• Title/Summary/Keyword: chlorine treatment

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Factors Affecting the Formation of Iodo-Trihalomethanes during Chlorination in Drinking Water Treatment (정수처리에서 염소 처리시 요오드계 트리할로메탄류 생성에 영향을 미치는 인자들)

  • Son, Hee-Jong;Yoom, Hoon-Sik;Kim, Kyung-A;Song, Mi-Jeong;Choi, Jin-Taek
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.8
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    • pp.542-548
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    • 2014
  • Effects of bromide ($Br^-$) and iodide ($I^-$) concentrations, chlorine ($Cl_2$) doses, pH, temperature, ammonia nitrogen concentrations, reaction times and water characteristics on formation of iodinated trihalomethanes (I-THMs) during oxidation of iodide containing water with chlorine were investigated in this study. Results showed that the yields of I-THMs increased with the high bromide and iodide level during chlorination. The elevated pH significantly increased the yields of I-THMs during chlorination. The formation of I-THMs was higher at $20^{\circ}C$ than $4^{\circ}C$, $10^{\circ}C$ and $30^{\circ}C$. In chloramination study, addition of ammonium chloride ($NH_4Cl$) markedly increased the formation of I-THMs. Among the water samples collected from seven water sources including wastewater treatment plant (WWTP) effluent water (EfOM water), prepared humic containing water (HA water) and algal organic matter (AOM) containing water (AOM water), EfOM water generated the highest yields of I-THMs ($12.31{\mu}g/mg$ DOC), followed by HA water ($4.96{\mu}g/mg$ DOC), while AOM water produced the lowest yields of I-THMs ($0.99{\mu}g/mg$ DOC). $SUVA_{254}$ values of EfOM water, HA water and AOM water were $1.38L/mg{\cdot}m$, $4.96L/mg{\cdot}m$ and $0.97L/mg{\cdot}m$, respectively. The I-THMs yields had a low correlation with $SUVA_{254}$ values ($r^2$ = 0.002).

Comparison of Biofilm Formed on Stainless Steel and Copper Pipe Through the Each Process of Water Treatment Plant (정수처리 공정 단계별 스테인리스관과 동관에 형성된 생물막 비교)

  • Kim, Geun-Su;Min, Byung-Dae;Park, Su-Jeong;Oh, Jung-Hwan;Cho, Ik-Hwan;Jang, Seok-Jea;Kim, Ji-Hae;Park, Sang-Min;Park, Ju-Hyun;Chung, Hyen-Mi;Ahn, Tae-Young;Jheong, Weonhwa
    • Korean Journal of Microbiology
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    • v.49 no.4
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    • pp.313-320
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    • 2013
  • Biofilm formed on stainless and copper in water treatment plant was investigated for sixteen weeks. Biofilm reactor was specially designed for this study. It was similar to that of a real distribution pipe. Raw water, coagulated, settled, filtered and treated water were used in this study. The average number of heterotrophic bacteria counts was $1.6{\times}10^4CFU/ml$, $5.8{\times}10^3CFU/ml$, $1.8{\times}10^3CFU/ml$, $1.3{\times}10^2CFU/ml$, 1 CFU/ml, respectively. Density of biofilm bacteria formed on stainless and copper pipes in raw, coagulated and settled water increased above $2.9{\times}10^3CFU/cm^2$ within second weeks while more biofilm bacteria counts were found on the stainless pipe than on the copper pipe. In case of filtered water (free residue chlorine 0.44 mg/L), there was no significant difference in the number of biofilm bacteria on both pipes and biofilm bacteria below $18CFU/cm^2$ were detected on both pipe materials after fifth weeks. Biofilm bacteria were not detected on both pipe materials in treated water (free residue chlorine 0.88 mg/L). According to the results of DGGE analysis, Sphingomonadacae was a dominant species of biofilm bacteria formed on the stainless pipe while the copper pipe had Bradyrhizobiaceae and Sphingomonadaceae as dominant bands. In case of filtered water, a few bands (similar to Propionibacterium sp., Sphingomonas sp., Escherichia sp., and etc.) that have 16S rRNA sequences were detected in biofilm bacteria formed on both pipes after fifth weeks. Stainless pipe had higher species richness and diversity than the copper pipe.

