• 제목/요약/키워드: confined polymer

검색결과 103건 처리시간 0.033초

철계 형상기억합금 스트립으로 보강된 콘크리트 기둥의 반복이력거동 평가 (Hysteretic Behavior Evaluation of Reinforced Concrete Columns Retrofitted with Iron-based Shape Memory Alloy Strips)

  • 정새벽;정동혁
    • 한국전산구조공학회논문집
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    • 제35권5호
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    • pp.287-297
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    • 2022
  • 본 논문에서는 철계형상기억합금(Fe SMA) 스트립으로 능동구속된 콘크리트 기둥의 실험적, 해석적 연구결과를 제시한다. Fe SMA과 탄소섬유보강시트(CFRP)로 각각 구속된 콘크리트 공시체의 압축실험을 통해 형상기억합금 기반 능동구속기법의 효과성을 평가하였다. 실험결과, Fe SMA 스트립으로 구속된 콘크리트 공시체가 낮은 구속력에도 불구하고 CFRP 시트로 구속된 공시체에 비해 더 우수한 변형능력을 가지는 것으로 밝혀졌다. 실험을 통해 얻은 구속된 콘크리트의 압축거동 결과를 이용해 소성힌지 영역이 각각 Fe SMA 스트립과 CFRP 시트로 보강된 콘크리트 기둥의 유한요소모델을 구축하였다. 기존 수행된 콘크리트 기둥의 수평반복가력 실험결과를 바탕으로 구축된 기둥 모델을 검증하였고, 각각의 기둥 모델에 대한 수평반복가력 해석을 수행하였다. 해석결과, Fe SMA 스트립으로 보강된 콘크리트 기둥이 CFRP 시트로 보강된 기둥모델에 비해 변형, 에너지 소산능력 향상에 효과적임을 확인하였다.

용매증발기반 자기조립을 이용한 단일벽 탄소나노튜브 정렬 및 트랜지스터 응용 (Evaporative Self-Assembly of Single-Walled Carbon Nanotubes for Field Effect Transistor)

  • 강석희;정도영;엄성운;황청석;홍석원
    • 한국재료학회지
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    • 제23권8호
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    • pp.453-461
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    • 2013
  • Controlling the stick and slip motions of the contact lines in a confined geometry comprised of a spherical lens with a flat substrate is useful for manufacturing polymer ring patterns. We used a sphere on a flat geometry, by which we could control the interfaces of the solution, vapor and substrate. By this method, hundreds of concentric ring-pattern formations of a linear conjugated polymer, poly [2-methoxy-5-(2-thylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), were generated with excellent regularity over large areas after complete solvent evaporation. Subsequently, the MEH-PPV ring patterns played a role as a directed template to organize highly regular concentric rings of single-walled carbon nanotubes(SWCNTs); when a droplet of the SWCNT suspension in water was casted onto the prepared substrate, hydrophobic polymer patterns confined the water dispersed SWCNTs in between the hydrophilicized $SiO_2/Si$ substrate. As the solvent evaporated, SWCNT-rings were formed in between MEH-PPV rings with controlled density. Finally, we used a lift-off process to produce SWCNT patterns by the removal of a sacrificial polymer template with organic solvent. We also fabricated a field effect transistor using self-assembled SWCNT networks on a $SiO_2/Si$ substrate.

Nanostructures of diblock copolymers under curved confinement

  • Shin, Kyu-Soon;Huh, June;Jo Won-Ho;Xiang hongqi;McCarthy Thomas J.;Russell Thomas P.
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.294-294
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    • 2006
  • Diblock copolymers whose morphology in the bulk is dictated by the volume fraction of the components and segmental interactions were confined within nanoscopic cylindrical pores. Since the confining geometry is nonplanar and nanoscopic, the extreme imposed curvature, comparable to molecular dimensions, places significant packing frustration on the chains. When incommensurability between the repeating period of diblock copolymers and the diameter of nanopore is coupled with the curvature, it causes the marked departures from bulk or even thin film behavior. The entropy penalty from the constraints and the curvature of the physical confinement determines unique nanostructures available only with this curved confinement.

