• Bulletin of the Korean Chemical Society
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• v.9 no.5
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• pp.292-295
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• 1988

Macrocyclic ligands have been studies as cation carriers in a bulk liquid membrane system. $Cu^{2+}$ has been transported using nitrogen substituted macrocycles as carriers and several transition metal ions($M^{n+}\;=\;Mn^{2+},\;Co^{2+},\;Ni^{2+},\;Cd^{2+},\;Pb^{2+}\;and\;Ag^{+}$) have been transported using $DBN_3O_2,\;DBN_2O_2,\;Me_6N_414C4$ and DA18C6 as carriers in a bulk liquid membrane system. Competitive $Cu^{2+}-M2^+$ transport studies have also been carried out for the same system. In single cation transport experiments, the best macrocyclic ligand for transport is a ligand that gives a moderately stable rather than very stable complex in the extraction. However, when both cations are present in the source phase, the cation which forms the most stable complex with carrier is favored in transport over other cations. Generally, the nitrogen substiituted macrocycles transport $Cu^{2+}$ selectively over $Mn^+$. Ligand structure, equilibrium constant (or stability constant) for complex formation, source phase pH and carrier concentration are also important parameters in transport experiments.

• Bulletin of the Korean Chemical Society
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• v.17 no.12
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• pp.1109-1111
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• 1996

The Podand Ⅰ (Figure 1) has been studied as cation carrier in a bulk liquid membrane system. Ag+ and some other transition metal ions (M2+=Cu, Ni, Co, Zn, and Cd) have been transported using the podand as carrier in a bulk liquid membrane system. Studies on the transport of equimolar mixtures of two or three competing components have also been carried out with the same system. Ag+ exhibited a higher transport rate than the other M2+ in the competitive experiments. Ligand structure and the equilibrium constant for complex formation are important parameters in the transport of the metal ions.

• Journal of Environmental Health Sciences
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• v.26 no.4
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• pp.88-96
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• 2000

The aim of the current study was to evaluate the transport system in EMT-6 cell for the uptake of the methylmercury(MeHg). Several inhibitors ere used to test used to test which potential transport system might be involoved in MeHg uptake. Probenecid was used to test the organic transport system, valinomycin for testing the effect of the membrane potential, cytochalasin B for testing the facilitated diffusive D-glucose transport system and colchicine for testing the microtubule system. Ouabain for evaluating active transport system, 4',4-diisothiocyano-2',2-stilbenedisulfonic acid(DIDS) the Cl- ion transport system and verapamil for the $Ca^{2+}$ transprot system. Significantly, MeHg decreased the synthesis of nitric oxcide(NO) and intracellular ATP in ENT-6 cells. In the condition of ouabain containing with MeHg decreased the production of NO and intracelluar ATP. In the treatment of inhibitors, ouabain showed protective effect against cytotoxicity of MeHg but ather inhibitors not showed protective effects. The protective effects of ouabain against the cytotoxicity of MeHg deoended on the concentration of added ouabain to the culture medium for MET-6 cells. These result showed that the uptake of MeHg might be involved in the active transport system. Active transports system seems to share similarities with the transport systems for the uptake of MeHg when using MeHg and MeHg-glutathione complex.x.

• Proceedings of the Membrane Society of Korea Conference
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• 1994.04a
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• pp.55-56
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• 1994

There has been many attempts to improve the membrane performance using pervaporation processes[l-3]. They are 1) blending polymer with the high flux and one with high selectivity, 2) an incorporation of functional groups interacting with permeants into a membrane through copolymerization or modification, 3) composite membrane or asymmetric membrane structure with a thin skin layer which acts as a selective layer. Among them, a polymeric membrane containing ion complex group receives an extensive attention recently because ionic complex is known to activate the water transport through ion-dipole interaction. It is especially advantageous in the separation of organic-water system. We applied the ideas of the activation of water transport through ion-dipole. We have reported on the in-sire complex membrane to separate water from aqueous aceiic acid and pyridme solution[4-5] based on the simple acid-base theory. Water transport was enhanced through in-situ complex between pyridine moiety in the membrane and the incoming acetic acid in the feed. In this case, catalytic transport mechanism was proposed. In the present study we used pyridine solution as a feed and the sulfonic acid group in the membrane.

• Environmental Engineering Research
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• v.13 no.2
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• pp.69-72
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• 2008

The movement of sediments in the stream crossing a large industrial complex to the mouth of Masan Bay was monitored for eight years. Sediment samples were seasonally collected in the period of $1992{\sim}1997$ and $2001{\sim}2002$. The heavy metal content of sediment was found to be higher at dry season with the peak on February and significantly decreased at rainy season. Metals content in stream sediments were rapidly decreased by large precipitation events in rainy season because the contaminants in the upstream sediments were transported to the dredged area of Masan Bay where is a typical enclosed bay in Korea. The increasing and decreasing tendency of heavy metals in sediment was repeatedly observed for six consecutive years. The heavy metals assessment of stream sediment provide us the information about the pollutant source, transport pattern and control strategy along the industrial complex. It was strongly suggested that the transportable stream sediments of an industrial area should be controlled as one of the important strategies to restore and manage the enclosed bay. Combined wastewaters have been collected and treated in a publicly owned treatment works (POTW) after industrial wastewater treatment at each location of industries since 1994. A field study was conducted to investigate the pollutant removal efficiency and performance of contact oxidation system installed and operated in two locations in the stream. The stream sediment quality was improved since then, and as a consequence the habitat of the estuary has been restored.

