• 제목/요약/키워드: confined polymer

검색결과 103건 처리시간 0.031초

Nanospace Confinement of Conducting Polymers using Mesoporous Silica and Organosilica

  • Itahara, Hiroshi;Inagaki, Shinji;Asahi, Ryoji
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.277-277
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    • 2006
  • Conducting polymers (e.g. poly[2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylen vinylene] (MEH-PPV)) confined in one-dimensional nanoscale channels of mesoporous materials, are expected to lead the novel applications for electroconductive and optoelectronic devices. We investigated the adsorption behavior of MEH-PPV on organically surface-modified mesoporous silica (FSM-16) and mesoporous organosilica. The amount of the confined MEH-PPV was found to strongly depend on the surface modifications of the mesoporous materials. The optical absorption edge of the confined MHE-PPV was clearly blue-shifted when compared to that of a free MHE-PPV.

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Behaviour of FRP composite columns: Review and analysis of the section forms

  • Rong, Chong;Shi, Qingxuan;Zhao, Hongchao
    • Advances in concrete construction
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    • 제9권2호
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    • pp.125-137
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    • 2020
  • As confining materials for concrete, steel and fibre-reinforced polymer (FRP) composites have important applications in both the seismic retrofit of existing reinforced concrete columns and in the new construction of composite structures. We present a comprehensive review of the axial stress-strain behaviour of the FRP-confined concrete column. Next, the mechanical performance of the hybrid FRP-confined concrete-steel composite columns are comprehensively reviewed. Furthermore, the results of FRP-confined concrete column experiments and FRP-confined circular concrete-filled steel tube experiments are presented to study the interaction relationship between various material sections. Finally, the combinations of material sections are discussed. Based on these observations, recommendations regarding future research directions for composite columns are also outlined.

Orientation and deformation of FENE dumbbells in confined microchannel and contraction flow geometry

  • Song, Sun-Jin;Kim, Ju-Min;Ahn, Kyung-Hyun;Lee, Seung-Jong;Yeo, Jong-Kee
    • Korea-Australia Rheology Journal
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    • 제19권3호
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    • pp.147-156
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    • 2007
  • The orientation and deformation of polymer chains in a confined channel flow has been investigated. The polymer chain was modeled as a Finitely Extensible Nonlinear Elastic (FENE) dumbbell. The Brownian configuration field method was extended to take the interaction between the flow and local chain dynamics into account. Drag and Brownian forces were treated as anisotropic in order to reflect the influence of the wall in the confined flow. Both Poiseuille flow and 4 : 1 contraction flow were considered. Of particular interest was molecular tumbling of polymer chains near the wall. It was strongly influenced by anisotropic drag and high shear close to the wall. We discussed the mechanism of this particular behavior in terms of the governing forces. The dumbbell configuration was determined not only by the wall interaction but also by the flow type of the geometric origin. The effect of extensional flow on dumbbell configuration was also discussed by comparing with the Poiseuille flow.

Multi-criteria analysis of five reinforcement options for Peruvian confined masonry walls

  • Tarque, Nicola;Salsavilca, Jhoselyn;Yacila, Jhair;Camata, Guido
    • Earthquakes and Structures
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    • 제17권2호
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    • pp.205-219
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    • 2019
  • In Peru, construction of dwellings using confined masonry walls (CM) has a high percentage of acceptance within many sectors of the population. It is estimated that only in Lima, 80% of the constructions use CM and at least 70% of these are informal constructions. This mean that they are built without proper technical advice and generally have a high seismic vulnerability. One way to reduce this vulnerability is by reinforcing the walls. However, despite the existence of some reinforcement methods in the market, not all of them can be applied massively because there are other parameters to take into account, as economical, criteria for seismic improvement, reinforcement ratio, etc. Therefore, in this paper the feasibility of using five reinforcement techniques has been studied and compared. These reinforcements are: welded mesh (WM), glass fiber reinforced polymer (GFRP), carbon fiber reinforced polymer (CFRP), steel bar wire mesh (CSM), steel reinforced grout (SRG). The Multi-Criteria Decision Making (MCDM) method can be useful to evaluate the most optimal strengthening technique for a fast, effective and massive use plan in Peru. The results of using MCDM with 10 criteria indicate that the Carbon Fiber Reinforced Polymer (CFRP) and Steel Reinforced Grout (SRG) methods are the most suitable for a massive reinforcement application in Lima.

Machine learning techniques for prediction of ultimate strain of FRP-confined concrete

  • Tijani, Ibrahim A.;Lawal, Abiodun I.;Kwon, S.
    • Structural Engineering and Mechanics
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    • 제84권1호
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    • pp.101-111
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    • 2022
  • It is widely known that axially loaded fiber-reinforced polymer (FRP) confined concrete presents significant and enhanced mechanical properties with reference to the unconfined concrete. Therefore, to predict the mechanical behavior of FRP-confined concrete two quantities-peak strength and ultimate strain are required. Despite the significant advances, the determination of the ultimate strain of FRP-confined concrete is one of the most challenging problems to be resolved. This is often attributed to our persistence in desiring the conventional methods as the sole technique to examine this phenomenon and the complex nature of the ultimate strain of FRP-confined concrete. To bridge the research gap, this study adopted two machine learning (ML) techniques-artificial neural network (ANN) and Gaussian process regression (GPR)-to analyze observations obtained from 627 datasets of FRP-confined concrete circular and non-circular sections under axial loading test. Besides, the techniques are also used to predict the ultimate strain of FRP-confined concrete. Seven parameters namely width/diameter of the specimens, corner radius ratio, the strength of concrete, FRP elastic modulus, FRP thickness, FRP tensile rupture strain, and the axial strain of unconfined concrete-are the input parameters used to predict the ultimate strain of FRP-confined concrete. The results of the current study highlight the merit of using AI techniques in structural engineering applications given their extraordinary ability to comprehend multidimensional phenomena of FRP-confined concrete structures with ease, low computational cost, and high performance over the existing empirical models.

