• Title/Summary/Keyword: composition ratios

Search Result 826, Processing Time 0.03 seconds

A Study on Copolymerization of Propylene over Butene-1 and Hexene-1 Comonomer (부텐-1과 헥센-1 코모노머를 이용한 프로필렌의 공중합에 관한 연구)

  • Yang, Hyun S.;Lee, Seng C.
    • Applied Chemistry for Engineering
    • /
    • v.7 no.4
    • /
    • pp.623-632
    • /
    • 1996
  • The reactivity ratios, melting temperature and polymer morphology in propylene/butene-1 and propylene/hexene-1 copolymerization reactions were studied by examining comonomer compositions of resulting polymers. The catalysts used here are different in their supports which are silica(catalyst I) and magnesium(catalyst II). As the content of comonomer(butene-1 and hexene-1) increased in the copolymer, the melting temperature of the copolymer decreased. The morphology of polymer was amorphous in the range of comonomer(butene-1) composition over 40% in the propylene/butene-1 copolymerization and comonomer(hexene-1) composition over 80% in the propylene/hexene-1 copolymerization. The reactivity ratios were obtained by the Fineman-Ross and Kelen-$T{\ddot{u}}d{\tilde{o}}s$ methods.

  • PDF

Research on vibration control of a transmission tower-line system using SMA-BTMD subjected to wind load

  • Tian, Li;Luo, Jingyu;Zhou, Mengyao;Bi, Wenzhe;Liu, Yuping
    • Structural Engineering and Mechanics
    • /
    • v.82 no.5
    • /
    • pp.571-585
    • /
    • 2022
  • As a vital component of power grids, long-span transmission tower-line systems are vulnerable to wind load excitation due to their high flexibility and low structural damping. Therefore, it is essential to reduce wind-induced responses of tower-line coupling systems to ensure their safe and reliable operation. To this end, a shape memory alloy-bidirectional tuned mass damper (SMA-BTMD) is proposed in this study to reduce wind-induced vibrations of long-span transmission tower-line systems. A 1220 m Songhua River long-span transmission system is selected as the primary structure and modeled using ANSYS software. The vibration suppression performance of an optimized SMA-BTMD attached to the transmission tower is evaluated and compared with the effects of a conventional bidirectional tuned mass damper. Furthermore, the impacts of frequency ratios and SMA composition on the vibration reduction performance of the SMA-BTMD are evaluated. The results show that the SMA-BTMD provides superior vibration control of the long-span transmission tower-line system. In addition, changes in frequency ratios and SMA composition have a substantial impact on the vibration suppression effects of the SMA-BTMD. This research can provide a reference for the practical engineering application of the SMA-BTMD developed in this study.

Effect of Synthesis Temperature on the Composition of Electrolytic Iron Phosphide

  • Kim, Hokon;Shin, Heon-Cheol
    • Journal of Electrochemical Science and Technology
    • /
    • v.9 no.1
    • /
    • pp.78-83
    • /
    • 2018
  • In this study, we investigated the composition of an electrolytic Fe phosphide at different synthesis temperatures. We found that the ratio of Fe in the electrodeposit increases with synthesis temperature, whereas the oxygen content introduced into the electrodeposit by the atmospheric oxidation of Fe decreases. The aim of this study was to identify the reason for this effect. For this purpose, the ratio of Fe and P in the electrodeposits prepared at different temperatures was analyzed in depth. In addition, the types and ratios of Fe phosphide phases were considered. It was proved that with increase in temperature, a significant amount of Fe reacted with P to form Fe phosphide phases, and consequently, the amount of residual pure Fe that would react directly with oxygen decreased.