• Proceedings of the KSR Conference
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• 2011.05a
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• pp.505-510
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• 2011

The railroad freight transport has great merits that can transport mass and specific items(dangerous goods), but it takes a long time because of low accessibility to the logistics facility and the complex process of loading freight in middle station. This paper analyzed volumes and characters of each railroad freight item, and was carried out the effect of applying E&S system to Gyeongbu line containers to find the method of reducing transport time and effective container transportation. As a result of Cost-Effectiveness analysis, the block train(B/T) is reducing transport time more about 1~2 hours. The road congestion cost is saving about 2.2 billion won. And due to skipping work of organizing train, personnel and equipment expenses savings expected about 9 billion won. It is expected that the E&S system enhances the container transport service and has an effect positive influence on making a efficient method of transport. But It is necessary to estimate pre-feasibility of applying E&S system that the standard of estimating cost and benefit is required further examination.

• Applied Microscopy
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• v.17 no.2
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• pp.55-71
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• 1987

To investigate the effects of lead on the electron transport system and ultrastructure of mouse kidney mitochondria, various lead acetate concentrations were treated in vitro and respiration rate, enzyme activities were measured. Ultrastructural changes at state IV respiration were also observed. To compare with in vivo experiments, mouse were injected intraperitoneally of 100 mg lead acetate per kg body weight and state IV respiration rate and enzyme activities were measured. Ultrastructure of renal proximal tubular cells were also observed. In in vitro treatement, decreased state IV respiration, decreased enzyme activities, ruptured membranes and inhibition of condensed to orthodox transformation were observed. In in vivo treatment, decreased state IV respiration and decreased enzyme activities were observed after 24 hrs of i.p. injection. Cytochrome c oxidase activity showed twice the inhibition compared to NADH-CoQ reductase activity at 24 hrs. Continuous decreased state IV respiration was observed after 48 and 72 hrs of injection, however, the enzyme activities were increased to control level. Lead-protein complex which probably inhibits the toxic effects of lead appeared. To conclude, dominant effect of lead on the electron transport system appeared at cytochrome c oxidase activity, and the increased enzyme activities may be a result of appearance of lead-protein complex.

• Journal of Navigation and Port Research
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• v.40 no.3
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• pp.147-157
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• 2016

The trend of globalization and the development of the communication-Information technology have led the organization of a complex supply chains which are more vulnerable to risks. The impact of risk on the supply chain can be adverse so importance of risk management on a supply chain has increased. In order to analyze the risk factors of transport system, this study described about the definition of transport risk and investigated the relationship between likelihood index and effect index of each risk factor. We identified risk factors on transport system and measured likelihood index and effect index of each risk factor. Finally, a numerical risk index, which is a value of total transport system, has been resulted by aggregating all indices. In addition, a case study using the proposed method has done on a heavy vehicle transport context with a transport company.

• Journal of Navigation and Port Research
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• v.31 no.1 s.117
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• pp.7-14
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• 2007

Recently, freight floe between south and north Korea is rising rapidly by increasing cf economical exchange between two Korea and growth of Gaeseoung Industrial Complex. Considering this trend of economic cooperation between two Korea, in addition to a land transportation route it is necessary to secure various logistics and transportation route. A barge transport system which has many merits such as a little initial investment and convenience of harbor loading/unloading has been also used to transport freight widely in the EU and USA. In this paper, firstly, a Gaeseoung industrial complex and its cargo transport are investigated and several candidate shipping routes which are using barge transportation system are proposed. And also we investigate a technical feasibility on a realistic possibility of shipping routes by some investigation activities. Finally, a suitable barge system of candidate shipping route(1) and(2) is proposed in this paper.

• The Magazine of the IEIE
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• v.24 no.2
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• pp.13-26
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• 1997

Throughout the world in major urban centers, the volume of vehicular traffic on roads continues to increase. ITS provides drivers with traffic information and new routing options on route In order to make them move quickly to their destinations. The higher mobility, the more productivity we gain. The ultimate goal of Intelligent Transport System is to improve mobility. ITS world is broad and quite varied, as demonstrated by ITS user services, their distinct needs, and complex Interactions and synergies. ITS ties the transportation and telecommunication worlds together. The complex world of telecommunications is evolving and expanding rapidly. Especially over the last two decades, the birth and unprecedented growth of wireless is really marvelous and further holds tremendous promise into the future. This wireless and emerging technologies will offer extensive opportunities to handle many ITS user services, and alter many of the traditional paradigms of transportation.