• Korean Journal of Materials Research
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• v.32 no.4
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• pp.181-185
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• 2022

In this study, phase-pure titanium dioxide TiO₂ ceramics are sintered using standard high-temperature solid-state reaction technique at different temperatures (1,000, 1,100, 1,200, 1,300, 1,400 ℃). The effect of sintering temperature on the densification and impedance properties of TiO₂ ceramics is investigated. The bulk density and average grain size increase with the increase of sintering temperature. Impedance spectroscopy analysis (complex impedance Z^* and complex modulus M^*), performed in a broad frequency range from 100 Hz to 10 MHz, indicates that the TiO₂ ceramics are dielectrically heterogeneous, consisting of grains and grain boundaries. The complex impedance Z^* -plane indicates the resistance of grains of the TiO₂ ceramics increases with increasing sintering temperature, while that of grain boundaries develops in the opposing direction. The complex modulus M^*-plane shows a grain capacitance that seems to be independent of the sintering temperature, while that of the grain boundaries decreases with increasing sintering temperature. These results suggest that different sintering temperatures have effects on the microstructure, leading to changes in the impedance properties of TiO₂ ceramics.

• The Transactions of the Korean Institute of Electrical Engineers D
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• v.51 no.7
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• pp.302-307
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• 2002

Digital watermarking is the technique, which embeds an invisible signal including signal including owner identification and copy control information into multimedia data such as audio, video, and images for copyright protection. A new MPEG watermark embedding algorithm using complex block effect based on the Human Visual System(HVS) is introduced in this paper. In this algorithm, $8{\times}8$ dark blocks are selected, and the watermark is embedded in the DC component of the discrete cosine transform(DCT) by using quantization and modulus calculation. This algorithm uses a blind watermark retrieval technique, which detects the embedded watermark without using the original image. The experimental results show that the proposed watermark technique is robust against MPEG coding, bitrate changes, and various GOP(Group of Picture) changes.

• Korea-Australia Rheology Journal
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• v.21 no.3
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• pp.185-191
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• 2009

Polystyrene/multi-walled carbon nanotube (PS/MWCNT) composites were prepared by the use of latex technology. The monodisperse PS latex was synthesized by an emulsifier-free emulsion polymerization from styrene/potassium persulfate/water system in the presence of ethanol. The MWCNTs were first treated with acid mixture to eliminate impurities, dispersed in deionized water driven by ultrasonicator, and then mixed with the PS latex. From these mixtures, PS/MWCNT composites were prepared by freeze-drying and subsequent compression molding. In the small-amplitude oscillatory shear experiments, both complex viscosity and storage modulus increased with increasing MWCNT content. A pronounced effect of MWCNT content was observed, resulting in larger storage modulus and stronger yield behavior at low frequencies when compared to unmodified PS. It showed a transition from viscous to elastic behavior with increasing MWCNT content. Over the MWCNT content of 3 wt%, the storage modulus was higher than the loss modulus across all frequencies.

• Korea-Australia Rheology Journal
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• v.20 no.4
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• pp.227-233
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• 2008

High impact polystyrene (HIPS)/organoclay nanocomposites via in situ polymerization were synthesized and their rheological properties were investigated. For the study, two types of organoclays were used: a commercially available organoclay, Cloisite 10A (C10A), and a laboratory-prepared organoclay having a reactant group, vinylclay (ODVC). The X-ray diffraction and transmission electron microscopy experiments revealed that the HIPS/ODVC nanocomposite achieved an exfoliated structure, whereas the HIPS/C10A nanocomposite achieved an intercalated structure. In the small-amplitude oscillatory shear experiments, both storage modulus and complex viscosity increased with increasing organoclay. A pronounced effect of the organoclay content was observed, resulting in larger storage modulus and stronger yield behavior in the low frequency region when compared to neat HIPS. The crossover frequencies associated with the inverse of a longest relaxation time decreased as the organoclay content increased. Over a certain value of ODVC content, a change of pattern in rheological properties could be found, indicating a solid-like response with storage modulus greater than loss modulus at all frequencies.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.15 no.2 s.95
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• pp.213-218
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• 2005

It is well known that the loss factor and Young's modulus are fundamental mechanical properties of materials. Recently, the use of complex plastics is increasing for vibration proof. In this study, we evaluated two mechanical values of polycarbonate and acrylonitrile butadiene styrene by using two different standard test methods of ASTM E 756 and ISO 6721. Because damping properties of material generally depend on temperature, test specimen‘s temperature were controlled in the temperature range between - $10^{\circ}C\;and\;60^{\circ}C$. The results shown that the loss factor of polycarbonate gradually increased as increasing temperature, while the Young's modulus decreased. However, the loss factor and the Young's modulus of acrylonitrile butadiene styrene are varied somewhat at $60^{\circ}C$.

