• Title/Summary/Keyword: codoped

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Degradation and mineralization of violet-3B dye using C-N-codoped TiO2 photocatalyst

  • Putri, Reza Audina;Safni, Safni;Jamarun, Novesar;Septiani, Upita;Kim, Moon-Kyung;Zoh, Kyung-Duk
    • Environmental Engineering Research
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    • v.25 no.4
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    • pp.529-535
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    • 2020
  • The present study investigated the photodegradation of synthetic organic dye; violet-3B, without and with the addition of C-N-codoped TiO2 catalyst using a visible halogen-lamp as a light source. The catalyst was synthesized by using a peroxo sol-gel method with free-organic solvent. The effects of initial dye concentration, catalyst dosage, and pH solution on the photodegradation of violet-3B were examined. The efficiency of the photodegradation process for violet-3B dye was higher at neutral to less acidic pH. The kinetics reaction rate of photodegradation of violet-3B dye with the addition of C-N-codoped TiO2 followed pseudo-first order kinetics represented by the Langmuir-Hinshelwood model, and increasing the initial concentration of dyes decreased rate constants of photodegradation. Photodegradation of 5 mg L-1 violet-3B dye achieved 96% color removal within 240 min of irradiation in the presence of C-N-codoped TiO2 catalyst, and approximately 44% TOC was removed as a result of the mineralization.

Highly efficient white organic light-emitting diodes using hybrid-spacer or/and codoped blue emitting layers

  • Seo, Ji-Hoon;Kim, Gu-Young;Hyung, Gun-Woo;Lee, Kum-Hee;Kim, You-Hyun;Kim, Woo-Young;Yoon, Seung-Soo;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1219-1221
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    • 2008
  • The Authors have demonstrated highly efficient white organic light-emitting diodes using hybrid-spacer which was inserted between each emitting layer or/and codoped blue emitting layers with the different functional material. The characteristics of WOLEDs showed the maximum external quantum efficiency of 13.8%, power efficiency of 33.66 lm/W, and Commission Internationale de I'Eclairage coordinates of (x=0.36, y=0.37), respectively.

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Controlled synthesis of mesoporous codoped titania nanoparticles and their photocatalytic activity

  • Mathis, John E.;Kidder, Michelle K.;Li, Yunchao;Zhang, Jinshui;Paranthaman, M.P.
    • Advances in nano research
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    • v.4 no.3
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    • pp.157-165
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    • 2016
  • The photocatalytic (PC) activity of anatase titania nanoparticles can be improved through codoping with transition metals and nitrogen. In addition, the PC activity can also be improved by creating monodisperse, mesoporous nanoparticles of titania. The question naturally arose as to whether combining these two characteristics would result in further improvement in the PC activity or not. Herein, we describe the synthesis and photocatalytic characteristics of codoped, monodisperse anatase titania. The transition metals tested in the polydisperse and the monodisperse forms were Mn, Co, Ni, and Cu. In each case, it was found that the monodisperse version had a higher PC activity compared to the corresponding polydisperse version.

Sintering Effect on Clamping Characteristics and Pulse Aging Behavior of ESD-Sensitive V2O5/Mn3O4/Nb2O5 Codoped Zinc Oxide Varistors

  • Nahm, Choon-Woo
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.6
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    • pp.308-311
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    • 2015
  • V2O5/Mn3O4/Nb2O5 codoped zinc oxide varistor ceramics were sintered at a temperature range as low as 875~950℃. The voltage clamping characteristics of V2O5/Mn3O4/Nb2O5 codoped zinc oxide varistor ceramics were investigated at a pulse current range of 1~50 A. The sintering temperature had a significant effect on clamp voltage ratio, which exhibits surge protection capabilities. The varistor ceramics sintered at 875℃ exhibited the best clamping characteristics, in which the clamp voltage ratio was 2.69 at a pulse current of 50 A. The varistor ceramics sintered at 900℃ exhibited the highest electrical stability, where = 3,824 V/cm (initial 3,909 V/cm), and E1 mA/cm2 = 27 (initial 39) after application of a pulse current of 100 A.

