• 제목/요약/키워드: conducting property

검색결과 213건 처리시간 0.026초

ZnO/Cu/ZnO 박막의 차량용 저방사 및 전기광학적 특성 연구 (The emissivity and opto-electrical properties of ZnO/Cu/ZnO thin films for the vehicle applications)

  • 이연학;김선경;엄태용;정용하;소상우;손영길;손동일;김대일
    • 한국표면공학회지
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    • 제56권6호
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    • pp.451-456
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    • 2023
  • Transparent conducting films having a three layered structure of ZnO/Cu/ZnO (ZCZ) were deposited onto the glass substrates by using RF and DC magnetron sputtering at room temperature. The emissivity and opto-electrical properties of the films were investigated with a varying thickness(5, 10, 15 nm) of the Cu interlayer. With increasing the Cu thickness to 15 nm, the films showed a enhanced electrical properties. Although ZnO 30/Cu 15/ZnO 30 nm film shows a lower resistivity of 5.2×10-5 Ωcm, it's visible transmittance is deteriorated by increased optical absorbtion of the films. In addition, X-ray diffraction patterns indicated that the insertion of Cu interlayer improve the grain size of ZnO films, which is favor for the electrical and optical properties of transparent conducting films. From the observed low emissivity of the films, it is concluded that the ZCZ thin films with optimal thickness of Cu interlayer can be applied effectively for the car's window coating materials.

탄소나노복합재료와 전고체 전해질 기반의 유연성 슈퍼커패시터의 전기화학적 특성 분석 (Electrochemical performance of the flexible supercapacitor based on nanocarbon material/conductive polymer composite and all solid state electrolyte)

  • 김창현;김용렬;정현택
    • 한국응용과학기술학회지
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    • 제36권1호
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    • pp.200-207
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    • 2019
  • 본 연구에서는 "이온젤"이라고 불리는 고분자 기반의 PVA(polyvinyl alcohol)-$H_3PO_4$의 고체 전해질에 이온성 액체 $BMIMBF_4$ (1-buthyl-3-methylimidazolium tetrafluoroborate)를 첨가하여 제조한 전고체 전해질과 환원된 그래핀 옥사이드/전도성 고분자 복합재료 기반의 전극 재료를 이용하여 유연성을 갖는 슈퍼커패시터를 제작 하였으며, 유연성에 따른 전기화학적 특성을 분석하여 보았다. 환원된 그래핀 옥사이드/전도성 고분자 복합재료와 전고체 전해질 기반의 유연성 슈퍼커패시터의 전기화학적 특성을 유연성에 따라서 측정하기 위해서 프레스로 $0.01kg/cm^2$의 일정한 압력으로 최대 100회 까지 굽힘 시험(bending test)을 진행 하였으며, 0~100 회의 굽힘 시험 이후에 순환 전압전류법(CV), 전기화학적 임피던스 분광법(EIS) 및 전정류 충 방전법(GCD)을 통하여 비교 및 분석하여 보았다. 그 결과로, 유연성 슈퍼커패시터의 초기 전기용량은 43.9 F/g으로 확인 할 수 있었고, 이 값은 50회, 100회의 굽힘 시험 후에 각각 42.0F/g, 40.1F/g로 감소하는 현상을 확인할 수 있었다. 이러한 결과로 미루어 보아 물리적인 응력이 슈퍼 커패시터의 전기화학적 특성 감소에 영향을 주는 것으로 사료되며 또한, 굽힘 횟수에 따른 슈퍼커패시터의 전기화학적 특성 감소 원인을 확인하기 위해서 굽힘 시험 전과 후의 전극표면을 전자주사 현미경으로 관찰하여 보았다.

문화재 교육 활성화를 위한 중학교 역사교육과정기준 개발 방안 연구 (A Study on the Development of Middle School History Curriculum Standards for Revitalization of Cultural Property Education)

