• Title/Summary/Keyword: coating layer

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Study on the Spraying Parameters of a Plasma-sprayed Hydroxyapatite Coating (플라즈마 용사법에 의한 Hydroxyapatite 코팅의 용사조건에 관한 연구)

  • 여인웅;안효석
    • Journal of the Korean Ceramic Society
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    • v.36 no.4
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    • pp.444-450
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    • 1999
  • Hydroxyapatite(HA) was spray-coated to alloy substrate(Ti-6Al-4V) using plasma-spray process for bioceramic application The coating morphology composition and crystallinity were influenced by following process parameters ; stand-off distance spray power level and auxiliary gas pressure. These parameters have been systematically varied in the present study to evaluate their relative influence on the coating qual-ity and to seek an optimum spraying condition. Amorphicity and decomposition of HA increased with stand-off distance and the imperfect coating layer was obtained at the short stant-off distance (55mm). The cry-stallinity of HA coating decreased with spray power level and auxiliary gas pressure but the bond strength between the HA coated layer and Ti alloy substrate increased with the spray power level.

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Development and Oxidation Resistance of B-doped Silicide Coatings on Nb-based Alloy

  • Li, Xiaoxia;Zhou, Chungen
    • Corrosion Science and Technology
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    • v.7 no.4
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    • pp.233-236
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    • 2008
  • Halide-activated pack cementation was utilized to deposit B-doped silicide coating. The pack powders were consisted of $3Wt.c/oNH_4Cl$, 7Wt.c/oSi, $90Wt.c/oAl_2O_3+TiB_2$. B-doped silicide coating was consisted of two layers, an outer layer of $NbSi_2$ and an inner layer of $Nb_5Si_3$. Isothermal oxidation resistance of B-doped silicide coating was tested at $1250^{\circ}C$ in static air. B-doped silicide coating had excellent oxidation resistance, because continuous $SiO_2$ scale which serves as obstacle of oxygen diffusion was formed after oxidation.

A Study of the High Sensitive Nonsilver Halide Imaging Material( II ) - Study of the aqueous coating mechanism and washing effect of the CGL in the $\varepsilon$-CuPc/PVK double-layered organic photoconductor - (고감도 비은염 화상재료 개발연구 ( II ) - Copper Phthalocyanine/PVK 전자사진감광체의 CGL의 수성 coating mechanism과 세정효과에 관한 연구 -)

  • 이상남
    • Journal of the Korean Graphic Arts Communication Society
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    • v.9 no.1
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    • pp.27-44
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    • 1991
  • In this research, double-layered photoconductor consist of the carrier generation layer(CGL) of ${\varepsilon}$ type copper phthalocyanine thin film by an aqueous coating method and the carrier transport layer(CGL) of polyvinyl carbazol(PVK) by spin coating. We inverstigated effect of the surfactant solution and cathod electrolysis to the crystal type of ${\varepsilon}$-CuPc in CGL with TEM, SEM and X-ray diffraction spectroscopy and studied the mechanism of an aqueous coating for the preparation of CGL. The effect of the washing of CGL about the electrophotographic characteristics of the ${\varepsilon}$-CUPC/PVK double-layered photoconductors is studied also.

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The relation of TiN coating condition of end-mill and cutting force increase rate (엔드밀의 TiN 코팅조건과 절삭력 증가율과의 관계)

  • 최석우;이위로;최광진;백영남
    • Journal of the Korean institute of surface engineering
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    • v.34 no.4
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    • pp.337-341
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    • 2001
  • TiN coating of high speed end mill is recently generalized. The study of coating layer using ion plating is mainly about the coating method and the why of the longer life of coated tools. In CNC machning process, metal cutting isn't carry out until the tools including the end-mill and so on are fractured. Namely, it is difficult precision processing when the cutting force of the cutting tool is near the limit the fracture cutting force. So, the estimate of the life by wear and fracture is important. Therefore, this study is about the method to estimate the capacity of the coating layer in relation to the tendency of cutting force and the influence of the cutting capacity of coated end-mill by the condition N2, Ar, temperature. The cutting length is in inverse proportion to the cutting force ratio. So, the life of the TiN coated end mill can be predicated by the ratio of the increase of the cutting force.

