• 제목/요약/키워드: compound matrix

검색결과 272건 처리시간 0.039초

Amino Silane, Vinyl Silane, TESPD, ZS (TESPD/Zinc Complex) Effects on Carbon Black/Clay Filled Chlorobutyl Rubber (CIIR) Compounds Part III: Comparative Studies on Hard Clay and Soft Clay Filled Compounds

  • Kim, Kwang-Jea
    • Carbon letters
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    • 제10권3호
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    • pp.190-197
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    • 2009
  • Various silanes, amino silane, vinyl silane, sulfur silane (TESPD), and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/soft clay/carbon black (CB) and CIIR/hard clay/CB compounds and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. Comparing hard clay and soft clay filled compounds, hard clay (Suprex) filled system shows a higher die C tear than the soft clay (GK) filled one. The other properties (Mooney, extrusion torque/pressure, torque rise ($M_H-M_L$), modulus at 300%) are close to each other. Among various silanes, the ZS treated hard clay (Suprex) compound shows the highest mechanical property following hard clay(S)/vinyl silane(V) and soft clay(GK)/vinyl silane(V) compounds. The TESPD and the ZS effectively helps a formation of a strong 3-dimensional network structure between silica and CIIR via coupling reaction due to bifunctional nature of TESPD. In addition to that, the ZS added compounds show both a better processability and mechanical properties compared to the S2 ones at low concentration due to improved compatibility between zinc soap and CIIR matrix. Only the ZS added compound shows both improved processabilities (Mooney, Extrusion torque-& pressure) and improved mechanical properties (degree of crosslinking, elongation modulus, tear, and fatigue to failure counts) on both CIIR/hard clay/CB and CIIR/soft clay/CB compounds.

20S-dihydroprotopanaxatriol modulates functional activation of monocytes and macrophages

  • Kim, Mi-Yeon;Cho, Jae Youl
    • Journal of Ginseng Research
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    • 제37권3호
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    • pp.300-307
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    • 2013
  • 20S-dihydroprotopanaxatriol (2H-PPT) is a derivative of protopanaxatrol from ginseng. Unlike other components from Panax ginseng, the pharmacological activity of this compound has not been fully elucidated. In this study, we investigated the modulatory activity of 2H-PPT on the cellular responses of monocytes and macrophages to understand its immunoregulatory actions. 2H-PPT strongly upregulated the release of radicals in sodium nitroprusside-treated RAW264.7 cells and the surface levels of costimulatory molecule CD86. More importantly, this compound remarkably suppressed nitric oxide production, morphological changes, phagocytic uptake, cell-cell aggregation, and cell-matrix adhesion in RAW264.7 and U937 cells in the presence or absence of lipopolysaccharide, anti-CD43 antibody, fibronectin, and phorbal 12-myristate 13-acetate. Therefore, our results suggest that 2H-PPT can be applied as a novel functional immunoregulator of macrophages and monocytes.

저surge 진공 차단기용 Se 전극 제조 (Se Electrode for Low Surge Vacuum Circuit Breaker)

  • 김봉서;우병철;변우봉;이희웅
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1651-1653
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    • 1996
  • As electrode materials like as Cu-Pb, Cu-Bi, WC-Ag, W-Ag for vacuum circuit breaker have high chopping current or bad insulation-recovery characteristics, it can affect induction machinery like as transformer and motor. To produce low surge electrode material, it have been suggested Co-Ag-Se electrode which were infiltrated with Ag-Se intermetallic compound into sintered Co matrix. In this study, we would like to represent that production method and microstructure of Co-Ag-Se electrode material. The microstructure and characteristics of Ag-Se intermetallic compound and Co-(Ag-Se) electrode were investigated by using SEM, XRD, EPMA.

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저surge 진공 차단기용 Te 전극 제조 (Production of Te Electrode for Low Surge Vacuum Circuit Breaker)

  • 김봉서;우병철;변우봉;이희웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.123-128
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    • 1996
  • As electrode materials like as Cu-Pb, Cu-Bi, WC-Ag, W-Ag for vacuum circuit breaker have high chopping current or bad insulation-recovery characteristics, it can affect induction machinery like as transformer and motor. To produce low surge electrode material, it have been suggested Co-Ag-Te electrode which were infiltrated with Ag-Te intermetallic compound into sintered Co matrix in vacuum. In this paper, we would like to represent that production method and microstructure of Co-Ag-Te electrode material in each condition. The microstructure and characteristics of Ag-Te intermetallic compound and Co-(Ag-Te) electrode were investigated by using optical microscope, SEM, XRD, EPMA.

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복합재료 Body Panel의 고온열화 특성 (Material Properties Degradation of Composite Body Panel Exposed to High Temperature)

  • 변현중;남현욱;한경섭
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2000년도 추계학술대회논문집A
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    • pp.219-224
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    • 2000
  • A research for development of composite body panel is in progress for lightening tare. Low specific weight LPMC (Low pressure molding compound) has advantages such as lightweight and resistance to dent and corrosion. In this study, tensile, bending and impact tests for the LPMC and SPRC35 (High tension steel plate) were carried out and compared. Although mechanical properties of SPRC35 are better than the LPMC, the LPMC satisfies basic requirements for car body panel. The high temperature exposed LPMC were degraded due to fiber-matrix debonding and deterioration of resin.

