• Title/Summary/Keyword: chloride-induced corrosion

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Degradation mechanisms of concrete subjected to combined environmental and mechanical actions: a review and perspective

  • Ye, Hailong;Jin, Nanguo
    • Computers and Concrete
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    • v.23 no.2
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    • pp.107-119
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    • 2019
  • In-service reinforced concrete structures are simultaneously subjected to a combination of multi-deterioration environmental actions and mechanical loads. The combination of two or more deteriorative actions in environments can potentially accelerate the degradation and aging of concrete materials and structures. This paper reviews the coupling and synergistic mechanisms among various deteriorative driving forces (e.g. chloride salts- and carbonation-induced reinforcement corrosion, cyclic freeze-thaw action, alkali-silica reaction, and sulfate attack). In addition, the effects of mechanical loads on detrimental environmental factors are discussed, focusing on the transport properties and damage evolution in concrete. Recommendations for advancing current testing methods and predictive modeling on assessing the long-term durability of concrete with consideration of the coupling effects are provided.

Analysis Technique for Chloride Penetration using Double-layer and Time-Dependent Chloride Diffusion in Concrete (콘크리트내의 이중구조와 시간의존성을 고려한 염화물 해석기법의 개발)

  • Mun, Jin-Man;Kim, Jin-Yeong;Kim, Young-Joon;Oh, Gyeong-Seok;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.5
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    • pp.83-91
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    • 2015
  • With varying conditions of concrete surface, induced chloride contents are changed and this is a key parameter for steel corrosion and service life in RC (Reinforced Concrete) structures. Many surface enhancement techniques using impregnation have been developed, however the evaluation techniques for chloride behavior through doubly layered media and time-dependent diffusion are rarely proposed. This paper presents an analysis technique considering double-layer concrete and time-dependent diffusion behavior, and the results are compared with those from the previous test results through reverse analysis. The chloride profiles from the surface-impregnated concrete exposed to atmospheric, tidal, submerged zone for 2 years are adopted. Furthermore surface chloride contents and diffusion coefficients are obtained, and are compared with those from Life365. Through consideration of time effect, the relative error decreases from 0.28 to 0.20 in atmospheric, 0.29 to 0.11 in tidal, and 0.54 to 0.40 in submerged zone, respectively, which shows more reasonable results. Utilizing the diffusion coefficients from Life365, relative errors increases and it needs deeper penetration depth (e) and lower diffusion coefficient ratio ($D_1/D_2$) due to higher diffusion coefficient.

Evaluations of Microstructure and Electrochemical Anodic Polarization of AISI 304L and AISI 316L Stainless Steel Weld Metals with Creq/Nieq Ratio (Creq/Nieq비에 따른 AISI 304L 및 AISI 316L 스테인리스강 용접부의 미세조직 및 전기화학적 양극분극 평가)

  • Kim, Yeon Hee;Jang, Ah Young;Kang, Dong Hoon;Ko, Dae Eun;Shin, Yong Taek;Lee, Hae Woo
    • Korean Journal of Metals and Materials
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    • v.48 no.12
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    • pp.1090-1096
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    • 2010
  • This pitting corrosion study of welded joints of austenitic stainless steels (AISI 304L and 316L) has addressed the differentiating solidification mode using three newly introduced filler wires with a flux-cored arc welding process (FCAW). The delta ferrite (${\delta}$-ferrite) content in the welded metals increased with an increasing equivalent weight ratio of chromium/nickel ($Cr_{eq}/Ni_{eq}$). Ductility dip cracking (DDC) was observed in the welded metal containing ferrite with none of AISI 304L and 0.1% of AISI 316L. The potentiodynamic anodic polarization results revealed that the $Cr_{eq}/Ni_{eq}$ ratio in a 3.5% NaCl solution didn't much affect the pitting potential ($E_{pit}$). The AISI 316L welded metals with ${\ddot{a}}$-ferrite content of over 10% had a superior $E_{pit}$ value. Though the AISI 316L welded metal with 0.1% ferrite had larger molybdenum contents than AISI 304L specimens, it showed a similar $E_{pit}$ value because the concentration of chloride ions and the corrosion product induced severe damage near the DDC.

Review of Research on Chloride-Induced Stress Corrosion Cracking of Dry Storage Canisters in the United States (미국의 건식저장 캐니스터에서의 CISCC 연구에 대한 검토)

  • Park, Hyoung-Gyu;Park, Kwang-Heon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.4
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    • pp.455-472
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    • 2018
  • It is important to study how to manage dry storage casks of spent nuclear fuels (SNF), because wet storage spaces for SNF will shortly be at full capacity in the Republic of Korea. The US has operated a dry storage cask system for several decades, and has carried out significant studies into how to successfully manage dry storage cask for SNF. This type of expertise and experience is currently lacking in the Republic of Korea. The degradation of dry casks is an important issue that must be considered. In particular, chloride-induced stress corrosion cracking (CISCC) is known to lead to the release of radioisotopes from canisters. The U.S. Department of Energy, U.S. Nuclear Regulatory Commission, and the Electric Power Research Institute have undertaken research into the CISCC mechanism. In addition, Sandia National Laboratories (SNL) has extensively researched CISCC and how to manage it in dry storage canisters. In this review paper, the probabilistic model proposed by the SNL is analyzed and, based on this model, US-based CISCC research is reviewed in detail. This paper will inform the management of dry cask storage of SNF from light water reactors in austenite stainless steel canisters in the Republic of Korea.

