• 멤브레인
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• 제31권1호
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• pp.80-85
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• 2021

본 논문에서는 ~1.5 ㎛의 기공 크기를 가지는 고투과도 알파 알루미나 지지체 위에 도포된 서스펜션의 증발유도 자기조립 현상을 이용하여 중간층을 형성하는 새로운 코팅 방식을 소개한다. 새로운 코팅 방법으로 만들어진 중간층은 일반적으로 사용되는 담지법으로 코팅된 중간층과 비교하여 표면거칠기와 불균일도가 낮아 코팅에 적합하였다. 복합막 지지체로서의 평가를 위해 제조된 지지체는 감마 알루미나 복합막 제조에 사용되었다. 메조 기공을 가지는 감마 알루미나 복합막은 반복코팅 없이도 매크로 기공 크기의 결함이 존재하지 않았으며 일반적으로 널리 사용되는 100~200 nm의 기공 크기를 가지는 지지체로부터 만들어진 같은 두께의 복합막과 비교하여 2.3배 이상의 높은 질소투과도를 보였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2009년도 제40회 하계학술대회
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• pp.1258_1259
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• 2009

염료감응형 태양전지 (dye-sensitized solar cell; DSC)는 경제성 한계에 달한 Si 태양전지를 대체할 수 있는 유력한 후보로서, 지금까지 많은 연구개발로 큰 효율향상을 기록했다. 다양한 연구 분야 중에서도, 투명전도성 막과 전해질 층간의 접촉으로 발생하는 전자의 재결합을 막기 위해 삽입하는 compact layer는 ZnO dip-coating, $TiCl_4$ dip-coating, Ti sputtering 등 다양한 제조방법이 제시되었다. 본 연구에서는 $TiCl_4$ 용액을 이용해 spin-coating 방법으로 $TiO_2$ compact layer를 제조하는 시도를 했다. 기존 dip-coating 방법과의 비교를 통해서 본 연구의 spin-coating 방법에 의한 효과를 확인한 결과, standard DSC 대비 33.4%, dip-coating 방법으로 compact layer를 삽입한 DSC 대비 6%의 효율 향상을 기록했다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.57-60
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• 2009

The conductive coating method was used for a various industrial fields. For example, Sputtering process is using to a coat of ITO layer in LCD or OLED panel manufacture process and fabricate a base layer of substrate of an electric printing device. However, conventional coating process (beam sputtering, spin coating etc.) has a problems in the industrial manufacturing process. These processes have a very high cost and critical manufacturing environment as a vacuum process. Recently, many researchers were proposed a various printing process instead of conventional coating process. In this paper, we propose an ESD printing process in ITO coating layer and apply to fabricate a conductive coating film. Ours transparent electrode had a surface resistance of about $66{\Omega}/{\square}$ and transparent of 74% in the wavelength of 500nm. This transparent electrode manufacturing process will be applied to Roll-to-Roll process. In addition, we developed roll printing process system for the next generation flexible solar cell.

• Journal of Welding and Joining
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• 제14권6호
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• pp.101-108
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• 1996

In this study, WC-l7wt% Co composite powder for thermal spray was fabricated by spray drying method. The agglomerated composite powder had spheroidal morphology and the particle size distribution was 20~60${\mu}{\textrm}{m}$. WC and Co were distributed homogeneously. However, the strength of the spray-dried agglomerate was low due to the pores within the agglomerate. Therefore, the spray-dried agglomerate was broken down during HVOF thermal spray and the microstructure was inhomogeneous with many pores within the coating layer. And the decomposition of WC to W and $W_{6}$ $C_{2.54}$ was accelerated. The strength and flowability of the agglomerate were greatly improved by sintering heat treatment(110$0^{\circ}C$, 1 hour, hi atmosphere), and then the coating layer showed dense and homogeneous microstructure with well-developed splats. The hardness of the coating layer was H $v_{300}$ = 1072.2.2.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 1996년도 제24회 추계학술대회
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• pp.183-188
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• 1996

Films and coatings are used for an enormous and diverse set of applications including mechanical, electronic and optical devices, protection at high temperature, cutting tools enhancement and automotive use. Many of these applications require the various properties associated with inorganic and metallic / non-metallic materials; i.e., with ceramics. Therefore, a large number of coatings have been developed and used for a long time in the various fields, especially in mechanical one. As one of the mutual surface actions, the problems of contact stresses are complex. The relationship between load and stress are nonlinear. Besides, the material is often apt to deform plastically under low load. However, analytical solutions exist only for some simple problems. If a material has a complicated shape or inhomogeneous properties, numerical method must be used. In this paper, the analysis of the contact stress of the coating layer was solved, using the finite element method.

