• Title/Summary/Keyword: complex conductivity

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Grain Size Dependence of Ionic Conductivity of Polycrystalline Doped Ceria

  • Hong, Seong-Jae
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.122-127
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    • 1998
  • Conductivities of polycrystalline ceria doped with several rare earth oxides were measured by AC admittance and DC four probe method. The conductions were separated into grain and grain boundary contributions using the complex admittance technique as well as grain size dependence of conductivity. The grain size dependence of polycrystalline conductivity, which can be adequately described by the so-called brick layer model, appears to give a more reliable measure of the grain conductivity compared to the complex admittance method. Polycrystalline resistivity(1/conductivity) increases linearly with the reciprocal of grain size. The intercept of resistivity vs. inverse grain size plot gives a measure of the grain resistivity and the slope gives a measure of the grain boundary resistivity. It was also noted that errors involved in the analysis of experimental data may be different between the complex admittance method and the impedance method. A greater resolution of the spectra was found in the complex admittance method, insofar as the present work is concerned, suggesting that the commonly used equivalent circuit may require re-evaluation.

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Electrical Impedance Tomography and Biomedical Applications

  • Woo, Eung-Je
    • 한국지구물리탐사학회:학술대회논문집
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    • 2007.06a
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    • pp.1-6
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    • 2007
  • Two impedance imaging systems of multi-frequency electrical impedance tomography (MFEIT) and magnetic resonance electrical impedance tomography (MREIT) are described. MFEIT utilizes boundary measurements of current-voltage data at multiple frequencies to reconstruct cross-sectional images of a complex conductivity distribution (${\sigma}+i{\omega}{\varepsilon}$) inside the human body. The inverse problem in MFEIT is ill-posed due to the nonlinearity and low sensitivity between the boundary measurement and the complex conductivity. In MFEIT, we therefore focus on time- and frequency-difference imaging with a low spatial resolution and high temporal resolution. Multi-frequency time- and frequency-difference images in the frequency range of 10 Hz to 500 kHz are presented. In MREIT, we use an MRI scanner to measure an internal distribution of induced magnetic flux density subject to an injection current. This internal information enables us to reconstruct cross-sectional images of an internal conductivity distribution with a high spatial resolution. Conductivity image of a postmortem canine brain is presented and it shows a clear contrast between gray and white matters. Clinical applications for imaging the brain, breast, thorax, abdomen, and others are briefly discussed.

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Sensitivity Analysis of Artificial Recharge in Consideration of Hydrogeologic Characteristics of Facility Agricultural Complex in Korea : Hydraulic Conductivity and Separation Distance from Injection Well to Pumping Well (국내 시설농업단지의 수리지질 특성을 고려한 인공함양 민감도 분석 : 수리전도도 및 주입정과 양수정의 이격거리)

  • Choi, Jung Chan;Kang, Dong-hwan
    • Journal of Environmental Science International
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    • v.28 no.9
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    • pp.737-749
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    • 2019
  • In this study, the sensitivity analysis of hydraulic conductivity and separation distance (distance between injection well and pumping well) was analyzed by establishing a conceptual model considering the hydrogeologic characteristics of facility agricultural complex in Korea. In the conceptual model, natural characteristics (topography and geology, precipitation, hydraulic conductivity, etc.) and artificial characteristics (separation distance from injection well to pumping well, injection rate and pumping rate, etc.) is entered, and sensitivity analysis was performed 12 scenarios using a combination of hydraulic conductivity ($10^{-1}cm/sec$, $10^{-2}cm/sec$, $10^{-3}cm/sec$, $10^{-4}cm/sec$) and separation distance (10 m, 50 m, 100 m). Groundwater drawdown at the monitoring well was increased as the hydraulic conductivity decreased and the separation distance increased. From the regression analysis of groundwater drawdown as a hydraulic conductivity at the same separation distance, it was found that the groundwater level fluctuation of artificial recharge aquifer was dominantly influenced by hydraulic conductivity. In the condition that the hydraulic conductivity of artificial recharge aquifer was $10^{-2}cm/sec$ or more, the radius of influence of groundwater level was within 20 m, but In the condition that the hydraulic conductivity is $10^{-3}cm/sec$ or less, it is confirmed that the radius of influence of groundwater increases sharply as the separation distance increases.