All-fiber Tm-Ho Codoped Laser Operating at 1700 nm

  • Park, Jaedeok;Ryu, Siheon;Yeom, Dong-Il
    • Current Optics and Photonics
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    • v.2 no.4
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    • pp.356-360
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    • 2018
  • We demonstrate continuous-wave operation of an all-fiber thulium-holmium codoped laser operating at a wavelength of 1706.3 nm. To realize laser operation in the short-wavelength region of the emission-band edge of thulium in silica fiber, we employ fiber Bragg gratings having resonant reflection at a wavelength around 1700 nm as a wavelength-selective mirror in an all-fiber cavity scheme. We first examine the performance of the laser by adjusting the central wavelength of the in-band pump source. Although a pump source possessing a longer wavelength is observed to provide reduced laser threshold power and increased slope efficiency, because of the characteristics of spectral response in the gain fiber, we find that the optimal pump wavelength is 1565 nm to obtain maximum laser output power for a given system. We further explore the properties of the laser by varying the fiber gain length from 1 m to 1.4 m, for the purpose of power scaling. It is revealed that the laser shows optimal performance in terms of output power and slope efficiency at a gain length of 1.3 m, where we obtain a maximum output power of 249 mW for an applied pump power of 2.1 W. A maximum slope efficiency is also estimated to be 23% under these conditions.

Implementation of High Carrier Mobility in Al-N Codoped p-Type ZnO Thin Films Fabricated by Direct Current Magnetron Sputtering with ZnO:Al2O3 Ceramic Target

  • Jin, Hujie;Xu, Bing;Park, Choon-Bae
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.4
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    • pp.169-173
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    • 2011
  • In this study, Al-N codoped p-type zinc oxide (ZnO) thin films were deposited on Si and homo-buffer layer templates in a mixture of $N_2$ and $O_2$ gas with ceramic ZnO:(2 wt% $Al_2O_3$) as a sputtering target using DC- magnetron sputtering. X-ray diffraction spectra of two-theta diffraction showed that all films have a predominant (002) peak of ZnO Wurtzite structure. As the $N_2$ fraction in the mixed $N_2$ and $O_2$ gases increased, field emission secondary electron microscopy revealed that the surface appearance of codoped films on Si varied from smooth to textured structure. The p-type ZnO thin films showed carrier concentration in the range of $1.5{\times}10^{15}-2.93{\times}10^{17}\;cm^{-3}$, resistivity in the range of 131.2-2.864 ${\Omega}cm$, and mobility in the range of $3.99-31.6\;cm^2V^{-1}s^{-1}$ respectively.

Red OLEDs containing the dotted-line doped layer structure in its emitting region.

  • Lee, Chang-Min;Han, Jeong-Whan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.612-615
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    • 2004
  • We present an extremely high efficient red organic light-emitting diodes (OLEDs) using a fluorescent dye 4-(dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB) doped into an emitting region which consists of multiple pairs of a doped and an undoped layer. An emitting region of OLEDs composes of a tris-(8-hydroxyquinolinato) aluminum (Alq3) codoped with rubrene of 5% wt. or a mixture of Alq3 and rubrene (1:1). The luminance yield of the codoped device and the mixed device are 6.5 cd/A and 9.2 cd/A at 10 mA/$cm^2$, respectively. We have considerably improved the luminance yields of red OLEDs as much as ${\sim}$90% at 10 mA/$cm^2$ compared with that of the device doped with only DCJTB. We attribute it to both the emitting assist dopant (rubrene) and the dotted-line doping structure in an emitting region of OLED.

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Synthesis and Luminescence Properties of CaS:Eu2+,Si4+,Ga3+ for a White LED

  • Oh, Sung-Il;Jeong, Yong-Kwang;Kang, Jun-Gill
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.419-422
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    • 2009
  • The luminescence intensity of calcium sulfide codoped with $Eu^{2+},\;Si^{4+}\;and\;Ga^{3+}$ was investigated as a function of the dopant concentration. An enhancement of the red luminescence resulted from the incorporation of $Si^{4+}\;and\;Ga^{3+}\;into\;CaS:Eu^{2+}.\;The\;non-codoped\;CaS:Eu^{2+}$ converted only 3.0% of the absorbed blue light into luminescence. As the $Si^{4+}\;and\;Ga^{3+}$ were embedded into the host lattice, the luminescence intensity increased and reached a maximum of Q = 10.0% at optimized concentrations of the codopants in CaS. Optimized CaS:$Eu^{2+},Si^{4+},Ga^{3+}$ phosphors were fabricated with blue GaN LED and the chromaticity index of the phosphor-formulated GaN LED was investigated as a function of the wt% of the optimized phosphor.