• Korean Chemical Engineering Research
• /
• v.50 no.3
• /
• pp.427-434
• /
• 2012

Waterborne polyurethane dispersions (PUD) were synthesized from poly (carbonate diol), isophrone diisocyanate and dimethylol propionic acid at different NCO/OH molar ratios. Subsequently, the PUD was mixed with different types of alkali metal salts ($LiClO_4$, $NaClO_4$, and $KClO_4$) to prepare antistatic waterborne polyurethane coating solutions. Effects of the types and amounts of alkali metal salts were investigated on the surface resistances of the resulting coating films. The surface resistances of coating films were decreased with increasing the amounts of alkali metal salts added in the PUD. The coating films prepared with the same amount of alkali metal salts showed increased ionic conductivity with the order of $LiClO_4$ > $NaClO_4$ > $KClO_4$. Also, the surface resistances of coating films were increased with increasing the molar ratios of NCO/OH in the PUD.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.17 no.4
• /
• pp.84-90
• /
• 2013

In this study we propose an effective method, Coating processing methods, which can improve the quality of recycled aggregate relatively easily without new equipment investment and complex treatment process and verify the improved effect using the devised method, Coating processing methods. To attain the research aim we used adequately diluted silicate solution for coating and carried out several property valuation for twelve types of material with different coating method. Also we formed concrete with coated aggregates which showed the best property. In conclusion the aggregates with the method of repeated impregnation in the silicate and drying showed the most excellent quality while other coating methods also resulted in an improvement of aggregate quality but failed to meet the KS Standard. Lastly with the optimal material we could obtain the approved compressive strength from the concrete allowing it to be utilized for road facility of which standard compressive strength of design is under 24MPa.

• Journal of Applied Reliability
• /
• v.17 no.1
• /
• pp.78-82
• /
• 2017

Purpose: The purpose of this study is to evaluate failure characteristic and mechanism of four commercial water-repellent coatings for elevated temperature machinery applications. Method: Thermal degradation was performed for up to 64 thermal cycles. 1 cycle consists of 15 minute holding at 523K under 300rpm revolution and 15 minute-natural cooling. Contact angle was measured and microstructure of the coating layer was observed by using a scanning electron microscope. Results: Four kinds of commercial repellent coating showed hydrophobic or super-hydrophobic property implying that all coatings are suitable for room temperature application. Contact angle of three kinds of commercial coatings decreased rapidly after thermal exposure, while only one specimen having hydrophobic surface showed extremely slow degradation. Conclusion: Observed decrease in contact angle of the coatings were attributed to formation of macro-sized pores and disappearance of micro-protrusion during thermal exposure. Optimum water-repellent coating needs to be selected under the consideration of initial contact angle as sell as service temperature.

• Composites Research
• /
• v.13 no.3
• /
• pp.38-47
• /
• 2000

The coating cracking on a substrate system was analyzed using a fracture mechanics approach. Multiple cracking in the bending configuration was analyzed using a variational mechanics approach to fracture mechanics of coatin $g_strate system. The strain energy release rate on bending geometry developed permits the prediction of crack growth in the coating layer on a substrate. Also, it can be used appropriately to the characterization of multiple cracking of coating. The obtained critical strain energy release rate (in-situ fracture toughness) will be a material property of coating and it will provide a better insight into coating cracking.ng.

• Tribology and Lubricants
• /
• v.13 no.4
• /
• pp.66-70
• /
• 1997

Thin films and coating technologies are used for an enormous and diverse set of application including mechanical and automotive components. Many of these applications require the various properties which can be used for decreasing wear, friction and cost, and increasing the long life. The relationship between the load and the stress is usually nonlinear. The material is often apt to deform plastically under the low loads. Numerical method may be used for some simple problems of the coating. If the property of coating and base materials are inhomogeneous and the geometry is complex, the numerical method may be recommended. In this paper, the contact normal stress of the coating layer has been solved using finite element method.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2006.05a
• /
• pp.308-313
• /
• 2006

The effect of coating time on surface properties of the TiN-coated high speed steel(SKH51) by arc ion plating is and presented in this paper. Surface roughness, micro-hardness, coated thickness, atomic distribution of TiN and adhesion strength are measured for various coating times. It has been shown that the coating time has a deep influence more than 60 minites on the micro-hardness, coated thickness, atomic distribution of Ti and adhesion strength of the SKH51 steels, but that the coating time has little influence on the surface roughness.