Effect of Sodiun Hypochlorite Pretreatment, Light Intensity and Depth of Soil Covering on Germination of Cattail(Typha spp.) Seeds (Sodium Hypochlorite 처리와 광도 및 복토 깊이의 차이가 부들의 종자 발아에 미치는 영향)

  • Kim Young-Ju;Heo Jin-Ah;Hwang Yong-Soo;Ku Ja-Hyeong
    • Asian Journal of Turfgrass Science
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    • v.19 no.2
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    • pp.115-123
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    • 2005
  • The effect of sodium hypochlorite treatment on the germination of cattail (Typha spp.) seeds was investigated in growth chambers maintained on a 14-h photoperiod with various temperatures and light intensities. Germination rates of seeds were, in general, enhanced by the increase of light intensity and temperature regardless of cattail species. Seeds of T. oreientalis had 4.3, 13.0 and $7.3\%$ germination at temperatures of 20, 25 and $30^{circ}$C, respectively, under light intensity of 7.5${\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$. T. angustata showed higher germination rate, thus, 10.7, 22.7 and $50.7\%$ under same temperature and light environment. Under high light intensity of 79.5${\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$, the germination rates of T. oreintalis and T angustata were $78.3\%$ and $88.7\%$ at $30^{circ}$C, respectively. Scarification of seeds with NaOC1 ($4\%$, available chlorine) increased germination rate in both species, especially even at low temperature of $20^{circ}$C. Germination speed was also enhanced by NaOC1 treatment. High light intensity further increased the germination rate. When NaOC1 treated seeds were sowed on the soil surface in plastic house, the seedling emergence was nearly $100\%$. Untreated seeds of T. oreintalis and T. angustara showed 40 and $50\%$, respectively, in germination under same condition. However, when the depth of soil covering was over 1.0 cm, seedling emergence was retarded more than 1 month. On the process of seedling development, emergence of mesocoty1 occurred firstly and after than primary root and first leaf were developed on the end of elongated mesocotyl. These results suggest that the promotion of seed germination by NaOC1 pretreament may be induced from the increase of light absorptivity as well as water permeability through scarifying and bleaching the seed coat.

The Effects of Calcinated Calcium Solution Washing and Heat Treatment on the Storage Quality and Microbial Growth of Fresh-cut Broccoli (신선편이 브로콜리의 품질과 미생물 성장에 영향을 주는 소성칼슘 용액 세척 및 열처리 효과)

  • Kim, Ji Gang;Nimitkeatkai, Hataitip;Choi, Ji Woen;Lee, Sang Gyu
    • Journal of Bio-Environment Control
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    • v.21 no.4
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    • pp.411-418
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    • 2012
  • This study was conducted to investigate the effect of calcinated calcium (CC) alone or combination with heat treatment on storage quality and microbial growth in fresh-cut broccoli. Fresh broccoli samples were cut into small pieces and washed in normal tap water (TW), $50{\mu}L{\cdot}L^{-1}$ chlorinated water (pH 6.5), $1.5g{\cdot}L^{-1}$ CC, heat treatment in TW at $45^{\circ}C$, and CC dissolved in TW at $45^{\circ}C$ for 2 minutes separately. Samples were then packaged in $50{\mu}m$ polyethylene bags and stored at $5^{\circ}C$. Results revealed that like $50{\mu}L{\cdot}L^{-1}$ chlorine, washing in CC at normal water temperature was effective in reducing microbial population in fresh-cut broccoli samples. Washing with CC combined with heat treatment increased an electrical conductivity of fresh-cut broccoli. Combined heat treatments with TW and CC reduced aerobic plate count on fresh-cut broccoli, only in initial period of storage. But, later on heat treatment induced injury of fresh-cut broccoli resulting more microbial population compared to non heat treatment. However, samples treated with CC alone had good quality with low off-odor at the end of storage. Results suggest that CC, an environment-friendly sanitizer could be an alternative to chlorinated water for washing of fresh-cut broccoli without affecting sensorial quality.

