• Title/Summary/Keyword: concentration of solution

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Determination of Plutonium Present in Highly Radioactive Irradiated Fuel Solution by Spectrophotometric Method

  • Dhamodharan, Krishnan;Pius, Anitha
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.727-732
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    • 2016
  • A simple and rapid spectrophotometric method has been developed to enable the determination of plutonium concentration in an irradiated fuel solution in the presence of all fission products. An excess of ceric ammonium nitrate solution was employed to oxidize all the valence states of plutonium to +6 oxidation state. Interference due to the presence of fission products such as ruthenium and zirconium, and corrosion products such as iron in the envisaged concentration range, as in the irradiated fuel solution, was studied in the determination of plutonium concentration by the direct spectrophotometric method. The stability of plutonium in +6 oxidation state was monitored under experimental conditions as a function of time. Results obtained are reproducible, and this method is applicable to radioactive samples resulting before the solvent extraction process during the reprocessing of fast reactor spent fuel. An analysis of the concentration of plutonium shows a relative standard deviation of <1.2% in standard as well as in simulated conditions. This reflects the fast reactor fuel composition with respect to uranium, plutonium, fission products such as ruthenium and zirconium, and corrosion products such as iron.

Suppression of Morningglory (Ipomoea Hederacea) Growth by Rhizobacteria and IAA-3-ACETIC Acid

  • Kim, Su-Jung
    • Korean Journal of Organic Agriculture
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    • v.14 no.4
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    • pp.411-420
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    • 2006
  • Indole-3-acetic acid (IAA) biosynthesis by bacteria occurs widely in rhizospheres. Bacterial species able to synthesize IAAmay be exploited for beneficial interactions in crop management systems. The objective of this study was to determine the response of ivyleaf morningglory (Ipomoea hederacea) seedlings to IAA and to an IAA-producing rhizobacterum, Bradyrhizobium japonicum isolate GD3. IAA solution and isolate GD3 suppression of seedling growth measured as radicle length and biomass depended on IAA concentration. Seedling radicle length was significantly reduced by ca. 29% with more than $1.0{\mu}M$ of IAA solution, compared to the control, 48 h after application. The cell concentration at 50% growth reduction ($GR_{50}$) of the seedling radicle was IAA production by isolate GD3 at $10^{4.82}\;cfu$, the cell concentration for 50% growth reduction ($GR_{50}$) of seedling radicle was 0.24 iM, which was much lower than the IAA solution concentration ($117.48{\mu}M$) required for $GR_{50}$. Therefore, excess IAA production by isolate GD3 may be more detrimental to morningglory radicle growth than standard IAA solution. Results confirmed involvement of IAA in suppressive effects of isolate GD3 on morning-glory seedlings grown in a hydroponic system.

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Fabrication and Characteristics of Porous Silicon (다공성 실리콘의 제조 및 특성에 관한 연구)

  • 이철환;조원일;백지흠;박성용;안춘호;유종훈;조병원;윤경석
    • Journal of Surface Science and Engineering
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    • v.28 no.3
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    • pp.182-191
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    • 1995
  • A highly porous silicon layer was fabricated by anodizing single crystalline silicon in a dilute solution of hydrofluoric acid. The color of the porous silicon changed from red and blue to yellow gold during the anodizing process. The current-voltage (I-V) curve of the anodizing process showed a typical Schottky diode rectification form. The cell voltage decreased with the increase of HF concentration in the solution at high current range. However, the voltage was independent on HF concentration in the solution at low current range. The pore size was dependant on anodizing condition (HF concentration, current and anodizing time). The pore size and wall width of porous silicon layer were 4~6 and 1~3 nm, respectively. Surface of the porous silicon was covered with silicon compound ($SiH_x$etc.) according to IR spectrum analysis. The peak wavelength and width of photoluminescence (PL) spectrum of porous silicon were 650~850 nm (1.5~1.9 eV) and 250 nm, respectively. The photoluminescence intensity and peak wavelength, and porosity of porous silicon increased with increasing anodizing current and decreased with increasing HF concentration in the anodizing solution.

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Improved Resolution of Paper-based Sensor for Proline Detection by Low-temperature Drying of Ninhydrin Solution (닌히드린 용액의 저온 건조에 의한 프롤린 검출을 위한 종이기반 센서의 분해능 개선)

  • Ji-Kwan, Kim;Young-Soo, Choi
    • Journal of Sensor Science and Technology
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    • v.31 no.6
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    • pp.428-432
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    • 2022
  • In this study, we describe the improvement of the resolution of a paper-based sensor by fabricating a high-concentration ninhydrin part using a low-temperature drying method to detect proline with high resolution. In the conventional paper-based sensor for detecting proline, the ninhydrin part is fabricated at room temperature, and in this process, the ninhydrin solution spreads around the ninhydrin part. Therefore, the concentration of the ninhydrin part becomes lower than that of the applied solution, lowering the resolution of the sensor. The proposed paper-based sensor better improved the sensitivity of the sensor compared to the existing sensor by fabricating a high-concentration ninhydrin part through drying the ninhydrin solution using a low-temperature drying method. Owing to the experiment, the intensity of the green color of the paper-based sensor with the integrated ninhydrin part fabricated at 10 ℃ is approximately 20% lower than the paper-based sensor with an integrated ninhydrin part fabricated at room temperature, indicating better sensor resolution. Therefore, the paper-based sensor with an integrated ninhydrin part fabricated at a high concentration could be useful for diagnosing drought.

