• 제목/요약/키워드: contact ratio

검색결과 1,203건 처리시간 0.025초

Solution-Processable Field-Effect Transistors Fabricated Using Aryl Phenoxazine Based Polymers as the Active Layer

  • Yoon, Hye-Seon;Lee, Woo-Hyung;Lee, Ji-Hoon;Lim, Dong-Gun;Hwang, Do-Hoon;Kang, In-Nam
    • Bulletin of the Korean Chemical Society
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    • 제30권10호
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    • pp.2371-2376
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    • 2009
  • Three phenoxazine-based conjugated polymers, namely, the aryl substituted phenoxazine homopolymer (P1) as well as the dimeric phenoxazine-fluorene (P2) and phenoxazine-bithiophene (P3) copolymers, were synthesized via the Ni(0) mediated Yamamoto reaction and the palladium-catalyzed Suzuki coupling reaction. The weight-averaged molecular weights ($M_w$) of P1, P2, and P3 were found to be 27,000, 22,000, and 15,000, respectively, and their polydispersity indices were 3.6, 1.8, and 2.1. All the polymers were soluble in common organic solvents such as chloroform, toluene, and so on. The UV-visible absorption maxima for P1, P2, and P3 in the film state were located at 421, 415 and 426 nm, respectively, and the ionization potentials of the polymers ranged between 4.90 and 5.12 eV. All the studied phenoxazine-based polymers exhibited amorphous behavior, as confirmed by X-ray diffraction (XRD) and atomic force microscopy (AFM) studies. Thin film transistors were fabricated using the top-contact geometry. P1 showed much better thin-film-transistor performance than P2 or P3: A thin film of P1 gave a saturation mobility of 0.81 ${\times}\;10^{-3}\;cm^2V^{-1}s^{-1}$ and an on/off ratio of about $10^2$.

도르래식 장력조정장치 개발 (Development of a Pulley-type Tensioning Device)

  • 이기원;조용현;박영
    • 한국철도학회논문집
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    • 제12권5호
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    • pp.663-669
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    • 2009
  • 전기철도에서 열차의 속도향상을 위하여 전차선의 장력상승은 필수적이며, 전차선로의 집전성능은 장력에 따라 크게 좌우한다. 경부고속철도에서 사용하고 있는 도르래식 장력장치는 장력변동율이 3% 이내로 규정되어 있고, 전량 수입에 의존하고 있다. 따라서 고속선에서의 장력변동을 요구소건을 만족하는 도르래식 장력조정장치를 개발하였다. 개발한 장력조정장치의 성능을 확인하기 위하여 경부고속철도 장력조정장치의 규격에 따라 성능시험, 내하중 시험 및 파단시험을 수행하였다. 장력조정장치의 신뢰성을 확보하기 위하여 공장에서의 피로시험과 충북선 본선에서 1 년 이상을 시범설치, 운영하였다. 이들 시험을 통하여 개발된 장력조정장치가 신뢰성을 가지며 본선에 적용할 수 있다는 것을 입증하였다.

Ga2Se3 층을 Cu-In-Ga 전구체 위에 적용하여 제조된 Cu(In,Ga)Se2 박막의 Ga 분포 변화 연구 (Ga Distribution in Cu(In,Ga)Se2 Thin Film Prepared by Selenization of Co-Sputtered Cu-In-Ga Precursor with Ga2Se3 Layer)