A Study on Relation of Attached Algae and Odor's Cause in Sedimentation Basin of Water Treatment Plant (정수처리공정 중 침전지 부착조류 특성과 이취발생에 관한 연구)

  • Kim, Young-Ung;Son, Hee-Jong;Yu, Myung-Ho;Lee, Chun-Sik;Cho, In-Cheol;Kim, Eun-Ho;Seung, Nak-Chang
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.887-894
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    • 2000
  • The purposes of this study are investigation of species of attached algae and the relation between attached algae and odor in tap water, Oscillatoria sp. and Mougeotia sp. were colonized at sedimentation basin in water treatment plant. Resulting from analysis, 3.7ppt of geosmin and dimethyl-disulfide with trace were detected in sample of Oscillatoria sp. only, 22 compounds were found in each of sample that had been incubated in room temperature for 5 days, 17 compounds were generated by algal decay. Decayed products were sulfur compounds of 10 species such as dimethyl-sulfide and phenol, p-cresol, indole and scatole. So, it is assumed that attached algae which tolerant to chlorine was the origin of odor in tap water. They usually formed big colonies. Colonies on the bottom were decayed because of anaerobic state. While decaying they were detached from colonies and so, odorous compounds are originated from this decayed algae.

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Effect of Postharvest Treatments on Storage Quality of Buckwheat Sprouts (메밀 새싹채소의 저장품질에 대한 수확 후 처리공정 효과)

  • Lee, Hyun-Hee;Hong, Seok-In;Kim, Dong-Man
    • Korean Journal of Food Science and Technology
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    • v.43 no.1
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    • pp.98-104
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    • 2011
  • The storage quality of fresh buckwheat sprouts, as influenced by pretreatment and packaging within processing steps, was investigated to establish appropriate postharvest handling treatment for the commodity. After harvest, the sprouts were dipped in chlorine water (100 ppm), rinsed twice with clean water, pre-cooled with iced water, de-watered, and packed in plastic trays. Sprout samples taken from each processing step were stored at $5^{\circ}C$ for 6 days to measure quality attributes. Viable cell counts of mesophilic aerobes and coliform bacteria were lower by about 1 log scale in the postharvest treated samples compared to an untreated control, although the initial microbial reduction due to the postharvest treatments was offset by cell growth during storage. All sprout samples showed a decrease of fresh weight by approximately 4% after 6 days of storage. However, moisture and soluble solid contents were maintained at the initial levels of the sprouts. No significant difference in surface color was observed among sample treatments. For sensory properties including discoloration, wilting, decay, and visual quality, there were no significant differences among sample treatments. The present results suggest that proper postharvest processing treatments can exert positive effects on extending the shelf-life of fresh buckwheat sprout.

Evaluation of Biological Aerated Filter Position on Water Treatment Processes for Water Quality Improvement (상수원수 전처리 시 효율향상을 위한 생물여과 반응기 위치선정)

  • Choi, Hyung-Joo;Choi, Dong-Ho;Bae, Woo-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.6
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    • pp.677-686
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    • 2006
  • This study was the effectiveness of two downflow BAF(Biological Aerated Filter) systems at conventional water treatment system. A BAF reactor placed in front of coagulation and sedimentation tanks(Mode A) and after coagulation and sedimentation tanks(Mode B) that were compared in terms of removal of suspended particles, organic matters, and ammonia nitrogen. The suspended particles removal efficiency was over 80% for both Mode A and B, although Mode A gave slightly better results. $BOD_5$ removal and nitrification efficiencies were more than 90% for both reactor. The organic matter and ammonia removals were also superior in the Mode A. The biofilm thickness and biomass increased as increment of EBCT and the upper part of reactor more about 30% than lower part. The specific oxygen uptake rate(SOUR) was higher the upper part of reactor and Mode A than the lower part of reactor and Mode B. A cost analysis showed that the Mode A system was more cost effectiveness. It could save the coagulant dose by about 67% and the chlorine demand by about 95%. The ideal place to put the BAF reactor was in front of the coagulation/sedimentation process.

Ship Sewage Treatment Using Fixed Media Method (고정식 메디아법을 이용한 선박의 오폐수 처리)

  • Han, Sang-Hwa;Lee, Dea-Ho;Nyung, Bu-Nyung;Bae, Sang-Bum;Yoon, Jong-Mun
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.2
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    • pp.99-104
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    • 2010
  • The purpose of this study is to develop Sewage Treatment Plant that treat sewage which occurred in ship using fixed media method and to consider applicable to the Pilot Scale device of the STP regulations in MLTM(Ministry of Land, Transport and Maritime Affairs) and MEPC(Marine Environment Protection Committee). In test results, pH geometric mean was 7.68, $BOD_5$(Biochemical Oxygen Demand) geometric mean was 7.28 mg/l, $COD_{cr}$(Chemical Oxygen Demand) geometric mean was 48.39 mg/l, TSS(Total Suspended Solid) geometric mean was 18.00/l, Residual chlorine geometric mean was 0.19 mg/l, and E. coli geometric mean was 1CFU/100 ml. In addition, about 97.4% of $BOD_5$ was reduced, the $COD_{cr}$ reduction averaged 96.4%and the TSS reduction averaged 97.6%. STP have been determined by the MLTM and MEPC regulation of the marine pollution prevention equipment for performance testing product.

