• 공업화학
• /
• 제16권3호
• /
• pp.337-341
• /
• 2005

본 논문은 니켈이 담지된 촉매를 이용하여 메탄의 이산화탄소 개질반응에서 발생하는 탄소퇴적의 속도와 반응온도에 따른 카본생성 경로를 연구하였다. 개질 반응이 진행되는 동안 촉매 위에 발생하는 탄소퇴적과 그 속도측정을 위한 반응장치로는 열분석기를 이용하였다. 메탄의 이산화탄소 개질반응에서 반응기체 조성을 달리하여 실험한 결과 코크형성의 반응차수가 1.33($CH_4$)과 -0.52($CO_2$)임을 확인하였다. 또한, 탄소퇴적속도를 이용한 모델식을 근거로 반응온도에 따른 반응속도인자를 계산한 결과 $600^{\circ}C$ 미만에서는 메탄의 분해반응만이 주로 발생하며 $600{\sim}700^{\circ}C$ 사이에서는 메탄의 분해반응과 더불어 이산화탄소 해리반응이 동시에 진행됨을 알았다.

• Carbon letters
• /
• 제28권
• /
• pp.38-46
• /
• 2018

Modified pitch A (MPA) and modified pitch B (MPB) were prepared by oxidative polymerization and thermal polycondensation reaction with refined pitch as the raw material, respectively. The toluene soluble components (TS-1 and TS-2) were obtained by solvent extraction from MPA and MPB, separately. The Flynn-Wall-Ozawa method and Kissinger-Akahira-Sunose method were used to calculate the pyrolysis activation energy of TS. The Satava-Sestak method was used to investigate the pyrolysis kinetic parameters of TS. Moreover, the optical microstructure of the thermal conversion products (TS-1-P and TS-2-P) by calcination shows that TS-1-P has more contents of mosaic structure and lower contents of fine fiber structure than TS-2-P. The research result obtained by a combination of X-ray diffraction and the curve-fitting method revealed that the ratios of ordered carbon crystallite (Ig) in TS-1-P and TS-2-P were 0.3793 and 0.4417, respectively. The distributions of carbon crystallite on TS-1-P and TS-2-P were calculated by Raman spectrum and curve-fitting analysis. They show that the thermal conversion product of TS-2 has a better graphite crystallite structure than TS-1.

• 한국수소및신에너지학회논문집
• /
• 제26권5호
• /
• pp.445-452
• /
• 2015

A tubular packed bed reactor for the steam-$CO_2$ combined reforming of natural gas to produce the synthesis gas of a target $H_2/CO$ ratio 2.0 was simulated. The effects of the reactor dimension, the feed gas composition, and the gas feeding temperature upon the possibility of coke formation across the catalyst bed were investigated. For this purpose, 2-dimensional heterogeneous reactor model was used to determine the local gas concentrations and temperatures over the catalyst bed. The thermodynamic potential distribution of coke formation was determined by comparing the extent of reaction with the equilibrium constant given by the reaction, $CH_4+2CO{\Leftrightarrow}3C+2H_2O$. The simulation showed that catalysts packed in the central region nearer the entrance of the reactor were more prone to coking because of the regional characteristics of lower temperature, lower concentration of $H_2O$, and higher concentration of CO. With the higher feeding temperature, the feed gas composition of the increased $H_2O$ and correspondingly decreased $CO_2$, or the decrease in the reactor diameter, the volume fraction of the catalyst bed subsequent to coking could be diminished. Throughout the simulation, reactor dimension and reaction condition for coking-free operation were suggested.

• 한국추진공학회:학술대회논문집
• /
• 한국추진공학회 2006년도 제26회 춘계학술대회논문집
• /
• pp.100-109
• /
• 2006

구리합금을 연소실 내벽으로 사용하고 탄화수소계 연료를 추진제로 사용하는 재생냉각 연소기에서 냉각채널 벽면온도가 상승함에 따라 냉각채널에 반응물이 침착되는 코킹현상이 일어난다. 이러한 현상은 냉각채널을 흐르는 연료에 의한 냉각효과를 감소시키게 되고, 높은 열유속으로 운영되는 연소기 내부벽면을 과열시켜 손상에 이르게 한다. 본 논문에서는 구성된 전기가열장치에 대해 소개하고 연소실 재질로 사용되고 있는 구리합금과 추진제로 사용되는 탄화수소계 연료 Jet A-1에 대해 가열시험 결과를 제시한다. 시험결과에 따라 각 조건에서의 구리합금과 Jet A-1의 적합성을 평가하였다.

• International Journal of Advanced Culture Technology
• /
• 제3권1호
• /
• pp.31-38
• /
• 2015

Coking accumulations via dry methane reforming (DMR) over 10NAM monolithic catalyst and pelletized catalyst was investigated. 10NAM catalyst was synthesized and coated on a wall of monolithic reactor. Pelletized catalyst of 10NAM was also prepared for the comparison. Consequently, catalyst was characterized by BET, $H_2-TPR$ and $H_2-TPD$. The catalytic reaction was undergone at $600^{\circ}C$ under atmospheric pressure and $CH_4$ to $CO_2$ reactant ratio of 1:2. The coking formation over spent catalyst was then carried out in the hydrogen flow using temperature programmed technique (TPH). According to the results, DMR over 10NAM monolithic catalyst exhibits a minimized coking formation comparing to the use of pelletized catalyst. This could be attributed to a prominent heat transfer efficiency of the monolithic catalyst.

