• 제목/요약/키워드: conductive polymer

검색결과 400건 처리시간 0.033초

DMSO 첨가에 따른 리튬이차전지용 복합필름의 전기적 특성 (The Electrical Characteristic of Composite Film for Lithium Secondary Battery by adding DMSO)

  • 박수길;김종진;이창진;김상욱;김현후;임기조;이주성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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    • pp.269-272
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    • 1997
  • The Lithium ion secondary battery has been developed for high energy density of portable electrical device and electronics. Among the many conductive polymer materials, the positive active film for Li polymer battery system was synthesized successfully from polyphenylene diamine(PPD) by chemical polymerization in our lab. And PPD-DMcT(2, 5-dimercapto-1, 3, 4-thi-adiazole) composite flim conductive material, at high temperature was also prerared with the addition of dimethylsulfoxide(DMSO). The surface morphology and thermal stability of prepared composite flim was carried out by using SEM and TGA, respectively. Electrochemical and electrical conductivity of composite flim were also discussed by cyclic voltammetry and four-probe method in dry box(<27pm). And the electrode reaction mechanism was detected and analyzed from the half cell unit battery system.

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Patterning of Conductive Polymer Anodes Using a Peel-off Method

  • Park, Jong-Woon;Yim, Youn-Chan;Heo, Gi-Seok;Lee, Jong-Ho;Kim, Tae-Won;Kim, Gwang-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.868-870
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    • 2009
  • Here we report another soft lithography, peel-off method, for patterning conductive polymer anodes in the fabrication of flexible ITO-free organic light-emitting diodes. This method doesn't require any heating process and UV light. We have demonstrated that such a peel-off technique enables the formation of a very sharp edge and the enhancement of edge roughness.

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전도성 폴리머와 셀룰로오스 종이를 결합한 EAPap 작동기 (Conductive Polymer Coated Electro-active Paper (EAPap) as Hybrid Actuator)

  • 윤성률;김재환
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2004년도 추계학술대회논문집
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    • pp.275-278
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    • 2004
  • Electro-Active Paper (EAPap) is attractive for EAP actuator due to its merit in terms of light weight, dry condition, large displacement output, low actuation voltage and low power consumption. The EAPap is based on cellulose paper, and is shown to involve primarily transport of ions in response to an external electric field. This actuating mechanism is similar to conductive polymer based actuators. For performance improvement of EAPap, hybrid actuators are tried. The actuators based on cellulose paper attached conducting polypyrrole, polyaniline and single wall carbon nanotube/polyaniline(emeraldine base) have been achieved by Electro chemical deposition and mechanical deposition of the polymers onto cellulose paper.

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Polymer/LC Composite for Holographic Grating

  • Kim, Byung-Kyu;Woo, Ju-Yeon;Kim, Eun-Hee
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.218-218
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    • 2006
  • A number of new ideas have been implemented to control the droplet morphology and electrooptic properties of holographic polymer dispersed liquid crystal (HPDLC). Doping of conductive fullerene particles to the conventional HPDLC induced dual effects of reducing both droplet coalescence and operating voltage. Chain transfer agent gave higher gel content with lower crosslink density, less dark reactions and less grating shrinkage with much smooth LC-polymer interfaces. Addition of octanoic acid (OA) to the formulation of HPDLC gave a decrease in droplet size and monotonic increase of the off state diffraction throughout the OA content.

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Study on the Cycling Performances of Lithium-Ion Polymer Cells Containing Polymerizable Additives

  • Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • 제30권2호
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    • pp.319-322
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    • 2009
  • Gel polymer electrolytes were prepared by immersing a porous poly(vinylidene fluoride-co-hexafluoropropylene) membrane in an electrolyte solution containing small amounts of polymerizable additive (3,4-ethylenedioxythiophene, thiophene, biphenyl). The organic additives were electrochemically oxidized to form conductive polymer films on the electrode at high potential. With the gel polymer electrolytes containing different organic additive, lithium-ion polymer cells composed of carbon anode and LiCo$O_2$ cathode were assembled and their cycling performances were evaluated. Adding small amounts of thiophene or 3,4-ethylenedioxythiophene to the gel polymer electrolyte was found to reduce the charge transfer resistance in the cell and it thus exhibited less capacity fading and better high rate performance.

