• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2014년도 추계 학술논문 발표대회
• /
• pp.57-58
• /
• 2014

For durability design to protect against chloride-induced corrosion, it is important to estimate the amount of chlorides on the surface. However, it is difficult to estimate the airborne chlorides, a boundary condition, due to the difference between the amount of chlorides attached to a surface of an actual structure and that in the air. Therefore, in this study the attachment rate analysis of airborne chlorides was evaluated for 13 types of finish materials. As a result, despite differences in the amount of airborne chlorides according to the finishing type, it was found that 60 percent of airborne chlorides were attached to mortar, 30 percent were attached to steel, and 25 percent were attached to tiles compared with the amount of chlorides in the air.

• Corrosion Science and Technology
• /
• 제8권2호
• /
• pp.81-88
• /
• 2009

Chloride induced corrosion of steel reinforcement inside concrete is a major concern for concrete structures exposed to a marine environment. It is well known that transport of chloride ions in concrete occurs mainly through ionic/molecular diffusion, as a gradient of chloride concentration in the concrete pore solution is set. In the process of chloride transport, a portion of chlorides are bound in cement matrix then to be removed in the pore solution, and thus only the rest of chlorides which are not bound (i.e. free chlorides) leads the ingress of chlorides. However, since the measurement of free/bound chloride content is much susceptible to environmental conditions, chloride profiles expressed in total chlorides are evaluated to use in many studies In this study, the capacity of chloride binding in cement matrix was monitored for 150 days and then quantified using the Langmuir isotherm to determine the portions of free chlorides and bound chlorides at given total chlorides and the redistribution of free chlorides. Then, the diffusion of chloride ion in concrete was modeled by considering the binding capacity for the prediction of chloride profiles with the redistribution. The predicted chloride profiles were compared to those obtained from conventional model. It was found that the prediction of chloride profiles obtained by the model has shown slower diffusion than those by the conventional ones. This reflects that the prediction by total chloride may overestimate the ingress of chlorides by neglecting the redistribution of free chlorides caused by the binding capacity of cement matrix. From the evaluation, it is also shown that the service life prediction using the free chloride redistribution model needs different expression for the chloride threshold level which is expressed by the total chlorides in the conventional diffusion model.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
• /
• pp.273-276
• /
• 2006

Airborne chlorides is moved to inland by sea wind and attach to the surface of concrete then penetrated into concrete. In addition, concrete structures are greatly affected by salt attack primarily due to airborne chlorides like it can be seen through the corrosion of rebar. Therefore, it is important to review the relationship among airborne, surface and penetrated chlorides. In this study, airborne, surface and penetrated chlorides were examined in terms of surface roughness of concrete. The results showed that penetrated and surface chlorides have close relationship with surface roughness of concrete.

• 한국방사성폐기물학회:학술대회논문집
• /
• 한국방사성폐기물학회 2017년도 추계학술논문요약집
• /
• pp.74-74
• /
• 2017

Electrorefining is a key step in pyroprocessing. The electrorefining process is generally composed of two recovery steps - the deposit of uranium onto a solid cathode and the recovery of the remaining uranium and TRU elements simultaneously by a liquid cadmium cathode. Uranium deposit recovered from the solid cathode is a dendritic powder. It is necessary to separate the adhered salt from the deposits prior to the consolidation of uranium deposit. The adhered salt is composed of lithium, potassium, uranium, and rare earth chlorides. Distillation process was employed for the cathode processing. One of the operation methods is distillation of the salt at low temperature ($900^{\circ}C$), and then melting of the deposit at high temperature to avoid a backward reaction. For the development of the salt distiller, the distillation behavior of the low vapor pressure chlorides should be studied. Rare earth chlorides in the adhered salt of uranium deposits have relatively low vapor pressures compared to the process salt (LiCl-KCl). In this study, the evaporation rates of the lanthanum and neodymium chlorides were measured for the salt separation from electrorefiner uranium deposits in the temperature range of $825{\sim}910^{\circ}C$. The evaporation rate of both chlorides increased with an increasing templerature. The evaporation rate of lanthanum chloride varied from 0.12 to $1.68g/cm^2/h$. Neodymium chloride was more volatile than lanthanum chloride. The evaporation rate of neodymium chloride varied from 0.20 to $4.55g/cm^2/h$. The evaporation rate of both chlorides are more than $1g/cm^2/h$ at $900^{\circ}C$. Even though the evaporation rates of both chlorides were less than that of the process salt, the contents of the lanthanide chlorides were small in the adhered salt. Therefore it can be concluded that $900^{\circ}C$ is suitable for the operation temperature of the salt distiller.