• 무역학회지
• /
• 제44권2호
• /
• pp.127-141
• /
• 2019

In this study, the relationship between Baltic Dry Index(BDI) and maritime trade volume in the dry cargo market was verified using the vector autoregressive (VAR) model. Data was analyzed from 1992 to 2018 for iron ore, steam coal, coking coal, grain, and minor bulks of maritime trade volume and BDI. Granger causality analysis showed that the BDI affects the trade volume of coking coal and minor bulks but the trade volume of iron ore, steam coal and grain do not correlate with the BDI freight index. Impulse response analysis showed that the shock of BDI had the greatest impact on coking coal at the two years lag and the impact was negligible at the ten years lag. In addition, the shock of BDI on minor cargoes was strongest at the three years lag, and were negligible at the ten years lag. This study examined the relationship between maritime trade volume and BDI in the dry bulk shipping market in which uncertainty is high. As a result of this study, there is an economic aspect of sustainability that has helped the risk management of shipping companies. In addition, it is significant from an academic point of view that the long-term relationship between the two time series was analyzed through the causality test between variables. However, it is necessary to develop a forecasting model that will help decision makers in maritime markets using more sophisticated methods such as the Bayesian VAR model.

• 한국추진공학회지
• /
• 제24권3호
• /
• pp.81-124
• /
• 2020

액체산소/케로신 액체로켓엔진에서 케로신은 추진제일 뿐만 아니라 3,000 K 이상의 연소가스로부터 연소실 벽면을 보호하기 위한 냉각제 역할도 수행한다. 케로신은 냉각채널을 통과하면서 높은 온도에 노출되기 때문에 열과 관련한 화학반응이 일어나 탄소 과잉 고체가 침전되는 현상이 발생할 수 있다. 이러한 케로신의 열/유체 특성 시험 데이터는 재생냉각 연소실 설계에 필수적이다. 본 논문에서는 재생냉각채널과 케로신에 관련된 해외 연구를 조사하였다. 탄화수소 연료에 대한 전반적인 정보를 시작으로, 냉각채널 벽면에 발생하는 퇴적 현상, 이에 대한 원인/연구결과, 케로신 코킹 시험 장치/예방 방법 등을 체계적으로 정리하고자 하였다.

• 유기물자원화
• /
• 제18권4호
• /
• pp.38-44
• /
• 2010

주물사는 규사에 벤토나이트나 resin 등의 점결제를 첨가한 것으로써 주물제품의 생산을 위한 주형에 사용되고 있다. 주물업체에서 반복적으로 사용된 주물사는 결국 열에 의해 파쇄되어 그 기능을 상실하며 폐주물사로 전락된다. 폐주물사는 점결제의 성분 및 함량에 따라 지정 또는 일반폐기물로 처분되고 있지만 주물사의 주종을 이루는 규사는 열에 의해 변성되지 않는 성질로 인하여 적절한 처리를 통하여 재사용이 가능하다. 본 연구에서는 국내 외 폐주물사의 발생 및 처리, 재활용현황, 그리고 재활용에 관련된 제도 및 재활용을 저해하는 요인 등을 조사하여 문제점을 도출하고 폐주물사의 재활용 활성화 방안을 제시하였다.

• Tribology and Lubricants
• /
• 제13권4호
• /
• pp.33-39
• /
• 1997

In order to establish a new temperature criterion to prevent the pistons from ring sticking due to deposit formation, bench test and engine test were performed. The effects of oil degradation and temperature on deposit formation was studied by a modified panel coking test. Oil degradation was analyzed by FTIR. Oil oxidation and nitration were selected as a factors to evaluate oil degradation. Bench test results show that oil oxidation is more effective to the deposit formation than oil nitration. And the temperature increase accelerates deposit formation and deposit formation increase rapidly above 26$0^{\circ}C$. Especially, in case of degraded oil, the deposit formation increases so rapidly that ring sticking can occur. The effect of piston temperature on the deposit formation was confirmed by engine test.

• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
• /
• pp.675-680
• /
• 2002

Cracking and bulging in welded and internally lined pressure vessels that work in thermal-mechanical cycling service have been well known problems in the petrochemical, power and nuclear industries. However, published literature and industry surveys show that similar problems have been occurring during the last 50 years. A better understanding of the causes of cracking and bulging causes is needed to improve the reliability of these pressure vessels. This study attempts to add information required for increasing the knowledge and fundamental understanding required. Typical examples of this problem are the coke drums in the delayed coking units refinery process. This case was selected for experimental work, field study and results comparison. Delayed coking units are among the refinery units that have higher economical yields. To shut down these units represents a high negative economical impact in refinery operations. Also, the maintenance costs associated with repairs are commonly very high. Cracking and bulging occurrences in the coke drums, most often at the weld areas, characterize the history of the operation of delayed coking units. To design and operate more robust coke drums with fewer problems, an improved metallurgical understanding of the cracking and bulging mechanisms is required. A methodology that is based field experience revision and metallurgical analyses for the screening of the most important variables, and subsequent finite element analyses to verify hypotheses and to rank the variables according to their impact on the coke drum lives has been developed. This indicated approach provides useful information for increasing coke drum reliability. The results of this work not only order the most important variables according to their impact in the life of the vessels, but also permit estimation of the life spans of coke drums. In conclusion, the current work shows that coke drums may fail as a combination of thermal fatigue and other degradation mechanisms such as: corrosion at high and low temperatures, detrimental metallurgical transformations and plastic deformation. It was also found that FEA is a very valuable tool for understanding cracking and bulging mechanisms in these services and for ranking the design, fabrication, operation and maintenance variables that affect coke drum reliability.