• Title/Summary/Keyword: colloid dispersion

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Evaluation of Cu nano-colloid prepared by electrical wire explosion in liquid phase (액중 전기선폭발법으로 제조된 구리 나노콜로이드의 특성 평가)

  • Yoon, Jae-Cheol;Yang, Sang Sun;Yu, Ji-Hun
    • Particle and aerosol research
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    • v.6 no.1
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    • pp.37-46
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    • 2010
  • Cu nano-colloid was prepared by wire electric explosion process under de-mineralized water and anhydrous ethanol. To control the properties of Cu nano-colloid, experimental conditions such as diameter of Cu wire and applied voltage were changed. The optimal Cu nano-colloid was prepared when the 0.1mm diameter of Cu wire with the applied voltage of 2000 V was used. The shape of Cu particles in colloid was spherical and the XRD result revealed that the phase of Cu particles was cubic phase. About 20nm Cu nanoparticles with high crystallinity were successfully prepared using wire explosion process under anhydrous ethanol and they showed more than 100 hours dispersion stability.

Re-dispersion Characteristics of Waster-Based Magnetic Fluids Using Oleic Acid and Saturated Fatty Acid $(C_9-C_11)$ System - Preparation and Redispersion Characteristics of Water-Based Magnetic Fluid With the Synthesized Magnetite(3) (오레인산-포화지방산$(C_9-C_11)$으로 제조한 수상자성유체의 재분산성 -합성 마그네타이트에 의한 수상자성유체의 제조 및 재분산 특성에 관한 연구(3))

  • Kim, Mahn;Oh, Jae-Hyun
    • Journal of the Korean Ceramic Society
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    • v.31 no.7
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    • pp.723-730
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    • 1994
  • Stable aqueous dispersion of magnetite colloid was obtained by allowing a fatty acid, such as nonanoic acid, decanoic acid and undecanoic acid, dissociated with NH4OH solution to adsorb on the monomolecular adsorption of oleate. To obtain a stable dispersion, added amounts of sodium oleate and nonanoic acid for magnetite 20g were more than 2.63$\times$10-2 mol and 0.04 mol respectively. In this colloid, good dispersions of magnetite which is sterically stabilized in aqueous system were achieved about pH 7.7. Water-based magnetic fluids using in this study were able to redisperse to water-based magnetic fluids by adding NH4OH solution to dried water-based magnetic fluid powders. Changing a magnetic fluid carrier such as kerosene was also attemped by adding kerosene to dried water-based magnetic fluid powders. In this study, we can obtain a kerosene-based magnetic fluids using drying process.

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Development of the Numerical Model for Complex Transport of Radionuclide and Colloid in the Single Fractured Rock (단일 균열암반에서 핵종/콜로이드 복합이동에 대한 수치모델 개발)

  • Lee, Sanghwa;Kim, Jung-Woo;Jeong, Jongtae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.4
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    • pp.237-246
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    • 2012
  • In this study, numerical model for transport of radionuclide and colloid was developed. In order to solve reaction-migration governing equation for colloid and radionuclide, Strang-splitting Sequential Non-Iterative (SNI), which is one of Operator Splitting Method, was used for numerical method and this was coded by MATLAB. From the verification by comparing the simulation results with analytical solution considering only solute transport and rock diffusion, the Pearson's correlation coefficient was greater than 0.99 which demonstrates the accuracy of the model.

Preparation and Dispersion Characteristics of Oil-based Magnetic Fluids with Synthesized Magnetite (합성마그네타이트를 이용한 유상자성유체의 제조 및 분산특성)

  • Cho, Myeong-Ho;Kim, Mahn;Min, Dong-Joon;Oh, Jae-Hyun
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.901-908
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    • 1996
  • The oil-based magnetic fluids were prepared with synthesized ultrafine magnette by allowing surfactactants such as sodium oleate and aliquat 336 to adsorb on the surface of magnetite particles. The dispersion ratio of oil-based magnetic fluids was higher than 90% when the amount of sodium oleate and aliqua 336 were more than 2.63$\times$10-2 mol and 6.56$\times$10-3 mol for 20g of magnetite respectively. The dispersion ratio of oil-based magnetic fluids with the amount of secondary surfactant addition was higher than 90% when oil-based magnetic fluids were prepared with aliquat 336 of cationic type. However oil-based magnetic fluids prepared with surfactants of anionic and nonionic type showed lower dispersion than whose with cationic surfac-tants.

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Preparation of Kerosine-Based Magnetic Ferrofluid by Steric Stabilizaton (Steric Stabilization에 의한 석유분산매 자성유체의 제조)

  • 신학기;장현명;김태옥
    • Journal of the Korean Ceramic Society
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    • v.27 no.5
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    • pp.684-692
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    • 1990
  • Ultrafine magnetite powder for the ferromagnetic fluid was prepared by an addition of alkaline solution to the solution containing Fe2+ and Fe3+ ions at 6$0^{\circ}C$. The optimum condition of the magnetite synthesis was delineated by examining such various physico-chemical properties as Fe2+/Fe+3 ratio in the powder, phase characteristics, MHC and $\sigma$max. A new scheme for the steric stabilization of colloidal dispersion was proposed using the concept of the buffer group action for the increased interfacial density of the stabilizing moieties at colloid particle/dispersion medium interface. The proposed concept was successfully applied to the preparation of the kinetically stable kerosinebased ferrofluid using Tween and Span as dispersants. In the dispersion of magnetite particles in a kerosine, Tween(polyoxyethylene sorbitan oleate) acts as a primary stabilizer which provides an anchor group, whereas Span(sorbitan oleate) can be classified as a secondary stabilizer which adsorbs on the surface of magnetite particle through the action of the buffer group. Dispersion studies using various quantities of Tween and Span supported the concept of the buffer group action for increased dispersion characteristics of the kerosine based ferromagnetic fluid.

