• Title/Summary/Keyword: coefficient of $CO_2$

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Degradation Characteristics of Pr/Co/Cr/Er Co-doped Zinc Oxide Varistors by Impulse Current Stress

  • Nahm, Choon-Woo
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.6
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    • pp.348-352
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    • 2014
  • In light of the sure protection function, the most important factors of a varistor are the clamping voltage ratio and degradation characteristics. The degradation characteristics of Pr/Co/Cr/Er co-doped zinc oxide varistors were investigated by impulse currents (0.4~2.1 kA) stress for the specified content of $Er_2O_3$ (0.5 and 2.0 mol%). The varistor doped with 2.0 mol% $Er_2O_3$ exhibited the best clamp characteristics, with the clamp voltage ratio (K) in the range of K = 1.63~1.88 at the impulse currents of 5-50 A. However, the varistor doped with 0.5 mol% exhibited excellent electrical stability, with variation rates for the breakdown field, for the nonlinear coefficient, and for the leakage current density of -6.9%, -12.6%, and -14.3%, respectively, after application of an impulse current of 2.1 kA. In contrast, the varistor doped with 2.0 mol% was destroyed after application of an impulse current of 1.2 kA.

Experimental Study on the Performance Characteristics of a CO2 Air-conditioning System for Vehicles (자동차용 CO2 에어컨 시스템의 성능 특성에 관한 실험적 연구)

  • Lee, Daewoong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.1
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    • pp.18-24
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    • 2015
  • In this study, a $CO_2$ air-conditioning system was investigated with different types of electrically driven compressors, parallel flow type gas cooler, four-pass type evaporator, internal heat exchanger integrated with accumulator, and electric expansion valve. The experimental study was conducted under various operating conditions (ie., different rotational compressor speeds, air inlet temperatures and air velocity coming into heat exchangers). The experimental results showed the cooling capacity was 3.5kW at $35^{\circ}C$ ambient temperature when the vehicle was idle (ie., the worst condition for cooling off the gas cooler). In terms of performance effect of the compressor, the e-RP model had a slightly better cooling capacity and coefficient of performance than the e-GR model under the same test conditions. An experimental equation for optimum cooling-performance control was also suggested based on the results. A high-pressure control algorithm for the super critical cycle was determined to achieve both maximum cooling performance and efficient energy consumption. The results from the experimental equation coincided with those of previous experimental studies.

Effect of Er2O3 Content on Nonlinear Properties and Impulse Clamping Characteristics of Pr/Co/Cr/Al Co-doped Zinc Oxide Ceramics

  • Nahm, Choon-Woo
    • Journal of the Korean Ceramic Society
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    • v.51 no.6
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    • pp.612-617
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    • 2014
  • The microstructure, nonlinear properties, and impulse clamping characteristics of Pr/Co/Cr/Al co-doped zinc oxide ceramics were investigated with various contents of $Er_2O_3$. Increasing $Er_2O_3$ content increased the density of the sintered pellets from 5.69 to $5.83g/cm^3$, and decreased the average grain size from 10.6 to $6.5{\mu}m$. With increased $Er_2O_3$ content, the breakdown field increased from 2318 to 4205 V/cm, and the nonlinear coefficient increased from 19.4 to 40.2. The clamp characteristics were improved with the increase of the content of $Er_2O_3$. The varistors doped with 2.0 mol% exhibited the best clamp characteristics, in which the clamp voltage ratio was 1.40-1.73 at 1-50 A in an impulse current.

Elemental Correlations of Chemical Compositions in Co-rich Mn-crusts of the Republic of Marshall Islands (마샬공화국 고코발트망간각 화학조성의 원소 상관관계)

  • 황의덕;장세원;김두영
    • Journal of the Mineralogical Society of Korea
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    • v.12 no.2
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    • pp.77-90
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    • 1999
  • Characteristics and variations of chemical compositions in Co-rich crusts occurred in the EEZ of the Republic of Marshall Islands were reviewed. Correlation coefficient analysis, hierarchical cluster analysis, and Q-mode factor analysis for 62 samples were done in this study. All data were selected and gathered from the open file report of the cooperative cruise done by United States Geological Survey with Scripps Institute of Oceanography, University of Hawaii or Korea Ocean Research Development Institute. The average of crust thickness. Co content, and Ni content of 62 samples from the 21 seamounts were 30mm, 0.58 wt% and 0.40%, respectively. The mineral phases and associated elements assigned by correlation coefficients, cluster analysis and Q-mode factor analysis are following four. 1) CFA: P, Ca, CO2, Y, Sr: 2) Mn-oxide mineral: As, Mn, Co, Na: 3) Al-silicate mineral: Pd,Si, Al, Cu, Fe: 4) PGE-bearing mineral: Rh, Pt, Ir.

