• Title/Summary/Keyword: chloride resistance performance

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Properties of SPE-Based Cement Grout for Semi-Rigid Pavements (Sulfur Polymer Emulsion을 활용한 반강성 포장용 시멘트 주입재의 특성)

  • Lee, Byung-Jae;Lee, Jun;Hyun, Jung-Hwan;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.4
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    • pp.57-65
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    • 2013
  • The development of the oil refining industry has resulted in an annual 120 million tons of sulphur, which is a by-product of the desulphurization process. To exploit this abundance, the applications of sulphur must be expanded. as excellent durability of reuse of leftover sulphur which has high potential for utilization in construction materials, the study is actively in progress. Meanwhile, there has been active research on semi-rigid pavements that draw on the strengths and overcome the weaknesses of asphalt and concrete pavements. Acrylate is used to prevent cracking but involves a high cost, thus, an alternative material is required. As such, this study presents methods on the reuse of leftover sulphur and examines the engineering performance of grout containing sulfur polymer emulsion (SPE) for use in semi-rigid pavements. Our analysis shows that grout in which 30% of acrylate is replaced with SPE has superior properties in terms of time of flow and strength compared to regular grout. However, performance declined when more than 50% of acrylate was replaced by SPE, indicating that the optimum replacement level is 30%. Through SEM analysis, we found that grout with utra harding cement in this study at three hours had similar hydration properties to that of Type 1 Ordinary Portland Cement (OPC) at seven days, and maintained the properties regardless of grout containing SPE. OPC and grout with a replacement level of 30% displayed similar levels of chloride invasion resistance, whereas grout without SPE was far less resistant. Within the scope of this paper, the optimum replacement level of acrylate with SPE was found to be 30% in consideration of various properties such as time of flow, strength, and chloride invasion resistance.

Evaluation of the concrete using low quality recycled aggregate (저품질 순환골재를 활용한 콘크리트 성능 평가)

  • Lee, Seung-Tae;Park, Kwang-Pil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.11
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    • pp.7-15
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    • 2017
  • The purpose of this study was to evaluate the properties of recycled aggregate concrete (RAC) using low quality recycled aggregate with or without washing before usage. The recycled aggregate concrete evaluated in this study contained various amounts of low quality recycled aggregate, viz. 30%, 60% and 100%. To evaluate the performance of the recycled aggregate concrete, various test methods were employed to assess its compressive strength, absorption, surface resistance, ultrasound velocity, chloride ion resistance, etc. The properties of the RAC with 30% and 60% washed recycled aggregate were similar those of the natural aggregate. However, the properties of the RAC with 100% washed recycled aggregate were slightly lower than those of the other versions. Also, the RAC with the non-washed recycled aggregate exhibited lower performance results. The results showed that the RAC with washed recycled aggregate had similar properties to normal concrete (concrete using natural aggregate). This implies that the recycled aggregate should be washed to improve the RCA.

Effect of RuCl3 Concentration on the Lifespan of Insoluble Anode for Cathodic Protection on PCCP

  • Cho, H.W.;Chang, H.Y.;Lim, B.T.;Park, H.B.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.14 no.4
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    • pp.177-183
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    • 2015
  • Prestressed Concrete steel Cylinder Pipe (PCCP) is extensively used as seawater pipes for cooling in nuclear power plants. The internal surface of PCCP is exposed to seawater, while the external surface is in direct contact with underground soil. Therefore, materials and strategies that would reduce the corrosion of its cylindrical steel body and external steel wiring need to be employed. To prevent against the failure of PCCP, operators provided a cathodic protection to the pre-stressing wires. The efficiency of cathodic protection is governed by the anodic performance of the system. A mixed metal oxide (MMO) electrode was developed to meet criteria of low over potential and high corrosion resistance. Increasing coating cycles improved the performance of the anode, but cycling should be minimized due to high materials cost. In this work, the effects of $RuCl_3$ concentration on the electrochemical properties and lifespan of MMO anode were evaluated. With increasing concentration of $RuCl_3$, the oxygen evolution potential lowered and polarization resistance were also reduced but demonstrated an increase in passive current density and oxygen evolution current density. To improve the electrochemical properties of the MMO anode, $RuCl_3$ concentration was increased. As a result, the number of required coating cycles were reduced substantially and the MMO anode achieved an excellent lifespan of over 80 years. Thus, we concluded that the relationship between $RuCl_3$ concentration and coating cycles can be summarized as follows: No. of coating cycle = 0.48*[$RuCl_3$ concentration, $M]^{-0.97}$.