Diffusion Coefficients and Membrane Potential within Carrier Membrane by Reverse Transport System

  • Yang, Wong-Kang;Jeong, Sung-Hyun;Lee, Won-Chul
    • Korean Membrane Journal
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    • v.4 no.1
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    • pp.36-40
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    • 2002
  • The diffusion coefficients of ions in the reverse transport system using the carrier mediated membrane were estimated from the diffusional membrane permeabilities and the ion activity in membrane system. In the aqueous alkali metal ions-membrane system diffusional flux of alkali metal ions driven by coupled proton was analyzed. The aqueous phase I contained NaOH solution and the aqueous phase II also contained NaCl and HCl mixed solution. The concentration of Na ions of both phases were $10^{0},\;10^{-1},\;10^{-2},\;5{\times}10^{-1}\;and\;5{\times}10^{-2}\;mol{\cdot}dm^{-3}$ and the concentration of HCI in aqueous phase II was always kept at $1{\times}10^{-1}\;mol{\cdot}dm^{-3}$. Moreover, the carrier concentration in liquid membrane was $10^{-2}\;mol{\cdot}dm^{-3}$. The results indicated that the diffusion coefficients depend strongly on the concentration of both phases electrolyte solution equilibriated with the membrane. The points were interpreted in terms of the energy barrier theory. Furthermore, eliminating the potential terms from the membrane equation was derived.

The Effects of Bee Venom and Melittin acupuncture solution on cPLA2, TNF-α and Calcium Concentration in RAW 264.7 Cells (봉약침액(蜂藥鍼液)과 Melittin 약침액(藥鍼液)이 RAW 264.7 Cell의 cPLA2, TNF-α 및 Calcium Concentration에 미치는 영향(影響))

  • Park, Young-eun;Song, Ho-sueb
    • Journal of Acupuncture Research
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    • v.21 no.5
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    • pp.179-190
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    • 2004
  • Objectives : The purpose of this study was to investigate the effect of Bee Venom and Melittin acupuncture solution on the lipopolysaccharide and sodium nitroprusside- induced expression of cytosolic phospholipase $A_2$, tumor necrosis factor-${\alpha}$ and calcium concentration in RAW 264.7 cells, a murine macrophage cell line. Methods : The expression of cytosolic phospholipase $A_2$ and tumor necrosis factor-${\alpha}$ was determined by western blotting with corresponding antibodies, and the generation of intracellular calcium concentration was investigated by delta scan system in RAW 264.7 cells. Results : 1. Compared with control, expressions of lipopolysaccharide-induced cytosolic phospholipase $A_2$ were decreased significantly by $5{\mu}g/mL$ of bee venom and 5, $10{\mu}g/mL$ of melittin acupuncture solution and decreased by 0.5, $1{\mu}g/mL$ of bee venom. 2. Compared with control, expressions of sodium nitroprusside-induced phospholipase $A_2$ were decreased significantly by 0.5, 1, $5{\mu}g/mL$ of bee venom and by 5, $10{\mu}g/mL$ of melittin acupuncture solution. 3. Compared with control, expressions of lipopolysaccharide-induced tumor necrosis factor-${\alpha}$ were decreased significantly by $10{\mu}g/mL$ of melittin acupuncture solution and were not changed significantly by 0.5, 1, $5{\mu}g/mL$ of bee venom and $5{\mu}g/mL$ of melittin acupuncture solution. 4. Compared with control, expressions of sodium nitroprusside-induced tumor necrosis factor-${\alpha}$ were decreased significantly by 1, $5{\mu}g/mL$ of bee venom and 5, $10{\mu}g/mL$ of melittin acupuncture solution and decreased by $0.5{\mu}g/mL$ of bee venom 5. Compared with control, lipopolysaccharide-induced intracellular calcium concentrations were decreased by 0.5, 1, $5{\mu}g/mL$ of bee venom and $10{\mu}g/mL$ of melittin acupuncture solution and increased by $5{\mu}g/mL$ of melittin acupuncture solution. 6. Compared with control, sodium nitroprusside-induced intracellular calcium concentrations were decreased by 0.5, 1, $5{\mu}g/mL$ of bee venom and 5, $10{\mu}g/mL$ of melittin acupuncture solution.

