• Atmosphere
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• v.25 no.1
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• pp.117-127
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• 2015

The presences of clouds significantly influence the accuracy of ozone retrievals from satellite measurements. This study focuses on the influence of clouds on Ozone Monitoring instrument (OMI) ozone profile retrieval based on an optimal estimation. There are two operational OMI cloud products; OMCLDO2, based on absorption in $O_2-O_2$ at 477 nm, and OMCLDRR, based on filling in Fraunhofer lines by rotational Raman scattering (RRS) at 350 nm. Firstly, we characterize differences between $O_2-O_2$ and RRS effective cloud pressures using MODIS cloud optical thickness (COT), and then compare ozone profile retrievals with different cloud input data. $O_2-O_2$ cloud pressures are significantly smaller than RRS by ~200 hPa in thin clouds, which corresponds to either low COT or cloud fraction (CF). On the other hand, the effect of Optical centroid pressure (OCP) on ozone retrievals becomes significant at high CF. Tropospheric ozone retrievals could differ by up to ${\pm}10$ DU with the different cloud inputs. The layer column ozone below 300 hPa shows the cloud-induced ozone retrieval error of more than 20%. Finally, OMI total ozone is validated with respect to Brewer ground-based total ozone. A better agreement is observed when $O_2-O_2$ cloud data are used in OMI ozone profile retrieval algorithm. This is distinctly observed at low OCP and high CF.

• Steel and Composite Structures
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• v.36 no.4
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• pp.383-398
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• 2020

This paper investigates the progressive collapse behavior of 3D steel-framed gravity buildings under fires with a cooling phase. The effect of fire protections and bracing systems on whether, how, and when a gravity building collapses is studied. It is found that whether a building collapses or not depends on the duration of the heating phase, and it may withstand a "short-hot" fire, but collapses under a mild fire or a "long-cool" fire. The collapse time can be conservatively determined by the time when the temperature of steel columns reaches a critical temperature of 550 ℃. It is also found that the application of a higher level of fire protection may prevent the collapse of a building, but may also lead to its collapse in the cooling phase due to the delayed temperature increment in the heated members. The tensile membrane action in a heated slab can be resisted by a tensile ring around its perimeter or by tensile yielding lines extended to the edge of the frame. It is recommended for practical design that hat bracing systems should be arranged on the whole top floor, and a combination of perimeter and internal vertical bracing systems be used to mitigate the fire-induced collapse of gravity buildings. It is also suggested that beam-to-column connections should be designed to resist high tensile forces (up to yielding force) during the cooling phase of a fire.

• Steel and Composite Structures
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• v.36 no.4
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• pp.447-462
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• 2020

The paper aims to investigate the mechanical mechanism and seismic effect of stiffeners in blind bolt endplate connection to CFST column. A precise 3D finite element model with considering the cyclic properties of concrete and steel materials was established, and the efficiency was validated through monotonic and cyclic test data. The deforming pattern and the seismic performance of the unstiffened and stiffened blind bolt endplate connections were investigated. Then a parametric analysis was conducted to analyze the contribution of stiffeners and the joint working behaviors with endplate under cyclic load. The joint stiffness classifications were compared and a supplement stiffness classification method was proposed, and the energy dissipation ability of different class connections were compared and discussed. Results indicated that the main deformation pattern of unstiffened blind bolt endplate connections was the local bending of end plate. The vertical stiffeners can effectively alleviate the local bending deformation of end plate. And influence of stiffeners in thin endplate and thick endplate was different. Based on the stiffness of external diaphragm welded connection, a more detailed rigidity classification was proposed which included the pin, semi-rigid, quasi-rigid and rigid connection. Beam was the main energy dissipation source for rigid connection. For the semi-rigid and quasi-rigid connection, the extended endplate, stiffeners and steel beam would all participate in the energy dissipation.

• Journal of the Korean GEO-environmental Society
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• v.17 no.2
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• pp.31-39
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• 2016

Vertical drain has usually been used to accelerate the consolidation of soft clay deposits with high moisture content. Busan thick clay deposits are subjected to artesian pressure from an aquifer in sand and gravel layers. However, effect of artesian pressure existing in drainage-installed soft ground on consolidation behaviors is not well known. This paper investigates the consolidation behavior of drainage-installed soft ground at the Nakdong river estuary with artesian pressure and without artesian pressure. A series of one-dimensional large size column test was carried out to find out the consolidation characteristics of clay. Test results indicated that total settlement of clay with artesian pressure was higher than that without artesian pressure because effective stress decreased due to upward flow. Dissipation rate of excess pore water pressure delayed and excess pore water pressure did not fully dissipate in clay layer with artesian pressure. Undrained shear strength of clay ground with artesian pressure was lower than that without artesian pressure.

• Journal of the Korean Geotechnical Society
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• v.15 no.1
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• pp.175-183
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• 1999

Recently, problems related to vibrations of decomposed granite soils have acquired increasing attention in Korea because those soils cover approximately one third of the country. Both resonant column and cyclic triaxial test were performed to investigate deformation characteristics of unsaturated and cement-mixed decomposed granite soils in Suwon region. The important soil parameters in this respect are the shear moduli, dynamic moduli of elasticity and damping ratios. The dynamic parameters are influenced by variables such as strain amplitude, ratio of loading cycles, and degree of saturations, etc. Test results and data have shown that the optimum degree of saturation to the maximum shear modulus due to a capillary menisci effect was about 17~18 % at low strain amplitude and 10~15 % at intermediate strain amplitude. This paper suggests the range of threshold strain and mean shear modulus of decomposed granite soils in Suwon region. It also proposed the empirical relationship between the dynamic parameters for cement-mixed and non-mixed decomposed granite soils.

