• Title/Summary/Keyword: conductive carbon

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Effects of binary conductive additives on electrochemical performance of a sheet-type composite cathode with different weight ratios of LiNi0.6Co0.2Mn0.2O2 in all-solid-state lithium batteries

  • Ann, Jiu;Choi, Sunho;Do, Jiyae;Lim, Seungwoo;Shin, Dongwook
    • Journal of Ceramic Processing Research
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    • v.19 no.5
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    • pp.413-418
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    • 2018
  • All-solid-state lithium batteries (ASSBs) using inorganic sulfide-based solid electrolytes are considered prospective alternatives to existing liquid electrolyte-based batteries owing to benefits such as non-flammability. However, it is difficult to form a favorable solid-solid interface among electrode constituents because all the constituents are solid particles. It is important to form an effective electron conduction network in composite cathode while increasing utilization of active materials and not blocking the lithium ion path, resulting in excellent cell performance. In this study, a mixture of fibrous VGCF and spherical nano-sized Super P was used to improve rate performance by fabricating valid conduction paths in composite cathodes. Then, composite cathodes of ASSBs containing 70% and 80% active materials ($LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$) were prepared by a solution-based process to achieve uniform dispersion of the electrode components in the slurry. We investigated the influence of binary carbon additives in the cathode of all-solid-state batteries to improve rate performance by constructing an effective electron conduction network.

An Experimental Study on Electric Resistivity and Exothermic Property of Electrically Conductive Mortar using Amorphous Graphite (흑연을 혼입한 전기전도 모르타르의 전기저항 및 발열특성에 관한 실험적 연구)

  • Ahn, Hong-JIn;Kim, Sang-Heon;Choi, Soo-Kyung
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.3
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    • pp.247-255
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    • 2016
  • The exothermic property of electrical conductivity concrete would allow the heating system of house or snow melting system of tunnel, road or bridge deck. This study was performed on electric resistance, exothermic property and mechanical property of the mortar with graphite of carbon-based conductive material as a fundamental research for the heat conductive concrete development. As the results of this experiment, the increasement on the amorphous graphite substitution rate was found to decrease in the compressive strength, however, the electric resistance was found to be significantly lower. And, in order to demonstrate the exothermic property, the graphite was found to be included more than 15% of the total mortar volume. When low electric resistance obtained with a certain level of the graphite inclusion, exothermic value and applied voltage has a higher correlation, and the exothermic value and the square of the voltage appeared to be in a proportional relationship.

Technology of Flexible Transparent Conductive Electrode for Flexible Electronic Devices (유연전자소자를 위한 차세대 유연 투명전극의 개발 동향)

  • Kim, Joo-Hyun;Chon, Min-Woo;Choa, Sung-Hoon
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.2
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    • pp.1-11
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    • 2014
  • Flexible transparent conductive electrodes (TCEs) have recently attracted a great deal of attention owing to rapid advances in flexible electronic devices, such as flexible displays, flexible photovoltanics, and e-papers. As the performance and reliability of flexible electronics are critically affected by the quality of TCE films, it is imperative to develop TCE films with low resistivity and high transparency as well as high flexibility. Indium tin oxide (ITO) has been the most dominant transparent conducting material due to its high optical transparency and electrical conductivity. However, ITO is susceptible to cracking and delamination when it is bent or deformed. Therefore, various types of flexible TCEs, such as carbon nanotube, conducting polymers, graphene, metal mesh, Ag nanowires (NWs), and metal mesh have been extensively investigated. Among several options to replace ITO film, Ag NWs and metal mesh have been suggested as the promising candidate for flexible TCEs. In this paper, we focused on Ag NWs and metal mesh, and summarized the current development status of Ag NWs and metal mesh. The several critical issues such as high contact resistance and haze are discussed, and newly developed technologies to resolve these issues are also presented. In particular, the flexibility and durability of Ag NWs and metal mesh was compared with ITO electrode.

