• Title/Summary/Keyword: conductivity measurement

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Synthesis of Self-doped Poly(PEGMA-co-BF3LiMA) Electrolytes and Effect of PEGMA Molecular Weight on Ionic Conductivities (자기-도핑형 poly(PEGMA-co-BF3LiMA) 전해질의 합성과 이온전도도에 대한 PEGMA분자량의 영향)

  • Kim, Kyung-Chan;Ryu, Sang-Woog
    • Journal of the Korean Electrochemical Society
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    • v.15 no.4
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    • pp.230-235
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    • 2012
  • Polymer electrolytes consisted of $BF_3LiMA$ and 300 (PEGMA300) or 1100 (PEGMA1100) g $mol^{-1}$ of PEGMA were prepared and the electrochemical properties were characterized. Interestingly, the AC-impedance measurement shows $1.22{\times}10^{-5}S\;cm^{-1}$ of room temperature ionic conductivity from PEGMA1100 based solid polymer electrolytes while $8.54{\times}10^{-7}S\;cm^{-1}$ was observed in PEGMA300 based liquid polymer electrolytes. The more suitable coordination between lithium ion and ethylene oxide (EO) unit might be the reason of higher ionic conductivity which can be possible in PEGMA1100 based electrolytes since it has 23 EO units in monomer. The lithium ion transference number was found to be 0.6 due to the side reactions between $BF_3$ and lithium metal expecially for longer time but 0.9 was observed within 3000 seconds of measuring time which is strong evidence of a single-ion conductor.

Thermophysical Properties of the Soybean Curd and Prediction of its Thermal Conductivity 1 Measurement of Thermophysical Properties of the Soybean Curd (두부의 전열물성 및 유효열전도도의 추정 1. 두부의 전열물성의 추정)

  • KONG Jai-Yul
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.15 no.3
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    • pp.211-218
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    • 1982
  • The specific heat capacity and density of soybean oil and soy protein composing of the soybean curd were measured between $30^{\circ}C\;and\;-40^{\circ}C$. The thermal conductivity of soybean oil was measured to be 0.160 and 0.140, $W/m{\cdot}K$ at unfrozen and frozen states, respectively. The effective thermal conductivity of the soybean curd depended not only on its water content but also on its fat and protein contents.

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A Study on the Dielectric Properties of SBS/Conductive Filler/Dielectrics Composites for Phantom Model (팬텀 모델 제작을 위한 SBS/도전체/유전체 3상 복합재료의 유전특성 연구)

  • Kim, Yoon-Jin;Choi, Hyung-Do;Cho, Kwang-Yun;Yoo, Don-Sik;Yoon, Ho-Gyu;Suh, Kwang-Seok
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.98-107
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    • 2001
  • Dielectric properties and shape memory characteristics of SBS composites filled with carbon black as conductive filler and (Ba,Ca)$(Sn,Ti)O_3$ or $SrTiO_3$ as dielectrics were investigated for the development of phantom model. SBS/carbon black composite showed an increment of complex dielectric constant with increasing the content of carbon black and the frequency dependence that the dielectric constant decreases with the frequency. The complex dielectric constant and the conductivity of SBS/carbon black/dielectrics composites increased with the increase of dielectrics and the characteristics of the frequency dependence also occurred by the effect of carbon black. Phantom materials with the dielectric properties and the conductivity corresponding to human tissues for the measurement of specific absorption rate(SAR) within the frequency range of current mobile phones(775MHz~2GHz) could be developed by adjusting the composition ratios of carbon black, dielectrics and SBS and by controlling the characteristic of frequency dependence of composite. From thermomechanical cycling test good shape recoverability could be obtained in SBS composite even though the residual strain was increased by the effect of filler.

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Electrical and Rheological Behaviors of VGCF/Polyphenylene Sulfide Composites (기상성장 탄소섬유/폴리페닐렌설파이드 복합체 제조 및 전기적$\cdot$유변학적 거동)

  • Noh, Han-Na;Yoon, Ho-Gyu;Kim, Jun-Kyung;Lee, Hyun-Jung;Park, Min
    • Polymer(Korea)
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    • v.30 no.1
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    • pp.85-89
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    • 2006
  • The effect of vapor grown carbon fiber (VGCF) contents on electrical and rheological properties of VGCF filled polyphenylene sulfide (PPS) composites prepared through melt mixing using a twin screw exruder was studied. This method was proved to be quite effective to produce good dispersion of VGCF in the matrix even for highly filled PPS. From the dependence of the electrical conductivity on VGCF content, the percolation phenomena began to occur above $10\;wt\%$. While there is only a marginal increase of viscosity for 1 and $5\;wt\%$ VGCF filled PPS, the composites containing $10\;wt\%$. While VGCF showed abrupt increase in viscosity as well as flattening of frequency vs modulus curve, indicating a transition from a liquid-like to a solid-like behavior due to the creation of VGCF network. This result agrees well to the fact that the network formation in the composite can be composite by rheological property dependence on filler content as well as by electrical conductivity measurement.