Design-oriented strength and strain models for GFRP-wrapped concrete

  • Messaoud, Houssem;Kassoul, Amar;Bougara, Abdelkader
    • Computers and Concrete
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    • 제26권3호
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    • pp.293-307
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    • 2020
  • The aim of this paper is to develop design-oriented models for the prediction of the ultimate strength and ultimate axial strain for concrete confined with glass fiber-reinforced polymer (GFRP) wraps. Twenty of most used and recent design-oriented models developed to predict the strength and strain of GFRP-confined concrete in circular sections are selected and evaluated basing on a database of 163 test results of concrete cylinders confined with GFRP wraps subjected to uniaxial compression. The evaluation of these models is performed using three statistical indices namely the coefficient of the determination (R2), the root mean square error (RMSE), and the average absolute error (AAE). Based on this study, new strength and strain models for GFRP-wrapped concrete are developed using regression analysis. The obtained results show that the proposed models exhibit better performance and provide accurate predictions over the existing models.

Experimental study and modelling of CFRP-confined damaged and undamaged square RC columns under cyclic loading

  • Su, Li;Li, Xiaoran;Wang, Yuanfeng
    • Steel and Composite Structures
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    • 제21권2호
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    • pp.411-427
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    • 2016
  • While the cyclic behaviour of fiber-reinforced polymer (FRP)-confined columns is studied rather extensively, the cyclic response especially the energy dissipation of FRP-confined damaged and undamaged square RC columns is not yet fully understood. In this paper, an experimental and numerical investigation was conducted to study the cyclic behavior of two different types of Carbon FRP (CFRP)-confined square RC columns: strengthened and repaired. The main variables investigated are initial damage, confinement of CFRP, longitudinal steel reinforcement ratio. The experimental results show that lower initial damage, added confinement with CFRP and longitudinal reinforcement enhance the ductility, energy dissipation capacity and strength of the columns, decrease the stiffness and strength degradation rates of all CFRP-confined square RC columns. Two hysteretic constitutive models were developed for confined damaged and undamaged concrete and cast into the non-linear beam-column fiber-based models in the software Open System for Earthquake Engineering Simulation (OpenSees) to analyze the cyclic behavior of CFRP-confined damaged and undamaged columns. The results of the numerical models are in good agreement with the experiments.

Mechanical behaviour of concrete filled double skin steel tubular stub columns confined by FRP under axial compression

  • Wang, Jun;Liu, Weiqing;Zhou, Ding;Zhu, Lu;Fang, Hai
    • Steel and Composite Structures
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    • 제17권4호
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    • pp.431-452
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    • 2014
  • The present study focuses on the mechanical behaviour of concrete filled double skin steel tubular (CFDST) stub columns confined by fiber reinforced polymer (FRP). A series of axial compression tests have been conducted on two CFDST stub columns, eight CFDST stub columns confined by FRP and a concrete-filled steel tubular (CFST) stub column confined by FRP, respectively. The influences of hollow section ratio, FRP wall thickness and fibre longitudinal-circumferential proportion on the load-strain curve and the concrete stress-strain curve for stub columns with annular section were discussed. The test results displayed that the FRP jacket can obviously enhance the carrying capacity of stub columns. Based on the test results, a new model which includes the effects of confinement factor, hollow section ratio and lateral confining pressure of the outer steel tube was proposed to calculate the compressive strength of confined concrete. Using the present concrete strength model, the formula to predict the carrying capacity of CFDST stub columns confined by FRP was derived. The theoretically predicted results agree well with those obtained from the experiments and FE analysis. The present method is also adapted to calculate the carrying capacity of CFST stub columns confined by FRP.

Reinforced high-strength concrete square columns confined by aramid FRP jackets -part I: experimental study

  • Wang, Yuan-Feng;Ma, Yi-Shuo;Wu, Han-Liang
    • Steel and Composite Structures
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    • 제11권6호
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    • pp.455-468
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    • 2011
  • Although retrofitting and strengthening reinforced concrete (RC) columns by wrapping fiber reinforced polymer (FRP) composites have become a popular technique in civil engineering, the study on reinforced high-strength concrete (HSC) columns is still not sufficient. The objective of these companion papers is to investigate the mechanical properties of reinforced HSC square columns confined by aramid FRP (AFRP) jackets under concentric compressive loading. In the part I of these companion papers, an experiment was conducted on 54 confined RC specimens and nine unconfined plain specimens, the considered parameters were the concrete strength, the thickness of AFRP jackets, and the form of AFRP wrapping. The experimental process and results are presented in detail. Subsequently, some discussions on the confinement effect, failure modes, strength, and ductility of the columns are carried out.

COMPRESSIVE STRENGH OF FRP-CONFINED CONCRETE COLUMNS UNDER THE ECCENTRIC LOADS

  • H.R. Salehian;M.R. Esfahani
    • 국제학술발표논문집
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    • The 3th International Conference on Construction Engineering and Project Management
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    • pp.978-982
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    • 2009
  • In recent years, due to some excellent properties of fiber reinforced polymer (FRP) composites, the use of FRP sheets for strengthening the weak concrete columns have become increasingly popular. Axial loading is the basic assumption in most of the models that are presented for estimating the compression strength of confined concrete columns. However a large number of weak concrete columns in the bending frames are under the combination of both axial and flexural loads. This paper presents the results of an experimental study on the effects of eccentricity of load on the compressive strength of concrete columns confined by FRP sheets. This research shows that the eccentricity of compression load affects decreasingly the performance of confining FRP jacket in confined columns.

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