Manufacturing Experiments using FDM 3D-printed Flexible Resistance Sensors with Heterogeneous Polymer Material Annealing (이종 폴리머재료 어닐링을 이용한 유연저항센서 FDM 3D프린팅 제작실험)

  • Lee, Sun Kon;Oh, Young Chan;Kim, Joo Hyung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.1
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    • pp.81-88
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    • 2020
  • In this paper, the performances of the electrical characteristics of the Fused Deposition Modeling (FDM) 3D-printed flexible resistance sensor was evaluated. The FDM 3D printing flexible resistive sensor is composed of flexible-material thermoplastic polyurethane and a conductive PLA (carbon black conductive polylactic acid) polymer. While 3D printing, polymer filaments heat up quickly before being extruded and cooled down quickly. Polymers have poor thermal conductivity so the heating and cooling causes unevenness, which then results in internal stress on the printed parts due to the rapidity of the heating and cooling. Electrical resistance measurements show that the 3D-printed flexible sensor is unstable due to internal stress, so the 3D-printed flexible sensor resistance curve does not match the increases and decreases in the displacement curve. Therefore, annealing was performed to eliminate the mismatch between electrical resistance and displacement. Annealing eliminates residual stress on the sensor, so the electrical resistance of the sensor increases and decreases in proportion to displacement. Additionally, the resistance is lowered in comparison to before annealing. The results of this study will be very useful for the fabrication of various devices that employ 3D-printed flexible sensor that have multiple degrees of freedom and are not limited by size and shape.

Effects of Filler Characteristics and Processing Conditions on the Electrical, Morphological and Rheological Properties of PE and PP with Conductive Filler Composites

  • Kim, Youn-Hee;Kim, Dong-Hyun;Kim, Ji-Mun;Kim, Sung-Hyun;Kim, Woo-Nyon;Lee, Heon-Sang
    • Macromolecular Research
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    • v.17 no.2
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    • pp.110-115
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    • 2009
  • The electrical, morphological and rheological properties of melt and dry mixed composites of poly ethylene (PE)/graphite (Gr), polypropylene (PP)/Gr and PP/nickel-coated carbon fiber (NCCF) were investigated as a function of filler type, filler content and processing temperature. The electrical conductivities of dry mixed PP/NCCF composites were increased with decreasing processing temperature. For the melt mixed PP/NCCF composites, the electrical conductivities were higher than those of the melt mixed PE/Gr and PP/Gr composites, which was attributed to the effect of the higher NCCF aspect ratio in allowing the composites to form a more conductive network in the polymer matrix than the graphite does. From the results of morphological studies, the fillers in the dry mixed PP/NCCF composites were more randomly dispersed compared to those in the melt mixed PP/NCCF composites. The increased electrical conductivities of the dry mixed composites were attributed to the more random dispersion of NCCF compared to that of the melt mixed PP/NCCF composites. The complex viscosities of the PP/Gr composites were higher than those of the PP/NCCF composites, which was attributed to the larger diameter of the graphite particles than that of the NCCF. Furthermore, the fiber orientation in the 'along the flow' direction during melt mixing was attributed to the decreased complex viscosities of the melt mixed PP/NCCF composites compared those of the melt mixed PP/Gr composites.

Charging Behavior of Chopped Carbon Fibers under High Intensity Electric Fields

  • Park, Min;Kim, Junkyung;Lim, Soon-Ho;Ko, Moon-Bae;Choe, Chul-Rim
    • Macromolecular Research
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    • v.8 no.1
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    • pp.6-11
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    • 2000
  • In this study, we examined the charging behavior of chopped carbon fibers during electro-flocking process, which is one of the key processes of the novel technique for fabricating conductive polymer composite films. Short carbon fibers (CF) during electroflocking were electrically charged by the combined effect of contact charging, corona charging and tribocharging. The specific charge built on CF surface was measured by using Faraday cup method. Specific charge increased not only with increasing electric field strength and potential impressed to mesh electrode as expected from theoretical considerations in literature, but with decreasing mesh opening size due to the improved contact charging condition. However, CF length was found unexpectedly to influence the amount of CF specific charge due to the agglomerated nature of CF flocks leading to the change in charging conditions.

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Interfacial Sensing and Evaluation of Carbon and SiC Fibers/Epoxy Composites with Different Embedding Angle using Electro-Micromechanical Technique (Electro-Micromechanical Technique을 이용한 각의 변화에 따른 Carbon과 SiC Fiber/Epoxy Composites의 계면감지능 및 평가)

  • Lee, Sang-Il;Kong, Jin-Woo;Park, Joung-Man
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.05a
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    • pp.199-202
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    • 2002
  • Interfacial properties and electrical sensing for fiber fracture in carbon and SiC fibers/epoxy composites were investigated by the electrical resistance measurement and fragmentation test. As fiber-embedded angle increased, interfacial shear strength (IFSS) of two-type fiber composites decreased, and the elapsed time was long to the infinity in electrical resistivity. The initial slope of electrical resistivity increased rapidly to the infinity at higher angle, whereas electrical resistivity increased gradually at small angle. Furthermore, both fiber composites with small embedded angle showed a fully-developed stress whitening pattern, whereas both composites with higher embedded angle exhibited a less developed stress whitening pattern. As embedded angle decreased, the gap between the fragments increased and the debonded length was wider for both fiber composites. Electro-micromechanical technique can be a feasible nondestructive evaluation to measure interfacial sensing properties depending on the fiber-embedded angle in conductive fiber reinforced composites.

