• Title/Summary/Keyword: contaminated part

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A geochemical study on the metal contamination of groundwater in Taegu City (대구시 지하수의 금속 오염에 대한 지화학적 연구)

  • 이재영;김영기;이진국;서정율
    • The Journal of Engineering Geology
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    • v.2 no.2
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    • pp.173-200
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    • 1992
  • The quality of groundwater in the central part of Taegu City is influenced by upstreams of Sin-stream and Beomeo-stream because the stream waters are main source of the groundwater, and chemical composition of the upstream waters has close relationship with andesite and monzonite in the igneous rock terrain. The pH of upstreams are weak acid ~ neutral in the igneous rock area and weak alkaline in the sedimentary rock area. Contents of $Ca^{2+}$ and $Mg^{2+}$ in the streams are apparently high, and $Na^{+}$ content is only slightly high in the sedimentary rock area. But $K^{+}$ content is lower in the Panyaweol formation area than in the monzonite area. The contents of heavy metals and $N0_3^{-}$ are also higher in the sedimentary rock area of residential sections and industrial complexes than those in the igneous rock area. The groundwater is contaminated in comparison to the upstream water of the igneous rock areas, and there are some differences in pollution level between the Panyaweol formation area of residential sections and the Haman formation area of industrial complexes. K, Na, Ca, Mg, Cl, $SO_4$ and $NO_3$ contents in the Haman formation area are relatively higher than those in the Panyaweol formation area. But pH is nearly equal in the two areas. The content of heavy metal ions is still lower than the drinking water standard of Korea and only slightly differs in the two sedimentary rock areas. But the groundwater in the Haman formation area is considerably contaminated by Kongdanstream and Dalseo-stream.

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Heavy Metal Uptake of Acacia from Tailing soil in Abandoned Jangun Mine, Korea (장군광산 광미 토양으로부터 아카시아의 중금속 전이에 관한 연구)

  • Jeong, Hong-Yun;Kim, Young-Hun;Kim, Jeong-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.28 no.2
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    • pp.173-185
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    • 2015
  • Janggun mine (longitude $129^{\circ}$ 03'38.91" Latitude $36^{\circ}$ 51'31.59") had been operated as an underground mine for last few decades. As the part of the remediation process, the surface of tailing dump was covered with uncontaminated soil about 20 cm in depth and acacia trees were planted. Heavy metal uptake of acacia from tailing soil has continued for the past 15 years. Heavy metal concentration ranges of tailing soil that contaminated with As (66.43-9325.34 mg/kg), Cd (0.96-1.09 mg/kg), Cu (16.90-57.60 mg/kg), Pb (57.33-945.67 mg/kg), and Zn (154.48-278.61 mg/kg) have higher than those of control soil As (38.98 mg/kg), Cd (0.42 mg/kg), Cu (10.26 mg/kg), Pb (8.21 mg/kg), Zn (46.74 mg/kg). The As, Cd, Cu, Pb and Zn concentrations of leaf of acacia in highly contaminated tailing dump were 165.95, 0.04, 10.68, 3.18, 48.11 mg/kg, respectively. The metal contents of leaf of acacia tree that obtained from uncontaminated control soil are 1.31 of As, 3.90 of Cu, 0.22 of Pb and 11.01 mg/kg of Zn. It was investigated that in the acacia tree, heavy metals such as As, Cu, Pb and Zn tend to be more highly concentrated in bark and leaf, compared with sapwood and heartwood.

Chemical Remediation and Recirculation Technologies of Wastewater from Metal-Contaminated Soil Washing (금속오염(金屬汚染) 토양세척(土壤洗滌) 폐수(廢水)의 화학적(化學的) 처리(處理)와 재순환(再循環) 기술(技術))

  • Lim, Mi-Hee;Abn, Ji-Whan
    • Resources Recycling
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    • v.20 no.3
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    • pp.28-39
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    • 2011
  • This review investigated theoretical principals and practical application examples on recirculation system of soil washing-wastewater treatment-treated water recycling. As for technologies which have attempted to remediating metals-contaminated soil in and around country, there are reactive barriers, encapsulation, solidification/stabilization, soil washing, and phytoremediation. Among those, in particular, this review covers soil washing technology which physicochemically removes contaminants from soils. The major drawbacks of this technology are to generate a large amount of wastewater which contains contaminants complexed with ligands of washing solution and needs additional treatment process. To solve these problems, many chemical treatment methods have been developed as follows: precipitation/coprecipitation, membrane filtration, adsorption treatment, ion exchange, and electrokinetic treatment. In the last part of the review, recent research and field application cases on soil washing wastewater treatment and recycling were introduced. Based on these integrated technologies, it could be achieved to solve the problem of soil washing wastewater and to enhance cost effective process by reducing total water resources use in soil washing process.