Electric Conductivities of LaCl3-KCl Binary Melts (용융 LaCl3-KCl 2성분계 혼합염의 전기전도도)

  • Kim, Kiho
    • Journal of the Korean institute of surface engineering
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    • v.47 no.1
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    • pp.48-52
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    • 2014
  • Electric conductivities of $LaCl_3$-KCl binary melts have been measured by the Kohlausch bridge method over the range from their liquidus temperatures to about 1280 K. The electric conductivity increased with the content of KCl for all over the composition range of binary melts. The composition dependence of the electric conductivity and molar conductivity for the binary melt showed a non-linear relation from the additivity line, and the deviation showed a maximum value at about 60 mol.% KCl. The deviation implies the existence of complex ion of $LaCl^{4-}$ in the melt. Activation energy for electric conductivity of the binary melts decreased monotonously with increasing content of KCl.

Electric Conductivities of LaC $l_3$-LiCl Binary Melts (용융 LaC $l_3$-LiCl 2성분계 혼합염의 전도도)

  • Kim Ki-Ho
    • Journal of the Korean institute of surface engineering
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    • v.37 no.5
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    • pp.301-306
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    • 2004
  • Electric Conductivities of $LaCl_3$-LiCl binary melts have been measured by the Kohlausch bridge method over the range of their liquidus temperatures to about 1200 K. The electric conductivity increases with the content of LiCl for all over the composition range of binary melts. Composition dependence of the electric conductivity and molar conductivity for the binary melt shows a non-linear relation from the additivity line, and the deviations displays a maximum value at about 60 mol % LiCl. This suggest the existence of the complex ion of$ LaCl_{4}^{-}$ in the melt. Activation energy for electric conductivity of the binary melts decrease monotonously with increasing content of LiCl.l.

Electrical Conductivity Change of Manganese oxide with Addition of Transition Metal (천이금속 첨가에 따른 이산화망간의 전기전도도 변화)

  • Kim, Bong-Seo;Lee, Dong-Yoon;Lee, Hee-Woong;Chung, Won-Sub
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2028-2030
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    • 2005
  • The electrical conductivity of manganese oxide and complex manganese oxide produced by anodic deposition method was measured. The additive transition metal is Cu, Co and Fe. The transition metals like as Cu, Co and Fe improved electrical conductivity of complex manganese oxide compared with manganese oxide. This is coincide with the results of molecular orbital calculation by DV-Xa.

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Comparison of Electrical Conductivities in Complex Perovskites and Layered Perovskite for Cathode Materials of Intermediate Temperature-operating Solid Oxide Fuel Cell (중·저온형 고체산화물 연료전지 공기극 물질로 사용되는 이중층 페로브스카이트와 컴플렉스 페로브스카이트의 전기 전도도 비교)

  • Kim, Jung Hyun
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.295-299
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    • 2014
  • Electrical conductivities of complex perovskites, layered perovskite and Sr doped layered perovskite oxides were measured and analyzed for cathode materials of Intermediate Temperature-operating Solid Oxide Fuel Cells (IT-SOFCs). The electrical conductivities of $Sm_{1-x}Sr_xCoO_{3-\delta}$ (x = 0.3 and 0.7) exhibit a metal-insulator transition (MIT) behavior as a function of temperature. However, $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$ (SSC55) shows metallic conductivity characteristics and the maximum electrical conductivity value compared to the values of $Pr_{0.5}Sr_{0.5}CoO_{3-\delta}$ (PSC55) and $Nd_{0.5}Sr_{0.5}CoO_{3-\delta}$ (NSC55). The electrical conductivity of $SmBaCo_2O_{5+\delta}$ (SBCO) exhibits a MIT at about $250^{\circ}C$. The maximum conductivity is 570 S/cm at $200^{\circ}C$ and its value is higher than 170 S/cm over the whole temperature range tested. $SmBa_{0.5}Sr_{0.5}Co_2O_{5+\delta}$ (SBSCO), 0.5 mol% Sr and Ba substituted at the layered perovskite shows a typically metallic conductivity that is very similar to the behavior of the SSC55 cathode, and the maximum and minimum electrical conductivity in the SBSCO are 1280 S/cm at $50^{\circ}C$ and 280 S/cm at $900^{\circ}C$.