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Cathodic Properties of $LiCoO_2$ Synthesized by a Sol-Gel Method for Lithium Ion Battery

  • 조봉준;정의덕;심윤보
    • Bulletin of the Korean Chemical Society
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    • v.19 no.1
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    • pp.39-44
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    • 1998
  • $LiCoO_2$ powder was synthesized in an aqueous solution by a sol-gel method and used as a cathode active material for a lithium ion rechargeable battery. The layered $LiCoO_2$ powders were prepared by igniting in air for 12 hrs at 600 ℃ $(600-LiCoO_2)$ and 850 ℃ $(850-LiCoO_2)$. The structure of the $LiCoO_2$ powder was assigned to the space group R bar 3 m (lattice parameters a=2.814 Å and c=14.04Å). The SEM pictures of $600-LiCoO_2$ revealed homogeneous and fine particles of about 1 μm in diameter. Cyclic voltammograms (CVs) of $600-LiCoO_2$ electrode displayed a set of redox peaks at 3.80/4.05 V due to the intercalation/deintercalation of the lithium ions into/out of the $LiCoO_2$ structure. CVs for the $850-LiCoO_2$ electrode had a major set of redox peaks at 3.88/4.13 V, and two small set of redox peaks at 4.18/4.42 V and 4.05/4.25 V due to phase transitions. The initial charge-discharge capacity was 156-132 mAh/g for the $600-LiCoO_2$ electrode and 158-131 mAh/g for the $850-LiCoO_2$ electrode at the current density of 0.2 mA/cm2. The cycleability of the cell consisting of the $600-LiCoO_2$ electrode was better than that of the $850-LiCoO_2$. The diffusion coefficient of the $Li^+$ ion in the $600-LiCoO_2$ electrode was calculated as $4.6{\times}10^{-8}\; cm^2/sec$.

XRD Patterns and Bismuth Sticking Coefficient in $Bi_2Sr_2Ca_nCu_{n+1}O_y(n\geq0)$ Thin Films Fabricated by Ion Beam Sputtering Method

  • Yang, Seung-Ho;Park, Yong-Pil
    • Journal of information and communication convergence engineering
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    • v.4 no.4
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    • pp.158-161
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    • 2006
  • [ $Bi_2Sr_2Ca_nCu_{n+1}O_y(n{\geq}0)$ ] thin film is fabricatedvia two different processes using an ion beam sputtering method i.e. co-deposition and layer-by-layer deposition. A single phase of Bi2212 can be fabricated via the co-deposition process. While it cannot be obtained by the layer-by-layer process. Ultra-low growth rate in our ion beam sputtering system brings out the difference in Bi element adsorption between the two processes and results in only 30% adsorption against total incident Bi amount by layer-by-layer deposition, in contrast to enough Bi adsorption by co-deposition.

Voltage Enhancement of ZnO Oxide Varistors for Various Y2O3 Doping Compositions

  • Yoon, Jung-Rag;Lee, Chang-Bae;Lee, Kyung-Min;Lee, Heun-Young;Lee, Serk-Won
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.5
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    • pp.152-155
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    • 2009
  • The microstructure and the electrical properties of a ZnO varistor, which was composed of a ZnO-$Bi_2O_3$-$Sb_2O_3$-CoO- $MnO_2$ -NiO-$Nd_2O_3$ system, were investigated at various $Y_2O_3$ addition concentrations. $Y_2O_3$ played a role in the inhibition of the grain growth. As the $Y_2O_3$ content increased, the average grain size decreased from $6.8{\mu}m$ to $4{\mu}m$, and the varistor voltage($V_{1mA}$) greatly increased from 275 to 400 V/mm. The nonlinearity coefficient ($\alpha$) decreased from 72 to 65 with increasing $Y_2O_3$ amount. On the other hand, the leakage current ($I_L$) increased from 0.2 to 0.9 ${\mu}A$. These results confirmed that doping the varistors with $Y_2O_3$ is a promising production route for production of a higher fine-grained varistor voltage ($V_{1mA}$) which can dramatically reduce the size of the varistors.

