• Macromolecular Research
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• v.16 no.6
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• pp.492-502
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• 2008

This study examined the adsorption of a synthetic cutting fluid and cutting fluid effluent on chitosan and SDS-modified chitosan, Chitosan and SDS-modified chitosan were prepared in form of beads and fibers. A series of batch experiments were carried out as a function of the initial concentration of cutting fluid, contact time and pH of the fluid. The contact angle study suggested that the SDS-modified chitosan was more hydrophobic than chitosan. The Zeta potential study showed that chitosan, SDS-modified chitosan and synthetic cutting fluid had a point of zero charge (PZC) at pH 7.8, 9 and 3.2, respectively. SDS-modified chitosan has a greater adsorption capacity than chitosan. The experimental results show that adsorption capacity of the cutting fluid on 1.0 g of SDS-modified chitosan at pH 3 and for a contact time of 120 min was approximately 2,500 g/kg. The adsorption capacity of chitosan and SDS-modified chitosan increased with decreasing pH. The Langmuir, Freundlich, and Brunauer Emmett and Teller (BET) adsorption models were used to explain the adsorption isotherm. The Langmuir isotherm fitted well with the experimental data of chitosan while the BET isotherm fitted well with the SDS-modified chitosan data. Pseudo first- and second-order kinetic models and intraparticle diffusion model were used to examine the kinetic data. The experimental data was fitted well to a pseudo second-order kinetic model. The significant uptake of cutting fluid on chitosan and SDS-modified chitosan were demonstrated by FT-IR spectroscopy, SEM and heat of combustion.

• Journal of Welding and Joining
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• v.31 no.6
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• pp.50-57
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• 2013

Characterization of microstructures and cryogenic mechanical properties of electro beam (EB) welds between cast and forged Inconel 718 superalloys has been investigated. Optimal EBW condition was found in the beam current range of 36~39 mA with the constant travel speed of 12 mm/s and arc voltage of 120 kV for 10 mm-thick specimens. Electron beam current lower than 25 mA caused to occur the liquation microfissuring in cast-side heat affected zone (HAZ) of EB welds. The HAZ liquation microfissure was found on the liquated grain boundaries with resolidified ${\gamma}/Laves$ and ${\gamma}/NbC$ eutectic constituents. EBW produced welds showing a fine dendritic structure with relatively discrete Laves phase due to fast cooling rate. After post weld aging treatment, blocky Laves phase and formation of ${\gamma}^{\prime}+{\gamma}^{{\prime}{\prime}}$ strengtheners were observed. Presence of primary strengthener and coarse Laves particles in PWHT weld may cause to reduce micro-plastic zone ahead of a crack, leading to a significant decrease in Charpy impact toughness at $-196^{\circ}C$. Fracture initiation and propagation induced by Charpy impact testing were discussed in terms of the dislocation structures ahead of crack arisen from the fractured Laves phase.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.20 no.4
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• pp.1123-1132
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• 1996

It has been reported that high temperature structural components represent the phenomenon of material degradation according to a long term service under high temperature and pressure. Especially, fossile power plant components using the fossil fuel and heavy oil are affected by dewpoint corrosion of $H_2SO_4$produced during a combustion. Therefore, the service materials subjected to high temperature and pressure may occur the stress corrosion cracking. The object of this paper is to investigate SCC susceptibility according to the material degradation of the high temperature structural materials in dewpoint corrosive environment-$H_2SO_4$.The obtained results are summarized as follows : 1) In case of secondary superheater tube, the fractograph of dimple is observed at the concentration of $H_2SO_4$-5%. When the concentration of $H_2SO_4$ is above 10%, the fracture mode is shifted from a transgranular fracture to an quasi-intergranular fracture according to the increment of concentration. 2) In the relationship between [$\Delta$DBTT]$_sp$ and SCC susceptibility, it is confirmed that the greater material degradation degree is, the higher SCC susceptibility is. In addition, it can be known that SP test is useful test method to evaluate SCC susceptibility for high temperature structural components. 3) When [$\Delta$DBTT]$_sp$ is above 17$17^{\circ}C$ the SCC fracture behavior is definitely observed with SCC susceptibility of above 0.4.

• Journal of Korean Society of Forest Science
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• v.78 no.4
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• pp.396-400
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• 1989

The oxygen index test was carried out to obtain the relative flammability of wood-based materials (plywood, MDF, particleboard) and their oxygen indices. The oxygen index is the minimum concentration of oxygen, expressed as volume percent, in a mixture of oxygen and nitrogen that will just support flaming combustion of a material under the specified laboratory conditions. In this study the oxygen indices were calculated by using the Dixon and Massey's Up and Down method("N" Large method). The obtained results were as follows : 1. The oxygen indices calculated with Up and Down method were 27.9% for plywood, 26.9% for MDF, and 26.2% for particleboard, indicative of plywood being more difficult to burn than MDF and particleboard Lender the same surrounding conditions. 2. The oxygen indices were not affected by the total gas flow rate.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2012.05a
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• pp.457-460
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• 2012

Design and fabrication of a sub-scale thrust chamber for verification of 7 tonf-class thrust chamber injectors were described in this paper. The 7 tonf-class thrust chamber consists of mixing head with 90 coaxial swirl injectors and regeneratively combustion chamber cooled by kerosene. The coaxial swirl injectors with different pressure drop and recess number were designed for 7 tonf full-scale thrust chamber. By applying the designed injectors to the sub-scale thrust chamber before applying them to the full-scale thrust chamber, the injector performance and functioning were verified. The sub-scale thrust chamber consists of 19 injectors, has chamber pressure of 70 bar, total propellant mass flow rate of 4.3 kg/s, mixture ratio(O/F) of 2.45.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.1
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• pp.28-35
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• 2018

