• Title/Summary/Keyword: colloid

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Experimental Study on Uranium Sorption onto Silica Colloids: Effects of Geochemical Parameters

  • Baik, Min-Hoon;Hahn, Pil-Soo
    • Nuclear Engineering and Technology
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    • v.33 no.3
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    • pp.261-269
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    • 2001
  • In this study, sorption experiments of uranium onto silica colloids were carried out and the effects of important geochemical parameters such as pH, ionic strength, carbonate concentration, colloid concentration, and total concentration of uranium were investigated. The sorption coefficients of uranium for silica colloids named as pseudo-colloid formation constants were about 10$^4$~ 10$^{5}$ mL/g depending on the experimental conditions. The effects of the geochemical parameters were found to be important in the sorption of uranium onto silica colloids. A Langmuir type sorption isotherm of uranium between silica colloids and the solution phase was also presented. The sorption mechanisms were explained by analyzing the effects of the geochemical parameters.

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$^{99m}Tc-Tin$ Colloid Uptake Ratio of Femoral Head in Healthy Korean (정상 한국인 대퇴골두의 $^{99m}Tc-Tin$ Colloid 섭취율)

  • Zhi, Won-Hee;Sohn, Hyung-Sun;Kim, Choon-Yul;Bahk, Yong-Whee
    • The Korean Journal of Nuclear Medicine
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    • v.23 no.2
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    • pp.215-218
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    • 1989
  • Tc-99m-tin colloid distribution in the hip is studied in 76 patients with no hepatic and hip disorder, because knowledge of normal uptake pattern in the hip is important in evaluation of femoral head vasculature after a fracture. The uptake in femoral head is decreased or disappeared with increasing age due to conversion of red marrow to white marrow.

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Analysis of Colloid Thrusters for Nano-satellite Propulsion (나노인공위성 추진용 콜로이드 추력기 해석)

  • Park, Kun-Joong;Kim, Ho-Young;Song, Seung-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.175-178
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    • 2007
  • The mode transition from cone-jet to dripping in colloid thruster operation has been analytically investigated. The transition has been predicted by the dynamic behavior of a liquid drop at the tip of the cone-jet. Conservation laws are applied to determine the upward motion of the drop, and an instability model of electrified jets is used to determine the jet breakup. Finally, for the first time, the analysis enables prediction of the transition in terms of the Weber number and electric Bond number. The predictions are in good agreement with experimental data.

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Study of Several Silica Properties Influence on Sapphire CMP

  • Wang, Haibo;Zhang, Zhongxiang;Lu, Shibin
    • Journal of Electrical Engineering and Technology
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    • v.13 no.2
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    • pp.886-891
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    • 2018
  • Colloid silica using as abrasive for polishing sapphire has been extensively studied, which mechanism has also been deeply discussed. However, by the requirement of application enlargement and cost reduction, some new problems appear such as silica service life time, particle diameter mixing, etc. In this paper, several influences of colloid silica usage on sapphire CMP are examined. Results show particle diameter and concentration, pH value, service life time, particle diameter mixing heavily influence removal rate. Further analysis discloses there are two main effect aspects which are quantity of hydroxyl group, contact area for abrasive density stacking between abrasive and sapphire. Based on the discussions, a dynamic process of sapphire polishing is proposed.

Modelling and Measurements of Normal and Lateral Stiffness for Atomic Force Microscopy

  • Choi, Jinnil
    • Applied Science and Convergence Technology
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    • v.23 no.5
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    • pp.240-247
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    • 2014
  • Modelling and measurements of normal and lateral stiffness for atomic force microscopy (AFM) are presented in this work. Important issues, such as element discretisation, stiffness calibration, and deflection angle are explored using the finite element (FE) model. Elements with various dimension ratios are investigated and comparisons with several mathematical models are reported to verify the accuracy of the model. Investigation of the deflection angle of a cantilever is also shown. Moreover, AFM force measurement experiments with conical and colloid probe tips are demonstrated. The relationships between force and displacement, required for stiffness measurement, in normal and lateral directions are acquired for the conical tip and the limitations of the colloid probe tip are highlighted.

Performance Evaluation of Substitution Radiopharmaceutical according to Restriction of the Radiocolloids in Lymphoscintigraphy (Lymphoscintigraphy에 이용되는 방사성의약품의 사용제한으로 인한 대체 방사성의약품의 성능평가)