Nanoscale Metal Powders Production and Applications

  • Gunther, Bernd-H
    • 한국분말재료학회지
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    • 제9권6호
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    • pp.409-415
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    • 2002
  • In this review the methods for production and processing of isolated or agglomerated nanoscale metal particles embedded in organic liquids (nanosuspensions) and polymer matrix composites are elucidated. Emphasis is laid on the techniques of inert gas condensation (IGC) and high pressure sputtering for obtaining highly porous metal powders ("nanopowder") as well as on vacuum evaporation on running liquids for obtaining nanosuspensions. Functional properties and post-processing are outlined in view of applications in the fields of electrically conductive adhesives and anti-microbially active materials for medical articles and consumer goods.mer goods.

스마트 윈도우용 리들 전도성 전해질 개발 (Development of Lithium Conductive Polymer Electrolyte for Smart Windows)

  • 박태성;백희원;진교원;김영호;조봉희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.262-265
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    • 1997
  • Various polymeric electrolytes were prepared from PEG, PEO and PMMA with LiClO$_4$ to develop lithium conductive electrolytes for smart windows. The complementary electrochromic devices were fabricated with these electrolytes involving cathodically coloring WO$_3$ and anodically coloring V$_2$O$\sub$5/ thin films. The performance of electrochromic device with PMMA/LiCLO$_4$ electrolyte was found to be excellent

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Effect of CNTs on Electrical Properties and Thermal Expansion of Semi-conductive Compounds for EHV Power Cables

  • Jae-Gyu Han;Jae-Shik Lee;Dong-Hak Kim
    • 한국전기전자재료학회논문지
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    • 제36권6호
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    • pp.603-608
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    • 2023
  • Carbon black with high purity and excellent conductivity is used as a conductive filler in the semiconductive compound for EHV (Extra High Voltage) power cables of 345 kV or higher. When carbon black and CNT (carbon nanotube) are applied together as a conductive filler of a semiconductive compound, stable electrical properties of the semiconductive compound can be maintained even though the amount of conductive filler is significantly reduced. In EHV power cables, since the semi-conductive layer is close to the conductor, stable electrical characteristics are required even under high-temperature conditions caused by heat generated from the conductor. In this study, the theoretical principle that a semiconductive compound applied with carbon black and CNT can maintain excellent electrical properties even under high-temperature conditions was studied. Basically, the conductive fillers dispersed in the matrix form an electrical network. The base polymer and the matrix of the composite, expands by heat under high temperature conditions. Because of this, the electrical network connected by the conductive fillers is weakened. In particular, since the conductive filler has high thermal conductivity, the semiconductive compound causes more thermal expansion. Therefore, the effect of CNT as a conductive filler on the thermal conductivity, thermal expansion coefficient, and volume resistivity of the semiconductive compound was studied. From this result, thermal expansion and composition of the electrical network under high temperature conditions are explained.

Electrical Properties of PVdF/PVP Composite Filled with Carbon Nanotubes Prepared by Floating Catalyst Method

  • Kim, Woon-Soo;Song, Hee-Suk;Lee, Bang-One;Kwon, Kyung-Hee;Lim, Yun-Soo;Kim, Myung-Soo
    • Macromolecular Research
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    • 제10권5호
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    • pp.253-258
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    • 2002
  • The multi-wall carbon nanotubes (MWNTs) with graphite crystal structure were synthesized by the catalytic decomposition of a ferrocene-xylene mixture in a quartz tube reactor to use as the conductive filler in the binary polymer matrix composed of poly(vinylidene fluoride) (PVdF) and poly(vinyl pyrrolidone) (PVP) for the EMI (electromagnetic interference) shielding applications. The yield of MWNTS was significantly dependent on the reaction temperature and the mole ratio of ferrocene to xylene, approaching to the maximum at 800 $^{\circ}C$ and 0.065 mole ratio. The electrical conductivity of the MWNTs-filled PVdF/PVP composite proportionally depended on the mass ratio of MWNTs to the binary polymer matrix, enhancing significantly from 0.56 to 26.7 S/cm with the raise of the mass ratio of MWNTs from 0.1 to 0.4. Based on the higher electrical conductivity and better EMI shielding effectiveness than the carbon nanofibers (CNFs)-filled coating materials, the MWNTs-filled binary polymer matrix showed a prospective possibility to apply to the EMI shielding materials. Moreover, the good adhesive strength confirmed that the binary polymer matrix could be used for improving the plastic properties of the EMI shielding materials.