• 제목/요약/키워드: compositional variation

검색결과 108건 처리시간 0.027초

Geomechanical assessment of reservoir and caprock in CO2 storage: A coupled THM simulation

  • Taghizadeh, Roohollah;Goshtasbi, Kamran;Manshad, Abbas Khaksar;Ahangari, Kaveh
    • Advances in Energy Research
    • /
    • 제6권1호
    • /
    • pp.75-90
    • /
    • 2019
  • Anthropogenic greenhouse gas emissions are rising rapidly despite efforts to curb release of such gases. One long term potential solution to offset these destructive emissions is the capture and storage of carbon dioxide. Partially depleted hydrocarbon reservoirs are attractive targets for permanent carbon dioxide disposal due to proven storage capacity and seal integrity, existing infrastructure. Optimum well completion design in depleted reservoirs requires understanding of prominent geomechanics issues with regard to rock-fluid interaction effects. Geomechanics plays a crucial role in the selection, design and operation of a storage facility and can improve the engineering performance, maintain safety and minimize environmental impact. In this paper, an integrated geomechanics workflow to evaluate reservoir caprock integrity is presented. This method integrates a reservoir simulation that typically computes variation in the reservoir pressure and temperature with geomechanical simulation which calculates variation in stresses. Coupling between these simulation modules is performed iteratively which in each simulation cycle, time dependent reservoir pressure and temperature obtained from three dimensional compositional reservoir models in ECLIPSE were transferred into finite element reservoir geomechanical models in ABAQUS and new porosity and permeability are obtained using volumetric strains for the next analysis step. Finally, efficiency of this approach is demonstrated through a case study of oil production and subsequent carbon storage in an oil reservoir. The methodology and overall workflow presented in this paper are expected to assist engineers with geomechanical assessments for reservoir optimum production and gas injection design for both natural gas and carbon dioxide storage in depleted reservoirs.

$Bi_{12}GeO_{20}$단결정 육성 및 표면탄성파 소자 제조 (Growth of Optical Quality $Bi_{12}GeO_{20}$ Crystals and Preparation of SAW-Filter)

  • 이태근;정수진
    • 한국결정학회지
    • /
    • 제2권2호
    • /
    • pp.32-40
    • /
    • 1991
  • The effects of compositional variation, rotation speel and pulling rate on the growth of optical quality Bi120e02(1 crystals were examined. It was found to flatten the shape of crystal-melt interface for yowing a single crystals less than about 30mm in diameter at the rotation speed of 50rpm. Diameter of crystals with flat interface was increased as the pulling rate. The precipitation of Bi40e3012 phase set limits to pulling rate of BGO crystals. Precipitate-free BGO crystals were grown under pulling rate of 2mm l hr which released the stress resulted from too hi어 Pulling rate, and from 6. IBi203·GeO2 batch composition obtained by addition of 0.1 mole Bi203 into Bi-deficient melts to fill up the deficiency resulted from gradual volatilization of Bi2O). The pale-yellow colored crystals had good quality in that dislocation density was less than 103pits/cm, and it also exhibited transmittance of 70% and optical activity of 23°/mm. and SAW velosity was measured 1700m/sec on 111 cut 110 propagating BGO crystals. The SAW filter with electrode thickness of 9.8um was fabricated by using the electron beam and dry etching technique, it makes Bi12GeO20 devices intersting for color TV IF with half device size.

  • PDF

Oxygen Deficiency, Hydrogen Doping, and Stress Effects on Metal-Insulator Transition in Single-Crystalline Vanadium Dioxide Nanobeams

  • 홍웅기;장성진;박종배;배태성
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
    • /
    • pp.424.1-424.1
    • /
    • 2014
  • Vanadium dioxide (VO2) is a strongly correlated oxide exhibiting a first-order metal-insulator transition (MIT) that is accompanied by a structural phase transition from a low temperature monoclinic phase to a high-temperature rutile phase. VO2 has attracted significant attention because of a variety of possible applications based on its ultrafast MIT. Interestingly, the transition nature of VO2 is significantly affected by stress due to doping and/or interaction with a substrate and/or surface tension as well as defects. Accordingly, there have been considerable efforts to understand the influences of such factors on the phase transition and the fundamental mechanisms behind the MIT behavior. Here, we present the influences of oxygen deficiency, hydrogen doping, and substrate-induced stress on MIT phenomena in single-crystalline VO2 nanobeams. Specifically, the work function and the electrical resistance of the VO2 nanobeams change with the compositional variation due to the oxygen-deficiency-related defects. In addition, the VO2 nanobeams during exposure to hydrogen gas exhibit the reduction of transition temperature and the complex phase inhomogenieties arising from both substrate-induced stress and the formation of the hydrogen doping-induced metallic rutile phase.