A Study on the RRA(Retrogression and Reaging) treatment of 7050 Al alloy (7050 Al 합금의 RRA 처리에 관한 연구)

  • Choi, Joong-Whoan;Kim, Jang-Ryang;Lee, Sang-Lae;Kim, In-Bae
    • Korean Journal of Materials Research
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    • v.10 no.7
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    • pp.493-498
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    • 2000
  • The effects of RRA treatment on the microstructures and mechanical properties of 7050 Al alloy were investigated by differential scanning calolimetry, transmission electron microscopy, microhardness measurement and electrical conductivity. The hardness of 2nd-step aged specimen at $175^{\circ}C$ was decreased to mimimum value and increased to a peak hardness, and then re-decreased with retrogression treatment. It was found that the hardness of 2nd-step aged specimen was further increased by 3rd step aging treatment($120^{\circ}C$x24h). The initial decrease in hardness during 2nd-step aging was due to the partial dissolution of pre-existing GP zone, the major precipitation hardening phase at T6 condition. It was confirmed that the major precipitation hardening phase at 3rd-step aging was GP zone and η' phase. The electrical conductivity increased continually through 2nd-step and 3rd-step aging treatment. It was conclude that the optium 2nd-step aging condition was at $175^{\circ}C$ for 50min by considering the hardness and electrical conductivity.

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Spatial Variability of Hydraulic Properties in a Multi-Layered Soils of Japanese Larch (Larix leptolepis) Stand (낙엽송림분의 다층구조 토광에 있어서 수리특성의 공간 변리)

  • Chung Doug Young;Jin Hyun O
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.1 no.1
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    • pp.29-35
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    • 1999
  • Soil structure and organic matter have been known to strongly affect water flow and solute transport, yet little information is available concerning soil hydraulic properties related to soil physical and chemical properties in the forest site. The purpose of this study was to quantify the spatial variability and spatial correlation of the measured parameter values from the plots established with the rainfall simulator on Japanese larch(Larix leptolepis) dominated site in Kwangju. Kyunggi-Do. Measurement of soil water flux and retention were made with the inherent soil texture, soil structure, and organic matter. The method was based on the observation that when water was applied at a constant rate to the soil surface on each plot. The method was simple to apply and consists of following steps: (i) Wet the soil from a rainfall simulator with several known discharge rates on a relatively leveled soil surface with and without organic matter. (ii) Once the borders of the ponded zone were steady, saturated hydraulic conductivity( $K_{s}$) and the matric flux function(F) was evaluated from a regression of flux vs. the reciprocal of the ponded area. A conductivity of the form $K_{i+}$$_1$ $_{c}$= $K_{i}$( $_{c}$) [1-d /dz] where flux continuity implies. For this, continuity of matric potential at the interface at all times are as follows: $_1$( $Z_{c}$) = $_2$( $Z_{c}$) = $_{c}$ for steady state intake from water ponded on the soil surface. Results of this investigation showed the importance of understanding spatial variability in wide differences of water retention and saturated hydraulic conductivity with respect to pore geometry and organic matter contents which influenced the water flux throughout the soil profile.l profile.ile.

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Fabrication of Electrolyte for Direct Carbon Fuel Cell and Evaluation of Properties of Direct Carbon Fuel Cell (직접탄소 연료전지용 전해질 제조 및 직접탄소 연료전지 특성 평가)

  • Pi, Seuk-Hoon;Cho, Min-Je;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.786-789
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    • 2011
  • In order to estimate the possibility of applying electrolytes generally used in solid oxide fuel cells(SOFCs) to direct carbon fuel cells(DCFCs), properties of YSZ(yttria stabilized zirconia) electrolyte were evaluated. In this study, vacuum slurry coating method was adapted to coat thin layer on anode support substrate. After sintering the electrolyte at $1400^{\circ}C$ for 5hrs, microstructure was analyzed by using SEM image. Also, gas permeability and ionic conductivity were measured to find out the potential possibility of electrolyte for DCFCs. The YSZ electrolyte represented dense coating layer and low gas permeability value. The ionic conductivity of YSZ electrolyte was high over $800^{\circ}C$. After measurement of the electrolyte properties, direct carbon fuel cell was fabricated and its performance was measured at $800^{\circ}C$.

