• Title/Summary/Keyword: compound-K

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Experimental and ab initio Computational Studies on Dimethyl-(4-{4-{3-methyl-3-phenyl-cyclobutyl)-thiazol-2-yl]-hydrazonomethyl}-phenyl)-amine

  • Yuksektepe, Cigdem;Saracoglu, Hanife;Caliskan, Nezihe;Yilmaz, Ibrahim;Cukurovali, Alaaddin
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3553-3560
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    • 2010
  • A new hydrazone derivative compound has been synthesized and characterized by IR, $^1H$-NMR, $^{13}C$-NMR and UV-vis. spectroscopy techniques, elemental analysis and single-crystal X-ray diffraction (XRD). The new compound crystallizes in monoclinic space group C2/c. In addition to the crystal structure from X-ray experiment, the molecular geometry, vibrational frequencies and frontier molecular orbitals analysis of the title compound in the ground state have been calculated by using the HF/6-31G(d, p), B3LYP/6-311G(d, p) and B3LYP/6-31G(d, p) methods. The computed vibrational frequencies are used to determine the types of molecular motions associated with each of the observed experimental bands. To determine conformational flexibility, molecular energy profile of (1) was obtained by semi-empirical (AM1) calculation with respect to a selected degree of torsional freedom, which was varied from $-180^{\circ}$ to $+180^{\circ}$ in steps of $10^{\circ}$. Molecular electrostatic potential of the compound was also performed by the theoretical method.

Study on Compound Humidifier Employing UV-LED using Environmental Life Cycle Assessment (환경전과정평가에 기반한 UV-LED 를 사용한 복합식 가습기에 관한 연구)

  • Choi, Won-Sik;Park, Si-Hyun;Lee, Si-Wang;Jung, Young-Mi;Yi, Hwa-Cho
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.9
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    • pp.931-937
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    • 2012
  • In this study, we assessed environmental impacts of compound humidifiers using environmental life cycle assessment and presented the ways to improvements in energy consumption of them. We found eco-design parameters and $CO_2$-eq emissions in each stage of raw material acquisition, manufacturing, transportation, use and disuse in life cycle of the compound humidifiers. The highest $CO_2$ emission is found to be in the stage of use among all stages of life cycle, which is mainly due to power consumption in thermal heating of heating coil for sterilization during humidification. The power consumption and $CO_2$ emission in the stage of use can be reduced to 1/4 and 1/3 at the highest estimate through improvement of sterilization method, respectively. We suggested the replacement of conventional thermal heating coil by ultra violet light-emitting diodes (UV-LED) for sterilization and then presented the experimental results on the sterilization effects of UV-LEDs.

Components of Potentilla Species -Isolation and Identification of 3, 3', 4-tri-O-methylellagic acid- (Potentilla속 식물의 성분연구 -3, 3', 4-tri-O-methylellagic acid의 분리 및 동정-)

  • Kim, Hack-Seang
    • YAKHAK HOEJI
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    • v.33 no.6
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    • pp.377-379
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    • 1989
  • The methylated compound of ellagic acid was isolated from Potentilla chinensis (Rosaceae). The isolated compound was 3, 3', 4-tri-O-methylellagic acid, [2, 3, 7-trimethoxy-8-hydroxy[1] benzopyrano-[5, 4, 3, cde][1] benzopyran-5, 10-dione], $C_{17}H_{12}O_8$, m.p. $293-295^{\circ}C$. The isolation of trimethylellagic acid was conducted by the column chromatography and the identification of the compound was carried out by the methods of IR, NMR and MS spectroscopy.

