• 한국입자에어로졸학회지
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• 제13권3호
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• pp.105-110
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• 2017

본 연구에서는 고온희석-상온희석 2단 희석의 다공 튜브형 희석장치를 제작하여 실제 배기가스와 시험챔버의 다양한 고수분 환경에서의 희석 조건에 따른 응축성 물질의 생성 억제와 생성된 응축 입자의 제거 특성에 관하여 살펴보았다. 디젤 엔진의 배출 입자는 응축 성분의 핵화 모드와 고체상의 응축성장 모드의 이중모드 분포를 나타내었고, 다공 튜브형 희석장치의 1차 고온희석 유량을 증가시킴으로써 핵화 모드 입자의 생성을 억제시키고 응축성장 모드의 입자만을 측정할 수 있었다. 석탄보일러에서 배출되는 미세먼지에 대해서도 다공 튜브형 희석장치를 적용하여 응축성 성분의 입자 생성 없이 응축성장 모드의 입자만을 측정할 수 있었고, $3{\mu}m$ 크기 이상의 입자에 대해서 기존 이젝터 방식에 비해 상대적으로 입자 손실이 적음을 확인할 수 있었다. 또한 $30m^3$ 시험챔버에서 가습기로 인위적으로 발생시킨 물입자가 측정하고자 하는 고체 입자와 공존할 때 다공 튜브형 희석장치를 사용하여 물입자를 증발시켜 제거함으로써 고체 입자만을 정확하게 분리하여 측정할 수 있음을 확인할 수 있었다.

• 한국산학기술학회논문지
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• 제19권3호
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• pp.699-706
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• 2018

플라즈마 고분자의 영구기체(He, $H_2$, $O_2$, $N_2$, $CH_4$) 및 응축성 증기($CO_2$, $C_2H_4$, $C_3H_8$)에 대한 투과 특성을 조사하였다. 플라즈마 고분자는 마이크로파 방전과 라디오파 방전을 이용하여 제조하였으며 플라즈마 중합의 단량체(monomer)로는 hexamethyldisiloxane(HMDS)을 사용하였다. 마이크로파를 이용하여 제조한 HMDS 플라즈마 고분자막의 투과도계수는 투과 기체의 분자지름에 의존하는 경향을 나타내었으며 라디오파를 이용하여 제조한 플라즈마 고분자막보다 높은 산소/질소 투과선택도를 나타내었다. 반면에 라디오파를 이용하여 제조한 HMDS 플라즈마 고분자막의 투과도계수는 투과기체의 임계온도에 의존하는 경향을 나타내었으며 질소에 대한 에틸렌 및 프로판의 투과선택도가 우수한 특성을 나타내었다. 마이크로파로 중합시킨 고분자막은 가교결합도가 높기 때문에 기체의 투과도계수가 주로 확산계수(또는 분자지름)에 의존하게 된다. 그러나 라디오파의 에너지 밀도는 마이크로파의 에너지 밀도보다 낮기 때문에 라디오파로 중합시킨 플라즈마 고분자막의 구조는 마이크로파로 중합시킨 고분자 막에 비하여 가교결합도가 떨어지게 되며 이 막을 통한 투과도계수는 분자크기 보다는 기체의 임계온도에 의존하는 경향을 나타내었다. 따라서 라디오파를 이용하여 중합시킨 HMDS 플라즈마 고분자막은 영구기체 보다는 공기 중의 유기물질을 제거하는데 보다 효과적으로 이용될 수 있을 것으로 생각된다.

• 한국초전도ㆍ저온공학회논문지
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• 제12권1호
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• pp.52-55
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• 2010

A sub-cooled liquid nitrogen system is known as a promising method to develop high voltage superconducting apparatuses such as superconducting fault current limiters (SFCLs) and superconducting cables. To develop a high voltage superconducting machine adopting the sub-cooled liquid nitrogen system with a constant pressure. injecting a non-condensable gas is indispensable. In this study. the dielectric characteristics of insulation gases are investigated and analyzed by using electric utilization factors ($\xi$). It is found that the maximum electric field at sparkover that occurs with 50 % probability. $E_{MAX.50%}$ exponentially decreases as the S increases. This means that the $E_{MAX.50%}$ at sparkover can be estimated with the $E_{MAX.50%}$

• 대한기계학회논문집B
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• 제20권6호
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• pp.1983-1993
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• 1996