• KSBB Journal
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• v.25 no.3
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• pp.205-214
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• 2010

Many successive liquid-liquid extractions occur enabling purification of the crude material to occur. In high performance counter-current chromatography (HPCCC), crude material is partitioned between two immiscible layers of solvent phases. The stationary phase (SP) is retained by hydrodynamic force field effect and the mobile phase (MP) is pumped through the column. Purification occurs because of the different solubility of the components in the liquid mobile and stationary phases. There are many key benefits of liquid stationary phases such as high mass and volume injection loadings, total sample recovery, and easy scale-up. Many researchers showed that predictable scale-up from simple test is feasible with knowledge of the stationary phase retention for the planned process scale run. In this review we review the recent advances in HPCCC research and also describe the key applications such as natural products and synthetics (small or large molecules).

• Analytical Science and Technology
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• v.12 no.2
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• pp.99-104
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• 1999

A stepwise gradient elution with two wavelengths detection was performed for the separation and determination of some anions in saline water. The eight anions such as iodate, bromate, nitrite, bromide, nitrate, chromate, iodide and thiocyanate were successfully separated using AS-7 column and sodium chloride/sodium phosphate buffer solution as an eluant within 40 min. The separation behaviors of anions were studied at various sodium chloride concentrations. The peak shapes of anions of bromate, nitrite, bromide and nitrate gradually broadened as the concentration of sodium chloride increased until 1.0 M in the sample solutions. However, no effect was observed in the peak shapes of chromate, iodide and thiocynate. A good linearity was obtained at the range of ppm(mg/L). The detection limit was proved to be $10-720{\mu}g/L$ for the eight anions with $50{\mu}L$ injection volume. This method was applied to the determination of $Br^-$, ${NO_3}^-$ and $I^-$ in sea water.

• Analytical Science and Technology
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• v.6 no.3
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• pp.261-265
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• 1993

The ion exchange capacity of DBPDA ion exchanger, {(4,5):(13,14)-dibenzo-6, 9, 12-trioxa-3, 15, 21-triazabicyclo [15.3.1] heneicosa-1(21), 17, 19-triene-2, 16-dione : DBPDA ion exchanger} was 4.2meq/g. The distribution coefficients of alkali and alkaline earth metal ions in the various concentrations of hydrochloric acid were determined using DBPDA ion exchanger. Also alkali and alkaline earth metal ions were separated using DBPDA ion exchanger. From these results the effect of pH of solution and ionic radii of the metal ions on the distribution coefficients of alkali and alkaline earth metal ions were discussed.

• Korean Journal of Food Science and Technology
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• v.29 no.2
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• pp.369-375
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• 1997

We have isolated an anticoagulant polysaccharide from the alkali extracts of Coriolus versicolor. The anticoagulant polysaccharide was purified through a gradual ethanol precipitation and three concecutive chromatography of DEAE-Toyopearl 650C, Sephadex G-100, and Sepharose CL-6B by measuring activated partial thromboplastin time (aPTT). The anticoagulant polysaccharide showed the homogenecity on HPLC using a gel permeation column and had about $7.2{\times}10^{5}$ molecular weight. The polysaccharide consisted of fucose, glucose, and galactose in a molar ratio of 1.0:0.2:0.2:0.1, and also compromised 19.32% of sulfate at its constituent sugars. The polysaccharide showed the two typical bands of C-O-S $(823\;cm^{-1})$ and S=O $(1257\;cm^{-1})$ in the IR spectroscopy. The sulfated polysaccharide (CV-40-Va-1) inhibited the blood coagulation via the intrinsic pathway like heparin whose activity produced a concentration dependent effect in aPTT and thrombin time (TT).

• Journal of Pharmacopuncture
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• v.22 no.4
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• pp.239-247
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• 2019

Objectives: Allium jesdianum (Aj) is a medicinal plant that has highlighted pharmacological features. In this study, the effects of Aj extract were examined on acetaminophen (APAP)-induced hepatic failure in rats. Methods: Methanolic fraction of hydro-alcoholic extract of Aj was obtained by silica gel column chromatography method. Animals were randomly divided into four groups each containing six rats and treated by gavage as follows: the first and second groups received normal saline, the third and fourth groups were received with 50 and 100 mg/kg of Aj extract, respectively. After two consecutive weeks, the groups 2-4 were given a single dose of APAP (2 g/kg). After 48 hours, blood and liver samples were collected for biochemical and histological examinations. Results: The findings of the study demonstrated that APAP caused a significant increase in ALT (P < 0.001), AST (P < 0.001), LDH (P < 0.001), ALP (P < 0.001) serum levels, hepatic lipid peroxidation (LPO; P < 0.001) and nitric oxide (NO; P < 0.001). In this regard, APAP led to the depletion of the total antioxidant capacity (TAC; P < 0.001), glutathione and total thiol groups (TTGs; P < 0.001), and structural change in the liver. In the Aj extract groups, a considerable improvement was found in the hepatic function alongside the histopathologic changes. Conclusion: This investigation indicated that the influential effects of Aj extract in APAP-induced hepatic failure might depend on its effect on improving oxidant/antioxidant balance in hepatic tissue.