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Noble LCD with a Single Supporting Substrate

  • Wook, Jung-Jong;Kim, Jae-Hoon
    • Journal of Information Display
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    • 제3권4호
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    • pp.4-7
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    • 2002
  • A recently developed phase separated composite film method has been employed to fabricate a liquid crystal (LC) based electro-optical device using a single glass substrate. The resulting device is made of adjacent parallel layers of LC and polymer maded by phase separation. The LC layer is confined between the solidified polymer layer on one side and the glass substrate on the other. The electro-optical properties of these devices demonstrate their technological potential in light weight and hand-held electronic products.

Noble LCD with a single supporting substrate

  • Kim, Il;Kim, Jae-Hoon;Agra-Kooijman, Dena M.;Kumar, Satyendra
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.463-466
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    • 2002
  • A new type of LCD has been developed using recently developed phase separated composite film method with a single glass substrate. The resultant structures are made of adjacent parallel layers of liquid crystal and polymer. The LC layer is confined between the solidified polymer layer and glass substrate. The electra-optical properties of the display have been investigated. This technique has the potential to realize a lightweight display for hand-held portable electronic products.

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Strength and strain modeling of CFRP -confined concrete cylinders using ANNs

  • Ozturk, Onur
    • Computers and Concrete
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    • 제27권3호
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    • pp.225-239
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    • 2021
  • Carbon fiber reinforced polymer (CFRP) has extensive use in strengthening reinforced concrete structures due to its high strength and elastic modulus, low weight, fast and easy application, and excellent durability performance. Many studies have been carried out to determine the performance of the CFRP confined concrete cylinder. Although studies about the prediction of confined compressive strength using ANN are in the literature, the insufficiency of the studies to predict the strain of confined concrete cylinder using ANN, which is the most appropriate analysis method for nonlinear and complex problems, draws attention. Therefore, to predict both strengths and also strain values, two different ANNs were created using an extensive experimental database. The strength and strain networks were evaluated with the statistical parameters of correlation coefficients (R2), root mean square error (RMSE), and mean absolute error (MAE). The estimated values were found to be close to the experimental results. Mathematical equations to predict the strength and strain values were derived using networks prepared for convenience in engineering applications. The sensitivity analysis of mathematical models was performed by considering the inputs with the highest importance factors. Considering the limit values obtained from the sensitivity analysis of the parameters, the performances of the proposed models were evaluated by using the test data determined from the experimental database. Model performances were evaluated comparatively with other analytical models most commonly used in the literature, and it was found that the closest results to experimental data were obtained from the proposed strength and strain models.

Data-driven prediction of compressive strength of FRP-confined concrete members: An application of machine learning models

  • Berradia, Mohammed;Azab, Marc;Ahmad, Zeeshan;Accouche, Oussama;Raza, Ali;Alashker, Yasser
    • Structural Engineering and Mechanics
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    • 제83권4호
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    • pp.515-535
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    • 2022
  • The strength models for fiber-reinforced polymer (FRP)-confined normal strength concrete (NC) cylinders available in the literature have been suggested based on small databases using limited variables of such structural members portraying less accuracy. The artificial neural network (ANN) is an advanced technique for precisely predicting the response of composite structures by considering a large number of parameters. The main objective of the present investigation is to develop an ANN model for the axial strength of FRP-confined NC cylinders using various parameters to give the highest accuracy of the predictions. To secure this aim, a large experimental database of 313 FRP-confined NC cylinders has been constructed from previous research investigations. An evaluation of 33 different empirical strength models has been performed using various statistical parameters (root mean squared error RMSE, mean absolute error MAE, and coefficient of determination R2) over the developed database. Then, a new ANN model using the Group Method of Data Handling (GMDH) has been proposed based on the experimental database that portrayed the highest performance as compared with the previous models with R2=0.92, RMSE=0.27, and MAE=0.33. Therefore, the suggested ANN model can accurately capture the axial strength of FRP-confined NC cylinders that can be used for the further analysis and design of such members in the construction industry.