Electrical and Structural Properties of $CuInS_2$ thin films fabricated by EBE(Electronic Beam Evaporator) Method (전자빔 증착기로 증착된 $CuInS_2$ 박막의 전기적 구조적 특성)

  • Yang, Hyeon-Hun;Kim, Young-Jun;Jeong, Woon-Jo;Park, Gye-Choon
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2006.06a
    • /
    • pp.170-173
    • /
    • 2006
  • [ $CuInS_2$ ] filims were appeared from 0.84 to 1.27 of Cu/In composition ratio and sulfur composition ratios of $CuInS_2$ thin films fabricated, Also when Cu/In composition ratio was 1.03, $CuInS_2$ thin film with chalcopyrite structure had the highest XRD peak (112). And lattice constant (a) of and grain size of the film tin s ambient were appeared a little larger than those in only Vacuum The films in S ambient were p-type with resistive of around $10^{-1}{\Omega}cm$ and optical energy band gaps of the films in S ambient were appeared a little larger than those in only Vacuum. Analysis of the optical energy band gap of $CuInS_2$ thin films a value of 1.53eV.

  • PDF

Characterization of Biometry and Chemical and Morphological Properties of Fibers from Bagasse, Corn, Sunflower, Rice, and Rapeseed Residues in Iran

  • Kiaei, Majid;Samariha, Ahmad;Kasmani, Jafar Ebrahimpour
    • Journal of Forest and Environmental Science
    • /
    • v.26 no.2
    • /
    • pp.75-82
    • /
    • 2010
  • The biometry, morphological properties and chemical composition of bagasse, corn, sunflower, rice, and rapeseed residues plants were analyzed. The results revealed differences in biometry properties and chemical composition of the different types of agricultural resides investigated. The greatest proportion of fiber length (1.32 mm) and cellulose (55.56%) was found in residues of bagasse plants, with a low ash (1.78%) and lignin (20.5%). The lignin of all types of agricultural resides was less than hardwood and softwood. In addition, the rice and rapeseed residues plants had highest amount of ash and extractive component. The slenderness and flexibility ratios of the all types of agricultural resides fibers were similar to some of hardwood and softwood species.

EFFECTS OF PHOSPHORUS AND CALCIUM ON FEED INTAKE AND YIELD AND COMPOSITION OF MILK OF HOLSTEIN COWS

  • Morse, D.;Head, H.H.;Wilcox, C.J.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.7 no.2
    • /
    • pp.231-237
    • /
    • 1994
  • Three concentrations of P (0.33, 0.43 and 0.54%) and two concentrations of Ca (0.60 and 0.97%) in ration dry matter were evaluated for effects on dry matter intake and on milk yield and composition using 24 Holstein cows. Cows were arranged in a $3{\times}2$ factorial experiment as an incomplete randomized block design with three 28-day periods. Each cow consumed at least one ration with each concentration of Ca. Dry matter intake, yield of 3.5% Fat Corrected Milk, and milk composition were not affected by concentration of P, but milk yield was greater when lowest concentration of P was fed (22.8 vs. 22.1 kg/day; p<0.07). Cows fed rations containing 0.60% Ca had greater milk (22.7 vs. 21.9 kg/day; p<0.02) and 3.5% Fat Corrected Milk yields (p<0.03) and slightly greater protein content than when fed 0.97% Ca. Dietary Ca:P ratios between 1.1:1 and 2.9:1 had no effect on dry matter intake, milk yield, or composition. Concentrations of P in plasma were within the normal range for all rations. Because cows had high dry matter intake, mean daily intakes of both P and Ca were greater than required for their level of milk yield.

Effects of different ratios and storage periods of liquid brewer's yeast mixed with cassava pulp on chemical composition, fermentation quality and in vitro ruminal fermentation