Simplified Carbonation Model Considering Ca(OH)2 Solubility and Porosity Reduction (수산화칼슘 용해도와 공극률 감소를 고려한 간략화 된 탄산화 모델)

  • Lee, Yun;Kwon, Seung-Jun;Park, Ki-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.1
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    • pp.128-138
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    • 2015
  • Carbonation is one of the most critical deterioration phenomena to concrete structures exposed to high $CO_2$ concentration, sheltered from rain. Lots of researches have been performed on evaluation of carbonation depth and changes in hydrate compositions, however carbonation modeling is limitedly carried out due to complicated carbonic reaction and diffusion coefficient. This study presents a simplified carbonation model considering diffusion coefficient, solubility of $Ca(OH)_2$, porosity reduction, and carbonic reaction rate for low concentration. For verification, accelerated carbonation test with varying temperature and MIP (Mercury Intrusion Porosimetry) test are carried out, and carbonation depths are compared with those from the previous and the proposed model. Field data with low $CO_2$ concentration is compared with those from the proposed model. The proposed model shows very reasonable results like carbonation depth and consuming $Ca(OH)_2$ through reduced diffusion coefficient and porosity compared with the previous model.

A CO2 Emission Reduction Method through Correlation Analysis of Design Parameters in Buildings (건축물 설계변수의 상관관계 분석을 통한 CO2 배출저감 방안)

  • Lee, Hyun-Woo;Chae, Min-Su
    • Journal of the Korean Solar Energy Society
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    • v.31 no.1
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    • pp.100-106
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    • 2011
  • This study proposes a $CO_2$ emission reduction method through correlation analysis of a sample building. First, energy saving factors of heating, cooling, lighting were determined for the correlation analysis and $CO_2$ emission contribution rate of the design parameters have been analyzed. Then optimal combination of each design parameter has been drawn. Heat transfer coefficient of walls and windows, air permeability, windows area ratio, and shading devices were selected as applicable energy saving factors of the sample building. Also computer simulation was conducted using experimental design by Orthogonal Arrays of the statistical method. And the contribution rate was estimated by Analysis of Variance-ANOVA. As a result, the $CO_2$ emission in heating was reduced to 51.9%; in cooling to 16.8%; and in lighting to 2% compared to the existing building. The majority of the reduction was presented by heating energy.

Crystalline Phases and Dielectric Properties of Crystallized Glasses in the System (Ca, Sr, Ba) O-Al2O3-B2O3-SiO2-TiO2

  • Tuzuku, Koichiro;Kishi, Hiroshi;Taruta, Seiichi;Takusagawa, Nobuo
    • The Korean Journal of Ceramics
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    • v.5 no.2
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    • pp.189-194
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    • 1999
  • Crystallization of glasses in the system (Ca, Sr, Ba)$O-Al_2O_3-B_2O_3-SiO_2-TiO_2$ and dielectric properties of crystallized glasses were investigated. As increasing B2O3 content and decreasing SiO2 content in the glass, the major crystalline phase changed from $(Sr, Ba)_2TiSi_2O_8$ to (Ca, Sr, Ba)TiO3, the dielectric constant of crystallized glasses increased and the Temperature Coefficient of Capacitance (TCC) changed to negative. The dielectric constant and TCC was estimated for (Sr, Ba)2TiSi2O8 phase as 18 and -440 $ppm/^{\circ}C$, respectively and for (Ca, Sr, Ba)TiO3 phase as 307 and -1900 $ppm/^{\circ}C$, respectively. The dielectric properties of (Ca, Sr, Ba)TiO3 phase (in this study) were similar to those of (Ca, Ba) TiO_3 solid-solution^12)$, but $(Sr, Ba)_2TiSi_2O_8$ phase (in this study) and $Sr_2TiSi_2O_\;8^4$ showed the different properties.

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