• Title/Summary/Keyword: chloride loss

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Effect of Partial Replacement of Sodium Chloride on Quality of Ground Pork Patties (돈육식품의 품질에 미치는 Chloride Salts의 대치 효과)

  • 박영숙
    • Journal of the East Asian Society of Dietary Life
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    • v.4 no.3
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    • pp.123-133
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    • 1994
  • The ground pork patties were made to add two level of sodium chloride(2.5%, 3.0%) and replace part(50%) of the sodium chloride(NaCl) with either potassium chloride(KCl), magnesium chloride(MgCl2) or calcium chloride(CaCl2). These samples were analyzed for their chemical composition, VBN value, TBA value, microbial counts, and cooking loss. The ground pork with NaCl 2.5% was more desirable in saltness than the ground pork with NaCl 3.0%. Replacing 50% of the sodium chloride with potassium chloride was more desirable to flavor, color, juiciness, and overall acceptability than replacing 50% of the sodium chloride with either magnesium chloride or calcium chloride. The ground pork with NaCl 2.5% or NaCl 1.25% +KCI 1.60% had higher pH value than the ground pork with NaCl 1.25% +MgCl2 0.67% or NaCl 1.25% +CaCl2 0.79%. The ground pork with the ground pork with NaCl 2.5% had lower VBN value than the ground pork with either NaCl 1.25%+KCI 1.60%, NaCl 1.25% + MgCl2 0.67%, or NaCl 1.25% +CaCl2 0.79%. The ground pork with NaCl 1.25% + CaCl2 0.67% had higher increase in total colony count than the ground pork with NaCl 2.5% or NaCl 1.25% + CaCl2 0.79%. Cooking loss of ground pork with NaCl 2.5% was lowest and cooking loss of ground pork with NaCl 1.25% + KCl 1.60% was highest. Potassium chloride would not be a substitute for sodium chloride in cooking loss and total colony count but potassium chloride more closely approximated the sensory properties of sodium chloride than either magnesium chloride or calcium chloride.

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Studies on the Treatment of Weight Loss of PET Fibers by Alkyldimethylbenzylammonium Chlorides (알킬디메틸벤질암모늄 클로라이드에 의한 PET섬유의 감량가공에 관한 연구)

  • Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.2
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    • pp.29-33
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    • 1993
  • n-Octyldimethylbenzylammonium chloride, dodecyldimethylbenzylammonium chloride, and octadecyldimethylbenzylammonium chloride were synthesized to be used as the accelerating weight loss agent. These synthesized compounds were used for the weight loss treatment of PET textile with sodium hydroxide. From the treatments, it was found that the lower carbon number of high alkyl group existed in quaternary ammonium salts, the better effect of weight loss was acquired. The proper concentration of accelerating weight loss agent was $8{\sim}10g/l$, the proper treatment time was $60{\sim}90$ minutes, the proper treating bath ratio was 1 : 50. It is proved that n-octyldimethylbenzylammonium chloride and dodecyldimethylbenzylammonium chloride are good accelerating weight loss agent.

Sytheses of Quaternary Ammonium Salts Containing Dodecyl Group and Theirs Applications as Weight Loss Accelerating Agents (도데실기를 함유한 제4급 암모늄염의 합성과 감량촉진제로서의 응용)

  • Park, Jin-Woo;Hahm, Hyun-Sik;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.1
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    • pp.81-86
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    • 1995
  • Some weight loss accelerating agents, dodecyltrimethylammonium chloride(DTAC), dodecyltrimethylammonium bromide(DTAB), dodecyldimethylammonium chloride(DDBAC), polyoxyethylene(2) dodecylbenzylammonium chloride(PDBAC), and 1-(2-hydroxyethyl)-1-benzyl-2-undecylimidazolinium chloride(AEUIC), were synthesized. As a result of weight loss treatment of the weight loss accelerating agents with NaOH to PET fiber, the increase of weight loss was the order of PDBAC > DDBAC > DTAC > DTAB > AEUIC. Among the weight loss accelerating agents, AEUIC hardly showed weight loss effect, and it was separated into two layer in the NaOH solution at the treatment concentration above 6g/L, but POBAC showed good weight loss effect of 21% that approach almost to a theoretical weight loss, 21.6%, at the concentration above 8g/L.