  • 정광선;신영민;조양휘;윤재호;안병태
    • 한국재료학회지
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    • 제20권8호
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    • pp.434-438
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    • 2010
  • The selenization process has been a promising method for low-cost and large-scale production of high quality CIGS film. However, there is the problem that most Ga in the CIGS film segregates near the Mo back contact. So the solar cell behaves like a $CuInSe_2$ and lacks the increased open-circuit voltage. In this study we investigated the Ga distribution in CIGS films by using the $Ga_2Se_3$ layer. The $Ga_2Se_3$ layer was applied on the Cu-In-Ga metal layer to increase Ga content at the surface of CIGS films and to restrict Ga diffusion to the CIGS/Mo interface with Ga and Se bonding. The layer made by thermal evaporation was showed to an amorphous $Ga_2Se_3$ layer in the result of AES depth profile, XPS and XRD measurement. As the thickness of $Ga_2Se_3$ layer increased, a small-grained CIGS film was developed and phase seperation was showed using SEM and XRD respectively. Ga distributions in CIGS films were investigated by means of AES depth profile. As a result, the [Ga]/[In+Ga] ratio was 0.2 at the surface and 0.5 near the CIGS/Mo interface when the $Ga_2Se_3$ thickness was 220 nm, suggesting that the $Ga_2Se_3$ layer on the top of metal layer is one of the possible methods for Ga redistribution and open circuit voltage increase.

불소/실리콘 고무 블렌드의 특성과 물성 (Characteristics and Properties of Fluoro/Silicone Rubber Blend System)

  • 이진국;송환제;김미라
    • 접착 및 계면
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    • 제9권3호
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    • pp.14-19
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    • 2008
  • 본 연구는 Silicone rubber (SR40)과 Fluororubber (FKM)을 여러 가지 무게비로 하여 블렌드를 제조하였고 그 특성을 고찰하였다. 블렌드의 가교 거동은 SR40의 함량이 증가함에 따라 SR40 내의 가교제에 의해 가교 속도는 빨라졌다. 블렌드에서 FKM의 함량이 증가하면, 열분해 온도가 증가는 경향이 있고 SR40/FKM 블렌드 비율이 50/50일 때 순수한 SR40보다 높은 열안정성을 나타내었다. 표면 발수성의 척도인 접촉각을 측정한 결과, SR40의 함량이 증가할수록 블렌드의 접촉각은 증가하는 것을 확인하였다. 또한, 제조한 블렌드들은 모든 조성에서 전형적인 상분리의 모폴로지를 나타내는 것을 확인할 수 있었고, SR40의 비율이 증가할수록 상분리 정도가 증가하는 것을 확인할 수 있었다.

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염약침(鹽藥鍼)을 위한 소금의 의학적 효용 (The Effect of Salt in Medicine for Salt Pharmacopuncture)

  • 김기현;김지화;송호섭
    • Journal of Acupuncture Research
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    • 제32권2호
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    • pp.131-145
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    • 2015
  • Objectives : The purpose of this study was to demonstrate the effectiveness and availability of salt pharmacopuncture of Korean sun-dried salt and processing salt on the basis of bibliographical review. Methods : This study was done through a narrative review of related bibliography including medical books, journals, general bibliography, and web sites. Results : 1. Korean sun-dried salt is produced in the ground with soil, tiles, and pottery. Sun-dried, traditional, granulated, bamboo, and grilled salts are all appropriate for medical use. They are composed of a lower level of NaCl and unnecessary substances, and have a higher water and mineral content. 2. The 9~30 g of NaCl included in the physiological saline matches the ratio of a normal human body. However, if the saline is used for water supply, it should be improved because the recommended amount is much lower. 3. Medicine that includes NaCl is applied for lessening the congestion of the nasal cavity, alleviating cornea swelling, or for a lack of water. NaCl can also be used for washing contact lenses as well as cleaning the mucous membrane of the eyes and nose. 4. Salt relieves anger, detoxifies, induces vomiting, builds strong muscles and bones, gives energy, slows aging, and ultimately improves health. 5. Salt treats many diseases including: cardiovascular, hematosis, respirometer, obstetric, musculoskeletal, mineral supplement, eye, teeth and skin issues, etc.. However, salt is not used for treating asthma, cough, or other ailments mainly affecting the vascular system. 6. While NaCl in salt absorbs water and the vascular constriction results in higher blood pressure, the pressure induced from salt is actually a physiologically temporary rise. Rather, salt helps remove oil from the body and its potassium lowers blood pressure. Conclusions : It was suggested that salt pharmacopuncture of Korean sun-dried salt and processing salt should be made available for adjusting the physiological salt concentration and control of the Na side effects, therefore it would be useful in the treatment of diseases.