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The Physical Properties and Shielding Efficiency of Electromagnetic Wave Shielding Cement Mortar Using Magnetite-Carbon (Magnetite-Carbon을 이용한 전자파 흡수형 차폐 시멘트 모르터의 물리적 특성과 차폐효율)

  • Park Dong Cheol;Lee Sea Hyun;Song Tae Hyup;Shin Jong Woo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.608-611
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    • 2004
  • As the use of various electronic equipments has been increased recently according to industrialization and information network establishment, concern about electromagnetic wave exposed environment has also been increased. Therefore, this study aims to verify electromagnetic wave absorbing effects of inorganic paint that is made of carbon, electro-conductive materials with regard to its physical characteristics, its electromagnetic wave absorbing rate through a mock-up test for proving its effects in the indoor condition. The results are as follows: The results of running tests on electromagnetic wave absorbing inorganic paints for checking their requirements as painting material such as adherence degree, resistance to fine crack, resistance to washing, alkali-resistance, discoloration-resistance, etc. show that inorganic paints have the physical characteristics meeting the requirements for painting materials. In addition, it shows that the electromagnetic wave absorbing effect, in line with the number of paintings and the thickness of paintings, secures $75\~89\%$ of efficiency. And the mock-up test shows that the electromagnetic wave absorbing effect inside building is directly proportional to the distance from the source of electromagnetic wave such as electronic equipments.

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The Effect of Energy-absorbing layers on Micro-patterning of Magnetic Metal Films using Nd:YAG Laser (Nd:YAG Laser를 이용한 자성금속막의 패턴 식각에 있어서 에너지 흡수층이 미치는 영향)

  • 이주현;채상훈;서영준;송재성;민복기;안승준
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.6
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    • pp.538-544
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    • 2000
  • The laser patterning of sputter-deposited CoNdZr/Cu/CoNbZr multi-layered films had been tried using Nd:YAG laser. However generally it is very difficult to remove metal films because of their high reflectance of the laser on the surfaces. As a counterproposal for this problem authors for the first time tried to deposit energy-absorbing layers on the metal films and then irradiated the laser on the surfaces of energy-absorbing layers. Here the energy-absorbing layers consisted of laser energy-absorbing fine powders and binding polymers. Three kinds of powders for the energy-absorbing layers had been used to see the difference in the pattern formation with the degree of laser energy absorption. They were electrically conductive silver powders insulating BaTiO$_3$powder and semiconducting carbon powder. Remarkable difference in width of the formed pattern and the roughness of pattern edge were observed with the characteristic of the powder for the energy-absorbing layer. The pattern width using carbon paste was about three times larger than that using BaTiO$_3$paste. It was observed that the energy-absorbing layer with carbon was the most effective on this micro-patterning.

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Effect of Binders on Electrochemical and Mechanical Properties of Activated Carbon Electrode for Electric Double Layer Capacitor (EDLC용 활성탄소 전극의 전기화학적 기계적 특성에 미치는 바인더의 영향)

  • Jeon, Min-Je;Kim, Ick-Jun;Yang, Sun-Hye;Moon, Seong-In;Kim, Hyun-Soo;Oh, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.12
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    • pp.1167-1171
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    • 2006
  • This work describes the effect of binders, such as carboxymethylcellulose (CMC), CMC+ Polytetrafluoroethylene (PTFE) and PTFE, on the electrochemical and mechanical properties of activated carbon-electrode for electric double layer capacitor. The cell capacitors using the electrode bound with binary binder composed of CMC and PTFE, especially in composition CMC PTFE = 60 : 40 wt.%, has better rate capability and the lower internal resistance than those of the cell capacitor with CMC. On the other hand, the sheet type electrode kneaded with PTFE was bonded with conductive adhesive on Al foil. This cell capacitor using the electrode with PTFE exhibited the best mechanical properties and rate capability compared to the CMC and CMC+PTFE one. These behaviors could be explained by the well-developed network structure of PTFE fibrils doting the kneading process.