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Aqeous Neutralizer as Reactive Solvents for Odorous Ammonia Removal

  • Park, Young-G.
    • Environmental Engineering Research
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    • v.13 no.3
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    • pp.119-124
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    • 2008
  • Ammonia is an inorganic compound that may cause severe odor problem. In this study the effectiveness of applying natural neutralizer to destroy and remove the odor-causing compound from gas streams was studied. Experimental result evaluated with a bench-scale apparatus via the neutralization of gas phase. This indicates that the natural neutralization depends on the gas concentration, gas residence time, temperature and pH. Removal efficiency of ammonia from gas stream was achieved by 95% using theconvection in the packed bed. This study proved the chemical neutralization technology was effective for controlling inorganic odor-causing compound.

Generating 3-D Models of Human Motions by Motion Capture

  • Yamaguchi, I.;Tou, K.;Tan, J.K.;Ishikawa, S.;Naito, T.;Yokota, M.
    • 제어로봇시스템학회:학술대회논문집
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    • 2003.10a
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    • pp.1629-1632
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    • 2003
  • A technique is presented for generating a compound human motion from its primitive motions obtained by a motion capture system. Some human fundamental motions are modeled in a 3-D way and registered as primitive motions. Because the factorization method is used for the motion capture, calibration of video cameras and connection of the motion in the direction of time is both unnecessary. Employing these motions, various compound human motions are generated by connecting the motions after having applied rotation and parallel transformation to them. Linear interpolation is done at the discontinuous boundary between primitive motions and smooth connection is achieved. Experimental results show satisfactory performance of the proposed technique. The technique may contribute to producing various complicated human motions without much effort using a strict motion capture system.

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Synthesis and Biological Evaluation of Heterocyclic Ring-substituted Chalcone Derivatives as Novel Inhibitors of Protein Tyrosine Phosphatase 1B

  • Chen, Zhen-Hua;Sun, Liang-Peng;Zhang, Wei;Shen, Qiang;Gao, Li-Xin;Li, Jia;Piao, Hu-Ri
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1505-1508
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    • 2012
  • Protein tyrosine phosphatase 1B (PTP1B) is a key factor in negative regulation of the insulin pathway, and is a promising target for the treatment of type-II diabetes, obesity and cancer. Herein, compound ($\mathbf{4}$) was first observed to have moderate inhibitory activity against PTP1B with an $IC_{50}$ value of $13.72{\pm}1.53{\mu}M$. To obtain more potent PTP1B inhibitors, we synthesized a series of chalcone derivatives using compound ($\mathbf{4}$) as the lead compound. Compound $\mathbf{4l}$ ($IC_{50}=3.12{\pm}0.18{\mu}M$) was 4.4-fold more potent than the lead compound $\mathbf{4}$ ($IC_{50}=13.72{\pm}1.53{\mu}M$), and more potent than the positive control, ursolic acid ($IC_{50}=3.40{\pm}0.21{\mu}M$). These results may help to provide suitable drug-like lead compounds for the design of inhibitors of PTP1B as well as other PTPs.

Effect of N-K Compound Fertilizer Top Dressing of Paddy (수도(水稻)에 대(對)한 질소(窒素), 가리(加里) 복비추비(複肥追肥) 효과시험(效果試驗))

  • Oh, Wang-Keun;Rhee, Kang-Man;Kim, Woo-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.12 no.3
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    • pp.133-139
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    • 1979
  • In order to evaluate the effect of developed Nk compound fertilizers, 17-0-17 granular and powder, and 17-0-14 granules in comparison with single fertilizers, urea and potassium on rice (Oryzae sativa) ; cultivar, Milyang 23, (Orizae Sativa), a field experiment was carried out. Results obtained are as follows : 1. The top dressing of NK compound fertilizers tended to produce higher paddy yield than that of single fertilizers; urea and patasstum muriate. 2. The absorption of potassium and nitrogen by rice plant from the plot of NK granular compound fertilizer, 17-0-17, was greater than from the plots the absorption of those elements received other types of ferilizers and application method The absorded K/Ca+Mg ratio in milli equivalent basis in plant was also appeared to be in same order as the absorption of nitrogen and potassium. 3. From the results of present study it seemed necessary to evaluate the NK compound fertilizer for the top dressing at effective tillering stage of rice as well.

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