• 한국건설순환자원학회논문집
• /
• 제10권3호
• /
• pp.300-306
• /
• 2022

본 연구에서는 제주도 해안가의 대기중 염분 분포 특성을 파악하였다. 이를 위해 제주도를 동, 서, 남, 북부지역의 4개 지역으로 구분하여 대기중 염분량을 조사하고, 지역별, 계절별 특징을 분석하였다. 아열대 기후이면서 섬으로 형성된 제주도는 대기중 염분량 분포에 있어서 지역별 편차가 크며 가장 높은 지역인 동부와 가장 낮은 지역인 남부 지역은 6배 이상 차이가 났다. 계절별 특징으로는 동부와 서부는 태풍의 영향으로 각 각 여름/가을철과 여름철이 높고, 북부는 북서풍의 영향으로 겨울철이 높으며, 남부는 여름철이 높았다. 한편 국내 동, 서, 남해안의 대기중 염분량과 비교하여 제주도는 높은 경향이 있다.

• 콘크리트학회논문집
• /
• 제24권5호
• /
• pp.553-558
• /
• 2012

대기 중의 비래염분은 해풍에 의해 내륙으로 이동되고 해안 인근 콘크리트 구조물의 표면에 부착하여 내부로 침투하게 된다. 비래염분 환경에 있는 콘크리트 구조물의 표면염분량은 비래염분량에 의해 영향을 받기 때문에 비래염분량의 분포 특성에 따라 표면염분량도 변화하는 경향이 있다. 따라서, 비래염분 환경 하의 구조물은 해수에 직접접하는 구조물과 달리 표면부의 염분량을 예측하기가 상대적으로 어렵고, 침투되는 경향 또한 다르기 때문에 이에 대한 결과를 얻는것은 중요하다고 할 수 있다. 따라서, 이 연구에서는 비래염분 환경에서 콘크리트 표면으로부터 내부로 침투하는 염분을 표면염분량과 침투 염분량으로 구분하여 그 특성을 파악하였다. 이를 위하여 콘크리트 시험체를 제작하여 해안 현장에서 옥외노출실험을 3년간 실시하였으며, 노출기간 1년과 2년, 3년차에서 시험체를 회수하여 표면염분량 및 표면으로부터 깊이별 비래염분 침투량을 분석하였다. 분석 결과, 콘크리트의 표면조도에 따라 표면염분량의 차이가 발생하였으며, 강우의 영향을 받지 않은 경우 더 많은 표면염분량이 존재하였다. 침투 염분량은 대기중의 비래염분량 및 노출기간에 따라 차이가 발생하였으며, 장기재령으로 갈수록 표면부보다 콘크리트 내부에서 많은 염분량을 나타내는 경향이 두드러졌다.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2014년도 춘계 학술논문 발표대회
• /
• pp.98-99
• /
• 2014

The newly developed eight-directional collector was installed at five different locations in the coastal area after its functionality was verified through experiments. Based on the airborne chloride amount measured for one year, the distribution characteristics of airborne chlorides were examined by direction. In terms of direction, a large amount of airborne chlorides was collected, not only in the direction facing the coast but also in the opposite direction. The amount measured at effective three directions was 1.5 times that measured at non-effective three directions.