The Extraction Characteristics of Metal-contaminated Soil by Soil Washing (토양세척기법을 이용한 중금속 오염토양 처리에서 중금속 추출특성)

  • Hwang, Seon-Suk;Lee, Noh-Sup;NamKoong, Wan
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.10
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    • pp.1072-1080
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    • 2005
  • The extraction characteristics of heavy metals(HM) from a contaminated soil at existing lead smelters were investigated with ethylene diamine tetraacetic acid(EDTA), citrate and HCl as washing solutions. EDTA was more effective for Pb than for other heavy metals. As the mol ratio of EDTA/HM increased, the removal efficiency of heavy metals became higher. When the mol ratio of EDTA/HM approached to 6.5, it removed Pb most effectively. Citrate was effective especially in extracting Zn. The removal efficiency of HCl was comparatively high in almost all heavy metals, and at 0.3N concentration it was the highest. After soil washing process by the use of EDTA, the great part of exchangeable fractions and most of heavy metals of weakly adsorbed like carbonate fraction were extracted. For washing with citrate and HCl, four heavy metals showed the similar exchange of chemical partitioning and the exchangeable fractions of Pb which has weakly adsorbed to soil were more increased than before the process. As removal efficiency of citrate washing process depends upon the distribution of non-detrital fractions, so it can be contended that only the amount of non-detrital fractions could be removed from all the heavy metal content. EDTA and HCl could remove most of non-residual fractions in all heavy metals except Zn. As a result of EDTA washing, toxicity characteristic leaching procedure(TCLP) concentration of the processed soil met the USEPA Pb limit of 5.0 mg/L.

Development of a Bioscrubber for Treatment of VOC Emissions from Contaminated Soil with Hydrocarbons (유류오염토양으로부터 발생하는 VOC가스처리를 위한 바이오스크러버 개발)

  • 장윤영;황경엽;곽재호;최대기
    • Journal of Korea Soil Environment Society
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    • v.2 no.1
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    • pp.83-90
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    • 1997
  • Aiming at the treatment of large volumes of gas with a low concentration of poorly water soluble VOC(Volatile Organic Compound), a new system is proposed: the combination absorption tower/bioreactor. In the scrubber part of the bioscrubbing system, the contaminating compounds are absorbed in a aqueous phase. The contaminated scrubbing liquid is transported to the bioreactor, where the compounds are biodegraded by aerobic microorganisms (mainly to carbon dioxide, water, and biomass). In this study, separation of a volatile organic compound(VOC) out of a waste gas stream has been carried out using a re-cyclable high boiling point extrant(HBE). The liquid stream containing a high boiling point entrant(HBE) scrubs the gas stream in a direct gas-liquid countercurrent contacting operation in a packed tower for the removal of said component from the gaseous stream. A packed-bed column using Pall Ring was set up in order to simulate practical conditions for the scrubbing tower. The liquid stream transported to the bioreactor is recovered and recycled to the scrubber. The model gas, which contained 400 mg/$\textrm{m}^3$ of toluene, at a rate of 100 L/min, flowed into the packed column where the scrubbing liquid trickled over the packing in countercurrent to the rising gas at 10~15L/min. The bioscrubber designed for large volume air streams containing VOCs showed removal efficiency up to 80% in an optimum operating conditions during the tests fer removing toluene from an air stream by scrubbing the air stream with HBE.

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In situ dental implant installation after decontamination in a previously peri-implant diseased site: a pilot study