Tracer diffusion in a polymer network: influence of network flexibility

  • Kim, Haein;Kim, Jun Soo
    • EDISON SW 활용 경진대회 논문집
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    • 제6회(2017년)
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    • pp.39-45
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    • 2017
  • We present a Brownian dynamics simulation study on the diffusion of a neutral tracer particle confined in a regularly crosslinked polymer network, especially, when the tracer size is comparable to the mesh size of the network. Polymer networks with different mesh sizes are prepared and compressed to the extent that the total polymer densities become the same. Irrespective of the network mesh size, the tracer diffusion in the networks is slowed down, showing the subdiffusion on intermediate time scales followed by the normal diffusion at long times. However, the confinement effect on the tracer diffusion becomes more significant when network strands are tightly stretched with smaller mesh size. The time scales of dynamic transitions are analyzed in terms of the probability distribution of time-correlated particle displacements.

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Numerical modelling of circular reinforced concrete columns confined with GFRP spirals using fracture-plastic model

  • Muhammad Saad Ifrahim;Abdul Jabbar Sangi;Shuaib H. Ahmad
    • Computers and Concrete
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    • 제31권6호
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    • pp.527-536
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    • 2023
  • Fiber Reinforced Polymer (FRP) bar has emerged as a viable and sustainable replacement to steel in reinforced concrete (RC) under severe corrosive environment. The behavior of concrete columns reinforced with FRP bars, spirals, and hoops is an ongoing area of research. In this study, 3D nonlinear numerical modelling of circular concrete columns reinforced with Glass Fiber Reinforced Polymer (GFRP) bars and transversely confined with GFRP spirals were conducted using fracture-plastic model. The numerical models and experimental results are found to be in good agreement. The effectiveness of confinement was accessed through von-mises stresses, and it was found that the stresses in the concrete's core are higher with a 30 mm pitch (46 MPa) compared to a 60 mm pitch (36 MPa). The validated models are used to conduct parametric studies. In terms of axial load carrying capacity and member ductility, the effect of concrete strength, spiral pitch, and longitudinal reinforcement ratio are thoroughly investigated. The confinement effect and member ductility of a GFRP RC column increases as the spiral pitch decreases. It is also found that the confinement effect and member ductility decreased with increase in strength of concrete.

Performance of FRP confined and unconfined geopolymer concrete exposed to sulfate attacks

  • Alzeebaree, Radhwan;Gulsan, Mehmet Eren;Nis, Anil;Mohammedameen, Alaa;Cevik, Abdulkadir
    • Steel and Composite Structures
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    • 제29권2호
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    • pp.201-218
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    • 2018
  • In this study, the effects of magnesium sulfate on the mechanical performance and the durability of confined and unconfined geopolymer concrete (GPC) specimens were investigated. The carbon and basalt fiber reinforced polymer (FRP) fabrics with 1-layer and 3-layers were used to evaluate the performances of the specimens under static and cyclic loading in the ambient and magnesium sulfate environments. In addition, the use of FRP materials as a rehabilitation technique was also studied. For the geopolymerization process of GPC specimens, the alkaline activator has selected a mixture of sodium silicate solution ($Na_2SiO_3$) and sodium hydroxide solution (NaOH) with a ratio ($Na_2SiO_3/NaOH$) of 2.5. In addition to GPC specimens, an ordinary concrete (NC) specimens were also produced as a reference specimens and some of the GPC and NC specimens were immersed in 5% magnesium sulfate solutions. The mechanical performance and the durability of the specimens were evaluated by visual appearance, weight change, static and cyclic loading, and failure modes of the specimens under magnesium sulfate and ambient environments. In addition, the microscopic changes of the specimens due to sulfate attack were also assessed by scanning electron microscopy (SEM) to understand the macroscale behavior of the specimens. Results indicated that geopolymer specimens produced with nano-silica and fly ash showed superior performance than the NC specimens in the sulfate environment. In addition, confined specimens with FRP fabrics significantly improved the compressive strength, ductility and durability resistance of the specimens and the improvement was found higher with the increased number of FRP layers. Specimens wrapped with carbon FRP fabrics showed better mechanical performance and durability properties than the specimens wrapped with basalt FRP fabrics. Both FRP materials can be used as a rehabilitation material in the sulfate environment.