Lithium Ion Conductivity in $Li_{3x}La_{(2/3-x)}TiO_3$ system ($Li_{3x}La_{(2/3-x)}TiO_3$계의 리튬 이온전도특성)

  • 정훈택;정태석;김호기
    • Journal of the Korean Ceramic Society
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    • v.33 no.3
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    • pp.293-298
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    • 1996
  • Room temperature Li+ ion conductivities of Li3xLa(2/3-x)TiO3 system with x=0.117~0.317 were measured by complex impedance method. ICP, SEM and XRD analysis were conducted to study the main factor which influence the Li+ ion conductivity. Li+ ion conductivity seems to have a close relationship with the crystal structure of primitive cell increase as the primitive cell as close to cubic.

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Conductivity Measurement of Soot at Microwave Frequency Using a Cylindrical Cavity (원통형 공진기를 이용한 마이크로파 대역에서 그을음의 도전율 측정)

  • Kim, Jae-Hee;Park, Wee-Sang
    • Proceedings of the IEEK Conference
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    • 2008.06a
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    • pp.341-342
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    • 2008
  • A conductivity of soot at microwave frequency is presented using a novel technique for complex permittivity of materials. The method overcomes limitations of conventional methods which are cavity perturbation and transmission/reflection method. Resonant frequencies and Q factors are measured and simulated for the cylindrical cavity, and they are compared to each other. Similar material property of both real material and simulation material produce similar values of resonant frequency and Q factor. The complex permittivity of material can be determined by simulating the cavity to change material property until the simulation results are nearly the same as the measurement results. Cylindrical cavity has been realized for measurement at 880 MHz, and conductivity of soot is measured. A sample was made by depositing the soot on the glass. The proposed method shows that the conductivity of soot is 11 S/m.

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Analysis of Groundwater Conductivity and Water Temperature Changes in Greenhouse Complex by Water Curtain Cultivation (수막용수 사용으로 인한 시설재배지역의 지하수 수온과 전기전도도 변화 특성 분석)

  • Baek, Mi Kyung;Kim, Sang Min
    • Journal of The Korean Society of Agricultural Engineers
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    • v.65 no.6
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    • pp.93-103
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    • 2023
  • This study aimed to analyze the impact of water curtain cultivation in the greenhouse complexes on groundwater's electric conductivity and water temperature. The greenhouse complexes are mainly situated along rivers to secure water resources for water curtain cultivation. We classified the groundwater monitoring well into the greenhouse (riverside) and field cultivation areas (plain) to compare the groundwater impact of water curtain cultivation in the greenhouse complex. The groundwater observation network in Miryang, Gyeongsangnam-do, located downstream of the Nakdong River, was selected for the study area. As a result of analyzing the electric conductivity and water temperature, the following differences were found in the observed characteristics by region. 1) The electric conductivity and water temperature of the riverside area, where the permeability is high and close to rivers, showed a constant pattern of annual changes due to the influence of river flow and precipitation. 2) The flat land in general agricultural areas showed general characteristics of bedrock observation in the case of water temperature. Still, it seemed more affected by the surrounding well's water use and water quality. The electric conductivity did not show any particular trend and was influenced by the surrounding environment according to the location of each point.