• 제목/요약/키워드: compound-K

검색결과 8,269건 처리시간 0.053초

Experimental and ab initio Computational Studies on Dimethyl-(4-{4-{3-methyl-3-phenyl-cyclobutyl)-thiazol-2-yl]-hydrazonomethyl}-phenyl)-amine

  • Yuksektepe, Cigdem;Saracoglu, Hanife;Caliskan, Nezihe;Yilmaz, Ibrahim;Cukurovali, Alaaddin
    • Bulletin of the Korean Chemical Society
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    • 제31권12호
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    • pp.3553-3560
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    • 2010
  • A new hydrazone derivative compound has been synthesized and characterized by IR, $^1H$-NMR, $^{13}C$-NMR and UV-vis. spectroscopy techniques, elemental analysis and single-crystal X-ray diffraction (XRD). The new compound crystallizes in monoclinic space group C2/c. In addition to the crystal structure from X-ray experiment, the molecular geometry, vibrational frequencies and frontier molecular orbitals analysis of the title compound in the ground state have been calculated by using the HF/6-31G(d, p), B3LYP/6-311G(d, p) and B3LYP/6-31G(d, p) methods. The computed vibrational frequencies are used to determine the types of molecular motions associated with each of the observed experimental bands. To determine conformational flexibility, molecular energy profile of (1) was obtained by semi-empirical (AM1) calculation with respect to a selected degree of torsional freedom, which was varied from $-180^{\circ}$ to $+180^{\circ}$ in steps of $10^{\circ}$. Molecular electrostatic potential of the compound was also performed by the theoretical method.

환경전과정평가에 기반한 UV-LED 를 사용한 복합식 가습기에 관한 연구 (Study on Compound Humidifier Employing UV-LED using Environmental Life Cycle Assessment)

  • 최원식;박시현;이시왕;정영미;이화조
    • 한국정밀공학회지
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    • 제29권9호
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    • pp.931-937
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    • 2012
  • In this study, we assessed environmental impacts of compound humidifiers using environmental life cycle assessment and presented the ways to improvements in energy consumption of them. We found eco-design parameters and $CO_2$-eq emissions in each stage of raw material acquisition, manufacturing, transportation, use and disuse in life cycle of the compound humidifiers. The highest $CO_2$ emission is found to be in the stage of use among all stages of life cycle, which is mainly due to power consumption in thermal heating of heating coil for sterilization during humidification. The power consumption and $CO_2$ emission in the stage of use can be reduced to 1/4 and 1/3 at the highest estimate through improvement of sterilization method, respectively. We suggested the replacement of conventional thermal heating coil by ultra violet light-emitting diodes (UV-LED) for sterilization and then presented the experimental results on the sterilization effects of UV-LEDs.

Potentilla속 식물의 성분연구 -3, 3', 4-tri-O-methylellagic acid의 분리 및 동정- (Components of Potentilla Species -Isolation and Identification of 3, 3', 4-tri-O-methylellagic acid-)

  • 김학성
    • 약학회지
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    • 제33권6호
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    • pp.377-379
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    • 1989
  • The methylated compound of ellagic acid was isolated from Potentilla chinensis (Rosaceae). The isolated compound was 3, 3', 4-tri-O-methylellagic acid, [2, 3, 7-trimethoxy-8-hydroxy[1] benzopyrano-[5, 4, 3, cde][1] benzopyran-5, 10-dione], $C_{17}H_{12}O_8$, m.p. $293-295^{\circ}C$. The isolation of trimethylellagic acid was conducted by the column chromatography and the identification of the compound was carried out by the methods of IR, NMR and MS spectroscopy.

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Aqeous Neutralizer as Reactive Solvents for Odorous Ammonia Removal

  • Park, Young-G.
    • Environmental Engineering Research
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    • 제13권3호
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    • pp.119-124
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    • 2008
  • Ammonia is an inorganic compound that may cause severe odor problem. In this study the effectiveness of applying natural neutralizer to destroy and remove the odor-causing compound from gas streams was studied. Experimental result evaluated with a bench-scale apparatus via the neutralization of gas phase. This indicates that the natural neutralization depends on the gas concentration, gas residence time, temperature and pH. Removal efficiency of ammonia from gas stream was achieved by 95% using theconvection in the packed bed. This study proved the chemical neutralization technology was effective for controlling inorganic odor-causing compound.