  • 안대현;홍후조
    • 헤리티지:역사와 과학
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    • 제54권3호
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    • pp.150-167
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    • 2021
  • 3차 교육과정 이후 중학교 역사교육은 정치사 중심으로 실시되어왔으나 많은 학생들은 역사 과목을 단순 암기 과목으로 인식하며 추상적인 학습에 어려움을 호소하고 있다. 연구자는 이러한 문제점이 역사교육과정기준에서 비롯되었다고 보고 중학교 역사교육과정기준에서 문화재 교육 활성화를 제안하기 위한 목적으로 본 연구를 수행하였다. 먼저 선행연구 분석을 통해 창의적 인재 양성과 학생 참여형 역사 수업 구현 등 문화재 교육의 유용성을 밝히고 현행 정치사 중심의 중학교 역사교육과정기준의 문제점을 지적하였다. 이후 중학교 3학년 학생들과 사회과 교사들을 대상으로 역사교육 및 문화재 교육에 관한 의견조사를 실시하였다. 그 결과 첫째, 중학생들은 현행 정치사 중심의 역사를 학습량이 많다고 생각하며 교사들도 이에 대해 동감하는 것으로 나타났다. 둘째, 모든 집단에서 역사교육에서 문화재 교육의 필요성을 공감하였다. 하지만 현실적으로 정치사 중심의 역사교육과정에서 문화재 교육을 충분히 하기가 쉽지 않다고 인식하는 것으로 나타났다. 셋째, 교사들은 문화재 교육을 강화하기 위해 정치사를 중심으로 구성된 현행 역사교육과정기준의 개선이 필요하다고 생각하였다. 이를 바탕으로 연구자는 2015 개정 역사교육과정기준의 개선안을 제시하였다. 먼저 '성격' 부분에서는 문화재 관련 내용을 추가할 것과 역사 자료에 문화재를 포함할 것, '목표' 부분에서는 정치·경제·사회·문화를 포함할 것과 문화재 학습을 통해 우리 민족의 전통과 문화를 계승·보존·발전시켜 나간다는 것을 추가 기술할 것, '내용 체계 및 성취 기준' 부분에서는 소주제에 문화재 관련 내용을 추가할 것과 성취 기준에 문화재 관련 내용을 좀 더 보강할 것, '교수·학습 및 평가' 부분에서는 사료 학습에 문화재 학습을 포함할 것과 문화재 교육의 교수·학습 방법에 대한 안내를 추가할 것을 제안하였다. 이러한 내용들이 현재 개발 중인 2022 개정 교육과정에 반영된다면 문화재 교육이 강화되어 보다 생동감 있는 역사교육을 학생들에게 실시할 수 있을 것이다.

부산임기광산 폐석적치장에서의 순간충격시험 적용성 연구 (Feasibility Study of Slug Test in Unsaturated Mine Tailings Pile of the Imgi Abandoned Mine in Busan)

  • 박학윤;주정웅;정영욱;여인욱
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제12권3호
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    • pp.10-16
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    • 2007
  • 불포화대 및 포화대에 걸쳐 존재하는 폐석더미의 수리적 특성을 조사하기 위해 물을 주입한 후 수두강하를 측정하는 순간충격시험을 실시하였다. 본 연구지역과 같이 관정이 수리적 특성이 크게 다른 두 지층에 걸쳐 설치된 경우, Bower and Rice해석 방법을 이용하여 두 대수층 각 각의 수리전도도를 산출할 수 있었으며, 하강하는 지하수위의 변곡점을 이용하여 폐석더미의 두께를 추정할 수 있었다. 갈수기 시 관정 내 낮은 지하수위 때문에 인위적인 지하수위를 형성시킨 후 순간충격시험을 실시한 결과, 그 결과는 풍수기 시험 결과와 차이가 크지 않았다. 이와 같은 순간 충격시험은 폐석적치장과 같은 곳의 수리적 특성을 파악할 수 있는 유효한 방법으로 판단된다.

AC4A 알루미늄 합금의 인장 및 응고균열 특성에 미치는 스크랩 첨가 비율의 영향 (Effect of Scrap Addition Ratio on Tensile and Solidification Cracking Properties of AC4A Aluminum Casting Alloy)

