• Title/Summary/Keyword: conditions of evaporation

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Fabrication of Transparent Conducting Films of $In_2O_3$ by Vacuum Deposition (진공증착법에 의한 $In_2O_3$ 투명전도막의 제작)

  • 이기선
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.17 no.5
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    • pp.43-47
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    • 1980
  • Transparent conducting films of In2O3 were fabricated by elect yon beam evaporation method in an oxygen atmosphere of -10-4 Torr., and the optimum conditions of film deposition, as well as their electrical and optical properties were measured and analysed. Evaporation rate of 3~7A/sec, substrate temperature of over 30$0^{\circ}C$, and SnO2 doping of 2~5wt. % were the optimum deposition conditions. Under these conditions , the resistivities of the films were 2$\times$10-4 $\Omega$.cm and the visible transmittances were 85~90%.

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Study on the deposition rate and vapor distribution of Al films prepared by vacuum evaporation and arc-induced ion plating (증착방법에 따른 Al 피막의 증착율 및 증기분포에 관한 연구)

  • 정재인;정우철;손영호;이득진;박성렬
    • Journal of the Korean Vacuum Society
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    • v.9 no.3
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    • pp.207-215
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    • 2000
  • Al films on cold-rolled steel sheet have been prepared by vacuum evaporation and arc-induced ion plating, respectively, and the evaporation rate and vapor distribution (thickness distribution over the substrate) have been investigated according to deposition conditions. The arc-induced ion plating (AIIP) method have been employed, which makes use of arc-like discharge current induced by ionization electrode located near the evaporation source. The AIIP takes advantage of high ionization rate compared with conventional ion plating, and can be carried out at low pressure of less than $10^{-4}$ torr. Very high evaporation rate of more than 2.0 mu\textrm{m}$/min could be achieved for Al evaporation using alumina liner by electron beam evaporation. The geometry factor n for the $cos^{n/\phi}$ vapor distribution, which affects the thickness distribution of films at the substrate turned out to be around 1 for vacuum evaporation, while it features around 2 or higher for ion plating. For the ion plated films, it has been found that the ionization condition and substrate bias are the main parameters to affect the thickness distribution of the films.

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Establishing the Models for Optimized Design of Water Injection in Boilers with Waste-heat-recovery System (가습연소 폐열회수 보일러의 물분사 설계모델 구축에 관한 연구)

  • Shin, Jaehun;Moon, Seoksu
    • Journal of ILASS-Korea
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    • v.26 no.2
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    • pp.96-103
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    • 2021
  • In order to improve the overall efficiency and meet the emission regulations of boiler systems, the heat exchanging methods between inlet air and exhaust gas have been used in boiler systems, named as the waste-heat-recovery condensing boiler. Recently, to further improve the overall efficiency and to reduce the NOx emission simultaneously, the concept of the water injection into the inlet air is introduced. This study suggests the models for the optimized design parameters of water injection for waste-heat-recovery condensing boilers and performs the analysis regarding the water injection amount and droplet sizes for the optimized water injection. At first, the required amount of the water injection was estimated based on the 1st law of thermodynamics under the assumption of complete evaporation of the injected water. The result showed that the higher the inlet air and exhaust gas temperature into the heat exchanger, the larger the amount of injected water is needed. Then two droplet evaporation models were proposed to analyze the required droplet size of water injection for full evaporation of injected water: one is the evaporation model of droplet in the inlet air and the other is that on the wall of heat exchanger. Based on the results of two models, the maximum allowable droplet sizes of water injection were estimated in various boiler operating conditions with respect to the residence time of the inlet air in the heat exchanger.

Preparation and Evaluation of Bupivacaine Microspheres by a Solvent Evaporation Method (II) (용매증발법에 의한 부피바카인 마이크로스피어의 제조 및 평가 (II))

  • 곽손혁;이시범;이종수;이병철;황성주
    • YAKHAK HOEJI
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    • v.45 no.6
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    • pp.623-633
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    • 2001
  • Various bupivacaine-loaded microspheres were prepared using poly(d,1-lactide) (PLA) and poly(d,1-lactic-co-glycolide) (PLGA) by a solvent evaporation method for the sustained release of drug. The effects of process conditions such as drug loading, polymer type and solvent type on the characteristics of microspheres were investigated. The prepared microspheres were characterized for their drug loading, size distribution, surface morphology and release kinetics. Drug loading efficiency and yield of PLGA micro- spheres were higher than those of PLA microspheres. The prepared microspheres had an average particle size below 5${\mu}{\textrm}{m}$. The particle size range of microspheres was 1.65~2.24${\mu}{\textrm}{m}$. As a result of SEM, the particle size of PLA microspheres was smaller than that of PLGA microspheres. In morphology studies, microspheres showed a spherical shape and smooth surface in all process conditions. In thermal analysis, bupivacaine-loaded microspheres showed no peaks originating from bupivacaine. This suggested that bupivacaine base was molecular-dispersed in the polymer matrix of microspheres. The release pattern of the drug from microspheres was evaluated for 96 hours. The initial burst release of bupivacaine base decreased with increasing the molecular weight of PLGA, and the drug from microspheres released slowly. In conclusion, bupivacaine-loaded microspheres were successfully prepared from poly(d,1-lactide) and poly (d,1- lactic-co-glycolide) polymers with different molecular weights allowing control of the release rate.