  • Kim, Young-Taek;Cha, Jae-Kook;Park, Jung-Chul;Jung, Ui-Won;Kim, Chang-Sung;Cho, Kyoo-Sung;Choi, Seong-Ho
    • Journal of Periodontal and Implant Science
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    • v.42 no.1
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    • pp.13-19
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    • 2012
  • Purpose: The aim of this study was to examine whether a previous peri-implantitis site can affect osseointegration, by comparing implant placement at a site where peri-implantitis was present and at a normal bone site. A second aim of this study was to identify the tissue and bone reaction after treating the contaminated implant surface to determine the optimal treatment for peri-implant diseases. Methods: A peri-implant mucositis model for dogs was prepared to determine the optimal treatment option for peri-implant mucositis or peri-implantitis. The implants were inserted partially to a length of 6 mm. The upper 4 mm part of the dental implants was exposed to the oral environment. Simple exposure for 2 weeks contaminated the implant surface. After 2 weeks, the implants were divided into three groups: untreated, swabbed with saline, and swabbed with $H_2O_2$. Three implants from each group were placed to the full length in the same spot. The other three implants were placed fully into newly prepared bone. After eight weeks of healing, the animals were sacrificed. Ground sections, representing the mid-buccal-lingual plane, were prepared for histological analysis. The analysis was evaluated clinically and histometrically. Results: The untreated implants and $H_2O_2$-swabbed implants showed gingival inflammation. Only the saline-swabbed implant group showed re-osseointegration and no gingival inflammation. There was no difference in regeneration height or bone-to-implant contact between in situ implant placement and implant placement in the new bone site. Conclusions: It can be concluded that cleaning with saline may be effective in implant decontamination. After implant surface decontamination, implant installation in a previous peri-implant diseased site may not interfere with osseointegration.

Antibiotic Resistance and R Plasmids in Edwardsiella tarda (양만장 사육조에서 분리한 Edwardsiella tarda의 약제 내성과 R Plasmid)

  • Choi, Min-Soon;Kim, Young-Gill
    • Journal of fish pathology
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    • v.7 no.1
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    • pp.37-46
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    • 1994
  • A total 103 strains of Edwardsiella tarda was isolated from eel culture-ponds and examined for drug resistance, distribution and transferabilities of R plasmids. The drugs used were lincomycin(LM), penicillin(PM), sulfamethazine(SF), sulfadimethoxine(SD), cephalosprin(CP), chloramphenicol(CH), streptomycin(SM), oxytetracycline(OT), ampicillin(AP), oxolinic acid(OA), kanamycin(KM), amikacin(AK), gentamicin(GM) and enrofloxacin(EF). Two strains were resistant to the all drugs used, and all isolates were multiply resistant to drugs(at least 8 among 14 drugs), mostly restricted to LM(103 strains), PM(103 strains), SD(103 strains), SF(103 strains), CP(102 strains), CM(101 strains), SM(100 strains), OT(94 strains), AM(92 strains), OA(80 strains), KM(60 strains), AK(30 strains), GM(19 strains) and EF(14 strains), in combination at high degree showing 34 different drug resistant patterns. The most frequently encountered patterns were LM PM SD SF CP CH SM OT AP OA KM(22 strains, 22.4%) followed by LM PM SD SF CP CH SM OT AP OT(12 strains, 11.7%). LM PM SD SF CP CH SM OT AP(7 strains, 6.8%), LM PM SD SF CP CH SM OT AP OA KM AK GM(6 strains, 5.8%) and LM PM SD SF CP CH SM OT AM OX KM AK GM(6 strains, 5.8%). Transfer experiment of drug resistance showed that of 103 resistant strains, 100 strains(97%) transferred part or all resistance to all drugs, indicating that most isolates carried conjugally transferrable R plasmids determining multiple drugs. The most frequently observed transferarble R plasmids were LM PM SD SF CP CH SM OT AP OA(10 strains), LM PM SD SF CP CH SM OT AP OX KM(7 strains) and LM PM SD SF CP CH AP OA(7 strains). These results sugested that eel culture-ponds were highly contaminated with different strains of Edwardsiella tarda, and that contaminated bacteria might be highly multiple resistant strains to drugs, carring transferable R plasmids.

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Hygienic Studies on the Various Commercial Feedstuffs in Korea -Part 1 Survey on Injury by Toxic Fungi and their Microflora- (우리나라에 시판(市販)되고 있는 각종가축사료(各種家畜飼料)에 대(對)한 위생학적(衛生學的) 연구(硏究) -제1보(第一報) 유독(有毒)곰팡이에 의(衣)한 피해(被害) 및 분포상황(分布狀況) 조사(調査)-)

  • Lee, Ke-Ho;Park, Sung-O
    • Applied Biological Chemistry
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    • v.25 no.3
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    • pp.189-196
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    • 1982
  • Seventy two samples of feedstuff were collected from commercial channels all over Korea. As a study on the moisture contents, microflora and mycotoxin production of each sample investigated. Moisture content of the samples was $11.2{\sim}15%$. Total counts of the samples were $1.8{\times}10^{2}{\sim}2.4{\times}10^{6}$ per gram. The Coli-form group were counted from 9 to $6.3{\times}10^{5}$ per gram which composed mainly of Enterobacter and Klebsiella, whereas Escherichia coli was minor ones. The contamination of many feeds was not remarkable, and only some broiler feeds was contaminated largely with Escherchia coli. Fungi were below detectable limit in 45% of the samples and the most contaminated sample had $4.5imes}10^{5}/g fungi counts.