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Effects of NaCl Concentration and Solution Temperature on the Galvanic Corrosion between CFRP and AA7075T6

  • Hur, S.Y.;Kim, K.T.;Yoo, Y.R.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.19 no.2
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    • pp.75-81
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    • 2020
  • To reduce structural weight, light metals, including aluminum and magnesium alloys, have been widely used in various industries such as aircraft, transportation and automobiles. Recently, composite materials such as Carbon Fiber Reinforced Plastics (CFRP) and Graphite Epoxy Composite Material (GECM) have also been applied. However, aluminum and its alloys suffer corrosion from various factors, which include aggressive ions, pH, solution temperature and galvanic contact by potential difference. Moreover, carbon fiber in CFRP and GECM is a very efficient cathode, and very noble in the galvanic series. Galvanic contact between carbon fiber composites and metals in electrolytes such as rain or seawater, is highly undesirable. Notwithstanding the potentially dangerous effects of chloride and temperature, there is little research on galvanic corrosion according to chloride concentration and temperature. This work focused on the effects of chloride concentration and solution temperature on AA7075T6. The increased galvanic corrosion between CRFP and AA7075T6 was evaluated by electrochemical experiments, and these effects were elucidated.

Effects of pH and Hardness Resulted from Total Carbonate Concentration on Sericin Solubilities (총탄산 농도에 따른 pH 및 경도가 견층 Sericin 용해에 미치는 영향)

  • Nam, Yeong-Rak;Chae, Dae-Seok;Seong, Jae-Cheon
    • Journal of Sericultural and Entomological Science
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    • v.31 no.2
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    • pp.121-126
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    • 1989
  • Two kinds of solution for the measurement of solubilities of Sericin are prepared as followings at temperature 90 deg. C. One has the total carbonate concentration as 0, 50, 100mg CO2/l prepared with non-carbonate distilled water, sodium hydrogen carbonate and 0.1N HCI and NaOH, the other has total hardness, that is, calcium hardness or magnesium hardness as 0, 20, 50, 100mg CaCO2/l respectively prepared with non-carbonate distilled water, calcium carbonate and magnesium oxide. Solubilities of Cocoon layer Sericin at above solution gives following results ; 1. pH shows little effect on the solubility of Sericin at the non-carbonate solution but at the carbonate solution pH shows a sensitive effect on the solubility of Sericin. These means that pH controls the concentration of H2CO3, HCO3-and CO32- which prevent and promote the solution of Sericin. 2. After the cocoon layer treatment at the solution, the initial pH of 4.0, 7.0, 9.0 of the solution changed to 6.0-6.5 at the lower total carbonate solution. However in the higher total carbonate solution pH did not changed very much. This may be explained by the buffer action of carbonate. 3. The effect of the hardness on the solubility of Sericin was not found in the non-carbonate solution with the standard hardness after treatment of cocoon layer.

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Comparison of Centrifugal Pump Performances for Newtonian and Non-Newtonian Fluids (뉴턴유체와 비뉴턴유체의 원심펌프성능특성 비교)

  • Kim, Dong-Joo;Roh, Hyung-Woon;Suh, Sang-Ho
    • 유체기계공업학회:학술대회논문집
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    • 2004.12a
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    • pp.57-62
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    • 2004
  • In the current study the effects on pump performances of a conventional centrifugal pump for Newtonian and non-Newtonian fluid were experimentally studied. The study aimed to compare the pump characteristics for Newtonian and non-Newtonian fluid. The working fluids are water, aqueous sugar solution, glycerin solution, muddy solution and pulp solution. The pump characteristics with high viscosity fluids were different. The operating efficiency for the sugar and glycerin solutions were decreased to $8.1\%$ and $12.9\%$ than that of water. The head reductions of the muddy solution for different concentration ratios were decreased to $7.97\%,\;15.11\%$ and $24.87\%$ than that of water And the head reductions of the pulp solution for different concentration ratios were decreased to $11.87\%,\;19.79\%$ md $36.81\%$ than that of water.

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Nacl Aqueous Solution Concentration Detection Using Slot-Coupled Capacitor Resonator (슬롯결합 커패시터 공진기를 이용한 Nacl 수용액 농도 검출)

  • Yun, Gi-Ho
    • Journal of the Korea Convergence Society
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    • v.9 no.11
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    • pp.29-35
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    • 2018
  • In this paper, we proposed a high sensitivity sensor that can detect the concentration change of Nacl aqueous solutions by using a slot coupling capacitor resonator in sub-microwave band. The resonator applied to the sensor consists of a parallel plate capacitor connected to an inductive slot utilizing the ground plane of the microstrip line. Based on the measurement data of the dielectric characteristics according to the concentration change, the resonance frequency was determined in the UHF band where the concentration change is evident and the Nacl aqueous solution is inserted into the capacitor. Based on the simulation, the proposed resonator was designed and fabricated. The concentration level was varied from 0 to 400 mg/dl as 100 mg/dl step, and the transmission scattering coefficient ($S_{21}$) was successfully measured. Experimental results show that it is applicable to the concentration detection sensor in Nacl aqueous solution by obtaining minimum 1.8 dB($S_{21}$) at each step.