  • Kamphayae, Sukanya;Kumagai, Hajime;Angthong, Wanna;Narmseelee, Ramphrai;Bureenok, Smerjai
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.30 no.4
    • /
    • pp.470-478
    • /
    • 2017
  • Objective: This study aims to evaluate the chemical composition, fermentation quality and in vitro ruminal fermentation of various ratios and storage periods of liquid brewer's yeast (LBY) mixed with cassava pulp (CVP). Methods: Four mixtures of fresh LBY and CVP were made (LBY0, LBY10, LBY20, and LBY30 for LBY:CVP at 0:100, 10:90, 20:80, and 30:70, respectively) on a fresh matter basis, in 500 g in plastic bags and stored at 30 to $32^{\circ}C$. After storage, the bags were opened weekly from weeks 0 to 4. Fermentation quality and in vitro gas production (IVGP) were determined, as well as the dry matter (DM), organic matter (OM), crude protein (CP), ether extract (EE), neutral detergent fiber, acid detergent fiber and acid detergent lignin contents. Results: The contents of CP and EE increased, whereas all other components decreased, in proportion to LBY inclusion (p<0.01). The DM and OM contents gradually decreased in weeks 3 and 4 (p<0.05), while EE contents were lowest in week 0. The pH, ammonia nitrogen per total nitrogen ($NH_3-N/TN$) and V-score in each mixture and storage period demonstrated superior fermentation quality ($pH{\leq}4.2$, $NH_3-N/TN{\leq}12.5%$, and V-score>90%). The pH increased and $NH_3-N/TN$ decreased, with proportionate increases of LBY, whereas the pH decreased and $NH_3-N/TN$ increased, as the storage periods were extended (p<0.01). Although IVGP decreased in proportion to the amount of LBY inclusion (p<0.01), in vitro organic matter digestibility (IVOMD) was unaffected by the mixture ratios. The highest IVGP and IVOMD were observed in week 0 (p<0.01). Conclusion: The inclusion of LBY (as high as 30%) into CVP improves the chemical composition of the mixture, thereby increasing the CP content, while decreasing IVGP, without decreasing fermentation quality and IVOMD. In addition, a preservation period of up to four weeks can guarantee superior fermentation quality in all types of mixtures. Therefore, we recommend limiting the use of CVP as a feed ingredient, given its low nutritional value and improving feed quality with the inclusion of LBY.

A Study on the Characteristics of Ion, Carbon, and Elemental Components in PM2.5 at Industrial Complexes in Ansan and Siheung (안산·시흥 산업단지 지역 PM2.5 중 이온, 탄소, 원소성분의 특성 연구)

  • Lee, Hye-Won;Lee, Seung-Hyeon;Jeon, Jeong-In;Lee, Jeong-Il;Lee, Cheol-Min
    • Journal of Environmental Health Sciences
    • /
    • v.48 no.2
    • /
    • pp.66-74
    • /
    • 2022
  • Background: The health effects of particulate matter (PM2.5) bonded with various harmful chemicals differ based on their composition, so investigating and managing their concentrations and composition is vital for long-term management. As industrial complexes emit considerable quantities of pollutants, higher PM2.5 concentrations and chemical component effects are expected than in other places. Objectives: We investigated the concentration distribution ratios of PM2.5 chemical components to provide basic data to inform future major emissions control and PM2.5 reduction measures in industrial complexes. Methods: We monitored five sites near the Ansan and Siheung industrial complexes from August 2020 to July 2021. Samples were collected and analyzed twice per week in spring/winter and once per week in summer/autumn according to the National Institute of Environmental Research in the Ministry of Environments' Air Pollution Monitoring Network Installation and Operation Guidelines. We investigated and compared composition ratios of 29 ions, carbon, and elemental components in PM2.5. Results: The analysis of PM2.5 components at the five sites revealed that ion components accounted for the greatest total mass at approximately 50% while carbon components and elemental components contributed 23~28% and 8~10%, respectively. Among the ionic components, NO3- occupies the greatest proportion. OC occupies the greatest proportion of the carbon components and sulphur occupies the greatest proportion of elemental components. Conclusions: This study investigated the concentration distribution ratios of PM2.5 chemical components in industrial complexes. We believe these results provide basic chemical component concentration ratio data for establishing future air management policies and plans for the Ansan and Siheung industrial complexes.

