• Title/Summary/Keyword: coefficient permeability

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The development of high-performance PRO module and effects of operating condition on the performance of PRO module (고성능 PRO 모듈 개발 및 운전조건이 모듈 성능에 미치는 영향)

  • Han, Man Jae;Sim, Yeonju;Lee, Jong Hwa
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.4
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    • pp.303-310
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    • 2017
  • Pressure retarded osmosis(PRO) has attracted much attention as potential technology to reduce the overall energy consumption for reverse osmosis(RO) desalination. The RO/PRO hybrid process is considered as the most logical next step for future desalination. The PRO process aims to harness the osmotic energy difference of two aqueous solutions separated by a semipermeable membrane. By using the concentrated water(RO brine) discharged from existing RO plants, the PRO process can effectively exploit a greater salinity gradient to reduce the energy cost of processing concentrated water. However, in order to use RO brine as the draw solution, PRO membrane must have high water flux and enough mechanical strength to withstand the high operational pressure. This study investigates the development of a thin film composite PRO membrane and spiral wound module for high power density. Also, the influence of membrane backing layer on the overall power density was studied using the characteristic factors of PRO membranes. Finally, the performance test of an 8-inch spiral wound module was carried out under various operating conditions(i.e. hydraulic pressure, flow rate, temperature). As the flow rate and temperature increased under the same hydraulic pressure, the PRO performance increased due to the growth of water permeability coefficient and osmotic pressure. For a high performance PRO system, in order to optimize the operating conditions, it is highly recommended that the flow pressure be minimized while the flow rate is maintained at a high level.

Free Volume in Polyers Note II。: Positron Annihilation lifetime Spectroscopy and Applications

  • G. Consolati;M. Pegoraro;L. Zanderighi
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.25-37
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    • 1999
  • positron annihilation Lifetime Spectroscopy has been extensively applied in recent years to investigate the free volume in polymers owing to the capability of the electron-positron bound system (positronium) to probe the typical size of sub-nanometric cavities among the macromolecular chains. In this paper we show recent results obtained through this technique in some amorphous polymeric mem-branes(olyurethanes. PUs and polytrimethilsylilpropine PTMSP) after a brief survey of the general features of the annihilation process as well as of the experimental apparatus. Lifetime of o-ps decay({{{{ tau _3}}}}) in PUs increases going from sub {{{{ TAU _g}}}} to over {{{{ TAU _g}}}} temperatures following a sigmoid curve. The coefficient of dilatation of the free volume fraction is shown to be the sum of two contributes due to the variation with T of the number of holes and of their mean volume. PAL spectrum of PTMSP freshly prepared shows four lifetime components: {{{{ tau _3}}}} and {{{{ tau _4}}}}: only are useful for free volume study. Two kinds of holes of different equivalent radius are reported ({{{{ gamma _s}}}} 4.60 nm and {{{{ gamma _1}}}} 0.754) The equivalent volume does not change in a range of 100 K. however the physical aging increases density and decreases oxygen permeability while {{{{ gamma _s}}}} goes down to 0.374 and r1 to 0.735 The number of holes obtained from the intensities{{{{ IOTA _3}}}} and {{{{ IOTA _4}}}} of PAL spectra decreases with aging 21.7% and 3.5% for large and small holes respectively.

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Measurement of Aerodynamic Properties of Screens for Windbreak Fence using the Apparatus for Testing Screens (공력 저항 측정기를 이용한 방풍펜스 방진막의 공기 투과 저항력 측정)

  • Kim, Rack-Woo;Lee, In-Bok;Hong, Se-Woon;Hwang, Hyun-Seob;Son, Young-Hwan;Kim, Tae-Wan;Kim, Min-Young;Song, Inhong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.6
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    • pp.145-154
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    • 2013
  • Recently, damage occurrence by wind erosion has been increasing in society. In times past, such problems only took place in desert area ; however, in recent years, the wind erosion problem is spreading out to agricultural land. Wind erosion in agricultural land can cause loss of loam soils, the disturbance of the photosynthesis of the crop fields and serious economic losses. To overcome the mentioned problems, installation of windbreak fence can be recommended which function as disturbing strong wind and wind erosion. However, there is still no proper guideline to install the windbreak fence and the installation used to rely on the intuition of the workers due to the lack of related studies. Therefore, this study measured the aerodynamic resistance of screens of the windbreak fence using the apparatus for testing screens. The apparatus for testing screens was designed to measure pressure loss around the screen. Measured pressure loss by wall friction compensated for pressure loss to calculate the aerodynamic resistance of screens. The result of pressure loss by regression analysis derived the aerodynamic coefficient of Darcy-Forchheimer equation and power law equation. The aerodynamic resistance was constant regardless of the overlapped shape when the screen was overlapped into several layers. Increasing the number of layers of the screen, internal resistance increased significantly more, and pressure loss caused by the screen also increased linearly when the wind speed was certain conditions, but permeability had no tendency. In the future, the results of this study will be applied to the computational fluid dynamics simulation. The simulation models will be also validated in advance by wind tunnel experiments. It will provide standard of a design for constructing windbreak fence.