• Bulletin of the Korean Chemical Society
• /
• 제3권1호
• /
• pp.30-33
• /
• 1982

Photochemical and thermal solvolysis of 2,3,4-picolyl chlorides (2,3,4-PC) were studied in amine solvents and the results were correlated with the electronic structures calculated by PPP-SCF-MO CI method. Activation parameters show that the thermal solvolysis of PC is $S_N2$ type rcaction. The rates of thermal reaction in pyridine or t-butylamine solvent decrease in the order of 2-PC > 3-PC > 4-PC. These results are consistent with the predictions based on the electron densities of picolyl chlorides. In photosolvolysis, the same products as those of thermal reactions were obtained. The results indicate that photochemical solvolysis undergoes through heterolytic cleavage. Relative quantum yields of photosolvolysis of 2,3,4-picolyl chlorides in t-butylamine solvent were determined to be 0.73, 1, and 0.50 respectively. These results are in good agreement with the electron densities of the excited triplet state of picolyl chlorides.

• Bulletin of the Korean Chemical Society
• /
• 제22권8호
• /
• pp.842-846
• /
• 2001

Solvolyses of N-methyl-N-phenylcarbamoyl chlorides in aqueous binary mixtures of acetone, ethanol, methanol and in water, D2O, and 50% D2O-CH3OD are investigated at 25.0 $^{\circ}C.$ The Grunwald-Winstein plots of first-ord er rate constants for N-methyl-N-phenylcarbamoyl chlorides with YCl (based on 2-adamantyl chloride) show a dispersion phenomenon. The ring parameter (I) has been shown to give considerable improvement when it is added as an hI term to the original Grunwald-Winstein and extended Grunwald-Winstein correlations for the solvolyses of N-methyl-N-phenylcarbamoyl chlorides. This study has shown that the magnitude of l, m and h values associated with a change of solvent composition is able to predict the dissociative SN2 transition state. The kinetic solvent isotope effects determined in deuterated water are consistent with the proposed mechanism of the general base catalyzed and/or a dissociative SN2 mechanism channel for N-methyl-N-phenylcarbamoyl chlorides solvolyses.

• 한국구조물진단유지관리공학회 논문집
• /
• 제26권2호
• /
• pp.59-67
• /
• 2022

본 연구에서는 해상교량에서 해수와 직접 접하지 않은 부재로 날아 들어오는 비래염분 분포를 월별, 높이별로 파악하였다. 이를 위하여 한국의 남해안과 서해안의 9개 해상교량을 대상으로 다양한 높이에서 1년 동안 비래염분량을 측정하여 분석하였다. 그 결과, 측정한 월에 따라서는 서해안과 남해안 모두 겨울철 북서 계절풍의 풍향과 강한 풍속의 영향으로 겨울철(11월~2월)의 비래염분량이 크게 증가하였고 그 차이는 서해안이 더 크게 나타났다. 높이별로는 해수면에서 높아질수록 비래염분량이 감소하는 경향을 나타내었으며, 감소 경향에 따라 주탑하단의 비래염분량을 기준으로 총 3개의 구간으로 분류하여 비래염분량 감소식을 도출하였다. 각 구간에 따른 감소 경향 차이는 해역별로, 동일 해역내에서도 국부적인 지형적 특징에 따라 다르게 나타났다. 따라서 해상교량의 유지관리를 위한 비래염분자료 수립을 위해서는 해역별 특징과 함께, 그 주변의 국부적인 지형적 특징도 고려하여야 할 것으로 판단된다. 본 연구의 결과로서, 해상 교량의 비래염분 염해환경에 대하여 안전한 구간과 열악한 구간을 구분할 수 있을 것으로 판단되며, 시설물 안전 및 유지관리 실시 세부지침[성능평가]_교량편의 열화환경 평가항목의 기반자료로 활용될 수 있을 것으로 기대한다.