  • Seo, Young-Deok;Jeong, Jae-Hun;Moon, Jong-Woon;Yun, Sang-Hyeok;Kim, Yeong-Seok;Kang, Se-Hun;Won, Woo-Jae;Kim, Seok-Ki
    • The Korean Journal of Nuclear Medicine Technology
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    • v.13 no.1
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    • pp.25-29
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    • 2009
  • Purpose: Several radioactive agents were used for lymphoscintigraphy in breast cancer. But recently, due to the change of local radiopharmaceutical licensing policy and discontinuation of supplies from manufacturer, we could not use many radiocolloids such as $^{99m}Tc$-Antimony Trisulfide Colloid, $^{99m}Tc$-Tin Colloid, $^{99m}Tc$-Human Serum Albumin. So it is necessary to use the substitution radiopharmaceutical. Therefore, this study aims to evaluate the performance of substitution radiopharmaceutical ($^{99m}Tc$-Phytate) including the existing radiocolloids and to set up of the appropriate protocol in lymphoscintigraphy. Materials and Methods: For each radiocolloids ($^{99m}Tc$-Antimony Trisulfide Colloid (ASC), $^{99m}Tc$-Tin Colloid (TC), $^{99m}Tc$-Human Serum Albumin (HSA), $^{99m}Tc$-Phytate) were performed the particle size by Zeta Sizer (Nano-ZS) and we compared the radiolabeling time, procedure and acquisition time for each of the radiocolloids (total 200 patients). For the last time, we made an analysis of image for each of the radiocolloids with our previous report (SJ Jang et al, Korean Nucl Med Mol imaging Vol.41, No.6, Dec 2007). Results: The particle size of each radiocolloids showed A.S.C (50 nm), T.C (310 nm), H.S.A (10.8 nm), $^{99m}Tc$-Phytate (499 nm). The labeling and acquisition time for each of the radiocolloids showed no substantial difference. But there is difference of the labeling time for the A.S.C. because the ASC procedure need to boiling process. There were no significant differences among those radiocolloids (p>0.005) in the identification rate (IR), false negative rate (FNR), and negative predictive value (NPV). Conclusions: $^{99m}Tc$-labeled radiocolloids showed equivalent results in lymphoscintigraphy. Therefore, in this exam of each radiocolloids could be applied appropriate protocol in lymphoscintigraphy.

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DA-7911, $^{188}Rhenium-tin$ Colloid, as a New Therapeutic Agent of Rheumatoid Arthritis

  • Shin, Chang-Yell;Son, Miwon;Ko, Jun-Il;Jung, Mi-Young;Lee, In-Ki;Kim, Soon-Hoe;Kim, Won-Bae;Jeong, Jae-Min;Song, Yeong-Wook
    • Archives of Pharmacal Research
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    • v.26 no.2
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    • pp.168-172
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    • 2003
  • Radiation synovectomy is one of the most useful methods for treating patients with refractory synovitis because of its convenience, long-term effects, repeatability and the avoidance of surgery. In this study, we investigated the toxicity, stability and biodistribution of a rhenium-188 ($^{188}$Re)-tin colloid to evaluate its suitability as a synovectomy agent. Twenty four hours after injecting the $^{188}$Re-tin colloids (74 KBq/0.1 mL) into the tail vein of ICR mice, most of the $^{188}$Retin colloidal particles was found in the lungs. In addition, there were no particle size changes at either room temperature or at $37^{\circ}C$ after injecting the $^{188}$Re-tin colloids in human plasma and synovial fluid. In vitro stability tests showed that the $^{188}$Re-tin colloid remained in a colloidal form without a critical size variation over a 2-day period. We investigated the leakage of $^{188}$Retin colloids from the intraarticular injection site with gamma counting in New Zealand white rabbits. The $^{188}$Re-tin colloids (55.5 MBq/0.15 mL) were injected at the cavum articular and the mean retention percentage of the $^{188}$Re-tin colloid was 98.7% for 1 day at the injection site, which suggests that there was neither change in the particle size nor leakage at the injection sites. In the biodistribution study with the SD rats, the liver showed the highest radioactivity (0.0427% ID/organ) except for the injected knees (99.49%). In the SD rats, mild toxicities including the skin or a synovium inflammation were observed as a result of a radioactivity of 15 mCi/kg at the intraarticular injection site. However, there was no systemic toxicity. In the Ovalbumin (OVA)-induced arthritic rabbits, the $^{188}$Re-tin colloid improved the macroscopic, the histological score and reduced the knee joint diameter when compared to the arthritic control. In conclusion, a $^{188}$Re-tin-colloid is considered as a strong candidate for radiation synovectomy with a superior efficacy and safety.

Sorption of Eu(III) and Th(IV) on Bentonite Colloids Considering Their Precipitation and Colloid Formation (침전 및 콜로이드 형성을 고려한 Eu(III)와 Th(IV)의 벤토나이트 콜로이드에 대한 수착)

  • Baik, Min-Hoon;Lee, Jae-Kwang;Lee, Seung-Yeop;Kim, Seung-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.2
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    • pp.129-139
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    • 2008
  • In this study, a sorption experiment of multivalent nuclides such as Eu(III) and Th(IV) relatively stable for redox reactions was carried out for bentonite colloids which had been prepared from the domestic Gyeongju bentonite. The amounts of the nuclides lost by an attachment to bottle walls, by a precipitation, and by a colloid formation were estimated by performing blank tests for the sorption experiments. Sorption coefficients, $K_d's$, reflecting the mass losses were obtained and investigated for the sorption of Eu(III) and Th(IV) onto the bentonite colloids. The net sorption coefficients $K_d's$ considering all the three mass losses were measured as about $10^6-10^7\;mL/g$ and $7{\times}10^6-10^7\;mL/g$ for Eu(III) and Th(IV), respectively, depending on pH. In particular, a precipitation occurred mainly at a pH greater than 5 for Eu(III) and a precipitation and colloid formation significantly occurred at a pH greater than 3 for Th(IV). The precipitation and colloid formation of the multivalent nuclides of Eu(III) and Th(IV) therefore should be considered when $K_d's$ are rightly obtained over the pH range where their precipitation and colloid formation become significant at a given concentration.