Acrylonitrile/Sodium Allylsulfonate 공중합체 방사선 접목을 이용한 다공성 Polytetrafluoroethylene 지지체의 친수화 (Hydrophilization of a Porous Polytetrafluoroethylene Supporter by Radiation Grafting Poly(Acrylonitrile-co-Sodium Allylsulfonate))

  • 박병희;손준용;윤기석;신준화
    • 폴리머
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    • 제38권3호
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    • pp.293-298
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    • 2014
  • 본 연구에서는 방사선을 이용하여 다공성 polytetrafluoroethylene(PTFE) 지지체에 acrylonitrile(AN)과 친수성 작용기를 가진 sodium allylsulfonate(SAS)를 접목시켜 복합 연료전지막의 지지체로 사용되는 친수화 다공성 지지체를 제조하였다. SAS/AN의 몰비율, 단량체 농도, 방사선의 조사선량에 변화를 주어 제조된 지지체의 물성을 평가하였다. 제조된 지지체의 FTIR 분석을 통하여 각 단량체들이 다공성 PTFE 지지체에 성공적으로 그래프팅되었음을 확인하였다. 또한 FE-SEM과 gurley number 측정을 이용하여 그래프트율이 증가할수록 지지체 표면의 기공이 감소하는 것을 관찰하였고, 그래프트율, 접촉각, TBO(toluidine blue O) uptake 분석을 통해 그래프트율이 증가됨에 따라 제조된 지지체의 친수화도가 증가하는 것을 확인하였다.

전기저항 측정법을 이용한 탄소나노튜브/폴리프로필렌 나노복합재료의 내부 손상 예측 (Electrical Resistance Measurement in Characterizing the Internal Damage of Carbon Nanotube/Polypropylene Nanocomposites)

  • 김학수;권동준;왕작가;구가영;김대식;이춘수;박종만
    • Composites Research
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    • 제26권3호
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    • pp.201-206
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    • 2013
  • 전기저항 측정법을 이용하여 전도성을 띄는 소재는 손상예측이 가능하다. 본 연구에서는 차량용 소재로 이용하는 폴리프로필렌(PP)를 이용할 때 재료 내부에 발생될 손상 평가법을 고안하였다. PP 내부에 전도성을 부여하기 위해 탄소나노튜브(CNT)를 0.5 wt% 삽입하여 CNT/PP 복합재료를 제조하였다. 손상 평가를 하기 위해 시편 내부에 구리선을 삽입하여 가로와 세로, 대각선 구간을 설정하여 측정하였다. 시편의 모형은 $20^{\circ}$ 휘어진 시편을 사용하였다. 동적 압축 실험에 따른 전기저항 측정을 통해 구간별로 전기저항 변화도를 분석하였다. 동적 압축 실험에 따른 구간별 전기저항 변화도의 신호는 재료 내부에 전가된 응력을 나타내는 신호이다. 전기저항 측정 구간에서 전기저항 변화도가 높은 경우는 미세 손상이 발생되었음을 의미한다. 전기저항 측정법을 이용한 동적 압축 실험에 따른 예상 손상부위와 실제 파괴 실험을 통해 본 평가 방법을 이용하여 재료 내부 미세 손상을 예측할 수 있는 방법임을 확인하였다.

권선계자형 자기 기어의 고 토크 리플 회전자에 대한 분석 및 개선 (Torque Ripple Improving and Analysis of Coil-winding Rotor of Magnetic Gear)