Microemulsion-based hydrogels for enhancing epidermal/dermal deposition of topically administered 20(S)-protopanaxadiol: in vitro and in vivo evaluation studies

  • Kim, Ki-Taek;Kim, Min-Hwan;Park, Ju-Hwan;Lee, Jae-Young;Cho, Hyun-Jong;Yoon, In-Soo;Kim, Dae-Duk
    • Journal of Ginseng Research
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    • v.42 no.4
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    • pp.512-523
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    • 2018
  • Background: 20(S)-Protopanaxadiol (20S-PPD) is a fully deglycosylated ginsenoside metabolite and has potent dermal antiaging activity. However, because of its low aqueous solubility and large molecular size, a suitable formulation strategy is required to improve its solubility and skin permeability, thereby enhancing its skin deposition. Thus, we optimized microemulsion (ME)-based hydrogel (MEH) formulations for the topical delivery of 20S-PPD. Methods: MEs and MEHs were formulated and evaluated for their particle size distribution, morphology, drug loading capacity, and stability. Then, the deposition profiles of the selected 20S-PPD-loaded MEH formulation were studied using a hairless mouse skin model and Strat-M membrane as an artificial skin model. Results: A Carbopol-based MEH system of 20S-PPD was successfully prepared with a mean droplet size of 110 nm and narrow size distribution. The formulation was stable for 56 d, and its viscosity was high enough for its topical application. It significantly enhanced the in vitro and in vivo skin deposition of 20S-PPD with no influence on its systemic absorption in hairless mice. Notably, it was found that the Strat-M membrane provided skin deposition data well correlated to those obtained from the in vitro and in vivo mouse skin studies on 20S-PPD (correlation coefficient $r^2=0.929-0.947$). Conclusion: The MEH formulation developed in this study could serve as an effective topical delivery system for poorly soluble ginsenosides and their deglycosylated metabolites, including 20S-PPD.

Numerical Analysis on Drain Capacity and Vegetation Potential of Unsaturated Made-Planting Soil (불포화 인공 식재 지반의 배수 성능과 식생 가능 조건에 대한 수치해석적 분석)

  • Kim, Sung-Min;Kim, Choong-Eon;Jung, Young-Hoon
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.6
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    • pp.33-41
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    • 2016
  • This study attempted to investigate drain capacity and vegetation potential of made-planting soil via finite element simulations. Engineering drain capacity of made-planting soil can be evaluated by an analysis of unsaturated soils. In a perspective for vegetation landscape, it is necessary to check whether the minimum amount of water in the made-planting soil can be supplied for the survival of plants. Herein, 1-m high soil column covered by made-planting soil were numerically simulated. Numerical results showed that how the coefficient of permeability of saturated soil and soil-water characteristics of unsaturated soil are considered significantly influences the drain capacity of soils. Variation in the volumetric water content within the Least Limiting Water Range (LLWR) provides us with information on whether the soil can contain a sufficient amount of water for the plants to survive the drought.

Prediction of Slope Hazard Probability around Express Way using Decision Tree Model (의사결정나무모형을 이용한 고속도로 주변 급경사지재해 발생가능성 예측)

  • Kim, Chan-Kee;Bak, Gueon Jun;Kim, Joong Chul;Song, Young-Suk;Yun, Jung-Mann
    • Journal of the Korean Geosynthetics Society
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    • v.12 no.2
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    • pp.67-74
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    • 2013
  • In this study, the prediction of slope hazard probability was performed to the study area located in Hadae-ri, Woochun-myeon, Hoengsung-gun, Gangwon Province around Youngdong express way using the computer program SHAPP ver 1.0 developed by a decision tree model. The soil samples were collected at total 10 points, and soil tests were performed to measure soil properties. The thematic maps of soil properties such as coefficient of permeability and void ratio were made on the basis of soil test results. The slope angle analysis of topography was performed using a digital map. As the prediction result of slope hazard probability, 2,120 cells among total 27,776 cells were predicted to be in the event of slope hazards. Therefore, the predicted area of occurring slope hazards may be $53,000m^2$ because the analyzed cell size was $5m{\times}5m$.