Examination for Controlling Chloride Penetration of Concrete through Micro-Cracks with Surface Treatment System (표면도장공법을 적용한 미세균열 콘크리트의 염소이온 침투 제어 특성)

  • Yoon, In-Seok;Chae, Gyu-Bong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.5A
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    • pp.729-735
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    • 2008
  • For well-constructed concrete, its service life is a long period and it has an enough durability performance. For cracked concrete, however, it is clear that cracks should be a preferential channel for the penetration of aggressive substance such as chloride ions accoding to author's previous researches. Even though crack width can be reduced due to the high reinforcement ratio, the question is to which extend these cracks may jeopardize the durability of cracked concrete. If the size of crack is small, surface treatment system can be considered as one of the best options to extend the service life of concrete structures exposed to marine environment simply in terms of cost effectiveness versus durability performance. Thus, it should be decided to undertake an experimental study to deal with the effect of different types of surface treatment system, which are expected to seal the concrete and the cracks to chloride-induced corrosion in particular. In this study, it is examined the effect of surfaced treated systems such as penetrant, coating, and their combination on chloride penetration through microcracks. Experimental results showed that penetrant can't cure cracks. However, coating and combined treatment can prohibit chloride penetration through cracks upto 0.06 mm, 0.08 mm, respectively.

Crack and Time Effect on Chloride Diffusion Coefficient in Nuclear Power Plant Concrete with 1 Year Curing Period (1년 양생된 고강도 원전 콘크리트의 염화물 확산에 대한 균열 및 시간효과)

  • Chun, Ju-Hyun;Ryu, Hwa-Sung;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.83-90
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    • 2017
  • Concrete structure for nuclear power plant is mass concrete structure with large wall depth and easily permits cracking in early age due to hydration heat and drying shrinkage. It always needs cooling water so that usually located near to sea shore. The crack on concrete surface permits rapid chloride intrusion and also causes more rapid corrosion in the steel. In the study, the effect of age and crack width on chloride diffusion is evaluated for the concrete for nuclear power plant with 6000 psi strength. For the work, various crack widths with 0.0~1.4 mm are induced and accelerated diffusion test is performed for concrete with 56 days, 180days, and 365 days. With increasing crack width over 1.0mm, diffusion coefficient is enlarged to 2.7~3.1 times and significant reduction of diffusion is evaluated due to age effect. Furthermore, apparent diffusion coefficient and surface chloride content are evaluated for the concrete with various crack width exposed to atmospheric zone with salt spraying at the age of 180 days. The results are also analyzed with those from accelerated diffusion test.

An Study on the Investigation of Bridge Deck Condition by Analysis of Concrete Core Properties (교량바닥판 콘크리트 코어의 물성분석을 통한 상태조사연구)

  • Suh, Jin-Won;Rhee, Ji-Young;Ku, Bon-Sung;Shin, Jae-In;Shin, Do-Chul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.789-792
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    • 2008
  • Recently, the deteriorations of RC bridge decks on express-way are frequently observed. The major cause of deterioration for the RC concrete bridge decks exposed to de-icing chemiclas would be chloride-induced reinforcement corrosion. Therefore, Waterproofing is necessary for improvement of bridge deck durability and comfortable utility. In this study is to investigate the appearance of deterioration and properties of concrete core from the collect in a bridge deck. The results of this study shows that penetration waterproofing agents shows low infiltration depth and low water-repellent. It appears that the damaging of concrete deck is primarily waterproofing system rather than physical property.

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A Study on the Concrete Durability by Fly Ash Replacement Ratio (플라이애쉬 치환율을 고려한 콘크리트의 내구성에 관한 연구)

  • Kim, Dongbaek;Lee, Kwangjae
    • Journal of the Society of Disaster Information
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    • v.10 no.4
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    • pp.566-571
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    • 2014
  • Recently, with concentrated social and engineering interests on durability, diversified subsequent researches have been progressed. The Chloride-induced corrosion, carbonation, freeze-thaw etc, deterioration factors of concrete act to concrete not privately but complexly, Fly ash is most frequently used admixture which is using a reduction method of deterioration. And the fly ash effects on improvement of durability with enhancement of fluidity, decrease of crack with reduction of hydration heat, promotion of long-age strength and have a economic advantage which replaces cement as a binding material. But, fly ash have different qualities and occasionally reduce the durability and strength by adhesion of AE admixture with unburned carbon powder etc. In this study, the experiments will take about various replacement ratio of fly ash concrete, and will analyze, consider the results, after these will verify applicability and validity as admixture and binding material.

Effect of Total Resistance of Electrochemical Cell on Electrochemical Impedance of Reinforced Concrete Using a Three-Electrode System (3전극방식을 활용한 철근 콘크리트의 교류임피던스 측정 시 전기화학 셀저항의 영향)

  • Khan, Md. Al-Masrur;Kim, Je-Kyoung;Yee, Jurng-Jae;Kee, Seong-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.82-92
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    • 2022
  • This study aims to investigate the effect of total electrochemical cell resistance (TECR) on electrochemical impedance (EI) measurements of reinforced concrete (RC) by electrochemical impedance spectroscopy (EIS) using a three-electrode system. A series of experimental study is performed to measure electrochemical behavior of a steel bar embedded in a concrete cube specimen, with a side length of 200 mm, in various experimental conditions. Main variables include concrete dry conditions, coupling resistance between sensing electrodes and concrete surface, and area of the counter electrode. It is demonstrated that EI values remains stable when the compliant voltage of a measuring device is sufficiently great compared to the potential drop caused by TECR of concrete specimens. It is confirmed that the effect of the coupling resistance of TECR is far more influential than other two factors (concrete dry conditions and area of the counter electrode). The results in this study can be used as a fundamental basis for development of a surface-mount sensor for corrosion monitoring of reinforced concrete structures exposed to wet-and-dry cycles under marine environment.