  • PDF

한국 중부지역 금은광상산 섬아연석의 조성변화와 성인적 특성 (Compositional Variations of Sphalerites and Their Genetic Characteristics from Gold and/or Silver Deposits in Central Korea)

  • 최선규
    • 자원환경지질
    • /
    • 제26권2호
    • /
    • pp.135-143
    • /
    • 1993
  • Chemical compositions of sphalerites from 25 gold and/or silver deposits in central Korea were obtained with an electron probe microanalyzer. The FeS contents of sphalerites depend generally upon the assemblage of associated iron sulphides (pyrite and/or pyrrhotite) especially. The sphalerites coexisting with pyrrhotite show a narrow range of FeS variation, but the sphalerites associated with pyrite and/or pyrrhotite have the variable and wide range of FeS contents. The sphalerites from Au-dominant deposits, which vary considerably in each deposit, are generally characterized by high CdS content and low MnS content. On the contrary, the sphalerites from Ag-dominant and Au-Ag deposits tend to be characterized by relatively high MnS and very low CdS content. Based upon the mineralogy, fluid inclusions and stable isotope data, the Au-dominant deposits were formed under higher temperature and deeper depth than the Ag-dominant and Au-Ag deposits. The results suggest the possibility that the diverse sources and evolution of ore fluid at the time of ore deposition are responsible for the deposition of Cd and Mn components in sphalerites.

  • PDF

The Composition of the Rare Earth Based Conversion Coating Formed on AZ91D Magnesium Alloy

  • Chang, Menglei;Wu, Jianfeng;Chen, Dongchu;Ye, Shulin
    • Corrosion Science and Technology
    • /
    • 제17권1호
    • /
    • pp.1-5
    • /
    • 2018
  • As structural materials, magnesium (Mg) alloys have been widely used in the fields of aviation, automobiles, optical instruments, and electronic products. There are few studies on the effect of coating conditions on the compositional variation during the formation process of the conversion coatings. Rare-earth based conversion coating on AZ91 magnesium alloy was prepared in ceric sulfate and hydrogen peroxide contained solution. The element composition and valence as well as their distribution in the coating were analyzed with energy dispersive X-ray spectroscopy (EDS), Electron probe micro-analyzer (EPMA), X-ray photoelectron spectroscopy (XPS). The effect of treating process on the element composition were also studied. It was found that the conversion coating surface consists of Mg, Al, O, Ce, and the weight content of Ce in the coating was affected by the treating solution concentration and immersion time; the Ce element was distributed in the coating non-uniformly and existed in the form of $Ce^{+3}$ and $Ce^{+4}$, while the O element existed in the form of $OH^-$, $O^{2-}$, $H_2O$. Based on microscopic analysis results, the electrochemical deposition mechanism on the micro-anode and micro-cathode in the process of the coating growth was suggested.

Insights into the Usage of Nucleobase Triplets and Codon Context Pattern in Five Influenza A Virus Subtypes

  • Deka, Himangshu;Chakraborty, Supriyo
    • Journal of Microbiology and Biotechnology
    • /
    • 제26권11호
    • /
    • pp.1972-1982
    • /
    • 2016
  • Influenza A virus is a single-stranded RNA virus with a genome of negative polarity. Owing to the antigenic diversity and cross concrete shift, an immense number of novel strains have developed astronomically over the years. The present work deals with the codon utilization partialness among five different influenza A viruses isolated from human hosts. All the subtypes showed the homogeneous pattern of nucleotide utilization with a little variation in their utilization frequencies. A lower bias in codon utilization was observed in all the subtypes as reflected by higher magnitudes of an efficacious number of codons. Dinucleotide analysis showed very low CpG utilization and a high predilection of A/T-ending codons. The H5N1 subtype showed noticeable deviation from the rest. Codon pair context analysis showed remarkable depletion of NNC-GNN and NNT-ANN contexts. The findings alluded towards GC-compositional partialness playing a vital role, which is reflected in the consequential positive correlation between the GC contents at different codon positions. Untangling the codon utilization profile would significantly contribute to identifying novel drug targets that will pacify the search for antivirals against this virus.

플라즈마 용사법을 이용한 원통형 고체산화물 연료전지의 요소피막 제조 (Fabrication of the Functional Coatings of a Tubular Solid Oxide Fuel by Plasma Spray Processes.)

  • 주원태;홍상희
    • 한국표면공학회지
    • /
    • 제30권5호
    • /
    • pp.333-346
    • /
    • 1997
  • Plasma spray processes for functional coatings of tubular SOFC ( Soild oxide Fuel Cell).consisting of air electrode, oxide electrolyte, an fuel electrode, are optimized by fully saturated fractional factorial testing. Material and electric characteristics of each coating are analtsed by the implementation of SEM and optical microscope for evaluating microstructure and porosity, X-ray diffraction method for investigating compositional change between raw powder and sprayed coating, and Van der Pauw method for measuring electrical conductivity. LSM ($La_{0.65}Sr_{0.35}MnO_3$air electrode and Ni-YSL fuel electrode coatings have porosities of around 23~30% sufficient for effective fuel and oxidant gas supply to electrochemical reaction interfaces and electrical conductivities of around 90 S/cm and 1000 S/cm, respectively, enough for acting as current collecting electrodes. YSZ($ZrO_2-8mol%Y_2O_3$) electrolyte film has a high ionic conductivities of 0.05~0.07 S/cm at $1000^{\circ}C$ in air atmosphere, but appears to be somewhat too porous to reduce the thickness. for enhancing the cell efficiency. A unit tubular SOFC has beem fabricated by the optimized plasma spray processes for each functional coating and the cell. Its electrochemical chracteristics are investigated by measuring voltage-current and power density with variation of operationg temperature, radio of fuel to air gas flowrates, and total gas flowrate of reactants.