For selected (pure and compound) metallic species effects of saturation ratio, temperature, particle size and number density on condensation mechanisms are first reviewed. The tendencies for vaporization and condensation differ between metallic species because of the significant differences in their saturation pressures. Then particle pressure of a metal vapor species at incineration temperature is calculated by simplifying waste as a compound of methane, chlorine and small amounts of metals and assuming a thermodynamic equilibrium state. Next the condition is assessed for which supersaturation of combustion gases by the species above the critical level for homogeneous condensation may occur, when the gases contain a large number of pre-existing particles such as entrained ashes. Regardless of the presence of chlorine in the waste, the homogeneous condensation of PbO vapors may occur, depending on number density of the pre-existing particles. However, when chlorine exists in the waste, the homogeneous condensation of PbCl$_2$vapors does not occur, which is similar to the case of Cd and Hg vapors. Thus these highly volatile species, PbCl$_2$, Cd, and Hg, may emit to atmosphere as vapor phase. In general, for reducing the emission of hazardous metallic species into the atmosphere, the number density of pre-existing particles has to be increased. For fixed particle number density, the temperature drop rate must be kept in low if the temperature at which a condensable vapor species emits from a incineration system is fixed, while the temperature drop rate must be kept in high if the residence time for which a condensable species stays in the system is fixed.

• 한국대기환경학회지
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• 제32권5호
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• pp.501-512
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• 2016

The study evaluated methods to measure condensable fine particles in flue gases and measured particulate matter by fuel and material to get precise concentrations and quantities. As a result of the method evaluation, it is required to improve test methods for measuring Condensable Particulate Matter (CPM) emitted after the conventional Filterable Particulate Matter (FPM) measurement process. Relative Standard Deviation (RSD) based on the evaluated analysis process showed that RSD percentages of FPM and CPM were around 27.0~139.5%. As errors in the process of CPM measurement and analysis can be caused while separating and dehydrating organic and inorganic materials from condensed liquid samples, transporting samples, and titrating ammonium hydroxide in the sample, it is required to comply with the exact test procedures. As for characteristics of FPM and CPM concentrations, CPM had about 1.6~63 times higher concentrations than FPM, and CPM caused huge increase in PM mass concentrations. Also, emission concentrations and quantities varied according to the characteristics of each fuel, the size of emitting facilities, operational conditions of emitters, etc. PM in the flue gases mostly consisted of CPM (61~99%), and the result of organic/inorganic component analysis revealed that organic dusts accounted for 30~88%. High-efficiency prevention facilities also had high concentrations of CPM due to large amounts of $NO_x$, and the more fuels, the more inorganic dusts. As a result of comparison between emission coefficients by fuel and the EPA AP-42, FPM had lower result values compared to that in the US materials, and CPM had higher values than FPM. For the emission coefficients of the total PM (FPM+CPM) by industry, that of thermal power stations (bituminous coal) was 71.64 g/ton, and cement manufacturing facility (blended fuels) 18.90 g/ton. In order to estimate emission quantities and coefficients proper to the circumstances of air pollutant-emitting facilities in Korea, measurement data need to be calculated in stages by facility condition according to the CPM measurement method in the study. About 80% of PM in flue gases are CPM, and a half of which are organic dusts that are mostly unknown yet. For effective management and control of PM in flue gases, it is necessary to identify the current conditions through quantitative and qualitative analysis of harmful organic substances, and have more interest in and conduct studies on unknown materials' measurements and behaviors.

• Nuclear Engineering and Technology
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• 제55권10호
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• pp.3754-3767
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• 2023

Turbulent jet discharges in subcooled water pools are essential for safety systems in nuclear power plants, specifically in the pressure suppression pool of boiling water reactors and In-containment Refueling Water Storage Tank of advanced pressurized water reactors. The gas and liquid flow in these systems is investigated using multiphase flow analysis. This field has been extensively examined using a combination of experiments, theoretical models, and Computational Fluid Dynamics (CFD) simulations. ANSYS CFX offers two approaches to model multiphase flow behavior. The non-homogeneous Eulerian-Eulerian Model has been used in this work; it computes global information and is more convenient to study interpenetrated fluids. This study utilized the Large Eddy Simulation Model as the turbulence model, as it is better suited for non-stationary and buoyant flows. The CFD results of this study were validated with experimental data and theoretical results previously obtained. The figures of merit dimensionless penetration length and the dimensionless buoyancy length show good agreement with the experimental measurements. Correlations for these variables were obtained as a function of dimensionless numbers to give generality using only initial boundary conditions. CFD numerical model developed in this research has the capability to simulate the behavior of non-condensable gases discharged in water.