Effect of Sodium Chloride on Weight Loss of AA1100 Aluminum Alloy and SGACD Zinc coated Steel Lap Joint

  • Maulidin, Achmad;Kimapong, Kittipong
    • International Journal of Advanced Culture Technology
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    • v.3 no.1
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    • pp.39-45
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    • 2015
  • This research aims to study an effect of sodium chloride solution concentration on the corrosion rate of AA1100 aluminium alloy and SGACD zinc coated steel lap joint with a test duration of 30 days and a test temperature of $45^{\circ}$. The summarized results are as follows. Increase of the NaCl solution concentration increased the weight loss of Al, corrosion rate of Al, weight loss of Fe and also decreased the corrosion rate of Fe. Increase of the test duration affected to increase the weight loss and corrosion rate of Al and also decrease the weight loss and corrosion rate of Fe. The corrosion that was formed in a lap joint consisted of the uniform corrosion on the surface of the metals and the galvanic corrosion in the lap area of the joint. The maximum weight loss of AA 1100 aluminium and SGACD zinc coated steel that was occurred in the sodium chloride with 3.25% was 2.203% and 3.208%, respectively.. The maximum corrosion rate of AA 1100 aluminium and SGACD zinc coated steel that was occurred in 4.00% and 3.5% sodium chloride solution was 0.156 mm/year and 0.479 mm/year, respectively.

Effects of Lime Compounds on the Reduction of Ammonia Gas Formation and Nitrogen Loss During the Formation of Poultry Manure-Sawdust (가축분에 몇가지 석회 화합물 처리에 의한 질소손실 경감과 $NH_3$ 가스 발생 감소에 미치는 영향)

  • 박창규;양장석;조광래;원선이
    • Korean Journal of Organic Agriculture
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    • v.8 no.2
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    • pp.89-96
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    • 2000
  • To reduce loss of nitrogen and generation of ammonia gas during composting, poultry manure and sawdust were mixed at the equivalent ratio and calcium chloride, fused superphosphate and vermiculite were added. Ammonia and sulfurous gas during composting, and NH4-N and NO3-N contents of composts were periodically measured. With the treatments of 0.5∼3% calcium chloride and 3% fused superphosphate, ammonia and sulfurous gas during composting significantly decreased, and especially generation of gases sharply reduced and a increase of calcium chlorde. Extractable NH4-N content in composts treasted with calcium chloride and fused superphosphate were high but extractable NO3-N markedly decreased. In conclusion, the results suggest that it is necessary the additon of 1∼3% calcium chloride or 3% fused superphosphate to reduce loss of nirogen and generation of offensive odor during composting of poultry manure mixed with sawdust.

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Investigation on Electrochemical Characteristics of Battery Housing Material for Electric Vehicles in Solution Simulating an Acid Rain Environment with Chloride Concentrations (산성비 환경을 모사한 수용액에서 염화물 농도에 따른 전기자동차 배터리 하우징용 재료의 전기화학적 특성 연구)

  • Shin, Dong-Ho;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.21 no.2
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    • pp.147-157
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    • 2022
  • Electrochemical characteristics and damage behavior of 6061-T6 aluminum alloy used as a battery housing material for electric vehicles were investigated in solution simulating the acid rain environment with chloride concentrations. Potentiodynamic polarization test was performed to analyze electrochemical characteristics. Damage behavior was analyzed through Tafel analysis, measurement of damage area, weight loss, and surface observation. Results described that corrosion current density was increased rapidly when chloride concentration excceded 600 PPM, and it was increased about 7.7 times in the case of 1000 PPM compared with 0 PPM. Potentiodynamic polarization experiment revealed that corrosion damage area and mass loss of specimen increased with chloride concentrations. When chloride concentration was further increased, the corrosion damage area extended to the entire surface. To determine damage tendency of pitting corrosion according to chloride concentration, the ratio of damage depth to width was calculated. It was found that the damage tendency decreased with chloride concentrations. Thus, 6061-T6 aluminum alloy damage becomes larger in the width direction than in the depth direction when a small amount of chloride is contained in an acid rain environment.

Structural behaviour of concrete beam under electrochemical chloride extraction against a chloride-bearing environment

  • Ki Yong Ann;Jiseok Kim;Woongik Hwang
    • Computers and Concrete
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    • v.34 no.1
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    • pp.49-61
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    • 2024
  • The present study concerns a removal of chloride ions and structural behaviour of concrete beam at electrochemical chloride extraction (ECE). The electrochemical properties included 1000 mA/m2 current density for 2, 4 and 8 weeks. It was found that an increase in the duration of ECE resulted in an increase in the extraction rate of chlorides, in the range of 35-85%, irrespective of chloride contamination. In structural behaviour, the strength and maximum bending moment of specimen was always lowered by ECE. Moreover, the flexural rigidity and bending stiffness were reduced by the loss of effective cross-section area in the linear elastic range. Simultaneously, the inertia moment was substantially subjected to 70% loss of the cross-section by the tensile strain at the condition of the failure. However, a lower rate of the inertia moment reduction was achieved by ECE, implying the higher resistance to the cracking, but the higher risk of deformation.