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The Effect of Oxide Layer Formed on TiN Coated Ball and Steel Disk on Friction Characteristics in Various Sliding Conditions (미끄럼조건에 따라 TiN 코팅볼과 스틸디스크에 형성되는 산화막이 마찰특성에 미치는 영향)

  • 조정우;이영제
    • Tribology and Lubricants
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    • v.17 no.6
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    • pp.459-466
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    • 2001
  • In this study, the effects of oxide layer formed on the contact parts of TiN coated ball and steel disk on friction characteristics in various sliding conditions were investigated. AISI52100 steel ball was used for the substrate of coated ball specimens, which were prepared by depositing TiN coating with 1(m in coating thickness. AISI1045 steel was used for the disk type counter-body. To investigate the effect of oxide layer on the contact parts of two materials, the tests were performed both in air for forming oxide layer on the contact parts and in nitrogen environment to avoid oxidation. From the test results, the frictional characteristic between the two materials was predominated by iron oxide layer that formed on wear tract of counter-body and this layer caused friction transition and high friction. And the adhesive wear occurred from steel disk to TiN coated ball caused the formation of oxide layer on counter parts between the two materials.

Bending Displace Improvement of Electro-active Paper Using Conductive Polyaniline Coating (전도성 폴리아닐린(Polyaniline)을 이용한 전기작동 종이(EAPap)의 굽힘변형 개선)

  • Kim, Joo-Hyung;Yun, Sung-Yuel;Kim, Jae-Hwan
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.18 no.12
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    • pp.1310-1316
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    • 2008
  • Bi-layer and tri-layer structures of electro-active paper(EAPap) using conductive polyaniline(PANI) coating were investigated to improve bending displacement of cellulose EAPap. Two different counter ions, perchlorate($CIO_4^-$) and tetrafluoroborate($BF_4^-$), are used as dopant ions in the PANI processing. The actuation performances of hi-layer and tri-layer structure are evaluated in terms of tip displacement, blocked force, strain energy density and power output density. The actuation performance of the tri-layer actuator was better than the hi-layer structure, and the maximum displacement and blocked force of tri-layer $CIO_4^-$ doped-PANI-EAPap were 13.2 mm and 0.15 mN, respectively. Also the power output of the actuator is similar to the required power of biological muscle application.

On Formation of Residual Carbon Layer in CuInSe2 Thin Films Formed via direct Solution Coating Process (직접 용액 코팅법에 의해 제조한 CuInSe2 에 잔존하는 탄소 불순물층 형성에 관한 연구)

  • Ahn, SeJin;Rehan, Shanza;Eo, Young-Joo;Gwak, Jihye;Yoon, Kyunghoon;Cho, Ara
    • Current Photovoltaic Research
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    • v.2 no.1
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    • pp.36-39
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    • 2014
  • Formation mechanism of residual carbon layer, frequently observed in the $CuInSe_2$ (CIS) thin film prepared by direct solution coating routes, was investigated in order to find a way to eliminate it. As a model system, a methanol solution with dissolved Cu and In salts, whose viscosity was adjusted by adding ethylcellulose (EC), was chosen. It was found that a double layer, a top metal ion-derived film and bottom EC-derived layer, formed during an air drying step presumably due to different solubility between metal salts and EC in methanol. Consequently, the top metal ion-derived film acts as a barrier layer inhibiting further thermal decomposition of underlying EC, resulting a formation of bottom carbon residue layer.