Generating 3-D Models of Human Motions by Motion Capture

  • Yamaguchi, I.;Tou, K.;Tan, J.K.;Ishikawa, S.;Naito, T.;Yokota, M.
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2003년도 ICCAS
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    • pp.1629-1632
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    • 2003
  • A technique is presented for generating a compound human motion from its primitive motions obtained by a motion capture system. Some human fundamental motions are modeled in a 3-D way and registered as primitive motions. Because the factorization method is used for the motion capture, calibration of video cameras and connection of the motion in the direction of time is both unnecessary. Employing these motions, various compound human motions are generated by connecting the motions after having applied rotation and parallel transformation to them. Linear interpolation is done at the discontinuous boundary between primitive motions and smooth connection is achieved. Experimental results show satisfactory performance of the proposed technique. The technique may contribute to producing various complicated human motions without much effort using a strict motion capture system.

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Synthesis and Biological Evaluation of Heterocyclic Ring-substituted Chalcone Derivatives as Novel Inhibitors of Protein Tyrosine Phosphatase 1B

  • Chen, Zhen-Hua;Sun, Liang-Peng;Zhang, Wei;Shen, Qiang;Gao, Li-Xin;Li, Jia;Piao, Hu-Ri
    • Bulletin of the Korean Chemical Society
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    • 제33권5호
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    • pp.1505-1508
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    • 2012
  • Protein tyrosine phosphatase 1B (PTP1B) is a key factor in negative regulation of the insulin pathway, and is a promising target for the treatment of type-II diabetes, obesity and cancer. Herein, compound ($\mathbf{4}$) was first observed to have moderate inhibitory activity against PTP1B with an $IC_{50}$ value of $13.72{\pm}1.53{\mu}M$. To obtain more potent PTP1B inhibitors, we synthesized a series of chalcone derivatives using compound ($\mathbf{4}$) as the lead compound. Compound $\mathbf{4l}$ ($IC_{50}=3.12{\pm}0.18{\mu}M$) was 4.4-fold more potent than the lead compound $\mathbf{4}$ ($IC_{50}=13.72{\pm}1.53{\mu}M$), and more potent than the positive control, ursolic acid ($IC_{50}=3.40{\pm}0.21{\mu}M$). These results may help to provide suitable drug-like lead compounds for the design of inhibitors of PTP1B as well as other PTPs.

수도(水稻)에 대(對)한 질소(窒素), 가리(加里) 복비추비(複肥追肥) 효과시험(效果試驗) (Effect of N-K Compound Fertilizer Top Dressing of Paddy)

  • 오왕근;이강만;김우진
    • 한국토양비료학회지
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    • 제12권3호
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    • pp.133-139
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    • 1979
  • 수도추비용(水稻追肥用)으로 시제(試製)된 NK 복비(複肥) 17-0-17 (입상(粒狀) 및 분말상(粉末狀))과 17-0-14의 효과를 단비(單肥)(요소(尿素) 및 염화가리(鹽化加里))와 비교(比較)하기 위하여 신품종 수도(水稻)(밀량 23호)를 써서 포장시험(圃場試驗)을 실시(實施)했든바 그결과(結果)를 요약(要約)하면 다음과 같다. 1. 수량면(收量面)에서 볼때 복비수비(複肥穗肥)는 단비수비(單肥穗肥)보다 더 효과적인 경향(傾向)이 였다. 2. 입상(粒狀) 17-0-17 수비구(穗肥區)에서 K 및 N의 흡수(吸收)가 타구(他區)에 비(比)해 많았으며 K/(Ca+Mg)값도 높았다. 3. 복비구(複肥區)에서 가리(加里)와 질소흡수량(窒素吸收量)이 많았든 원인(原因)에 대(對)해서는 본시험(本試驗)성적만으로 설명(說明)이 어려웠다. 4. N-K복비(複肥)는 수비(穗肥)로 뿐만아니라 수도(水稻)에 대(對)한 즉(卽) 기비(基肥) 유효분벽기(有效分蘗期)나 최고분벽기(最高分蘗期)에 추비(追肥) 하여도 그 효과(效果)를 검토(檢討)해볼 만 할것 같다.

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