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Heavy Metals in Sediments and Organisms from Tidal Flats along the Mokpo Coastal Area (목포연안 갯벌 및 서식생물에서의 중금속 함량)

  • 나춘기
    • Economic and Environmental Geology
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    • v.37 no.3
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    • pp.335-345
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    • 2004
  • Total and extractable contents of heavy metals were measured in sediment and seafood from Bukhang and Boggil-ri tidal flats along the Mokpo coastal area, south-western part of Korean peninsular in order to assess the degree of metal pollution, metal bioavailability and metal hioaccumulation. The metal concentrations, except Pb were found to be greater than the background concentrations of sediments indicating the progress of cumulative contamination by anthropogenic origin of metals. The order of extractable metal concentrations in sediments were Mn(32-53 mg/kg)>Zn(14-42 mg/tg)>Cu(2.5-17.0 mg/kg)>Pb(2.4-6.8 mg/kg)>Cd(0.5-0.7 mg/kg). However, the amount of metals associated with extractable fraction of sediments were significantly high in Bukhang relative to Boggil-ri. Significant bioaccumulation of all metals, except Pb were observed in seaweed and benthos. The order of bioaccumulation of metals were: in concentration; all biota commonly, Mn(129-374 mg/kg)>Zn(19-106 mg/kg)>Cu(6-87 mg/kg)>Cd(4.6-7.6 mg/kg)>Pb(0.2-3.7 mg/kg), in BCF; Enteromorpha, Cd>Mn>Cu>Zn>Pb, Ilyoplax deschampsi, Cu>Cd>Mn>Zn>Pb, Urechis unicinctus, Cd>Zn>Mn>Cu>Pb. Some metal concentrations of Enteromorpha, especially Cu, Zn, weakly Pb in bukhang, Mn, Cd in boggili-ri, were correlate well with concentrations in sediment, indicating relatively more contaminated by the anthropogenic origin of metals in each tidal flat. The results clearly indicate that the seafood of bukhang, even of Boggili-ri known as clean area, are contaminated with metals.

Distribution and remediation design of heavy metal contamination in farm-land soils and river deposits in the vicinity of the Goro abandoned mine (고로폐광산 주변 농경지 토양 및 하천 퇴적토의 중금속 오염 분포 및 복원 대책 설계)

  • 이민희;최정찬;김진원
    • Economic and Environmental Geology
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    • v.36 no.2
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    • pp.89-101
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    • 2003
  • River deposits and farmland soils were analyzed to investigate the pollution level of heavy metals in the vicinity of the Goro abandoned Zn-mine. Surface (0-40 cm) and subsurface (40-100 cm) soils were collected around a main river located at the lower part of the Goro mine, and analyzed by ICP-MS for Cd, Cu, Pb, Zn and Cr after 0. 1N HCI extraction and by AAS for As after IN HCI extraction. Concentrations of cadmium and lead at the surface river deposits close to the mine were over the Soil Pollution Warning Limit (SPWL), and 43% of sample sites (6 of 14 samples) were over SPWL for As suggesting that river deposits were broadly contaminated by arsenic. Results from farmland soil analysis showed that surface soils were contaminated by heavy metals, while only arsenic was over SPWL at 50% of sampling sites. Main pollution mechanism around the Goro mine was the discharge of mine tailing and waste rocks from the storage site to the river and to adjacent farmland during flood season. Pollution Grades for sample locations were prescribed by the Law of Soil Environmental Preservation, suggesting that the pollution level of heavy metals around the Goro mine was serious, and the remediation operation fur arsenic and the isolation of mine tailing and waste rocks from river and farmland should be activated to protect further contamination. The area needed to clean up was estimated from pollution distribution data and the remediation methods such as a soil washing method and a soil improvement method were considered as the further remediation operation for arsenic contaminated soils and river deposits around the Goro abandoned mine.