch could be controlled using different porous ceramics as the substrate layer. Then we applied 150 N force using WC sphere with a radius of 3.18 mm by Hertzian indentation. As a result, the crack initiation in the coating layer was delayed at lower porosity in the substrate layer, and the damage in the coating layer was relatively smaller at the bilayer structure coated on higher elastic substrate.

Reinforcement of Porous Mullite Ceramics Using Ultra Fine Mullite Precursor Powders

  • Cho, Yong-Ick;Hisao Suzuki;Hidehiro Kamiya
    • The Korean Journal of Ceramics
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    • v.5 no.2
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    • pp.137-141
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    • 1999
  • To increase the strength of high-purity porous mullite ceramics, ultra fine mullite precursor powders of about 10nm in diameter were deposited at point of contact between primary coarse mullite particles of about 60$\mu\textrm{m}$. The deposited and hetero coagulated structures of ultra fine mullite precursor powders were controlled by pH. The optimum pH condition to form a uniform deposition of mullite powders between coarse mullite particles was in the range from 7 to 8. Deposition of the ultra fine powders did not form at pH < 7 and pH > 10 irregular deposition was observed from pH 8 to 9.

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Pore properties and Microstructure on the each regions of a Light-Weight Aggregate using Glass Abrasive Sludge (유리연마슬러지를 사용한 경량골재의 미세구조 및 기공 특성)

  • Kwon, Choon-Woo;Chu, Yong-Sik;Kim, Young-Yup;Jung, Suk-Joe;Song, Hun;Lee, Jong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.533-536
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    • 2006
  • A light-weight aggregate with a surface layer was fabricated using glass abrasive sludge and expanding agents. The glass abrasive sludges were mixed with expanding agents ($Fe_2O_3,\;graphite,\;CaCO_3$) and formed into precursors. These precursors were sintered in the range of $700-900^{\circ}C$ for 20min. The sintered light-weight aggregate had a surface layer with smaller pores and an inner region with larger pores. The surface layer and pores controlled the water absorption ratio and physical properties. As the expanding agent fraction and the sintering temperature increased, the porosity and pore size increased. The light-weight aggregate with $Fe_2O_3$ and graphite as the expanding agents had a low water absorption ratio while the porous material with $CaCO_3$ as the expanding agent had a higher water absorption ratio and more open pores.

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