  • 박의종;김용재
    • 한국전자통신학회논문지
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    • 제15권2호
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    • pp.259-266
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    • 2020
  • 자기 기어는 기계식 기어와 동일하게 기어의 특성을 나타내면서 각 회전자가 접촉하지 않아 마찰에 의한 소음 및 발열, 유지보수문제에서 기계식 기어보다 유리하다. 또한 권선계자를 사용하는 회전자를 적용할 경우 기어의 출력조절은 물론, 기어비 및 위급상황에서 자체적인 구동차단까지 가능하여 자기 기어의 활용가능성은 무한하다. 하지만 권선계자를 사용할 경우 영구자석과 철심간의 흡인력에 의한 코깅토크가 나타나게 되고 이는 회전자의 진동을 유발하는 토크 리플성분의 증가로 이어진다. 따라서 본 논문에서는 권선계자를 사용하는 회전자의 토크 리플을 저감하기 위해 회전자의 다양한 형상을 분석하였으며, 자기 기어의 토크 리플을 저감하기 위한 최적의 형상을 제시하였다.

The first photometric analysis of the close binary system NSVS 1461538

  • Kim, Hyoun-Woo;Kim, Chun-Hwey
    • 천문학회보
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    • 제41권1호
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    • pp.41.2-41.2
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    • 2016
  • The follow-up BVRI photometric observations of NSVS 1461538, which was discovered as an $Algol/{\beta}$ Lyr eclipsing variable by Hoffman, Harrison & McNamara (2009), were performed for three years from 2011 to 2013 by using the 61-cm telescope and CCD cameras of Sobaeksan Optical Astronomy Observatory (SOAO). New light curves have deep depths both of the primary and secondary eclipses, rounded shapes outside eclipses and a strong O'Connell effect, indicating that NSVS 1461538 is a typical W UMa close binary system rather than an $Algol/{\beta}$ Lyr type binary star. A period study with all the timings shows that the orbital period may vary in a sinusoidal way with a period of about 5.6 yr and a small semi-amplitude of about 0.008 d. The cyclical period variation was interpreted as a light-time effect due to a tertiary body with a minimum mass of $0.66M{\odot}$. The first photometric solution with the Wilson-Devinney binary model shows that the system is a W-subtype contact binary with the mass ratio ($q=m_c/m_h$) of 3.46, orbit inclination of 85.6 deg and fill-out factor of 30%. From the existing empirical relationship between parameters, the absolute dimension was estimated. The masses and radii of the component stars are $0.28M{\odot}$ and $0.71R{\odot}$ for the less massive but hotter primary star, respectively, and $0.96M{\odot}$ and $1.21R{\odot}$ for the more massive secondary, respectively. Possible evolution of the system is discussed in the mass-radius and the mass-luminosity planes.

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고압 WGS 반응을 위한 Cu-ZnO/Al2O3 촉매상에서 기-액 계면 촉매 반응 특성 연구 (Catalytic Activity Tests in Gas-Liquid Interface over Cu-ZnO/Al2O3 Catalyst for High Pressure Water-Gas-Shift Reaction)

  • 김세훈;박노국;이태진
    • 한국수소및신에너지학회논문집
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    • 제22권6호
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    • pp.905-912
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    • 2011
  • In this study, the novel concept catalytic reactor was designed for water-gas shift reaction (WGS) under high pressure. The novel concept catalytic reactor was composed of an autoclave, the catalyst, and liquid water. Cu-ZnO/$Al_2O_3$ as the low temperature shift catalyst was used for WGS reaction. WGS in the novel concept catalytic reactor was carried out at the ranges of 150~$250^{\circ}C$ and 30~50 atm. The liquid water was filled at the bottom of the autoclave catalytic reactor and the catalyst of pellet type was located at the gas-liquid water interface. It was concluded that WGS reaction occurred over the surface of catalysts partially wetted with liquid water. The conversion of CO for WGS was also controlled with changing content of Cu and ZnO used as the catalytic active components. Meanwhile, the catalyst of honey comb type coated with Cu-ZnO/$Al_2O_3$ was used in order to increase the contact area between wet-surface of catalyst and the reactants of gas phase. It was confirmed from these experiments that $H_2$/CO ratio of the simulated coal gas increased from 0.5 to 0.8 by WGS at gas-liquid water interface over the wet surface of honey comb type catalyst at $250^{\circ}C$ and 50 atm.