  • PDF

니켈기 초내열 합금 GTD 111에서 편석에 의한 합금원소 분포 및 미세조직 변화 (Variation of Alloying Element Distribution and Microstructure due to Microsegregation in Ni-base Superalloy GTD 111)

  • 최백규;김인수;도정현;정중은;조창용
    • 한국주조공학회지
    • /
    • 제35권6호
    • /
    • pp.170-177
    • /
    • 2015
  • Segregation during solidification and homogenization during thermal exposure in GTD 111 were investigated. The microstructures of as-cast, standard heat-treated, and thermally exposed specimens were observed by SEM. A compositional analysis of each specimen was conducted by EDS. The dendrite core was enriched in W and Co, though lower levels of Ti and Ta were observed. An unexpected phase, in this case like the ${\eta}$ phase, was observed due to segregation near the ${\gamma}-{\gamma}^{\prime}$ eutectic in the standard heat-treated specimen. Segregation also induced microstructural evolution near the ${\gamma}-{\gamma}^{\prime}$ eutectic during the standard heat treatment. A quantitative analysis and microstructural observations showed that the thermal exposure at a high temperature enhanced the chemical homogeneity of the alloy.

전통창살문양을 응용한 패션문화상품디자인 개발 (Design Development for Fashion-Cultural Products Incorporating Traditional Lattice Patterns)

  • 김선영
    • 복식
    • /
    • 제60권9호
    • /
    • pp.16-25
    • /
    • 2010
  • This study reinterpreted the formative design elements of traditional grate patterns to create new lattice patterns and come up with a design concept for fashion-cultural products that highlight the uniqueness of traditional Korean culture and its characteristic features. Methodologically, the computer design software programs Adobe Illustrator CS2 and Adobe Photoshop were used to make grate patterns motifs. and they were applied to scarves and again to blouses using a three-dimensional simulation technique. In this study, three basic motifs for a new formative image were set using graphical functions such as omitting, simplifying, overlapping, repeating and reducing shapes based on the images of traditional 亞-shaped, arched and floral lattices, and each motif was expanded to have two variations with different colors applied to them. The direction of basic motif design was set to fit for each of fashion-cultural items such as scarves and blouses. Basic colors for motifs were arranged to create a colorful and modern but staid image in pink, blue, purple, green, yellow and brown tones. Based on a developed motif, changes were made in blouse design with lattice patterns through a variety of effects such as repetition, rotation, cross-arrangement, and oblique arrangement, and three-dimensional simulation was used to bring the design to life. Scarf design employed and applied the existing motifs in an appropriate manner for design purposes and reconstructed them through such effects as repetition, rotation, compositional variation and gradation to express a gorgeous and refined image.

One-step microwave synthesis of surface functionalized carbon fiber fabric by ZnO nanostructures

  • Ravi S. Rai;Vivek Bajpai
    • Advances in nano research
    • /
    • 제14권6호
    • /
    • pp.557-573
    • /
    • 2023
  • The rapid growth of zinc-oxide (ZnO) nanostructures (NSs) on woven carbon fiber (WCF) is reported in this study employing a microwave-aided chemical bath deposition process. The effects of different process parameters such as molar concentration, microwave duration and microwave power on morphologies and growth rate of the ZnO on WCF were studied. Furthermore, an attempt has been taken to study influence of different type of growth solutions on ZnO morphologies and growth rates. The surface functionalization of WCF fabrics is achieved by successful growth of crystalline ZnO on fiber surface in a very short duration through one-step microwave synthesis. The morphological, structural and compositional studies of ZnO-modified WCF are evaluated using field-emission scanning electron microscopy, X-ray diffraction and energy dispersive X-ray spectroscopy respectively. Good amount of zinc and oxygen has been seen in the surface of WCF. The presence of the wurtzite phase of ZnO having crystallite size 30-40 nm calculated using the Debye Scherrer method enhances the surface characteristics of WCF fabrics. The UV-VIS spectroscopy is used to investigate optical properties of ZnO-modified WCF samples by absorbance, transmittance and reflectance spectra. The variation of different parameters such as dielectric constants, optical conductivity, refractive index and extinction coefficient are examined that revealed the enhancement of optical characteristics of carbon fiber for wide applications in optoelectronic devices, carbon fiber composites and photonics.