In order to analyze the flammability limit and structure of the gaseous methane-gaseous oxygen diffusion flame formed through a shear coaxial injector, combustion experiments were carried out according to the condition of injector recess and propellant mass-flow rate. As a result, it was confirmed that stable anchored flame was observed even at the high oxygen Reynolds number as the propellant momentum flux ratio increased, and that the recess had no significant influence on the flame shape and flammability limit. The anchored flame visualized through a chemiluminescence showed the maximum OH radical emission intensity at a specific position, irrespective of the propellant injection condition, and the radical intensity was greatly reduced by the injector recess.

• Transactions of Materials Processing
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• v.30 no.6
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• pp.291-300
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• 2021

Currently, starting with electric vehicles, the application of ultra-high-strength steel sheets and light metals has expanded to improve mileage by reducing vehicle weight. At a time when internal combustion engine vehicles are rapidly changing to electric vehicles, the application of ultra-high-strength steel is expanding to satisfy both weight reductions and the performance safety of the chassis parts. There is an urgent need to improve the quality of parts without defects. It is particularly difficult to estimate the part formability through the finite element method (FEM) in the burring operation, so product design has been based on the hole expansion ratio (HER) and experience. In this study, design of experiment (DOE), analysis of variance (ANOVA), and regression analysis were combined to optimize the formability by adjusting the process variables affecting the burring formability of ultra-high-strength steel parts. The optimal variables were derived by analyzing the influence of variables and the correlation between the variables through FE analysis. Finally, the optimized process parameters were verified by comparing experiment with simulation. As for the main influence of each process variable, the initial hole diameter of the piercing process and the shape height of the preforming process had the greatest effects on burring formability, while the effect of a lower round of punching in the burring process was the least. Moreover, as the diameter of the initial hole increased, the thickness reduction rate in the burring part decreased, and the final burring height increased as the shape height during preforming increased.

• Journal of Climate Change Research
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• v.2 no.3
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• pp.143-159
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• 2011

Projects applying the CDM methodology AM0035 of the $SF_6$ Emission Reductions in Electrical Grids should provide direct monitoring of all the key parameters that are related to estimation of baseline and project emissions including detailed explanations of key operating conditions and procedures, and an explanation addressing uncertainty as the result of EB meeting 41. Through this study, recovery ratio during maintenance, purity of $SF_6$ before and after disposal, replacing, loss rate of $SF_6$ before and after reclamation, leakage emission from electricity consumption and fossil fuel combustion, considered conservatively the key parameter of various monitoring. Consequently, confirmed the reduction in the amount of reduction due to the baseline emission decrease, project emission increase.

• Journal of the Korean Society of Propulsion Engineers
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• v.23 no.1
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• pp.79-92
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• 2019

Titanium hydride potassium perchlorate (THPP) is one of the commonly utilized pyrotechnic materials in aerospace industries. The current study elucidates the effects of hygrothermal aging on the combustion of THPP experimentally. First, applying the Differential Scanning Calorimetry (DSC) and isocoversional method, both the delay of reaction start and decrease in maximum reaction rate were observed. The kinetics parameters tended to fluctuate depending the thermal reaction or intermediate product formation of THPP. Also, the oxidants decomposition and fuel oxidation phenomenon were discovered by X-ray photoelectron spectroscopy (XPS). The experimental heat from DSC data were verified as reasonable by comparing with the theoretical heat obtained utilizing both THPP formulation from XPS and NASA Chemical Equilibrium with Applications (CEA). Both data had identical variation trend, which expecially had the highest heat value at 10 weeks aged sample.

• Journal of The Korean Society of Agricultural Engineers
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• v.64 no.5
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• pp.9-16
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• 2022

Syngas, also known as synthesis gas, synthetic gas, or producer gas, is a combustible gas mixture generated when organic material (biomass) is heated in a gasifier with a limited airflow at a high temperature and elevated pressure. The present research was aimed at modifying the existing LPG engine generator for fully operated syngas. During this study, the designed gasifier-powered woodchip biomass was used for syngas production to generate power. A 6.0 kW LPG engine generator was modified and tested for operation on syngas. In the experiments, syngas and LPG fuels were tested as test fuels. For syngas production, 3 kg of dry woodchips were fed and burnt into the designed downdraft gasifier. The gasifier was connected to a blower coupled with a slider to help the air supply and control the ignition. The convection cooling system was connected to the syngas flow pipe for cooling the hot produce gas and filtering the impurities. For engine modification, a customized T-shaped flexible air/fuel mixture control device was designed for adjusting the correct stoichiometric air-fuel ratio ranging between 1:1.1 and 1.3 to match the combustion needs of the engine. The composition of produced syngas was analyzed using a gas analyzer and its composition was; 13~15 %, 10.2~13 %, 4.1~4.5 %, and 11.9~14.6 % for CO, H₂, CH₄, and CO₂ respectively with a heating value range of 4.12~5.01 MJ/Nm³. The maximum peak power output generated from syngas and LPG was recorded using a clamp-on power meter and found to be 3,689 watts and 5,001 watts, respectively. The results found from the experiment show that the LPG engine generator operated on syngas can be adopted with a de-ration rate of 73.78 % compared to its regular operating fuel.