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Diagnostic Significance of the Blood Disappearance Rate of $^{131}I$-Rose Bengal and of $^{198}Au$ colloid in Hepatobiliary Diseases (간담도질환(肝膽道疾患)에 있어서 $^{131}I$-Rose Bengal 및 $^{198}Au$ 교질(膠質)의 혈중소실율(血中消失率)의 진단적(診斷的) 의의(意義)에 관(關)한 연구(硏究))

  • Chun, Young-Kyoon;Koh, Chang-Soon;Hahn, Shim-Suk
    • The Korean Journal of Nuclear Medicine
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    • v.5 no.2
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    • pp.7-18
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    • 1971
  • The liver function test was performed by means of two radioisotope tracer techniques in 20 normal subjects and in 63 patients with hepatobiliary diseases. The blood disappearance rates of $^{131}I$-rose bengal and of $^{198}Au$ colloid were determined by external counting method. The hepatocellular function and the hepatic blood flow were estimated from the observed data and the results were compared with those of the conventional liver function tests. The results obtained were as follows: 1. The mean blood disappearance half time of $^{131}I$-rose bengal was $6.6{\pm}0.63$ minutes in normal control, $17.7{\pm}6.93$ in cirrhosis of the liver, $16.6{\pm}4.80$ in acute hepatitis, and $14.7{\pm}3.46$ in obstructive jaundice. It was markedly prolonged in the hepatobiliary diseases as compared with the normal control, but there was no significant difference among the hepatobiliary diseases. 2. The mean blood disappearance half time of $^{198}Au$ colloid was $4.0{\pm}0.66$ minutes in normal control, $9.8{\pm}3.42$ in cirrhosis of the liver, $4.4{\pm}0.82$ in acute hepatitis, and $5.0{\pm}1.42$ in obstructive jaundice. The difference between cirrhosis of the liver and normal control Was statistically significant. However, there was no definite difference among acute hepatitis, obstructive jaundice, and normal control. The mean blood disappearance rate constant (K value) was $0.177{\pm}0.028/minute$ in normal control. In cirrhosis of the liver, it was markedly decreased which was suggestive of the reduced hepatic blood flow. 3. The ratio of $^{131}I$-rose bengal blood disappearance half time to $^{198}Au$ colloid disappearance half time was $1.68{\pm}0.20$ in normal control, $1.82{\pm}0.31$ in cirrhosis of the liver, $3.80{\pm}0.82$ in acute hepatitis, and $3.01{\pm}0.54$ in obstructive jaundice. The ratios in acute hepatitis and obstructive jaundice were remarkably higher than those in normal control and cirrhosis of the liver. 4. There was a significant correlation between the blood disappearance half time of $^{131}I$-rose bengal and that of $^{198}Au$ colloid in cirrhosis of the liver. 5. In cirrhosis of the liver, the blood disappearance half times of $^{131}I$-rose bengal and of $^{198}Au$ colloid were inversely correlated to the serum albumin level. In acute hepatitis, there was a good positive correlation between the blood disappearance half time of $^{131}I$-rose bengal and the serum transaminase activities. In obstructive jaundice, the blood disappearance half time of $^{131}I$-rose bengal was correlated to the serum bilirubin level.

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Photonic Crystals Based on Colloid Self-Assembly (콜로이드 자기 조립체를 이용한 광결정)

  • 박정호;구혜영;김동유
    • Polymer Science and Technology
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    • v.15 no.3
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    • pp.274-285
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    • 2004
  • 콜로이드 결정 (Colloid crystal)이란 용액 상에서 부유 하는 작은 입자들의 자기 조립 (self-assembly)에 의해 형성된 주기적인 2차원 혹은 3차원 구조를 말한다. 이러한 결정 구조는 광학 필터나 스위치, 광 밴드 갭 재료, 바이오 센서 등의 과학 기술적인 응용을 비롯하여 액화 물질의 상 변화 등과 같은 물리적 현상을 규명함에 있어서 중요한 모델을 제시한다. 특히 최근에 콜로이드의 자기 조립체는 자연적으로 갖게 되는 주기적인 유전율 변화 때문에 빛의 진행 방향이나 특성을 조절할 수 있는 광자 결정 (Photonic Crystal) 구조 제작의 경쟁력 있는 접근 방법으로 각광 받고 있다. (중략)

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