Quality Changes in 'Elliot' Blueberries and 'Sulhyang' Strawberries Packed with Two Different Packaging Materials during Refrigerated Storage (기체투과도가 다른 포장재로 포장한 '엘리오트' 블루베리와 '설향' 딸기의 냉장 저장 중 품질 변화)

  • Jung, Seung Hun;Kang, Ji Hoon;Park, Seung Jong;Seong, Ki Hyun;Song, Kyung Bin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.6
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    • pp.901-908
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    • 2014
  • Blueberries and strawberries are highly perishable and easily contaminated with microorganisms. To maintain the quality of these commodities during refrigerated storage, the effects of two packaging materials as well as passive modified atmosphere packaging on the quality of blueberries and strawberries were investigated. The harvested blueberries and strawberries were first treated with combined non-thermal treatment of aqueous chlorine dioxide and fumaric acid, followed by packaging with polyolefin film (6,000 mL $O_2/m^2{\cdot}24hr{\cdot}atm$ at $24^{\circ}C$) and polyamide/polyamide/polyethylene film (PA/PA/PE, 60 mL $O_2/m^2{\cdot}24hr{\cdot}atm$ at $24^{\circ}C$), respectively. After combined sanitizer treatment, the populations of total aerobic bacteria in blueberries and strawberries were reduced by 2.50 and 1.97 log CFU/g while those of yeast and molds were reduced by 1.95 and 2.18 log CFU/g, respectively, compared with the control. In particular, microbial growth in these samples packed with PA/PA/PE film was reduced during refrigerated storage. In addition, the blueberries and strawberries packed with PA/PA/PE film underwent lower weight loss than those packed with polyolefin film during storage. These results suggest that appropriate packaging with proper gas permeability is necessary to maintain the quality of blueberries and strawberries during refrigerated storage.

A Study on the Optimum Operating Conditions and Effects of Wastewater Characteristics in Electrochemical Nitrogen Removal Process (질소 제거를 위한 전기화학적 처리 공정의 최적 운전조건 및 폐수 성상에 따른 영향에 관한 연구)

  • Sim, Joo-Hyun;Kang, Se-Han;Seo, Hyung-Joon;Song, Su-Sung
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.1
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    • pp.29-34
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    • 2009
  • This study was performed under four operational conditions for nitrogen removal in metal finishing wastewater. The conditions include electrode gap, reducing agent, the recycling of treated wastewater in 1st step and the simultaneous treatment of nitrate and other materials. Result showed that the removal efficiency of $NO_3{^-}-N$ was highest at the electrode gap of 10 mm. As the electrode gap was shorter than 10 mm, the removal efficiency of $NO_3{^-}-N$ decreased due to increasing in concentration polarization on electrode. And, in case that the electrode gap was longer than 10 mm, the removal efficiency of $NO_3{^-}-N$ increased with an increase in energy consumption. Because hydrogen ions are consumed when nitrate is reduced, reducing reaction of nitrate was effected more in acid solution. As 1.2 excess amount of zinc was injected, the removal efficiency of $NO_3{^-}-N$ increased due to increasing in amount of reaction with nitrate. As the effluent from 1st step in the reactor was recycled into the 1st step, the removal efficiency of $NO_3{^-}-N$ increased. Because the zinc were detached from the cathode and concentration-polarization was decreased due to formation of turbulence in the reactor. The presence of $NH_4{^+}-N$ did not affect the removal efficiency of $NO_3{^-}-N$ but the addition of heavy metal decreased the removal efficiency of $NO_3{^-}-N$. As chlorine is enough in wastewater, the simultaneous treatment of nitrate and ammonia nitrogen may be possible. The problem that heavy metal decrease the removal efficiency of $NO_3{^-}-N$ may be solved by increasing current density or using front step of electrochemical process for heavy metal removal.