Experimental Study on Fracture Pressure, Permeability Enhancement and Fracture Propagation using Different Fracture Fluids (다양한 파쇄 유체별 파쇄압력, 투과도 증진 및 균열전파에 관한 실험적 연구)

  • Choi, JunHyung;Lee, Hyun Suk;Kim, Do Young;Nam, Jung Hun;Lee, Dae Sung
    • Tunnel and Underground Space
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    • v.31 no.1
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    • pp.41-51
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    • 2021
  • The hydraulic fracturing developed to improve permeability of tight reservoir is one of key stimulation technologies for developing unconventional resources such as shale gas and deep geothermal energy. The experimental study was conducted to improve disadvantage of hydraulic fracturing which has simple fracture pattern and poor fracturing efficiency. The fracturing experiments was conducted for tight rock using various fracturing fluids, water, N2, and CO2 and the created fracture pattern and fracturing efficiency was analyzed depending on fracturing fluids. The borehole pressure increased rapidly and then made fractures for hydraulic fracturing with constant injection rate, however, gas fracturing shows slowly increased pressure and less fracture pressure. The 3D tomography technic was used to generate images of induced fracture using hydraulic and gas fracturing. The stimulated reservoir volume (SRV) was estimated increment of 5.71% (water), 12.72% (N2), and 43.82% (CO2) respectively compared to initial pore volume. In addition, permeability measurement was carried out before and after fracturing experiments and the enhanced permeability by gas fracturing showed higher than hydraulic fracturing. The fracture conductivity was measured by increasing confining stress to consider newly creating fracture and closing induced fracture right after fracturing. When the confining stress was increased from 2MPa to 10MPa, the initial permeability was decreased by 89% (N2) and 50% (CO2) respectively. This study shows that the gas fracturing makes more permeability enhancement and less reduction of induced fracture conductivity than hydraulic fracturing.

SiC(3C)/Si Photodetector (SiC(3C)/Si 수광소자)

  • 박국상;남기석;김정윤
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.2
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    • pp.212-216
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    • 1999
  • SiC(3C) photodiodes (PDs) were fabricated on p-type Si(111) substrates using chemical vapor deposition (CVD) technique by pyrolyzing tetramethylsilane (TMS) with $H_{2}$ carrier gas. Electrical properties of SiC(3C) were investigated by Hall measurement and current-voltage (I-V) characteristics. SiC(3C) layers exhibited n-type conductivity. Ohmic contact was formed by thermal evaporation Al metal through a shadow-mask. The optical gain $(G_{op})$ of the SiC(3C)/Si PD was measured as a function of the incident wavelength. For the analysis of the photovoltaic detection of the Sic(3C) n/p PD, the spectral response (SR) has calculated by using the electrical parameters of the SiC(3C) layer and the geometric structure of the PD. The peak response calculated for properly chosen parameters was about 0.75 near 550 nm. We expect a good photoresponse in the SiC(3C) heterostructure for the wavelength range of 400~600 nm. The SiC(3C) photodiode can detect blue and near ultraviolet (UV) radiation.

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Development of Realtime Ubiquitous River Monitoring System (실시간 유비쿼터스 하천정보 모니터링 시스템의 개발)

  • Jang, Bok-Jin;Lee, Jong-Kook;Yeo, Woon-Kwang
    • Proceedings of the Korea Water Resources Association Conference
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    • 2006.05a
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    • pp.1305-1312
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    • 2006
  • This study is about the development of measurement system using ubiquitous wireless communication for river flow monitoring. The system can acquire water depth, quality (temperature, pH, conductivity, turbidity etc.) while a GPS module for getting the location data of measurement points. Also this system is able to acquire the field data via RF connection and can be controlled same time. The acquired data is transmitted to a gateway system from the remote buoy using Zigbee wireless connection. And the gateway system is able to monitor the data through GIS monitoring tool. Finally the data are transmitted to a server computer using CDMA wireless connection by gateway system. The D/B of server computer are constructed automatically and monitored the project web site. The resulting system can be used for scour monitoring, environment monitoring and the other monitoring purposes such as a river flow monitoring system.

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