• Title/Summary/Keyword: co-agent

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Effect of Plating Condition and Surface on Electroless Co-Cu-P Alloy Plating Rate (무전해 Co-Cu-P 도금속도에 미치는 도금 조건과 표면상태의 영향)

  • Oh, L.S.
    • Journal of Power System Engineering
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    • v.4 no.2
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    • pp.31-39
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    • 2000
  • Relationships between the plating condition and the plating rate of the deposition film for the electroless plating of Co-Cu-P alloy were discussed in this report. The result obtained from this experiment were summarized as follow ; The optimum bath composition was consisted of 0.8 ppm thiourea as a stabilizing agent. Composition of the deposit was found to be uniform after two hours of electroless plating. Plating rates of nickel-catalytic surface and zincate-catalytic surface were found to be very closely equal, but the plating time of nickel-catalytic surface took longer than that of the zincated-catalytic surface.

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Analysis of cyanide free electroless Au plating solution by capillary elecrophoresis (캐피라리 전기 영동법에 의한 비시안 무전해 Au 도금액의 분석)

  • Han, Jaeho;Kim, DongHyun
    • Journal of the Korean institute of surface engineering
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    • v.55 no.2
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    • pp.120-132
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    • 2022
  • In the non-cyanide-based electroless Au plating solution using thiomalic acid as a complexing agent and aminoethanethiol as a reducing agent, analysis of each component constituting the plating solution is essential for the analysis of the reaction mechanism. And component analysis in the plating solution is important for monitoring component changes in the plating process and optimizing the management method. Capillary Electrophoresis (CE) method is rapid, sensitive and quantitative and could be readily applied to analysis of Aun+ ion, complexing agent and reducing agent in electroless Au plating solution. In this study, the capillary electrophoresis method was used to analyze each component in the electroless Au plating solution in order to elucidate the complex bonding form and the plating mechanism of the non-cyanide-based electroless Au plating bath. The purpose of this study was to establish data for optimizing the monitoring and management method of plating solution components to improve the uniformity of precipitation and stability. As a result, it was confirmed that the analysis of thiomalic acid as a complexing agent and Aun+ ions and the analysis of aminoethanethiol as a reducing agent were possible by capillary electrophoresis. In the newly developed non-cyanide-based electroless Au plating solution, it was confirmed that Aun+ ions exist in the form of Au+ having a charge of +1, and that thiomalic acid and Au+ are combined in a molar ratio of 2 : 1. In addition, it was confirmed that aminoethanethiol can form a complex by combining with Au+ ions depending on conditions as well as acting as a reducing agent.

A Technical Description on The Safety Aspects related To Gas Suppression Fire Protection System (가스계 소화시스템관련 안전기술)

  • 이창욱
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2002.05a
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    • pp.21-29
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    • 2002
  • With regard to the personnel safety and other safety when the gas suppressants are discharged into the area where occupants exist, the short term and long term effects to the health of people are discussed mainly with the Carbon dioxide agent and Halon Replacement agents system. To gain the benefits of CO2 extinguishing systems while minimizing risk to people serious attention must be given to personnel safety in the design, installation, and maintenance of CO2 systems. Training of personnel is essential. A major factor in the use of a clean agent fire suppressant in a normally occupied area is toxicity. While all halocarbon agents are tested for long-term health hazards, the primary endpoint is acute or short-term exposure, The primary acute toxicity effects of the halocarbon agents described here are anesthesia and cardiac sensitization. For inert gases, the primary physiological concern is reduced oxygen concentration.

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Effects on Electrochemical Performances of Conducting Agents for Lithium-ion Batteries (리튬이온전지용 Conducting Agents의 전기화학적 성능에 미치는 영향)

  • Lee, Chang-Woo;Lee, Mi-Sook;Moon, Seong-In;Kim, Young-Gyu;Kim, Byung-Hwa;Kim, Dong-Hoon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.593-594
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    • 2005
  • Lithium-ion batteries have used the layered $LiCoO_2$ materials as cathodes, but Co is relatively toxic and expensive. In this regard, the spinel $LiMn_2O_4$ has become appealing because manganese is inexpensive and environmentally benign. In general, cathodes for lithium ion batteries include carbon as a conductive agent that provides electron transfer between the active material and the current collector. In this work, we selected Acetylene Black and Super P Black as conducting agents, and then carried out comparative investigation for the performances of the cells using different conducting agents with different particle size. As a consequence, Li/$LiMn_2O_4$ cells with Super P Black show better electrochemical performances than those with Acetylene Black.

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Construction of Environmentally Friendly Roadbed by Reinforecing Type Soil Solidification Agent (보강형 고화제를 이용한 친환경 도로노반조성 방안)

  • Koh, Yong-Kook
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.667-671
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    • 2004
  • The purpose of this paper is to study on the construction of environmentally friendly roadbed by reinforcing type soil solidification agent. The soil amendment agent used in this study is friendly to the environment, and has a function of soil-cement-agent solidification. The soil amendment agent was admixed with reinforced fiber material for enhancement of strength and durability of roadbed. The project of trial field test of roadbed construction with special reinforcing soil treatment agent was performed in Gyunggido on December 2003. A series of field and laboratory experiments including unconfined compressive strength, permeability were carried out to investigate the physical and mechanical characteristics of solidified roadbed treated by this reinforced solidifying agent. The results of this research showed that the roadbed using normal and poor soil could be efficiently constructed by treatment of this reinforcing type solidification agent admixed with fiber material.