Manufacturing Techniques of Bronze Seated Bodhisattva Statue of Goseongsa Temple in Gangjin (강진 고성사 청동보살좌상의 제작기술 연구)

  • LEE Seungchan;BAE Gowoon;CHUNG Kwangyong
    • Korean Journal of Heritage: History & Science
    • /
    • v.57 no.1
    • /
    • pp.146-159
    • /
    • 2024
  • In this study, a study on the production technology of the Buddha statue and the production of raw material origin was conducted through scientific analysis on the Bronze seated Bodhisattva Statue of Goseongsa Temple, a treasure. As a result of microstructure analysis through a metal microscope, it was confirmed that the microstructure of the Bronze seated Bodhisattva Statue of Goseongsa Temple was a process-type dendritic structure, and the casting structure of bronze was well represented, so it was manufactured through casting. Subsequently, as a result of analyzing the alloy composition ratio through SEM-EDS, it was identified as a ternary alloy with 81.26 wt% of copper (Cu) and 16.42 wt% of tin (Sn) and 1.72 wt% of lead (Pb). The results of the analysis of lead isotope ratios using a thermal ionization mass spectrometer (TIMS) were substituted into the distribution of lead isotope ratios on the Korean Peninsula, it was shown in corresponding to Jeolla-do and Chungcheong-do regions and North and South Gyeongsang Province. This suggests that the raw materials used in their production were likely sourced from the mines around Goseong Temple in Gangjin. Despite the fact that the statue is a medium and large Buddha with a total height of 51 centimeters, 1.72 wt% of lead (Pb) was found as a result of alloy composition ratio analysis, which showed a similar composition to the lead content ratio of small bronze and gilt-bronze Buddha statues. Therefore, we compared and analyzed the results of the analysis of the composition ratio of the alloys of bronze and gilt bronze statues, which has been scientifically analyzed with a compositional age similar to that of the Bronze seated Bodhisattva Statue of Goseongsa Temple. Comparison results, Various factors, such as the size of the Buddha statue as well as its stylistic characteristics and the age of composition, may exist in determining the alloy composition ratio of the bronze and gilt bronze Buddha statues, and it was confirmed that the alloy composition ratio or casting technology was properly adjusted when the Buddha statue was created. In other words, it is judged that a more comprehensive system of Buddha statue production technology should be investigated by conducting archaeological and art history studies on stylistic characteristics and age of composition, as well as scientific analysis results such as observation of internal structure, microstructure observation, and analysis of alloy composition ratio using radiation transmission irradiation.

Nutrients and Phytoplankton Blooms in the Southern Coastal Waters of Korea: I. The Elemental Composition of C, N, and P in Particulate Matter in the Coastal Bay Systems

  • Kang, Chang-Keun;Kim, Pyoung-Joong;Lee, Won-Chan;Lee, Pil-Yong
    • Journal of the korean society of oceanography
    • /
    • v.34 no.2
    • /
    • pp.86-94
    • /
    • 1999
  • An investigation was conducted to determine limiting nutrients in the bay systems of the southern coastal area of Korea. The elemental composition of C, N, and P in suspended particulate matter was monitored nearly monthly in Chinhae and Koje Bays and seasonally in Deukryang Bay for 2 years. Atomic C:N ratio in particulate matter ranges from 4.3 to 9.6, typical of marine phytoplankton. C:P and N:P ratios vary from the Redfield ratio to 229 (C:P) and 37 (N:P). A constant C:N ratio of 6.87 from regression of particulate C and N concentrations demonstrates that the particulate matter in the systems originates from primary production. C:P and N:P ratios from regression of C on P and N on P are well associated with changes in salinity. The low N:P ratio of 13.1 implies N limitation in the environments of the systems. This seems to result from the low N:P ratio of nutrients released across sediment-water interface. Phytoplankton response, expressed here as the increase of chlorophyll a, to N addition also verifies N limitation for phytoplankton communities. In heavy rainfall season (from June to September), the addition of excessive N via streams into the stratified coastal water proliferates phytoplankton greatly. During the phytoplankton blooms, C:P and N:P ratios are much higher than the Redfield ratio, implying P limitation. This results from the high N:P ratio in nutrients supplied from stream waters. Strong stratification during the blooms also interrupts the supply of nutrients, particularly p, from bottom waters. Dependent upon precipitation, this tendency shows great inter-annual variation.

  • PDF