A Study on the Self-Weight Consolidation Procedure of Very Soft Ground Reclaimed by Dredging Clayey Soil (연약한 준설 매립 점성토지반의 자중압밀 과정에 관한 연구)

  • 김형주;오근엽
    • Journal of the Korean Geotechnical Society
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    • v.15 no.2
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    • pp.129-138
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    • 1999
  • This study is performed for the development of a field monitoring and test technique both of self-weight and hydraulic consolidation by which the soil parameters of dredge-reclaimed clay can be obtained effectively. The field monitoring development and tests mentioned above make it possible to reproduce the process of the self-weight consolidation from settling to reclaimed soft ground. The experimental research is mainly focussed on the characteristics of self-weight consolidation of dredged clayey soil. And theoretical study has pointed out the limits in the application of Terzaghi's one dimensional consolidation theory in interpreting reclaimed clayey ground. Furthermore, a finite difference analysis has been made on the basis of Mikasa s self-weight consolidation theory which takes the problems of Terzaghi's theory into consideration. The relationships between specific volume, effective stress, and the coefficient of permeability of Kunsan reclaimed clayey soil have been obtained by laboratory tests. On the other hand, through the field monitoring, pore pressure, total pressure, and water levels have been measured after pouring. The results of these experiments have been analyzed, and compared with those from Terzaghi's method and the finite difference analysis of Mikasa's self-weight consolidation theory. In conclusion, the measured settlements is comparatively consistent with Mikasa's self-weight consolidation theory rather than Terzaghi's consolidation theory.

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A Simple Method for Estimating Wetting Path of Soil Water Characteristic Curve on Unsaturated Soils (불포화지반의 습윤과정 함수특성곡선 추정을 위한 간편법)

  • Park, Hyun-Su;Kim, Byeong-Su;Park, Seong-Wan
    • Journal of the Korean Geotechnical Society
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    • v.33 no.6
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    • pp.37-48
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    • 2017
  • Soil-water characteristic curve (SWCC) has been widely used to estimate the shear strength and coefficient of permeability for unsaturated soils. In general, it is divided into the drying path in which the water is discharged and the wetting path in which the water is permeated, and it has a hysteresis indicating different suctions at the same volumetric water content. In reality the field behavior of unsaturated soils is much closer to the wetting path during the infiltration. The drying path has been practically used for various analyses because obtaining the wetting path takes longer than the drying path. Although many approaches for estimating wetting path have been studied till now, these are complex and do not fit well. Therefore, a simple method for estimating wetting path based on empirical approach in this study is proposed in unsaturated soils, and a feasibility study is conducted as well.

A Study on Runoff Analysis of Urban Watershed by Hydrologic Infiltration Experiment of Permeable Pavement (투수성 포장의 침투 실험을 통한 도시유역 유출 변화 연구)

  • Koo, Young Min;Jo, Jae An;Kim, Young Do;Park, Jae Hyeon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.2
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    • pp.559-571
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    • 2013
  • Recently, due to increase of the impervious layer, the storage of surface layer has been reduced. Otherwise the peak runoff and the total surface runoff have been raised. Because of larger amount of the peak runoff and the rapid time of concentration, the flood damage of the urban watershed was increased. The groundwater level is descended by reducing the amount of rainfall that infiltrated into the soil. Thereby the hydrologic cycle is degenerated by the dry stream. Therefore, in this study, the evaluation and the quantitative analysis of the percolation effect were performed through the infiltration experiment of permeable pavement, which is one of the ways that can reduce the problem of the dry stream. Also the SWMM model is used to analyze the effect of the hydrologic cycle for permeable pavement in Changwon stream and Nam stream watersheds, with the coefficient of permeability from the infiltration experiments.

Synthesis and characterization of poly(vinyl-alcohol)-poly(β-cyclodextrin) copolymer membranes for aniline extraction

  • Oughlis-Hammache, F.;Skiba, M.;Hallouard, F.;Moulahcene, L.;Kebiche-Senhadji, O.;Benamor, M.;Lahiani-Skiba, M.
    • Membrane and Water Treatment
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    • v.7 no.3
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    • pp.223-240
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    • 2016
  • In this study, poly(vinyl-alcohol) and water insoluble ${\beta}$-cyclodextrin polymer (${\beta}$-CDP) cross-linked with citric acid, have been used as macrocyclic carrier in the preparation of polymer inclusion membranes (PIMs) for aniline (as molecule model) extraction from aqueous media. The obtained membranes were firstly characterized by X-ray diffraction, Fourier transform infrared and water swelling test. The transport of aniline was studied in a two-compartment transport cell under various experimental conditions, such as carrier content in the membranes, stirring rate and initial aniline concentration. The kinetic study was performed and the kinetic parameters were calculated as rate constant (k), permeability coefficient (P) and flux (J). These first results demonstrated the utility of such polymeric membranes for environmental decontamination of toxic organic molecules like aniline. Predictive modeling of transport flux through these materials was then studied using design of experiments; the design chosen was a two level full factorial design $2^k$. An empirical correlation between aniline transport flux and independent variables (Poly ${\beta}$-CD membrane content, agitation speed and initial aniline concentration) was successfully obtained. Statistical analysis showed that initial aniline concentration of the solution was the most important parameter in the study domain. The model revealed the existence of a strong interaction between the Poly ${\beta}$-CD membrane content and the stirring speed of the source solution. The good agreement between the model and the experimental transport data confirms the model's validity.