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Volatilization and Toxicity Control of Heavy Metal Chlorides under Combustion Conditions (연소조건에서 중금속 염화물의 휘발 및 유독성 제어)

  • 서용칠
    • Journal of the Korean Society of Safety
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    • v.8 no.4
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    • pp.175-182
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    • 1993
  • Volatilization of toxic heavy metals, especially, metal chlorides at elevated temperatures in oxidation conditions was observed using a thermogravimetric furnace since such metal chlorides used to be a cause for the disease of industrial workers by their toxicity and high volatile extent. Most of tested metal chloride compounds were evaporated or decomposed into gas phase at elevated temperatures ranged from 200~90$0^{\circ}C$, while CrCl$_3$ and NiC1$_2$became stable with converting into oxide forms. A kinetic model for evaporation/condensation could predict maximum evaporation flux and the calculated values were compared with real evaporation flux. The ratio of two fluxes could be explained as the fraction of impinging gas molecules to the condensing surface( $\alpha$ ) and obtained in the range of 10$^{-3}$ ~10$^{-9}$ for the experimented toxic heavy metal chlorides. This ratio might be used to define the volatile extent or toxicity of such toxic metal compounds. The schemes to avoid volatilization of toxic heavy metals Into the atmosphere were suggested as follows ; 1 ) controlling the compositions of metals and Chlorine produced substances( such as PVC ) in the treated materials using a reverse estimation from regulatory limit and characteristics of a processing facility, 2) Installation of wet type devices such as a scrubber for condensing the metal compounds.

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1-D Modeling of Heater Surface Temperature Distribution in EHC-based Urea-SCR System (EHC 기반 Urea-SCR 시스템 히터 표면온도 분포의 1-D 모델링)

  • Park, Sunhong;Son, Jihyun;Moon, Seoksu;Oh, Kwangchul;Jang, Sungwook;Park, Sungsuh
    • Journal of ILASS-Korea
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    • v.27 no.1
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    • pp.11-17
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    • 2022
  • In upcoming Post Stage-V and Tier 5 regulations of construction machineries, nitrogen oxide (NOx) emissions are strictly limited in cold start conditions. In response to this, a method of improving NOx conversion efficiency has been applied by installing an electric heating catalyst (EHC) in front of conventional urea-SCR systems so that the evaporation and thermal decomposition of urea-water solution can be promoted in cold start conditions. In this strategy, the evaporation and thermal decomposition of urea-water solution and corresponding NOx conversion efficiency are governed by temperature conditions inside the EHC. Therefore, characterizing the temperature distribution in the EHC under various operating conditions is crucial for the optimized operation and control of the EHC in Urea-SCR systems. In this study, a 1-D modeling analysis was performed to predict the heater surface temperature distribution in EHC under various operating conditions. The reliability of prediction results was verified by comparing them with measurement results obtained using an infrared (IR) camera. Based on 1-D analysis results, the effects of various EHC operation parameters on the heater surface temperature distribution were analyzed and discussed.

The Optical Properties of Amorphous Se Films in the Visible Range (비정질 Se박막의 가시광선영역 광특성)

  • 박창엽;김영호
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.31 no.11
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    • pp.141-145
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    • 1982
  • Optical absorption properties of an orphous Se film due to interband electronic transitions are observed in the visible range by varying the folm thickness. Amorphous Se films were prepared by evaporation method. As the experimental results, it is found that optical energy gap is around 2.07(e V), and the optical constants depend on the film thickness, evaporation-deposition conditions, and incident photon energy.

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Defect Formation in Epitaxially Grown Silver Films (배향 성장시킨 은박막중의 결함생성)

  • Lee Ki-Seon;Kim Key-Soo
    • Applied Microscopy
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    • v.6 no.1
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    • pp.33-38
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    • 1976
  • Formation of crystal defects which may occur during and after the vacuum deposition of silver films on rocksalt substrates were studied by electron microscopy. To obtain defect free films, various evaporation conditions, such as evaporation rate, substrate temperature, substrate treatments and annealing of films were examined. Stacking faults and micro-twins are dominant defects in silver films.

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Simulation of Physical Chemistry Phenomena Inside a Naturally Smoldering Cigarette (자연 연소중인 궐련내에서 일어나는 물리화학적 현상의 시뮬레이션)

  • 오인혁;김기환;정경락
    • Journal of the Korean Society of Tobacco Science
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    • v.20 no.1
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    • pp.87-94
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    • 1998
  • After we made the computer source code with mathematical model of Muramatsu et al. that was expressed by the set of simultaneous first-order ordinary differential equations in evaporation-pyrolysis zone of cigarette, we simulated the distribution profiles of temperature and density of flue-cured tobacco. Those equations were solved numerically with the Runge-Kutta-Gill algorithm assuming step size of 0.025mm by Muramatsu at at,, but in this study the advanced algorithm of Runge-Kutta 4th Order assuming step size of 0.0005mm. The initial conditions and physical parameters of Muramatsu et at. were used for solving them. The calculated values corresponded well with results of Muramatsu et al., especially the gradient of the temperature profile increased with smoldering speed and the thickness of the evaporation-pyrolysis zone decreased with increasing of smoldering speed. On the other hand, the temperature gradient decreased with increasing of the effective thermal-conductivity value and the thickness of the evaporation-pyrolysis zone increased with the effective thermal-conductivity value.

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Unstable Inverted Phases of Di- and Tri-block Copolymers on Solution-Casting Films

  • Sun Dachun;Huang Lei;Liang Haojun
    • Macromolecular Research
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    • v.13 no.2
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    • pp.152-155
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    • 2005
  • A dynamic density functional theory is presented for the observation of the phase revolutions of a solution-casting film of di- and tri-block copolymers under solvent evaporation conditions. With the evaporation of the solvent, the inverted phases, the minor part of the component becomes the continuous phase at the higher solvent evaporation rate, as observed in this experiment. Further simulation revealed that these inverted phases are converted into the normal phase and the major part of the component becomes the continuous phase, implying that the inverted phases observed in this experiment are unstable.