• Journal of Powder Materials
• /
• v.24 no.6
• /
• pp.457-463
• /
• 2017

Nanosized $Gd_2O_3:Eu^{3+}$ red phosphor is prepared using a template method from metal salt impregnated into a crystalline cellulose and is dispersed using a bead mill wet process. The driving force of the surface coating between $Gd_2O_3:Eu^{3+}$ and mica is induced by the Coulomb force. The red phosphor nanosol is effectively coated on mica flakes by the electrostatic interaction between positively charged $Gd_2O_3:Eu^{3+}$ and negatively charged mica above pH 6. To prepare $Gd_2O_3:Eu^{3+}$-coated mica ($Gd_2O_3:Eu/mica$), the coating conditions are optimized, including the stirring temperature, pH, calcination temperature, and coating amount (wt%) of $Gd_2O_3:Eu^{3+}$. In spite of the low luminescence of the $Gd_2O_3:Eu/mica$, the luminescent property is recovered after calcination above $600^{\circ}C$ and is enhanced by increasing the $Gd_2O_3:Eu^{3+}$ coating amount. The $Gd_2O_3:Eu/mica$ is characterized using X-ray diffraction, field emission scanning electron microscopy, zeta potential measurements, and fluorescence spectrometer analysis.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2007.11a
• /
• pp.339-339
• /
• 2007

Metal coating on ceramic powder has long been attracting interest for various applications such as superconductor where the brittle nature of high temperature ceramic superconductor was complemented by silver coating and metalloceramics where mechanical property improvement was achieved via electroless plating. More recently it has become of great interest in embedded passive device applications since metal coating on ceramic particles may result in the enhancement of the dielectric properties of ceramic-polymer composite capacitors. In our study, nickel ion-containing solution was used for coating commercial capacitor-grade $BaTiO_3$ powder. After filtering process, the powder was dried and heat-treated in 5% forming gas at $900^{\circ}C$. XRD and TEM were utilized for the observation of crystallization behavior and morphology of the particles. It was found that the nickel coating characteristics were strongly dependent on the several parameters and processing variables, such as starting $BaTiO_3$ particle size, nickel source, solution chemistry, coating temperature and time. In this paper, the effects of these variables on the coating characteristics will be presented in some detail.

• Tribology and Lubricants
• /
• v.25 no.1
• /
• pp.7-12
• /
• 2009

Coating brittle intermetallic compounds on metal can enlarge the range of their use. It is found that intermetallic compound coating layers made by only combustion synthesis in an electric furnace have porous multi-phase structures containing several intermediate phases, even though the coating layers show good wear resistance. In this study, dense $Ni_{3}Al$ single phase layer corresponding to the initial composition of the mixed powder is coated on two different ferrous materials by the diffusing treatment after combustion synthesis. After- ward, sliding wear behaviors of the coating layer are evaluated in comparison with that of the coating layer with porous multi-phase structure made by only combustion synthesis. As a result, the wear properties of the coating layer composed of dense $Ni_{3}Al$ single phase are considerably improved at the range of low sliding speed com- pared with that of the coating layer with porous multi-phase structure, particularly in the running-in wear region. This is attributed to the fact that wear of the coating layer is progressed by shearing as a sequence of adhesion, not by occurring of pitting on the worn surface due to having dense structure without pores.

• Fibers and Polymers
• /
• v.2 no.3
• /
• pp.148-152
• /
• 2001

Cotton yarns were coated with a polymer solution to hold surface fibers to the yam body, which caused fiber-fly generation during knitting process. The physical property of the coated yarn, especially a bending rigidity was investigated in order to evaluate the performance of the coated yam during knitting. SEM images showing the surface condition of the coated yarn demonstrated that the thickness of a coating material increased as the concentration of the coating solution increased. The results of the bending rigidity measured using KES-FB2 system showed that the bending rigidity of the coated yam increased as the concentration of the coating solution increased. The results also revealed the possibility that yarn coated with a low amount of coating material should be employed for further research of reducing fiber-fly generation during knitting process.