• 동력기계공학회지
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• 제8권4호
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• pp.38-43
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• 2004

Thermal spraying onto the metal substrate has been widely used as a technique of the surface treatment in the various industrial field. A wide range of thermal spray technologies exist and all rely on the fundamental process of fusing a metal feedstock, atomizing it and transporting it to the surface of a substrate. Specially, these methods have been taken into account as the protection method against the corrosion. In this study, the polarization characteristics were carried out on the thermal sprayed coating layer immersed in various pH of diluted aqueous solutions at $25^{\circ}C$. Aluminum, Zinc, Ni-base alloy, alumina and polyethylene powder were used with sprayed coating materials. From the polarization curves, the electrochemical corrosion potential($E_{corr}$) and the corrosion current density($I_{corr}$) were investigated.

• 한국세라믹학회지
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• 제54권6호
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• pp.525-529
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• 2017

To improve the thermal resistance of a porous borosilicate lining block, we prepared and applied polysiloxane-fumed silica-ethanol slurry on top of the block and fired the coating layer using a torch for 5 minutes at $800^{\circ}C$. We conducted magnified characterizations using a microscope and XRD analysis to observe phase transformations, and TGA-DTA analysis to determine the thermal resistance. Thermal characterizations showed improved heat resistance with relatively high polysiloxane content slurry. Cross-sectional optical microscope observation showed less melting near the surface and decreased pore formation area with higher polysiloxane content slurry. XRD analysis revealed that the block and coating layer were amorphous phases. TGA-DTA analysis showed an endothermic reaction at around $550^{\circ}C$ as the polysiloxane in the coating layer reacted to form SiOC. Therefore, coating polysiloxane on a borosilicate block contributes to preventing the melting of the block at temperatures above $800^{\circ}C$.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2000년도 제32회 추계학술대회 정기총회
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• pp.80-88
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• 2000

The plasma spray technics has known as one of the surface modification methods to improve the mechenical properties or the functional charactristics of materials. This paper has been aimed to investigate the effects of plasma sprayed conditions, such as spray distance and arc power level, on sliding wear properties of plasma sprayed $Al_2$O$_3$-40%TiO$_2$coating layer. The sliding wear test using pin-on-disc type wear machine, has been conducted in several sliding speed for coating layer sparyed under different conditions. The result of this paper is that the wear resistance of plasma sprayed $Al_2$O$_3$-40%TiO$_2$coating layer is fluctuated with tile spray distance and the arc power level. The wear resiatance could be improved with decreasing the spray distance and with increasing the arc power level.

• Korean Chemical Engineering Research
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• 제55권4호
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• pp.483-489
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• 2017

The loss of the sulfur cathode material through dissolution of the polysulfide into electrolyte causes a significant capacity reduction of the lithium-sulfur cell during the charge-discharge reaction, thereby debilitating the electrochemical performance of the cell. We addressed this problem by using a chemical and physical approach called reduction of polysulfide dissolution through direct coating functional inorganic (graphene oxide) or organic layer (polyethylene oxide) on electrode, since the deposition of external functional layer can chemically interact with polysulfide and physically prevent the leakage of lithium polysulfide out of the electrode. Through this approach, we obtained a composite electrode for a lithium-sulfur battery (sulfur: 60%) coated with uniform and thin external functional layers where the thin external layer was coated on the electrode by solution coating and drying by a subsequent heat treatment at low temperature (${\sim}80^{\circ}C$). The external functional layer, such as inorganic or organic layer, not only alleviates the dissolution of the polysulfide electrolyte during the charging/discharging through physical layer formation, but also makes a chemical interaction between the polysulfide and the functional layer. As-formed lithium-sulfur battery exhibits stable cycling electrochemical performance during charging and discharging at a reversible capacity of 700~1187 mAh/g at 0.1 C (1 C = 1675 mA/g) for 30 cycles or more.

• 한국세라믹학회지
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• 제34권12호
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• pp.1268-1274
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• 1997

Effect of elastic/plastic mismatch on the fracture of Si3N4 coating in Si3N4/Si3N4 -BN bilayer was investigated by Hertzian indentation testing. A different amount of mismatch between two layers was induced by different BN addition in the substrate layer, and Hertizian cracks were induced by using WC ball indenter. As a result, as the elastic/plastic mismatch between coating and substrate layer increased, the coating fracture easily occurred. A bending stress induced by different elastic/plastic mismatch was main reason to cause the fracture of coating.