Effects of surface characteristics of electrolytic tinplate on frictional properties during ironing operaration of 2-piece can-making process (전기주석도금강판의 표면특성이 투피스캔 제관공정의 아이어닝 가공시 마찰특성에 미치는 영향)

  • 김태엽
    • Journal of the Korean institute of surface engineering
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    • v.30 no.3
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    • pp.191-201
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    • 1997
  • Non-passivated electrolytic tinplates withour conventinal chemical treatment self-oxidize in ambient atmosphere to from yellow stain on the outermost surface during the long-term storage. The degree of yellowness of the stain increased linerly with the oxide thickness due to the interfeefence color of the $SnO_2$ Even though the thickness of the oxide layer was very thin, less than 100$\AA$ , it exerts an undesirable influence on the can-making processes, particularly the stripping behavior after ironing. Investigations were carried out on the morphologies of the coating layer, the changes in oxide thickness during successive can-making processes and the averge friction coefficients with the different oxide thinkness. These oxide layers were broken up and distributed within the bulk tin coating during the ironing process. This redistribution of the oxide layer prvented smooth pressing-aside of the tin coating layer, resulting in an increase in the ironing friction coefficient. As the friction was increased, the residual stress along the can wall thinkness(i.e., the hoop stress) was also increased. Due to both the oxibe layer accumulation, which increased the friction coefficient, and the hoop stress, can stripping efficiency without roll-back is reduced.

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Effect of Al2O3-ZrO2 Composite Oxide Thickness on Electrical Properties of Etched Al Foil

  • Chen, Fei;Park, Sang-Shik
    • Korean Journal of Materials Research
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    • v.26 no.3
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    • pp.160-165
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    • 2016
  • To increase the capacitance of an Al electrolytic capacitor, the anodic oxide film, $Al_2O_3$, was partly replaced by an $Al_2O_3-ZrO_2$ (Al-Zr) composite film prepared by the vacuum infiltration method and anodization. The microstructure and composition of the prepared samples were investigated by scanning electron microscopy and transmission electron microscopy. The coated and anodized samples showed multi-layer structures, which consisted of an inner Al hydrate layer, a middle Al-Zr composite layer, and an outer $Al_2O_3$ layer. The thickness of the coating layer could go up to 220 nm when the etched Al foil was coated 8 times. The electrical properties of the samples, such as specific capacitance, leakage current, and withstanding voltages, were also characterized after anodization at 100 V and 600 V. The capacitances of samples with $ZrO_2$ coating were 36.3% and 27.5% higher than those of samples without $ZrO_2$ coating when anodized at 100 V and 600 V, respectively.

THE EFFECT OF SI-RICH LAYER COATING ON U-MO VS. AL INTERDIFFUSION

  • Ryu, Ho-Jin;Park, Jae-Soon;Park, Jong-Man;Kim, Chang-Kyu
    • Nuclear Engineering and Technology
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    • v.43 no.2
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    • pp.159-166
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    • 2011
  • Si-rich-layer-coated U-7 wt%Mo plates were prepared in order to evaluate the diffusion barrier performance of the Si-rich layer in U-Mo vs. Al interdiffusion. Pure Si powder was used for coating the U-Mo plates by annealing at $900^{\circ}C$ for 1 h under vacuum of approximately 1 Pa. Si-rich layers containing more than 60 at% of Si were formed on U-7 wt%Mo plates. Diffusion couple tests were conducted in a muffle furnace at $560-600^{\circ}C$ under vacuum using Si-rich-layer-coated U-Mo plates and pure Al plates. Diffusion couple tests using uncoated U-Mo plates and Al-(0, 2 or 5 wt%)Si plates were also conducted for comparison. Si-rich-layer coatings were more effective in suppressing the interaction during diffusion couple tests between coated U-Mo plate and Al, when compared with U-Mo vs. Al-Si diffusion couples, since only small amounts of Al in the coating could be found after the diffusion couple tests. Si-rich-layer-coated U-7wt%Mo particles were also prepared using the same technique for U-7 wt%Mo plates to observe the microsturctures of the coated particles.