Corrosion Protection Method of Reinforcing Steel in Concrete by Using Corrosion Inhibitors

  • Bae Su-Ho;Chung Young-Soo;Kim Dae-Ho
    • KCI Concrete Journal
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    • v.14 no.4
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    • pp.145-150
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    • 2002
  • Reinforced concrete is inherently a durable composite material. When properly designed for the environment to be exposed and carefully constructed, reinforced concrete is capable of giving maintenance-free performance. However, unintentionally using improper materials such as non-washed sea sand having much salt together with poor controlled quality, or the concrete are placed in highly severe environment such as marine atmosphere, the corrosion of reinforcing steel in concrete becomes one of the most significant concerns of concrete. The purpose of this experimental research is to evaluate the performance of corrosion inhibitors for normal strength and high strength concrete, and to propose desirable measures for controlling corrosion of reinforcing steel in concrete. Test specimens in normal strength and high strength concrete were made with and without corrosion inhibitors. The accelerated corrosion test for reinforcing steel in concrete was adopted in accordance with JCI-SC3, which required the periodic 20 cycles for 140 days. One cycle includes 3 days for the wetting condition of $65^{\circ}C$ and $90\%$ RH, and 4 days for the drying condition of $15^{\circ}C\;and\;60\%$ RH. It was observed from the test that corrosion inhibitors in normal strength concrete and high strength concrete showed excellent corrosion resistance for reinforcing steel in concrete, but the silica fume in high strength concrete was found to have a negligible corrosion resistance if not used with corrosion inhibitors, since the chloride corrosion threshold limit in concrete containing silica fume without corrosion inhibitor was found to be considerably smaller than that of the case with corrosion inhibitor.

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Effect of Latex and Mineral Additive on Durability of Remicon LMC (라텍스와 광물질 첨가제가 레미콘LMC (Remicon Latex Modified Concrete) 내구성에 미치는 영향)

  • Choi, So Yeong;Choi, Yoon Suk;Heo, Hyeong Seok;Yang, Eun Ik
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.6
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    • pp.1743-1751
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    • 2014
  • It is well known that latex modification can lead to enhancement compressive and flexural performance, tensile bond strength, chloride penetration resistance and freezing-thawing resistance for concrete. For these, many studies for LMC pavement have been widely conducted more than those for conventional pavement concrete. However, due to several problems such as noise and construction cost, new approaches for LMC have been executed to improve the performance of LMC. Recently, Remicon LMC was developed in order to solve the problems of LMC. In this study, the durability of Remcion LMC was compared with latex and mineral additive mixing ratio. From the results, when latex and mineral additive were mixed in Remicon LMC, compressive, flexural and bond strength were satisfied with Korea Highway Construction Guide Specification. And, it showed that the qualitative effect of latex and mineral additive mixing ratio on the durability of Remicon LMC was investigated experimentally. Also, the latex mixed in Remicon LMC must be at least 8%, in order to ensure the durability equivalent or higher than conventional LMC.

An Electrochemical Evaluation of the Corrosion Property on the Welded Zone of Sea Water Pipe according to Welding Materials (용접 재료 별 해수 배관 용접부위의 부식 특성에 관한 전기화학적 평가)

  • Kim, Jin-Gyeong;Won, Chang-Uk;Jo, Hwang-Rae;Lee, Myung-Hoon;Kim, Yun-Hae;Moon, Kyung-Man
    • Journal of Ocean Engineering and Technology
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    • v.21 no.5
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    • pp.39-46
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    • 2007
  • The sea water pipe of a ship's engine room is a severely corrosive environment caused by fast flawing sea water containing chloride ions and high conductivity. Therefore, leaking of sea water may occur as a result of local corrosion of the welded zone. Leaking is usually controlled by various welding methods. In this study, when the sea water pipe is welded with certain welding methods and welding electrodes, the corrosion resistance of WM (Welding metal) and HAZ (Heat affected zone) was investigated using electrochemical methods. Although the corrosion potential of the HAZ is higher than that of WM, the corrosion resistance of WM is superior to HAZ. However, when WM and HAZ are both opened to the sea water, the WM part with the anode was more seriously corroded than was the HAZ of the cathode by performance of a galvanic cell due to difference of the corrosion potential between HAZ and WM. In particular TIG welding showed relatively good results in corrosion resistance of both HAZ and WM compared to other welding methods.