Studies on the Residual Bending Strength of Burned Wood treated with Fire-retardant Chemicals (내화처리연소목(耐火處理燃燒木)의 잔류(殘留) 휨강도에 관(關)한 연구(硏究))

  • Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.12 no.2
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    • pp.10-19
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    • 1984
  • The $3{\times}3{\times}30$ ($cm^3$) sized lumbers of Populus alba-grandulosa L. were treated with four fire-retardant solutions of ammonium sulfate, monoammonium phosphate, diammonium phosphate and aluminium chloride for 1, 15, 30, and 60 minutes and 1, 3, and 7 days. Thereafter they were air-dried and burned at high temperature about $1,800^{\circ}C$ and for short time of five minutes. This study estimated the relationship between absorbed chemical amounts and rate of weight loss or residual bending strength of these burned lumbers. The results were as follows: 1) In absorption amount of fire-retardant chemicals, diammonium phosphate showed the largest, aluminium chloride the smallest, but monoammonium phosphate and ammonium sulfate showed similar level. 2) The absorption amount of chemicals was decreased with the increase of specific gravity in the same species except aluminium chloride. 3) The rate of weight loss was decreased as the absorption amount of chemicals increased, especially monoammonium phosphate was most effective. 4) The MOR value of the residual bending strength was increased as the absorption amount of chemicals increased and especially monoammonium phosphate showed the most efficient effect. 5) Aluminium chloride showed more striking increase of MOR value of residual bending strength with the increase of absorption amount than any other chemical, therefore its MOR value was similar to the maximum MOR value of the most effective monoammonium phosphate. 6) The correlation between weight loss and MOR value of the residual bending strength was negative and aluminium chloride showed the most striking negative relation, but the others showed similar trends. 7) The correlation between work to proportional limit and absorption amount of chemicals was positive and the degree of increase in work to proportional limit was most in aluminium chloride, and the next, in monoammonium phosphate and diammonium phosphate in turn. 8) The correlation between work to maximum load and absorption amount of chemicals showed positive and diammonium phosphate revealed the best result and aluminium chloride showed better results than other two chemicals.

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Chemical Reactions in Solid State Complexes of 1,2-Polybutadiene and Palladium Chloride : High Temperature Infrared Study

  • Lee, Joon Y.;Laurence A. Belfiore
    • Bulletin of the Korean Chemical Society
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    • v.17 no.9
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    • pp.826-830
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    • 1996
  • Fourier transform infrared (FTIR) temperature studies were performed to examine the microstructural changes that occur in annealing process of the thin films of 1,2-polybutadiene (1,2-PBu)/palladium chloride (PdCl2) complex. The disappearance of the infrared absorption intensities at 1640, 1418, 994 and 910 cm-1 signifies the consumption of 1,2-vinyl groups of 1,2-PBu. The progressive loss of unsaturation and production of methyl groups as a function of temperature were identified by the enhanced infrared absorption intensities at 1447 and 1375 cm-1. The loss of pendent carbon-carbon double bond is considered to involve both palladium-catalyzed addition reaction and thermally induced cyclization.

Corrosion Behavior of Cr-bearing Corrosion Resistant Rebar in Concrete with Chloride Ion Content

  • Tae, Sung Ho
    • Architectural research
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    • v.7 no.1
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    • pp.49-54
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    • 2005
  • Conventional studies have focused on the reduction in the water-cement ratio, the use of various admixtures, etc., to ensure the durability of reinforced concrete structures against such deterioration factors as carbonation and chloride attack. However, improvement in the concrete quality alone is not considered sufficient or realistic for meeting the recent demand for a service life of over 100 years. This study intends to improve the durability of reinforced concrete structures by improvement in the reinforcing steel, which has remained untouched due to cost problems, through subtle adjustment of the steel components to keep the cost low. As a fundamental study on the performance of Cr-bearing rebars in steel reinforced concrete structures exposed to corrosive environments, The test specimens were made by installing 8 types of rebars in concretes with a chloride ion content of 0.3, 0.6, 1.2, 2.4 and $24kg/m^3$. Corrosion accelerated curing were then conducted with them. The corrosion resistance of Cr-bearing rebars was examined by measuring crack widths, half-cell potential, corrosion area and weight loss after 155 cycles of corrosion-accelerating curing. The results of the study showed that the corrosion resistance increased as the Cr content increased regardless of the content of chloride ions, and that the Cr-bearing rebars with a Cr content of 5% and 9% showed high corrosion resistance in concretes with a chloride ion content of 1.2 and $2.4kg/m^3$, respectively.