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The Dose Effect of Stabilizing Agent on Stabilization of Heavy Metals in Soil (안정화제 주입량에 따른 중금속 오염토양의 안정화 분석)

  • Choi, Hee-Chul;Yoon, Yi-Joon;Lee, Byung-yong;Choi, Sang-il
    • Journal of Soil and Groundwater Environment
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    • v.25 no.4
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    • pp.7-13
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    • 2020
  • In this study, a stabilization method was applied to stabilize heavy metals in soils collected from a domestic contaminated area and a Canadian mine site. The stabilizing agent used in the experiment was a solidifying agent developed by KERT Co., Ltd., Korea. The agent was applied to the samples at varying weight ratios of 0, 2, 5, 7, and 10% (w/w). and the concentrations of heavy metals in the effluent were monitored at predetemined time intervals. The results indicated that the stabilization efficiency of heavy metals (Cd, Cu, Pb) increased proportionally until the agent was increased to 5%, which showed almost no leaching of heavy metals after 28 days after agent application. Therefore, addition of 5% relative to soil mass was proposed to be the optimum dose for the stabilization agent.

Velume Phase Transition of Poly (N-isopropylacrylamide-co-sodium methacrylate) Hydrogel Crosslinked with Poly(ethylene glycol) diacrylate (Poly(ethylene glyco1) diacrylate로 가교된 Poly(N-isopropylacrylamide) Hydrogel의 부피 상전이 특성)

  • 김선아;한영아;손성옥;지병철
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.653-660
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    • 2002
  • The volume phase transition of poly(N-isopropylacrylamide) (PNIPAAm) and poly (N-isopropylacrylamide-co-sodium methacrylate) (P (NIPAAm-co-SMA)) hydrogels crosslinked with poly (ethylene glycol) diacrylate (PEGDA) was investigated in consideration of water content and surface area. The volume phase transition temperature of hydrogel was not affected by the concentration of crosslinking agent, which increased over 40$\^{C}$ by incorporating a small amount of SMA. Higher volume phase transition temperature was obtained when PEGAD was used as a crosslinking agent, suggesting that the chain length of crosslinking agent had a significant effect on the volume phase transition temperature. The surface area of PNIPAAm and P (NIPAAm-co-SMA) gels fell off around the volume phase transition temperature, resulting from the fact that the size of pores reduced remarkably in the course of the volume phase transition. Hence, the surface area and the pore size were considered to be important factors indicating the volume phase transition.

The Adsorption Properties of Heavy Metal Ions on to Cotton Fabrics Treated with Reactive Anionic Agent (반응형 음이온화제 처리 면직물에 대한 중금속 이온의 흡착특성)

  • Kim Mi-Kyung;Yoon Seok-Han;Kim Tae-Kyeong;Lim Yong-Jin
    • Textile Coloration and Finishing
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    • v.17 no.1
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    • pp.20-29
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    • 2005
  • Cotton fabric was treated with a reactive anionic agent in order to have anionic sites(-S03-) on it, which made it possible for the fabric to adsorb various cationic materials. In this study, the adsorptivity of various heavy metal ions such as Pb(II), Cd(II), Cr(III), Co(II), Cu(II), Ni (II) and Cr(VI) on the cotton fabrics treated with anionic agent was examined at the various conditions; concentrations of heavy metal ions, pHs of solution, reaction time and temperature. As a result, the adsorptivity of the heavy metal ions on the cotton fabrics treated with the anionic agent was highly increased comparing to that of untreated cotton fabrics. The order of the adsorptivity was as follows: $Pb(II)>Cd(II)>Cu(II)\geqNi(II)\geqCo(II)>Cr(III)\ggCr(VI)$. The adsorption amounts of most heavy metal ions were increased in weak alkaline conditions and were reached to an adsorption equilibrium within 10 ~ 30 minutes. The maximum adsorption ratios of Pb(II) and Cd(II) were respectively 99% and 80% of the initial concentration of heavy metal ions. Therefore the anionized cotton fabrics seem to be utilized as an adsorption fabrics for the removal of heavy metal ions in the waste water.

Preparation of the Nano Cobalt Powder by Wet Chemical Reduction Method (액상환원공정을 이용한 나노 코발트 분말의 합성)

  • Hong, Hyun-Seon;Ko, Young-Dae;Kang, Lee-Seung;Kim, Geon-Hong;Jung, Hang-Chul
    • Journal of Powder Materials
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    • v.18 no.3
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    • pp.244-249
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    • 2011
  • Spherical nanosized cobalt powder with an average size of 150-400 nm was successfully prepared at room temperature from cobalt sulfate heptahydrate ($CoSO_4{\cdot}7H_2O$). Wet chemical reduction method was adopted to synthesize nano cobalt powder and hypophosphorous acid ($H_3PO_2$) was used as reduction agent. Both the HCP and the FCC Co phase were developed while $CoSO_4{\cdot}7H_2O$ concentration ranged from 0.7 M to 1.1 M. Secondary phase such as $Co(OH)_2$ and $CO_3O_4$ were also observed. Peaks for the crystalline Co phase having HCP and FCC structure crystallized as increasing the concentration of $H_3PO_2$, indicating that the amount of reduction agent was enough to reduce $Co(OH)_2$. Consequently, a homogeneous Co phase could be developed without second phase when the $H_3PO_2/CoSO_4{\cdot}7H_2O$ ratio exceeded 7.