  • 오승환;김헌주
    • 한국주조공학회지
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    • 제40권3호
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    • pp.85-96
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    • 2020
  • The effect of an aluminum scrap addition ratio on the tensile and solidification cracking properties of the AC4A aluminum alloy in the as-cast state and heat-treated state were investigated in this study. Generally, the expected problem of using scrap in aluminum casting is an increase of hydrogen and Fe element inside the aluminum melt. Another issue is an oxide film which has a weak interface with the molten aluminum and acts as potent nucleation sites for internal porosity and crack initiation. Solidification cracking is one of the critical defects that must be resolved to produce high quality castings. A conventional evaluation method for solidification cracking is a relative and qualitative analysis method which does not provide quantitative data on the thermal stress in the solidification process. Therefore, a newly designed solidification cracking test apparatus was used in this study, and the device can provide quantitative data. As a result, after conducting experiments with different scrap addition ratios (0%, 20%, 35%, 50%), the tensile strengths and elongations in the as-cast state were 214, 187.7, 182.1 and 170.4MPa and 4.6%, 3.4%, 3.1% and 2.3%, respectively. In the case of the T6 heat-treated state, the tensile strengths and elongations were 314.9, 294.6, 293.1 and 271.1MPa and 5.4%, 4.6%, 3.8% and 3.1%, respectively. The strength of the solidification cracking was 3.1, 2.4, 2.2and 1.6MPa as the scrap addition ratio increases.

Flexible ITO/PEDOT:PSS Hybrid Transparent Conducting Electrode for Organic Photovoltaics

  • Lim, Kyounga;Jung, Sunghoon;Kang, Jae-Wook;Kim, Jong-Kuk;Kim, Do-Geun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.299-299
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    • 2013
  • Indium Tin Oxide (ITO) has widely been used as a transparent conductive oxide (TCE) for photovoltaic devices. Lately, flexibility of ITO becomes an issue as demand of flexible device increases. Several scientists have tried to substitute ITO to different materials such as conductive polymer, graphene, CNT, and metal nanowire because of ITO brittleness. Among the substitute materials, PEDOT:PSS has mostly paid attention because PEDOT:PSS has excellent flexibility and good conductivity. The conductivity of PEDOT:PSS increases up to 1000 S/cm with additives such as DMSO, EG, sorbitol, and so on. In our research group, we introduce a conductive polymer PEDOT:PSS as a buffer layer to improve not only flexibility but also conductivity. As PEDOT:PSS layer forms beneath ITO thin film (20 nm), sheet resistance decreases from $230{\Omega}$/${\Box}$ to $85{\Omega}$/${\Box}$ and crack initiation decreases from 4.5 mm to 3.5 mm as well. We have fabricated organic photovoltaic device and power conversion efficiencies using conventional ITO electrode and ITO/PEDOT:PSS hybrid electrode. The photovoltaic property such as power conversion efficiency for ITO/PEDOT:PSS hybrid electrode is comparable to the value obtained using conventional ITO electrode on glass substrate.

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STM/STS에 의한 Au (111)에 자기조립된 니트로분자의 전기적 특성 측정 (Study on electrical property of self-assembled nitro molecule onto Au(111) by Using STM/STS)

  • 이남석;최원석;신훈규;장정수;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.1844-1846
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    • 2005
  • The characteristic of negative differential resistance(NDR) is decreased current when the applied voltage is increased. The NDR is potentially very useful in molecular electronics device schemes. Here, we investigated the NDR property of self-assembled 4,4- Di(ethynylphenyl)-2'-nitro-1-(thioacetyl)benzene, which has been well known as a conducting molecule. Self-assembly monolayers(SAMs) were prepared on Au(111), which had been thermally deposited onto pre-treatment$(H_2SO_4:H_2O_2=3:1)$ Si. The Au substrate was exposed to a 1mM/l solution of 1-dodecanethiol in ethanol for 24 hours to form a monolayer. After thorough rinsing the sample, it was exposed to a $0.1{\mu}M/l$ solution of 4,4-Di(ethynylphenyl)-2'-nitro-1-(thioacetyl)benzene in dimethylformamide(DMF) for 30 min and kept in the dark during immersion to avoid photo-oxidation. After the assembly, the samples were removed from the solutions, rinsed thoroughly with methanol, acetone, and $CH_2Cl_2$, and finally blown dry with $N_2$. Under these conditions, we measured electrical properties of self-assembly monolayers(SAMs) using ultra high vacuum scanning tunneling microscopy(UHV-STM). The applied voltages were from -2V to +2V with 299K temperature. The vacuum condition is $6{\times}10^{-8}$ Torr. As a result, we found the NDR voltage of the nitro-benzene is $-1.61{\pm}0.26$ V(negative region) and $1.84{\pm}0.33$ (positive region), respectively.