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EVALUATION 01 OIL DISPERSION AGENT BY ASSESSMENT 01 COLOR STRENGTH 01 ORGANIC PIGMENT

  • H., Young-Chan;R., Seo-Joon;L., Dong-Wook;H., Soon-Taek
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.24 no.3
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    • pp.73-80
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    • 1998
  • This Study was performed to get the suitable oil dispersion agent by assessment of color strength of organic pigment in non-aqueous systems. Organic pigment is used as a color expression material with other body pigments in the make-up products. But occasionally aggregation or agglomeration occurs for the lack of affinity with medium, This function is the cause of disturbing homogeneous dispersion, and then bring about an instability of products. Our study, research of dispersion mechanism between the pigment and oil phase, has been executed to solve this problem, and find a oil dispersion agent having optimum dispersion condition. Generally dispersion is related to between the solid-liquid mutual properties and electrical phenomena associated with solid-liquid interface. This factor is determined to input energy, milling time, optical properties, particle size, rheological properties, etc. Ideal dispersion state is told that coloring primary solid particle is homogeneously dispersed in medium. Good dispersed colorants are strongly and clearly appeared. We are already known that the particle size of organic pigment, chemical properties and viscosity of medium, refractive index. Consequently We determine the affinity of medium and organic pigment by measuring of color strength in the same mechanical condition. UV-VISIBLE RECORDING SPECTRO PHOTOMETER is used for measuring apparatus. We can decided the dispersion level of oil dispersion agent by measuring absorbance of color strength in the visible range that diluted medium for colloid colorant particles.

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Thixotropic Equation and Rheological Parameters on Non-Newtonian Flow Mechanism (비 뉴톤 유동 메카니즘에서 틱소트로피 식과 유변 파라메타)

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.386-393
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    • 2015
  • The rheological properties of complex materials such as colloid dispersion show complicated non-Newtonian flow phenomena when they are subjected to shear flow. These flow properties are controlled by the characteristics of flow units and the interactions among the flow segments. The rheological parameters of relaxation time $({\beta}_2)_0$, structure factor $C_2$ and shear modulus $X_2/{\alpha}_2$ for various thixotropic flow curves was obtained by applying thixotropic equation to flow curves. The variations of rheological parameters are directly related to non-Newtonian flows, viscosities and activation energies of flow segments.

Chemical Characteristics and Water Dispersible Colloid Content of Jeju Citrus Orchard Soils (제주도 감귤원 토양의 화학적 특성과 물 분산성 콜로이드 함량)

  • Oh, Sang-Sil;Chung, Jong-Bae;Hyun, Hae-Nam
    • Korean Journal of Environmental Agriculture
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    • v.21 no.2
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    • pp.130-135
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    • 2002
  • Water-dispersible colloids are suspected to facilitate transport of contaminants to groundwater. This study evaluated some soil chemical properties in relation to the stability of colloids in soils of Jeju citrus orchards. Thirty surface soil samples were collected, and pH, organic matter content oxalate-extractable Al and Fe contents, and water-dispersible colloid content were measured. In soils of higher pH, water-dispersible colloid contents were higher. The stability of colloids was found to be significantly promoted at pH above 5$\sim$6. Since organic matter can act as a flocculant organic matter content significantly enhanced the colloid stability. In soils of less than 5% organic C, water-dispersible colloid content was expected to be significantly higher. In soils of higher oxalate-extractable Al and Fe contents, colloids remaining in suspension were lower. This indicated that amorphous oxides and hydroxides play important stabilizing roles in soil structure and can stabilize soil clay against dispersion. Therefore in soils of higher pH, lower organic matter, and lower amorphous clay minerals, the stability of water-dispersible colloids and the potential of colloid-mediated transport of organic chemicals to groundwater could be higher.

Fabrication of Multi-Layered Graphenes/P(S-co-BA) Nanocomposite via Sudden Heating Heterocoagulation Process

  • Choi, JinKyu;Lee, Eun-Kyoung;Shim, Sang Eun
    • Elastomers and Composites
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    • v.52 no.4
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    • pp.272-279
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    • 2017
  • The heterocoagulation of latex is a simple and useful method to fabricate various polymer nanocomposites in which a precise control of the colloid stability is essential. In this work, a multi-layered graphenes (MLGs)/poly(styrene-co-butyl acrylate) (P(S-co-BA)) nanocomposite having an excellent dispersion of MLGs was prepared via the sudden heating heterocoagulation process. The P(S-co-BA) component was obtained by emulsion polymerization. This process can effectively shorten the process and particles growth steps. The colloid stability of these dispersions was controlled by factors such as ionic charge, temperature, and reaction times. The influence of these factors on heterocoagulation was evaluated and the properties of the nanocomposites were investigated. The conductivity of the MLGs/P(S-co-BA) nanocomposites increased from -11.53 to -5.70 S/cm for an increase in MLG content from 0.01 to 5 wt%. Moreover, percolation threshold was observed in the case of 0.01 wt% MLGs.