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디아오화합물의 광분해반응과 카르벤 중간체의 확인 (Photolysis of Diazotetracyanocyclopentadiene and Identification of Carbene Intermediate)

  • 김민식;엄태섭;성대동
    • 한국식품영양학회지
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    • 제7권1호
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    • pp.29-35
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    • 1994
  • Photolysis of diazotetracyanocyclopentadiene has been investigated by means of IR and UV-vis spec troscopy in Ar matrix. Parent carbene is produced in low yield and could be detected by UV-vis spectroscopy and IR spectroscopy. The carbene produced from the diazo compound is very photolabile and also decay thermally at temperature as low as 10K. When the diazo compound is photolyzed the Arrhenius plots show a tunneling effect that is not shown as non linearity.

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Improving of Corrosion Resistance of Aluminum Alloys by Removing Intermetallic Compound

  • Seri, Osami
    • Corrosion Science and Technology
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    • 제7권3호
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    • pp.158-161
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    • 2008
  • It is well known that iron is one of the most common impurity elements found in aluminum and its alloys. Iron in the aluminum forms an intermetallic compounds such as $FeAl_3$. The $FeAl_3$ particles on the aluminum surface are one of the most detrimental phases to the corrosion process and anodizing procedure for aluminum and its alloys. Trial and error surface treatment will be carried out to find the preferential and effective removal of $FeAl_3$ particles on the surfaces without dissolution of aluminum matrix around the particles. One of the preferable surface treatments for the aim of getting $FeAl_3$ free surface was an electrochemical treatment such as cathodic current density of $-2kAm^{-2}$ in a 20-30 mass% $HNO_3$ solution for the period of 300s. The corrosion characteristics of aluminum surface with $FeAl_3$ free particles are examined in a $0.1kmol/m^3$ NaCl solution. It is found that aluminum with free $FeAl_3$ particles shows higher corrosion resistance than aluminum with $FeAl_3$ particles.

Microstructures of W-Mo-Ni-Fe Heavy Alloys

  • Lin, Kuan-Hong;Hsu, Chen-Siang;Lin, Shun-Tian
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.937-938
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    • 2006
  • Tungsten heavy alloys with different ratios of Mo and Ni-Fe matrix were liquid-phase-sintered to investigate their microstructural evolution. Results indicated that increased Mo in the alloy promoted the formation of a (W,Mo)(Ni,Fe) type intermetallic compound in the furnace-cooled condition. It was a monoeutectic reaction when the added Mo content was higher than 49at.%, or a eutectic reaction when this value was between 37at,% to 49at.%. When Mo was added between 25at.% to 37at.%, the precipitation of the intermetallic compound took place by either a eutectoid or peritectoid reaction.

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Improvement of the Functional Qualities of Sea Tangle Extract through Fermentation by Aspergillus oryzae

  • Bae, Hyang-Nam;Kim, Young-Mog
    • Fisheries and Aquatic Sciences
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    • 제13권1호
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    • pp.12-17
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    • 2010
  • This study was conducted to evaluate the potential of a microbial fermentation procedure to improve the functional qualities of seaweeds. Aspergillus oryzae, which has been used in traditional Korean fermented foods, was inoculated and cultivated in an aqueous extract of sea tangle (Laminaria japonica). Fermentation of the sea tangle extract by A. oryzae for 4 days resulted in a 3-fold increase in $\gamma$-aminobutyric acid (GABA) content. GABA is known to be a bioactive compound. Fungal fermentation of the extract also enhanced its antioxidant activity and increased its total content of phenolic compounds. It was assumed that these changes stemmed from the biodegradation of active compounds of the sea tangle packaged within its rigid structural matrix or occurred as result of fungal fermentation. These results suggested that the application of microbial fermentation to the processing of seaweeds will help in the development of processed foods to meet consumer demands.

급속응고 Al-Si-Fe 합금의 압출거동 및 유한요소 해석 (Extrusion Behavior and Finite Element Analysis of Rapidly Solidified Al-Si-Fe Alloys)

  • 정기승
    • 한국분말재료학회지
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    • 제6권1호
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    • pp.56-61
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    • 1999
  • The plastic deformation behaviors for powder extrusion of rapidly soildified Al-Si-Fe alloys at high temperature were investigated. During extrusion of Al-Si-Fe alloys, primary Si and intermetallic compound in matrix are broken finely. Additionally, during extrusion metastable $\delta$ phase($Al_4SiFe_2$) intermetallic compound disappears and the equilibrium $\beta$ phase($Al_5FeSi_2$) is formed. In gereral, it was diffcult to establish optimum process variables for extrusion condition through experimentation, because this was costly and time-consuming. In this paper, in order to overcome these problems, we compared the experimental results to the finite element analysis for extrusion behaviors of rapidly solidified Al-Si-Fe alloys. This ingormation is expected to assist in improving rapidly solidified Al-Si alloys extrusion operations.

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