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대전류 및 용가재 직경에 따른 Al5083 아크 용접부 마그네슘 기화 및 기계적 성질 (Effects of High Current and Welding Wire Diameter on the Magnesium Vaporization and Mechanical Properties of Al5083 Arc Welds)

  • 권혜미;박철호;홍인표;강남현
    • Journal of Welding and Joining
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    • 제31권6호
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    • pp.84-89
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    • 2013
  • The demand of LNG tank and the constituting material, i.e., the Al5083 thick plate, increased due to the rapid growth LNG market. To weld the Al5083 thick plate, the gas metal arc welding (GMAW) of high current is necessary to increase manufacturing productivity incurred by the multi pass welding. However, the arc welding vaporizes the volatile element such as magnesium (Mg). This phenomenon changes the Mg composition of the weld metal and the mechanical properties. The study investigated the weldability of Al5083 alloys after conducting high current GMAW. The Al5083 alloy was welded by using different size of welding wires and high current (800-950A). As the arc current increased from 800A to 950A, the mechanical strength decreased and the secondary dendrite arm spacing (SDAS) increased. Even though the arc current increased SDAS, the mechanical strength decreased due to the Mg loss in the weldment. The large diameter of welding wire decreased the dilution of the weld, therefore increasing the Mg content and the strength of the weld. For the reason, the content of Mg in welds was a major parameter to determine the mechanical property for the high current GMAW. For the arc current between 800A and 950A, the yield strength of the weldments showed a relationship with the weight percent of Mg content ($X_{Mg}$): Y.S = 27.9($X_{Mg}$)-11.

Size-dependent flexoelectricity-based vibration characteristics of honeycomb sandwich plates with various boundary conditions

  • Soleimani-Javid, Zeinab;Arshid, Ehsan;Khorasani, Mohammad;Amir, Saeed;Tounsi, Abdelouahed
    • Advances in nano research
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    • 제10권5호
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    • pp.449-460
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    • 2021
  • Flexoelectricity is an interesting materials' property that is more touchable in small scales. This property beside the sandwich structures placed in the center of scientists' attention due to their extraordinary effects on the mechanical properties. Furthermore, in the passage of decades, more elaborated sandwich structures took into consideration results from using honeycomb core. This kind of structure, inspiring from honeycomb core, provides more stiffness to weight ratio, which plays a crucial role in different industries. In this paper, based on the Love-Kirchhoff's hypothesis, Hamilton's principle, modified couple stress theory and Fourier series analytical method, equations of motion for a sandwich plate containing a honeycomb core integrated by two face-sheets have derived and solved analytically. The equations of both face sheets have derived by flexoelectricity consideration. Moreover, it should be noticed that the whole structure rests on the visco-Pasternak foundation. Conducting current research provided an acceptable and throughout study based on flexoelectricity to address the effect of materials' characteristics, length-scale parameter, aspect, and thickness ratios and boundary conditions on the natural frequency of honeycomb sandwich plates. Also, based on the presented figures and tables, there is a close agreement between previous studies and recent work. Due to the high ratio of strength to weight, current model analyzing is capable of taking into account for different vehicles' manufacturing in a high range of industries.

선박평형수 처리용 흡입 펌프 임펠러 형상 최적화 연구 (A Study on Suction Pump Impeller Form Optimization for Ballast Water Treatment System)

  • 이상범
    • 한국산업융합학회 논문집
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    • 제25권1호
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    • pp.121-129
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    • 2022
  • With the recent increase in international trade volume the trade volume through ships is also continuously increasing. The treatment of ballast water goes through the following five steps, samples are taken and analyzed at each step, and samples are obtained using a suction pump. These suction pumps have low efficiency and thus need to be improved. In this study, it is to optimize the form of the impeller which affects directly improvements of performance to determine the capacity of suction pump and to fulfill the purpose of this research. To do it, we have carried out parametric design as an input variable, geometric form for the impeller. By conducting the flow analysis for the optimum form, it has confirmed the value of improved results and achieved the purpose to study in this paper. It has selected the necessary parameter for optimizing the form of the pump impeller and analyzed the property using experiment design. And it can reduce the factor of parameter for local optimization from findings to analyze the property of form parameter. To perform MOGA(Multi-Objective Genetic Algorithm) it has generated response surface using parameters for local optimization and conducts the optimization using multi-objective genetic algorithm. with created experiment cases, it has performed the computational fluid dynamics with model applying the optimized impeller form and checked that the capacity of the pump was improved. It could verify the validity concerning the improvement of pump efficiency, via optimization of pump impeller form which is suggested in this study.