• 멤브레인
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• 제13권4호
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• pp.246-256
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• 2003

폴리올레핀 산업에서 발생되는 올레핀 함유 배 가스(off-gas)에서 올레핀만을 선택적으로 분리하기 위해, 폴리디메틸실록산(Polydimethylsiloxane)계열의 막 소재들에 대한 올레핀과 질소의 투과특성을 연구하였다. 막 소재로는 가교 형태의 폴리디메틸실록산(Polydimethylsiloxane, 이하 PDMS라 칭함)막, 폴리실록산이미드(Polysiloxaneimide, 이하 PSI라 칭함)막, 아크릴변성 Oligo-PDMS가 부가된 Oligo-PDMS막들을 대상으로 공급기체의 온도($-20{\sim}50^{\circ}C$)와 압력(1∼25 atm)을 변화시키면서 에틸렌($C_2H_4$), 프로필렌($C_3H_6$), 부틸렌($C_4H_8$), 질소($N_2$) 기체의 단일투과특성을 조사하였다. 실험결과, 사용되는 막소재의 특징에 따라 다양한 투과특성을 보였다. 세 가지 막소재중에서 PDMS막이 가장 넓은 사용압력범위에서 높은 에틸렌투과도 및 에틸렌/질소의 분리특성을 보였으며 이 막을 대상으로 여러 투과조건에서 투과특성을 연구하였다. 선택된 가교 PDMS막을 통한 올레핀, 질소 기체들의 투과도는 투과기체의 분자크기(확산도 선택성)보다, 투과기체의 응축온도(용해도 선택성)에 좌우되는 경향을 보였다. 공급기체의 온도가 감소하거나 압력이 증가할 때, 응축성 기체인 올레핀 기체의 투과도는 증가하고, 비응축성 기체인 질소는 감소하는 특징을 보였으며 이에 따라 올레핀/질소의 선택도가 크게 증가하는 특징을 보였다. 이러한 결과들은 고무상 고분자막에서 보여지는 응축성, 비응축성 기체들의 전형적인 투과특성을 보여준다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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• pp.33-36
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• 2014

Gasification of biomass produces syngas containing CO, $H_2$ and/or $CH_4$, which can then be converted into energy or value-added fuels. One of key issues for efficient gasification is to minimize tar concentration in the syngas for use in a final conversion device such as gas engine. This study investigated the decomposition of primary tar by catalytic cracking using char as catalyst, of which the feature can be integrated into a fixed bed gasifier design. The pyrolysis vapor containing tar from pyrolysis of wood at $500^{\circ}C$ was passed through a reactor filled with or without char at $800^{\circ}C$ for a residence time of 1, 3 or 5 sec. Then, the condensable vapor (water and tar) and gases were analyzed for the yields and elemental composition. Four types of char particles with different microscopic surface area and pore size distribution: wood, paddy straw, palm kernel shell and activated carbon. The results were analyzed for the mass and carbon yields of tar and the composition of product gases to conclude the effects of char types and residence time.

• 전력전자학회논문지
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• 제9권3호
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• pp.203-212
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• 2004

히트파이프를 이용하는 전력반도체 냉각용 히트파이프가 장기간 사용에도 안정된 작동을 이루도록 하기 위해서는 제조 과정에서 발생할 수 있는 산화막 존재 등 문제 요인의 제거와 함께 시험을 통한 확인이 필요하다. 본 연구에서는 전력반도체 냉각용 히트파이프가 요구하는 여러 기하학적, 열적조건에 의해 결정되는 열수송 한계 및 특성과 안정된 작동을 확인하기 위한 시험방법을 제시하고 시험을 통하여 확인된 결과를 정리하였다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제44회 KOSCO SYMPOSIUM 초록집
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• pp.235-237
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• 2012

Geodae-Uksae 1 is a variety of Miscanthus sacchariflorus recently discovered in Korea. It is being mass-cultivated for use as energy crop due to its superior productivity, as high as 30 ton/ha/yr for the dry mass. This study investigates the method of producing biochar and bio-oil from the crop using slow pyrolysis. Especially, the study focused on assessing the biochar properties for its application to soil to improve soil quality and sequestrate carbon. Using an electrically heated packed bed reactor, the products of slow pyrolysis from Geodae-Uksae 1 were produced over a temperature range of $300-700^{\circ}C$ with a heating rate of $10^{\circ}C/min$. The biochar, condensable vapor (bio-oil) and residual gases were characterized for the physical and chemical properties. It was concluded that the ideal temperature for pyrolysis to produce biochar is $500^{\circ}C$.