The Analysis of Thermal Conductivity and Basic Quality Performances of Decoration Wood-based Flooring Board Laminated with PVC Surface Decoration Materials (PVC 표면치장재를 적층한 치장목질마루판의 열특성 및 기초 품질성능 분석)

  • Park, Cheul-Woo
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.1
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    • pp.53-60
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    • 2018
  • For test on flooring board laminated with PVC decoration materials in order to replace the current surface materials such as HPL in decoration wood-based flooring board. the Results of comparison and analysis are as follows: For thermal conductivity, flooring board decorated with PVC did not show huge differences when temperature was rising and lowering compared to the flooring materials laminated with the existing HPL surface materials. It seems the most meaningful results for using it as indoor flooring materials. That is, in Korea where there is the culture focusing on ondol heating, use amount of heat energy and efficiency of flooring materials are very important and sensitive issues, involving immediately with household economy of final consumers, and it might be a criteria to judge basic performances required as flooring materials. As a result of the analysis on mandatory durability test items such as abrasion resistance, absorption width expansion rate, impact resistance, surface hardness, and impact absorption for flooring materials, compared to flooring board laminated with general HPL surface decoration materials, decoration wood-based flooring board laminated with PVC surface decoration materials which is higher abrasion resistance with smaller transformation and has better durability and impact absorption of the surface, is available for actual application as indoor flooring board, and for replacing surface decoration materials impregnated with heat-hardened resion such as HPL.

A Fundamental Study on the Influence of Performance of Cementitious Composites of Inorganic Core Material for Self-Healing Capsule of Cracks (균열 자기치유를 위한 캡슐용 무기계 코어재료의 시멘트 복합체 성능에 미치는 영향에 관한 기초적 연구)

  • Choi, Yun-Wang;Oh, Sung-Rok;Choi, Byung-Keol;Kim, Cheol-Gyu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.1
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    • pp.74-82
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    • 2017
  • In this study, we prepared a core material based on the inorganic materials in liquid form for applying an inorganic-based core material to a core material for the self-healing capsules as a part of the basic study to manufacture of self-healing capsule that can heal cracks of cementitious composite. Manufactured core material based on the inorganic materials were applied directly to the cement composite before its encapsulation, were evaluated the effect on performance of cementitious composite as wall as repair performance of the cracks in the cracks. The test results showed that core material based on the inorganic materials was effective to improve the compressive and adhesion strength, had an absorption, permeation water, penetration of chloride iones and freeze-thaw resistance performance. Through the results of this paper, we want to utilize the results as a basis data of the performance of the cement composite that can be obtained when applied to inorganic core materials based on self-healing capsules and future advances localized self-healing capsule technology.

Properties of Polymer Cement Mortars under Combined Cures (복합양생에 의한 폴리머 시멘트 모르타르의 성질)

  • Jo, Young-Kug
    • Journal of the Korea Concrete Institute
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    • v.18 no.5 s.95
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    • pp.667-675
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    • 2006
  • Concrete is much more easily damaged by various parameters than by the only one and performance reducing mechanism grows more complicated in that condition. In addition, the factors which really act in concrete structure tend to be activated in turn and the degradation of concrete is very rapidly progressed. The purpose of this study is to evaluate the properties of polymer cement mortars under combined cures. The polymer cement mortars are prepared with various polymer types, polymer-cement ratios and cement-fine aggregate ratio, and tested for compressive and flexural strengths, accelerated carbonation, chloride ion penetration and acid resistance test, and freezing-thawing test. The properties of polymer cement mortars under combined cures is discussed. From the test results, polymer cement mortars have superior strengths compared with plain cement mortar under combined cures. The strengths of polymer cement mortars are markedly increased at curing condition II and V, however strengths are not improved at curing condition I and IV irregardless of polymer types. The carbonation and chloride ion penetration depths of polymer cement mortars tend to decrease in curing conditions, III-C, IV-B, V-A order, and decrease with increasing polymer cement ratios. It is concluded that polymer cement ratio of 10 to 15% are considered optimum for the preparation of such polymer cement mortars.

Thermodynamic Modeling of Long-Term Phase Development of Slag Cement in Seawater (해수에 노출된 슬래그 시멘트의 장기 상변이 열역학 모델링)

  • Park, Solmoi;Suh, Yongcheol;Nam, Kwang Hee;Won, Younsang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.4
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    • pp.341-345
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    • 2021
  • Known to improve resistance to chloride ingress, blast furnace slag is a widely used supplementary cementitious material. However, a detailed characterization of cements blended with slag exposed to seawater remains unavailable. This study employs thermodynamic modeling as a toolkit for assessing the long-term phase evolution of slag cement in seawater. The modeling result shows that slag incorporation leads to the formation of phases that are less prone to structural alteration in seawater. Formation of more ettringite is expected to induce expansion in both plain and blended cements, while brucite is unstable in the blended systems. Despite this, the porosity is expected to increase in the blended cements, and aluminate hydrates with a higher chloride binding capacity are more abundant in the blended cements. The results suggest that the use of slag in concrete improves the durability performance of concrete in marine environments.