• Journal of The Korean Society of Agricultural Engineers
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• v.66 no.1
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• pp.15-24
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• 2024

Unlike artificially created homogeneous materials, the process of calculating the elastic modulus of natural soil involves the possibility of errors. Because the stress-strain behavior of soil is nonlinear, the secant modulus of elasticity is often used based on 1/2 of the stress at failure. Since soil has the property of changing its elastic modulus depending on the confining pressure, numerical analysis models that analyze its behavior inevitably include complex elements. The hyperbolic model, which relatively accurately simulates the behavior immediately after loading in soft ground, assumes that the stress-strain curve of the consolidated undrained triaxial test is hyperbolic and requires the slope of the tangent line at the starting point. However, the slope of the initial tangent in the stress-strain curve obtained from an actual triaxial test is difficult to have regularity according to changes in confining pressure. Additionally, due to the characteristics of a hyperbola, even small changes in related factors cause large changes in the hyperbola. Therefore, there is a lot of randomness in the process of calculating model parameters from the triaxial test results, which causes large differences in the results. Therefore, the method of calculating the initial elastic modulus by the consolidation test presented in this study is also used to verify the method by the triaxial test. It can be applied. However, since this study was applied to only one sample showing typical consolidation characteristics, it is necessary to check samples with various physical properties in the future.

• Food Science and Biotechnology
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• v.15 no.6
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• pp.871-876
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• 2006

Rheological behavior of commercial hot pepper-soybean paste (HPSP) was evaluated in small amplitude oscillatory and steady shear tests. Storage modulus (G'), loss modulus (G"), and complex viscosity (${\eta}^*$) as a function of angular frequency (${\omega}$), and shear stress (${\sigma}$) as a function of shear rate (${\gamma}$) data were obtained for 5 commercial HPSP samples. HPSP samples at $25^{\circ}C$ exhibited a non-Newtonian, shear-thinning flow behavior with high yield stresses and their flow behaviors were described by power law, Casson, and Herschel-Bulkley models. Time-dependent flow properties were also described by the Weltman, Hahn, and Figoni & Shoemaker models. Apparent viscosity over the temperature range of $5-35^{\circ}C$ obeyed the Arrhenius temperature relationship with activation energies (Ea) ranging 18.3-20.1 kJ/mol. Magnitudes of G' and G" increased with an increase in ${\omega}$, while ${\eta}^*$ decreased. G' values were higher than G" over the most of the frequency range (0.63-63 rad/sec), showing that they were frequency dependent. Steady shear viscosity and complex viscosity of the commercial HPSP did not fit the Cox-Merz rule.

• International Journal of Control, Automation, and Systems
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• v.5 no.1
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• pp.1-7
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• 2007

In this paper, the necessary and sufficient conditions for strict positive realness of the rational transfer functions directly from basic definitions in the frequency domain are studied. A new frequency domain approach is used to check if a rational transfer function is a strictly positive real or not. This approach is based on the Taylor expansion and the Maximum Modulus Principle which are the fundamental tools in the complex functions analysis. Four related common statements in the strict positive realness literature which is appeared in the control theory are discussed. The drawback of these common statements is analyzed through some counter examples. Moreover a new necessary condition for strict positive realness is obtained from high frequency behavior of the Nyquist diagram of the transfer function. Finally a more simplified and completed conditions for strict positive realness of single-input single-output linear time-invariant systems are presented based on the complex functions analysis approach.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.25 no.4 s.34
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• pp.65-74
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• 1999

We have studied the stability of W/O high internal phase emulsions(HIPE) containing water, cetyl dimethicone copolyol and oils varying magnesium sulfate in the range 0 to 0.5 wt% and oil polarities, respectively. The rheological consistency was mainly destroyed by the coalescence of the deformed water droplets. The greater the increase of complex modulus was, the less coalescence occurred and the more consistent the concentrated emulsions were. The increasing pattern of complex modulus versus volume fraction has been explained with the resistance to coalescence of the deformed interfacial film of water droplets in concentrated W/O emulsion. The stability is dependent on: (i) the choice of the oil is important, the requirements coincide with the requirements for the formation of the rigid liquid crystalline phases; and (ii) addition of salts the aqueous phase opposes the instability due to coalescence. Increasing the salt concentration increases the refractive index of the aqueous phase. It lowers the difference in the refractive index between the oil and aqueous phases. This decreases the attraction between the water domains, thus increasing the stability.

• Carbon letters
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• v.10 no.2
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• pp.101-108
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• 2009

Various silanes, amino silane, vinyl silane, TESPD, and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/hard clay/carbon black (CB) compound and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. In hard clay/CB filled system, only ZS silane added compound shows both lower Mooney viscosity and extrusion torque while vinyl silane added compound showed only a lower extrusion torque. All the ZS added compounds showed the lowest viscosity among them. The silane added compounds showed an increased modulus. In 'fatigue to failure' count test, the ZS added compound showed superior counts compared to other silane (amino, vinyl, TESPD) added compounds. The mechanical properties were significantly increased when the S2 and ZS were added into CIIR/hard clay/CB compound. The ZS added compounds showed a significant improvement on elongation modulus.